SULIT 4541/2(PP) 4541/2 (PP) ‘Chemistry Kertas 2 October 2020 MAKTAB RENDAH SAINS MARA. PEPERIKSAAN AKHIR SIJIL PENDIDIKAN MRSM 2020 (CHEMISTRY Kertas 2 Peraturan Pemarkahan Leen Untuk Kegunaan Pemeriksa Sahaja Peraturan Pemarkahan ini mengandungi 19 halaman bercetak {Lihat halaman sebelah 4541/2(PP) 0 tak Cipts Bahagian Pendidikan Menengah MARA SULITSULIT 2 4541/2(PP) MARKING GUIDELINES SPMRSM CHEMISTRY PAPER 2 Symbol Meaning W - replace the whole sentence 1 - replace the previous word a - can be summarized from explanation __orbold - key word adp - avoid double penalty wer = wrong cancel right a - accept r - reject ecf = error carry forward 4541/2 (PP) © Hak Cipta Bahagian Pendidikan Menengah MARA SULIT wea isuSULIT 3 4541/2 (PP) ‘SUB | TOTAL 1 MARK SCHEME MARK | MARK (@) | @ | [Able to state definition for melting point correctly] Answer Temperature at which solid change to liquid fat] 1 1 particular pressure} Gi)_| [Able to state the physical properties of substance R at room temperature] Answer : Gas (iii) |[Able to state the change of kinetic energy and attraction forces between particles of substances Q] Sample answer PI. Kinetic energy decreases 1 P2. Attraction force between particles / molecules} 1 2 becomes stronger (6) | @ [[Able to state a labeled beaker that shows the reaction of potassium with water] Answer: X. 1 1 Gi_| [Able to name gas produced correctly] Answer: Hydrogen 1 1 Gi) [Able to write a balanced chemical equation correctly] Answer: 2Li +2H.0 > 2LiOH +H; // 2Na + 2H;0 > 2Na0H + Hy Pl.Correct formula of reactants & products 1 P2.Balance z () | [Able to infer the density of metal group Lin water] ‘Sample answer, Group 1 metals have lower density than water // Group | metals are less dense than water 1 I Total} 9 ; [Likat halaman sebelah SULIT © 2020 Hak Cipta Bahagian Pendidikan Menengah MARA 4541/2(PP)SULIT 4541/2(PP) MARK SCHEME SUB MARK | TOTAL MARK @ [Able to state all ion present in copper(II) sulphate correctly] Answer: Cation: Cu”, H Anion: S02, OH {a: Name} ®) [Able to state the negative terminal correctly] Answer: Zine (a: Formula] ©) @ [Able to state the observation at zinc metal] Sample answer Zine metal thinner/ smaller /dissolve (i) [Able to write half equation at zinc electrode and copper electrode correctly] Answer: Zinc electrode: Zn. > Zn™* +20 Copper electrode: Cu? +2e > Cu v Gili) [Able to state the observation of copper(II) sulphate solution and reason] ‘Sample answer 1. Blue solution becomes pale blue / paler // Intensity of blue solution decreases [r: Blue solution becomes colourless] P2. Concentration of Cu”* / copper(II) ion decreases. ala [Able to suggest a suitable metal (o replace zinc) Answer: Mg // Al [reject: Metal Group 1, Ca] Total 4541/2 (PP) 0 tisk Cipta Bahsgian Pendidikan Mencogah MARA SULITSULIT 5 4541/2 (PP) Pa SUB [TOTAL 3 MARK SCHEME, MARK | MARK | (@) [Able (0 name solution T] Answer: Zine chloride Ja: formula] 1 1 © [Able to explain to identify and confirmed gas U] ple answer PI. Placed a burning wooden splinter at the mouth / 1 0 the test tube. P2. ‘Pop’ sound produced indicates H2 gas 1 2 (c) |_| [Able to write and balance chemical equation of zinc and hydrochloric acid] Answer: Zn+2HCl — ZnCl + He PI. Correct formulae of reactants and products 1 2. Balance equation 1 2 Gi) | [Able to calculate the maximum volume of gas U at room temperature] ‘Sample answer P1. No. of mol HCI = 1.0 x 20 = 0.002 1 1000 P2. 