Material Safety Data Sheet

and Safe Handling and Disposal Information

ENFORCER Products Section 1. Chemical Product and Company Identification
A Division of Acuity Specialty Products Product name Citrus Cleaner & Degreaser Concentrate
Group, Inc.
P.O. Box 1060 Product Code HDCIT32/128
Cartersville, GA 30120
1-888-805-HELP
Date of issue 01/21/05 Supersedes 12/10/03
www.zepcommercial.com

Emergency For MSDS Information:

Telephone Compliance Services (404) 352-1680
Numbers
For a Medical Emergency:
INFOTRAC
(877) 541-2016 (Toll Free - Calls Recorded)

For a Transporation Emergency:

CHEMTREC
(800) 424-9300 (Toll Free - Calls Recorded)

Printing Date: Prepared by Compliance Services Group

Acuity Specialty Products Group
1420 Seaboard Industrial Blvd.
Atlanta, GA 30318
Section 2. Composition, Information on Ingredients
Name of Hazardous Ingredients CAS # % by Weight Exposure Limits
D-LIMONENE - orange distillate; citrus terpene; 5989-27-5 1-5 Not established
cyclohexene, 1-methyl-4-(1-methylethenyl)-, (R)-
MONOETHANOLAMINE; 2-aminoethanol; MEA 141-43-5 1-5 OSHA PEL / ACGIH TLV
(United States).
TWA: 3 ppm 8 hour(s).
OSHA /ACGIH (United States).
STEL: 6 ppm 15 minute(s).
DIETHYLENE GLYCOL MONOBUTYL ETHER; 112-34-5 1-5 Manufacturer (United States).
2-(2-butoxyethoxy)-ethanol; butyl carbitol TWA: 35 ppm 8 hour(s).
DIPROPYLENE GLYCOL N-BUTYL ETHER; 1-(2- 29911-28-2 1-5 Not established
butoxy-1-methoxy)- 2-propanol; glycol ether dpnb
Section 3. Hazards Identification HMIS
Acute Effects Routes of Entry Dermal contact. Eye contact. Health 1
Skin Hazardous in case of skin contact (irritant, permeator). Product may be dermal absorbed. May Fire Hazard 2
cause skin sensitization. Direct contact may cause irritation and redness. Skin inflammation is Reactivity 0
characterized by itching, scaling, or reddening.
Eyes Hazardous in case of eye contact (irritant). Inflammation of the eye is characterized by redness,
watering, and itching. Personal B
Inhalation Hazardous in case of inhalation. Avoid breathing vapors or spray mists. Over-exposure by Protection
inhalation may cause respiratory irritation.
Ingestion May be harmful if swallowed. Can cause gastrointestinal disturbances.
Carcinogenic Ingredients: Not listed as carcinogen by OSHA, NTP or IARC.
Effects
Chronic Effects Prolonged or repeated contact may dry skin and cause irritation. The substance may be
toxic to blood, kidneys, lungs, liver, gastrointestinal tract, central nervous system
(CNS). Repeated or prolonged exposure to the substance can produce target organs
damage.
See Toxicological Information (section 11)

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 Product Code HDCIT32/128 Material Safety Data Sheet Product Name C i t r u s C l e a n e r & D e g r e a s e r
Concentrate

Section 4. First Aid Measures

Eye Contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes. Get medical attention.
Skin Contact In case of contact, immediately flush skin with plenty of water. Get medical attention if irritation develops.
Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get medical attention.
Ingestion Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to
an unconscious person. Get medical attention immediately.
Section 5. Fire Fighting Measures
Flash Point Closed cup: 51.111°C (124°F). Flammable Limits Not determined. 2
(Tagliabue.) 1 0
Flammability Combustible.
Fire Hazard Combustible liquid and vapor. Avoid all possible sources of ignition (spark or flame).
Fire-Fighting Procedures Use DRY chemicals, CO2, water spray or foam. Fire-fighters should wear
proper protective equipment.
Section 6. Accidental Release Measures
Spill Clean up Eliminate all ignition sources. Dilute with water and mop up, or absorb with an inert dry material and place in
an appropriate waste disposal container.
Section 7. Handling and Storage
Handling Keep away from heat, sparks and flame. Avoid contact with eyes. Avoid prolonged or repeated contact with skin.
Avoid breathing vapors or spray mists. Use only with adequate ventilation. Do not ingest. Do not reuse product
container. Observe label precautions. Wash thoroughly after handling.
Storage Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Avoid
all possible sources of ignition (spark or flame). Store between 40°F - 120°F (4.4°C - 49°C). Keep out of the reach
of children.
Section 8. Exposure Controls, Personal Protection
Personal Protection Protective Clothing (Pictograms)
Eyes Safety glasses.
Body Gloves. Recommended: Nitrile gloves. Rubber gloves. Neoprene
gloves.
Respiratory Use with adequate ventilation. A respirator is not needed under normal and intended conditions of product use.
Section 9. Physical and Chemical Properties
Physical State Liquid. Color Amber.
pH 11.0-12.0 Odor Citrus
Boiling Point Not determined. Vapor Pressure Not determined.
Specific Gravity 1.01 (Water = 1) Vapor Density Not determined.
Evaporation Rate 1 compared to water
Solubility Soluble in cold water, hot water.
VOC (Consumer) 40.33 (g/l). 0.34 lbs/gal 4.00%
Section 10. Stability and Reactivity
Stability and Reactivity The product is stable.
Incompatibility Slightly reactive to reactive with oxidizing agents, alkalis. Keep away from heat, sparks and flame.
Hazardous Polymerization Will not occur.
Hazardous Decomposition These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...).
Products
Section 11. Toxicological Information
Toxicity to Animals d-Limonene:
ORAL (LD50): Acute: >5000 mg/kg [Rat].
DERMAL (LD50): Acute: >5000 mg/kg [Rabbit].
Monoethanolamine:
ORAL (LD50): Acute: 1720 mg/kg [Rat.].
Diethylene Glycol Monobutyl Ether:
ORAL (LD50): Acute: 5660 mg/kg [Rat]. 2400 mg/kg [Mouse].
DERMAL (LD50): Acute: 2700 mg/kg [Rabbit].

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 Product Code HDCIT32/128 Material Safety Data Sheet Product Name C i t r u s C l e a n e r & D e g r e a s e r
Concentrate

Section 12. Ecological Information

Ecotoxicity Not available.
Biodegradable/OECD Not available.

Section 13. Disposal Considerations

Waste Information Waste must be disposed of in accordance with federal, state and local environmental control
regulations.
Waste Stream Code: D001
Classification: - (Hazardous waste.)
Origin: - (RCRA waste.)
Consult your local or regional authorities.
Section 14. Transport Information
Proper shipping name Not regulated.
DOT Classification Not a DOT controlled material (United States).
UN number Not regulated.
TDG Classification Not a TDG controlled material.
Section 15. Regulatory Information
U.S. Federal Regulations SARA 313 toxic chemical notification and release reporting:
Diethylene Glycol Monobutyl Ether (Certain Glycol Ethers)
Clean Water Act (CWA) 311: No products were found.
Clean air act (CAA) 112 regulated toxic substances: Diethylene Glycol Monobutyl Ether
State Regulations California prop. 65: No products were found.
WHMIS (Canada) Class B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F).
Class D-2B: Material causing other toxic effects (TOXIC).
Section 16. Other Information
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any
liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.