The Revamping of

Fosfertil Cubatao Ammonia Plant,

A Successful Experience
In August 2001 Fosfertil started up its ammonia plant in Cubatão, Brazil,
after revamping it in order to save energy and increase its capacity.
Fosfertil and Ammonia Casale successfully performed this project together.
This revamping is also the first industrial application of an axial-radial adiabatic pre-reformer.
This paper describes the revamping project, the technologies used and the results achieved.

S. A. De Oliveira Guirado
FOSFERTIL, Cubatao, Brazil

E. Filippi, M. Badano
AMMONIA CASALE S.A., Lugano, Switzerland

Introduction Ammonia, Urea, Nitric Acid, Ammonium Nitrate, Sul-

phuric Acid, Phosphoric Acid, low and high concen-

F OSFERTIL S/A, a private Brazilian com-

pany, is a Fosfertil subsidiary and con-
trolled by the holding Fertifos administra-
tion and participations Inc. and has a large
share in the national market of fertilizers, controlling
trate Phosphate fertilizer, Methanol and Phosphate
rock.

Strategically located in the state of São Paulo, the

Piaçaguera Ammonia Plant, which is the subject of this
37% of the phosphate segment and 35% of nitrogenous paper, was built in 1970 by Foster Wheeler, and de-
segment in the Midwest and Southeast region of Bra- signed for naphtha as feedstock for both process and
zil. fuel. Due to the high cost of naphtha, the unavailability
of Natural Gas and to the vicinity of a refinery, in 1981
Fosfertil has four industrial sites in the states of Fosfertil started to use the off-gas from the refinery as
São Paulo (Cubatão and Piaçaguera), Minas Gerais fuel and in 1984 as feed.
(Uberaba) and Paraná (Araucária), three mining com-
plexes Minas Gerais (Tapira and Patos de Minas) and The problem with this feedstock is its continuous
Goiás (Catalão), and a Maritime Terminal located in change in composition, which obliged the plant to
São Paulo (Cardoso Island). maintain a higher than normal steam carbon ratio in
order to guarantee a safe run to the primary reformer,
Operating in the chemical segment, fertilizer mar- but this has consequently caused a high consumption
kets and logistic services areas, Fosfertil produces of energy.

2004 33 AMMONIA TECHNICAL MANUAL

The ammonia synthesis converter presented another • Revamping of syngas compressor
problem, since it consisted of three separate vessels. • Revamping of feed gas compressor
After 31 years of operation it had to be replaced due to • Replacement of some heat exchangers
mechanical reasons. • Installation of an additional Boiler Feed Water
Pre-heater
FOSFERTIL decided to ask Ammonia Casale for a
proposal to revamp the ammonia plant. The goal of In the following paragraphs only the 600 MTD
this proposal, as a first step, was to increase the capac- (544 STD) case will be illustrated in detail.
ity from 520 MTD (472 STD) to 600 MTD (544 STD),
which was successfully implemented and is the subject
of this paper. AMMONIA CASALE S.A. was also Technologies Used
requested to recommend a second project for further
increase capacity to 800 MTD (726 STD).

AMMONIA CASALE S.A. of Switzerland is an inde-

Pre-Reforming Reactor Technology
pendent engineering company that has been operating The first step to be taken in order to be able to re-
worldwide for more than 80 years in the field of am- duce the steam to carbon ratio, with consequent reduc-
monia and methanol plants. tion of energy consumption and potential for capacity
increase in the primary reformer, is to eliminate the
AMMONIA CASALE had already performed re- fluctuation of composition in the refinery off-gas.
vamping jobs for Fosfertil in its plant in Araucaria,
where in 1995 it had successfully revamped the am- As it is not possible to improve the feed gas qual-
monia converter internals and in 2000 the high ity from the refinery, the pre-reforming of this gas be-
temperature shift converter. comes the best solution.