2 mol HCI: 1 mol H 0.002 mol HCI : 0.001 mol He 1 [a : sentence relationship] 3. Volume of Ha = 0.001x 24 1 3 = 0.024 dm3// 24 cm* @ [Able to explain to separate substance V from the mixture] [reject filtration} 1 P2. Rinse with led water I 2 Total 10 [Lihat halaman sebelah SULIT © 2020 Hat cipta Bahapian Pendiditan Menengah MARA, 4541/2(PP)SULIT 6 4541/2(PP) SUB TOTAL 4 MARK SCHEME MARK | MARK Ta) | [Able to state the condition for rusting correctly] Answer: oxygen and water fa: formula] 1 1 ( ] @ | [Able to state the substance that is oxidised correctly] Answer: Iron [r: formula] 1 1 [Abie to write a half equation correctly} Answer: Fe > Fe" + 2c 1 1 © | @ | [Able to explain the rusting phenomenon of iron gate in coastal area] ‘Sample answer PI. Presence of salt vapours in the air. 1 P2, Increase the concentration of electrolyte in the air 1 2 [Able to suggest one way to prevent the rusting of iron Gi) | gate in coastal area] Sample answer Paint / grease / galvanizing the iron gate 1 1 @ | @ | [Able to suggest metal X] Answer: Copper 1 1 Gi | [Able to explain the differences in the observations] Sample answer P1. In Set I, no reaction while in Set I, reaction occur // I Copper! Cu is formed. P2, Carbon is less reactive than aluminium/AI but more 1 2 reactive than X Notes: PI. Inference P2. Reason (ii | [Able to arrange elements in ascending order of reactivity correctly] Answer: X/Cu, Carbon, Aluminum 1 1 Total 10 4541/2 (PP) 0 Hak Cipta Bahagian Peodiditan Mencogah MARA, SULITSULIT 4541/2 (PP) MARK SCHEME SUB_ [TOTAL MARK | MARK @ @ [Able to give definition of rate of reaction correctly] Sample answer CChange/Increase in volume of H2 gas per unit time 1/ decrease in mass of magnesium powder per unit time (b) @ [Able to calculate the average rate of reaction with correct unit] Answer: Experiment l= 0.4 30 = 0.0133 gst Gi) [Able to calculate the average rate of reaction correctly with unit] Answer: Experiment I= 0.4 12 = 0.0333 gs 1 1 (iii) [[Able to sketch and labeled energy profile diagram correctly] Answer: Experiment 1 on [Correct shape of graph & Label] ' 1 [Lihat halaman sebelah ‘SULIT © 2020 Hak Cipa Bahapian Pendidikan Meneogah MARA 454U2(PP)SULIT 4S41/2(PP) © [Able to compare and explain the rate of reaction based on collision theory between Set I and Set IT] Sample answer PI. Rate of reaction in Set Il is higher than Set I. P2. Copper) sulphate solution provide an alternative route/ path with a lower activation energy. P3, More colliding particles able to achieve the lower activation energy. P4. The frequency of effective collisions between hydrogen ions and magnesium atom higher. @ [Able to choose and explain which foods will last longer] Answer: LA 2. Lower temperature 3. The bacteria/microorganism is less reactive 1/ The bacteria produced less toxin 1/ Rate of food decay is lower Total iv 4541/2 (PP) © Hak Cipta Bahagian Pendidikan Menengah MARA SULITSULIT 9 4541/2 (PP) SUB_ | TOTAL 6 MARK SCHEME Renee ne @ [Abie to name the enzyme in Process 1] Answer: Zymase 1 1 o [Able to draw the correct structural formula of compound X] Answer: n | H-C-C-H 1 H mz-o-n-= ©} @ [Able to draw a labeled diagram in Pocess II correctly] Answer: 1. Functional diagram P2. Label Gi) [Able to suggest a chemical test to identify compound Y) ‘Sample answer PI, Flow/channel compound ¥ / ethene into a test tube containing bromine water / Acidified potassium manganate( VII) solution P2. Brown [bromine water] decolourises / changes to colourless / purple (acidified potassium manganate(VII)] decolourises / change to colourless [Lihat halaman sebelah 4541/2(PP) SULIT © 2020 Hat Cipta Batagian Pendidikan Menengah MARA,SULIT 10 4541/2(PP) @ [Able to write a balance chemical equation] Answer: CsHsOH +302 >2CO, +3H20 PI. Correct formula of reactants and products P2. Balanced the chemical equation | @ [Able to state the functional group of compound Z] Answer: Carboxyl group /-COOH @ [Able to name the oxidizing reagent] Answer: Acidified potassium manganate(VI1) solution “ Acidified potassium dichromate(VI) solution o [Able to write molecular formula of compound produce correctly] Answer: CHsCOOC3Hs // CuHs02 Total rt 4541/2 (PP) © tisk Cipa Bahapan Pendititan Mescngah MARA SULITSULIT " 4541/2 (PP) MARK SCHEME SUB TOTAL, MARK | MARKS. @]@ [Abie fo state the polymer and write the chemical equation for the polymerisation of chloroethene] Answer: PI: Polyvinyl chloride // polychloroethene /-f CalsCH-// P2: nGHsCl > ~fC2HsCl fe fa:using structural formula] Gi TAble to explain how the usage of synthetic polymer substances can cause environmental pollution] ‘Sample answer 1: Synthetic polymer [PVC/ polystyrene/ nylon/ Kevlar/etc] P2: Not biodegradable P3: Blockage drainage systeny flash flood OR Pl: Combustion/burning of polymer will released poisonous/toxic gas (CO / SO2/ Cla/ HCI] P2: Gas dissolved in rainwater to produce acid rain 3: Increasing the acidity/ Lower pH of soil/lake/tiver/corrode metal/carbonate structure / fertility of soil decreases. OR PI: Combustion/burning of polymer, will released CO2 gas P2: Greenhouse effect P3: Global warming. (b) [Able to explain why alloy rim harder than iron rim] ‘Sample answer PI. Alloy rim is harder than iron rim P2. In iron rim, Fe atom are of the same size P3. The presence of carbon atoms of different size, P4, disrupts the orderly arrangement [lattice arrangement] of iron atoms. 5: Layers of atoms cannot slide easily Anardly/ difficult slide. [Lihat halaman sebelah SULIT © 2020 Hak Cipta Bahagian Pendidikan Menengah MARA 4541/2(PP)SULIT 2 A541/2(PP) TAble to state the quantitative information from the equation correctly and calculate the volume of oxygen gas evolved] © PI: 2 mol of Cu(NOs)2 produced 2 mol of CuO 4 mol of NOx | I and I mol of O2 P2: Number of mol of Cu = _3.2_ = 0.04 mol 1 (4416) P3: 2 mol of CuO release 1 mol of Oz 1 0.04 mol of CuO release 0.02 mol of Oz .02 (24) 1 4 48 dm3 fr: no unit} P4: Volume of Oz (| @_| (Able to write a chemical equation correctly] Answer: 2Mg +02 > 2MgO PI. Correct formula of reactants and products 1 2. Balance equation 1 2 (i) | [Able to explain the differences in the method used] Sample answer PJ. Magnesium is a reactive metal P2. Magnesium easily reacts/oxidised with oxygen to form 1 magnesium oxide 3. Copper is less reactive than hydrogen (vice versa) 1 P4, Hydrogen can reduce copper(II) oxide / CuO to copper 1 4 Total} 20 4541/2 (PP) © Hak Cipts Bahagian Pendidikan Menengah MARA, SULITSULIT 13 4541/2 (PP) MARKING SCHEME. TOTAL MARK | MARKS @ TAble to suggest one substance correctly and give (wo reasons for the suggestion] Sample answer PI.Vinegar//ethanoic acid// acetic acid // Lemon juice (citric acid) // {weak acid] P2. Acid/ H* can neutralize the alkali P3: Less corrosive // does not produce too much heat // does not harm skin w/a [Able to suggest acid X and acid ¥ correctly] Answer: sulphuric acid / H2SOs Nitric acid/HNOs // Hydrochloric acid /HCI Gi) [Able