Revamping Strategy In fact the off-gas contains mainly hydrogen,

methane, and higher saturated and unsaturated
AMMONIA CASALE developed a plan to reach the hydrocarbons.
specified goals, after a careful plant survey, which in-
volved the following steps: The refinery off-gas is a mixture between off-
gases from three Petrobras Units - Fluid Catalytic
a) To reach 600 MTD (544 STD) Cracking (FCC), Delayed Coking Unit and Catalytic
Reforming Unit - and it is the feed gas used to produce
• Installation of a pre-reformer reactor ammonia at Cubataõ.
• Modifications to the primary reformer convec-
tion section The refinery off-gas is treated before feeding the
• Replacement of the primary reformer burners ammonia process at the Refinery Off-Gas Treatment
Unit (RogTu). This treatment consists of saturation of
• Reduction of the steam to carbon ratio from
the Olefins into Paraffin by catalytic hydrogenation in
3,9 to 3,5.
a NiMo/CoMo reactor and removal of sulphur com-
• Replacement of the ammonia converter ves-
pounds by catalytic absorption in a ZnO bed.
sels with new ones, still in three separate
units, but with cold gas flushing, and axial-
Olefins may cause fast coke deposition on the
radial internals
Primary Reformer catalyst; sulphur compounds are
poisonous to this catalyst and to the other catalysts of
b) To reach 800 MTD (main items only)
the ammonia plant. High level of olefins can cause an
over temperature at the NiMo/CoMo bed, and a recy-
• Revamping of the air compressor
cle of gas to control this rise of temperature is neces-
• Revamping of CO shift internals to axial- sary.
radial ones
• Revamping of the CO2 removal section

AMMONIA TECHNICAL MANUAL 34 2004

 The figure below represents the schematic flow of The small-size catalyst has two advantages in com-
The Refinery Gas Treatment Unit (RogTu) and the parison with the large-size one:
next table (Table 1) represents the inlet and the outlet • higher sulphur pick-up, resulting in a
RogTu streams analysis. longer life, since sulphur is the main poi-
son;
• greater activity.

This means that, with respect to the larger size

catalyst, it is possible to reduce the catalyst volume to
achieve the same life or to attain a longer life with the
same volume.

Regarding the operation of an axial-radial pre-

reformer, it is to be noted that the temperature profile
in the catalyst bed can be measured and followed
Figure 1: Refinery Off-Gas Treatment RogTu thanks to the presence of thermocouples in different
Table Unit Gas flow Schematic positions along the radial direction in the bed.
Compound RogTu inlet (%) RogTu outlet (%)
H2 22,65 13,84
Also catalyst loading and unloading is easy, as the
N2 3,79 4,49 axial-radial bed is completely open on the top, grant-
CH4 45,44 53,89 ing an easy access to the bed even for small diameter
CO2 0,11 0,13 vessels, while for unloading there are drop out pipes
Ethane 12,92 24,68
Ethene 7,89 provided at the bottom.
Propane 2,91 1,28
Propene 2,44 Thanks to the pre-reformer installation, it is, there-
Iso-Butane 0,43 0,70
N-Butane 0,65 0,71
fore, possible to operate the primary reformer
Butene 0,54 smoothly, with stable operating conditions and to re-
C5+ 0,23 0,27 duce the steam carbon ratio to the primary reformer, as
H2S-PPM 78 < 0,1 the only feed gas is methane plus steam, CO, CO2 and
hydrogen. It is also possible to use the natural gas type
Table 1: Comparison between inlet and outlet catalyst that is more active, and to increase the reform-
from the Refinery Off-Gas Treatment Unit RogTu ing capacity.

The pre-reforming reactors convert the hydrocar-

bon impurities in this gas to hydrogen, methane, CO
and CO2 only, enabling to maintain the operation of
the primary reforming stable, and therefore making it
possible to reduce the S/C ratio down from 3,9 to 3,5.

The pre-reforming reactor installed by

AMMONIA CASALE is designed according to the
well-known axial-radial technology for catalyst beds.

The advantages of using this technology for pre-

reforming reactors are:
• the low pressure drop achievable
• the use of small-size catalyst This picture shows the new installed pre-reformer
The low-pressure drop is an important energy sav-
ing feature and helps the compressors reach higher ca-
pacities.

2004 35 AMMONIA TECHNICAL MANUAL

 These new burners are John Zink ones. There are
120 burners and 10 auxiliary burners. Burners are GO-
SFG-M type, the maximum heat released to these
burners is 0,95 MMkcal/h and the maximum capacity
pressure is 0,8 bar. Auxiliary burners are PVYD-12-
RM, the maximum heat released is 0,625 MMkcal/h
and the maximum capacity pressure is 1,5 bar

The Axial-Radial Pre-Reformer

Primary Reformer Modification

The existing primary reformer was a Foster
Wheeler design, terrace wall type, with 120 catalytic
tubes, 60 in each cell. The convection section has
process steam, process air, high pressure steam (100
This picture shows the Primary Reformer
bar) super heater and boiler feed water coils. Here the
and the Secondary Reformer
following areas of intervention were applied:
3. Catalytic tubes
1. Modification of the convection section for
reliability improvement The tubes that were operating before the revamp,
were Villares “LRE9” with 140mm of external diame-
The convection section modification consisted in
ter an 16 mm thickness and a lifetime of 65.000 oper-
the replacement of the process steam heater coil due to
ating hours. Manaurite “XM”, from Manoir, replaced
its age and limitation in design temperatures.
those tubes with 141,5 mm of external diameter and
9,5 mm thickness, which have an expected lifetime of
2. Burners replacement 100.000 hrs. Before the revamp, the wall temperature
The burners were replaced due to the poor per- was 950 ºC (Average) and after revamp, reduced down
formance with the off-gas of the old one and naphtha to 880 ºC.
as fuel was no longer used.

The new burners can run with natural gas, or a

mixture of natural gas and off-gas, in case this fuel be-
comes available to the plant in the future.

AMMONIA TECHNICAL MANUAL 36 2004

 This drawing shows the coils that were
substituted on the revamp

Ammonia Synthesis Converter

Foster Wheeler designed the ammonia synthesis
converter according to a Pritchard scheme. The Con-
verter has three adiabatic beds, each one contained in a
separate vessel, with indirect cooling between them, by This photograph shows the three new
HP steam generation and feed gas preheating. converters and the HP waste heat boilers

All the reactor vessels, the connecting nozzles and

piping, and the heat exchangers and boilers were re-
fractory lined.

The pressure vessels are a multi layer design, hav-

ing 11 (eleven) layers. In 1993 the pressure vessels
were repaired because of some cracking between the
shell and the bottle part. These vessels were at the end
of their useable life guaranteed by the repair executors.

The AMMONIA CASALE design proposed main-

taining the existing configuration, in order to re-use
the intermediate exchangers and boilers that were still
in good condition, and replace the old reactor vessels
with new ones flushed with cool feed synthesis gas, in
order to avoid problems of hydrogen attack and nitrad-
ing. This solution was preferred to the replacement of
the three reactors with a new one, since the modifica-
tion to the external equipment has been to be much
more expensive.

The new vessel would have, of course, the axial-

radial internals, achieving in this way a considerable Loop schematic before revamp
increase in the performance of the converter, allowing
for the capacity increase in all the rest of the synloop.

2004 37 AMMONIA TECHNICAL MANUAL

 Original Ammonia Converter

New Axial-Radial Ammonia Converter

The Goal of Fosfertil in this Project

Fosfertil studied several alternatives such as ac-
quiring a new high capacity ammonia plant or buying
a used ammonia plant, or revamping its existing one.

The high price of the raw material for the new

Loop schematic after revamp plant and the high cost of dismantling, transporting
and assembling the used plant made both of these op-
The main advantages achieved after revamping are: tions unfeasible, revamp was the best option that fitted
with Fosfertil objective.
• Pressure drop decrease
• Conversion per pass increase
• Heat recovery increase
• Reliability increase

AMMONIA TECHNICAL MANUAL 38 2004

The objectives were: model of the burners supporting structure to
simulate this installation.
• To guarantee the operational continuity of the • The shut down was concluded on time as the
ammonia plant by changing the synthesis re- revamping time schedule predicted. The
actors that had been repaired in the past due downtime period took over 45 days to change
mechanical problems and the maintenance the converters.
warranty period of which had almost expired; The catalytic pre-commissioning and reduc-
• To take advantage of this event to look for the tion were concluded on time as the time
plant modernization, mainly synthesis loop; schedule predicted, although some difficulties
• Reduction of the energy consumption of the appeared, like the problem experienced to
ammonia plant; keep the circulation gas under the specifica-
• Increase to the maximum possible capacity tion of CO+CO2 (100 ppm) to the pre-
with the smallest investment in the first step reformer catalyst.
and for 800 ton/d (726 STD) in the future;
• Reduction of the amount of ammonia im-
ported to supply the Fosfertil Group and the
internal market.