to write a balanced chemical equation correctly] Answer: 2KOH + H2SOs -> K2SOs+ 2H20 P1. Correct formulae of reactants and products 2. Balanced equation 0) [Able to describe one chemical test to verify acid or alkali and write ionic equation for neutralization correctly] ‘Sample answer PI. Pour (2-5] cm? of each solution in two different test tubes 2. Add {a piece] of metal/Mg / AV Zn [powder] // metal carbonate powder // CaCOs into each test tube. P3. If gas bubbles are released, an acid is present P4, If no change, alkali is present. OR P1. Pour [2-5] cm’ of each solution in two different test tubes P2. Add 2. cm’ of ammonium chloride solution [or any ammonium salt solution] into the test tube. 3, Heat the mixture. P4. The gas tums damp red litmus to blue and alkali is present. {Lihat halaman sebelah SULIT © 2020 a Cipta Bshagian Peniikan Menengah MARA, 4541/2(PP)SULIT 4 AS412(PP) ®]@ | [Able to state the temperature of X and ¥ correctly] Answer: 1 1 [Able to calculate the heat of neutralization correctly} Answer: P1. Number of mole HCI /NaOH = 50 X 2.0/1000 i =0.1 mol P2. Heat released = (50 + 50) x 4.2 x [43.0 - (29.0 428.0)] 1 2 = 60905 P3.0.1 mol H20 -> 6090 J heat 1 1 mot H20 > “24 = 60, 900 3 P4, AH = - 60.9 kJ molt 1 6 Gi | {Able to predict and explain the change in heat of neutralization] Sample answer PI. Lower. i 2, Ethanoic acid is a weak acid / dissociate partially in water to form H’ ion. ' P3. Some of the heat released is absorbed to ionise acid 2 molecule completely. Total] 20 4541/2 (PP) 0 Ha CiptsBahagian Pendidikan Menengsh MARA SULITSULIT 15 4541/2 (PP) MARK SCHEME @ToO TAble to explain the formation of compound] Sample answer 1. Electron arrangement of sodium atom is 2.8.1 and chlorine atom is 2.8.7 To achieve [stable] octet electron arrangement. ‘Sodium atom will donate | electron to form sodium ion/Na* Chlorine atom will receive | electron to form chloride ior Strong electrosta forming ionic bond. eR force of attraction between Na’ and CI [any combination of Group I and Group 17 element] max 4 oa [Able to suggest metal ¥ correctly] Answer: Mg/Zn/Al Ir: Group I element / Ca} wo [Able to determine and explain redox reaction] ‘Sample answer PI. Reaction Fis a redox reaction. P2. Oxidation number of Y increase from 0 to +2 3. Oxidation number of Cu decrease from +2 10 0 P4. Reaction I is not a redox reaction. PS. No change oxidation number for all elements // [shows oxidation number for each element] ) TAble to describe an experiment to investigate the reactivity of metals toward oxygen} ‘Sample answer Procedure: PI. One spatula of potassium manganate(VID powder is placed in a boiling tube. P2. The boiling tube is clamped horizontally to a retort stand. 3. Glass woo! is placed in the boiling tube. P4, One spatula of magnesium powder is placed on a piece of asbestos paper and put into the boiling tube. PS. The magnesium powder is heated strongly 6, Potassium manganate (VII) powder is heated. 7. Observation is recorded, P8. Steps 1 ~ 7 are repeated using iron and copper. [Lihat halaman sebelah 4541/2(PP) SULIT © 2020 Hak Cipts Bahagian Pendidikan Menengah MARA4541/2(PP) SULIT 16 Observation = Metal Observation Magnesium | Burns vigorously with bright’ white 1 flame Tron Glows brightly. 1 ‘Copper Glows dimly 1 max 10 Total| 20 SUI TOTAL [ 10 MARK SCHEME ee oe @ [Able to identify type of rubber A and B and explain the differences in properties] PI. Rubber A : Vulcanised rubber ‘i 2, Rubber B : Unvulcanised rubber Elasticity P3. There are sulphur cross-linkages /links between [polymer] | molecules in vulcanised rubber 4. When force is applied, sulphur cross-link / linkage will pull 1 the rubber molecules back to its initial position. Heat resistance PS. The presence of sulphur in vulcanized rubber increases the 1 size of rubber molecules/ molecular mass P6. Difficult to melt //More heat needed. u 6 ©] @ | [Able to suggest compound P and Q] Sample answer P1. Compound P : methanol/ethanol/propanol 1 > P2. Compound Q : methanoic acid/ethanoic acid/propanoic acid : 2 (ii) | [Able to state the general formula and functional group of compound P and Q] General Formula Functional group PL[ P| CoH OH; n= 1,2,3... Hydroxyl-OH_ 1 P2. | Q | CaH2iCOOH; n= 0,1,2 CarboxyV/ 1 2 -COOH a SULIT AS41/2 (PP) 0 tisk Cipta Bahazin Pendidian Menengah MARA ————eeanncuwrar veSULIT 17 4541/2 (PP) ti [Able to describe an experiment to prepare compound Z] PI. Material: - Pure methanol/absolute ethanol/propanol, pure methanoic acid/glacial ethanoic acid/pure propanoic acid, concentrated sulphuric acid Procedure: P2. Pour [3-6]cm’ pure ethanol into a boiling tube P3. Add [3-6] cm’ of pure ethanoic acid. 4, Add [a few drops] of concentrated sulphuric acid. PS. Heat/Warm the mixture carefully/over a small flame for a few minutes P6. Pour the product formed into a beaker containing water. P7. Observation: Fruity/Pleasant/Fragrance smell substance produced // A layer formed on the surface of water OR Procedure: P2. Pour [20- 100]cm’ pure ethanol into a round bottom flask P3. Add [20- 100]cm’ of pure ethanoic acid. 4. Add [4 cm’ Jof concentrated sulphuric acid. P5. Reflux the mixture. P6. Pour the product formed into a beaker containing water. P7. Observation: Fruity/Pleasant/Fragrance smell substance produced // A layer formed on the surface of water CH3COOH + C:HsOH + > CHsCOOCHs + 20 P8. Correct formula of reactants P9. Correct formula of products P10. Ethyl ethanoate/depend to the students’ answer] Total} 20 SULIT © 2020 Hak Cipta Bahagian Pendidikan Mencagah MARA [Lihat halaman sebelah 4541/2(PP)SULIT 18 4841/2(PP) ‘TEST SPECIFICATION TABLE SLJIL PENDIDIKAN MRSM CHEMISTRY PAPER 2, 2020 Construct of Elements Evaluated Section | Question Number(Topic) cKO. csor cso cs03 cso Knowledge | Conpretemion | Application | Analysis | Synthesis 4 5 a Ta (lim) STRUCTURE OF ATOM | !@(i){tm] Tb¢{tm] PERIODIC TABLE | POU! | Gvitim) 3 7 @ 2et{Im] ELECTROCHEMISTRY | 2s(2m) | 2ctii)[2m} Zbl Im (2m) [2m 1 5 Qa a ear 2a(Gi)(3m] | 3e)12m) 3a{tm] | 3ef2m} | 3eci){3m) 2 7 1 TaD] a 4a{im] | 4{3m} Cees 4bcifim) | 44ci{tm] | saci) S 4dGii)[2m] 1 5 2 2 Qs ; Secioriey | ecoLim) RATE OF REACTION ‘Sa(i)[1m] ‘Se[3m} ‘SbGi)[1m] ‘Sd[2m} 1 3 4 2 Q ; ‘CARBON COMPOUND 6afim) | 6bfimy | 6ecinf2my | SCL 6e(i)[2m) 6d {2m} cata Q7 6 4 MANUFACTURED Tel) SUBSTANCE & 3 iD i B | yg SUBSTARCES Spat | 740121 | 74Gint sem AND EQUATION Q8 s 4 8 4541/2 (PP) © Hak Cipta Bahagian Pendidikan Menengab MARA SULIT* suutr 19 4541/2 (PP) ‘ACID BASES anal ‘THERMOCHEMISTRY coe : ifm Betaml | satsm | sacitsm) Construct of Elements Evaluated Section | Question NumbertTopic) | cxor | cso | csm ] cso | csos Knowledge | Comprehension | Application | Analysis | Synthesis 4 6 10 ICAL-BOND CHEMICAL BO! 9(){ 1m] REDOX Saltm) | gpcintsmy | lm) : 10 10 uo 10a{6m] CARBON COMPOUND on END OF MARKING SCHEME [Lihat halaman sebetan ‘SULIT © 2070 Cis tahaian Pendidikan Meoengah MARA 4541/2(PP)