Among all of the consulting technology companies

with knowledge in ammonia plant revamping, Ammo-
nia Casale offered Fosfertil the most attractive eco-
nomical alternatives.

The scope of the work was:

• Study by Ammonia Casale and Fosfertil to

develop the improvements to be implemented
to get the best return on investment; This photograph shows the Assembly of the New
• Basic engineering by Ammonia Casale; Converter
• Design of synthesis and pre reformer reactor
vessel by Ammonia Casale; Plant Performances After Revamp
• Detailed engineering by Engevix Engenharia
S/C Ltda/Inepar (Consortium), Brazil; Operating condition of the Pre-Reformer
• Synthesis and pre reformer reactor vessels
fabricated by Confab Industrial S/A; Compound
Pre Reformer Pre Reformer
• inlet (%) outlet (%)

• Synthesis and pre reformer internals by Am- H2 13,84 17,38

monia Casale Design and VRV manufactur- N2 4,49 2,68
ing; CH4 53,89 73,26
• Internal’s assembly by Confab Industrial S/A CO2 0,13 6,68
under Ammonia Casale supervision; Ethane 24,68
• Field assembly by Alston Industries S/A under Ethene
Ammonia Casale supervision. Propane 1,28
• To reduce the shut down time, Fosfertil de- Propene
cided to take out the old vessels without tak- Iso-Butane 0,70
ing out the catalyst (inert with nitrogen). Fos- N-Butane 0,71
fertil required an engineering study for the
Butene
installation of the new burners to the original
C5 + 0,27
Foster Wheeler design, which used a real
H2S-PPM < 0,1
Pre-Reformer Inlet and Outlet Streams

2004 39 AMMONIA TECHNICAL MANUAL

Primary Reformer after Pre- Reformer Conclusions
installation
From the above explanation regarding the revamp-
• Reduction of 20ºC (36°F) at the outlet tem- ing of Fosfertil’s ammonia plant, we can conclude that:
perature of the catalytic tubes;
• Reduction of Steam/Carbon ratio from 3,9 to
3,5; Pre Reformer installation was a good solution
• Reduction of outside wall temperature from to:
950°C (1742 °F) to 880 °C (1616 °F) of the
catalytic tubes that lengthens their durability; • Stabilize the Feed Gas composition of the Pri-
• Reduction of DP on catalytic side of the tubes mary Reformer
of about 1 bar (14,5 psi); • Reduce the Steam/Carbon ratio from 3,9 to
• Use of standard NG catalyst for the Primary 3,5
Reformer; • Increase the capacity by about 15%
• Stable operation thanks to the stabilization of • Increase life of catalytic tubes
the Primary Reformer feed. • Reduce the maintenance costs
• Synthesis Loop • Reduce the final cost of production
• Reduction of DP on converter of about 3 bar
(43.5 psi); Synthesis Loop revamp was an excellent way
• Use more efficient catalyst with f 1,5 - 3,0 to:
mm (0,06 " ~ 0.12 "); “
• Reduction of the operation pressure from 165 • Reduce the operation pressure by about 20 bar
(2393 psig) bar to 145 bar (2103 psig); (290 psi)
• Increasing the conversion from 10% to 14% in • Reduce the DP by 3,0 bar (43,5 psi) with the
NH3 at converter outlet flow. installation of Axial-Radial internals
• Increase the conversion efficiency and per-
formance of the converters
Final Results* • Increase the capacity at the rest of the Synthe-
sis Loop
After more then two years of operation it is now
possible to list the benefits achieved over a long period Finally we conclude that the Fosfertil Ammonia
of time. Plant Revamp by Ammonia Casale was a complete
success.
These benefits are:
• Average Production : 614 MTD (557 STD)
• Maximum Production : 634 MTD (575 STD)
• Reduction on Imported Steam: 12 %
• Reduction on gas Consumption: 11,59%
• Reduction on Energy Consumption: 10,55%

* Comparative with reference to the year 2000

AMMONIA TECHNICAL MANUAL 40 2004