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    Safety Data Sheet For Polyu

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    Mehedi Hasan
    This safety data sheet provides information on Matrix 500, which contains small amounts of isocyanates that are harmful if inhaled or through skin contact and may cause sensitization or irritation. The product contains substances that are toxic to aquatic life and may cause long-term damage to the environment. Personal protective equipment including gloves, eye protection and respiratory protection should be worn when handling the product.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    Safety Data Sheet For Polyu

    Uploaded by

    Mehedi Hasan
    88 views4 pages
    This safety data sheet provides information on Matrix 500, which contains small amounts of isocyanates that are harmful if inhaled or through skin contact and may cause sensitization or irritation. The product contains substances that are toxic to aquatic life and may cause long-term damage to the environment. Personal protective equipment including gloves, eye protection and respiratory protection should be worn when handling the product.

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    Safety Data Sheet for Polyu

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    This safety data sheet provides information on Matrix 500, which contains small amounts of isocyanates that are harmful if inhaled or through skin contact and may cause sensitization or irritation. The product contains substances that are toxic to aquatic life and may cause long-term damage to the environment. Personal protective equipment including gloves, eye protection and respiratory protection should be worn when handling the product.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    88 views4 pages

    Safety Data Sheet For Polyu

    Uploaded by

    Mehedi Hasan
    This safety data sheet provides information on Matrix 500, which contains small amounts of isocyanates that are harmful if inhaled or through skin contact and may cause sensitization or irritation. The product contains substances that are toxic to aquatic life and may cause long-term damage to the environment. Personal protective equipment including gloves, eye protection and respiratory protection should be worn when handling the product.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    You are on page 1of 4

    1 / 4

    REVISION DATE: October 2010 SDS NO.: 14514

    SAFETY DATA SHEET


    MATRIX 500
    1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

    PRODUCT NAME MATRIX 500


    PRODUCT NO. 91530, 91531, 91533
    SUPPLIER BOSTIK LIMITED
    COMMON ROAD
    STAFFORD
    STAFFORDSHIRE
    ST16 3EH
    +44 1785 272625
    +44 1785 272650 (24 HOUR)
    sds.uk@bostik.com

    2 HAZARDS IDENTIFICATION

    Harmful by inhalation. May cause sensitisation by inhalation and skin contact. Limited evidence of a carcinogenic effect. Harmful to aquatic
    organisms, may cause long-term adverse effects in the aquatic environment.
    Contains very small amount of isocyanate.
    CLASSIFICATION (1999/45) Xn;R20. Carc. Cat. 3;R40. R42/43. R52/53.

    3 COMPOSITION/INFORMATION ON INGREDIENTS

    Name EC No. CAS-No. Content Classification (67/548)

    AROMATIC NAPHTHA TYPE I 265-199-0 64742-95-6 5-10% Xn;R65. Xi;R37. N;R51/53. R10,R66,R67.

    DIPHENYLMETHANE-4,4'-DI-ISOCYANATE 202-966-0 101-68-8 1-5% Carc. Cat. 3;R40 Xn;R20,R48/20


    Xi;R36/37/38 R42/43
    ISOPHORONE DI-ISOCYANATE 223-861-6 4098-71-9 < 1% T;R23 R42/43 Xi;R36/37/38 N;R51/53

    The Full Text for all R-Phrases are Displayed in Section 16

    4 FIRST-AID MEASURES

    INHALATION
    Remove victim immediately from source of exposure. Move the exposed person to fresh air at once. Get medical attention.
    INGESTION
    DO NOT induce vomiting. Get medical attention immediately.
    SKIN CONTACT
    Remove affected person from source of contamination. Promptly flush contaminated skin with water. Promptly remove clothing if soaked
    through and flush the skin with water. Get medical attention if irritation persists after washing.
    EYE CONTACT
    Rinse the eye with water immediately. Continue to rinse for at least 15 minutes and get medical attention.

    5 FIRE-FIGHTING MEASURES

    EXTINGUISHING MEDIA
    Use fire-extinguishing media appropriate for surrounding materials.
    SPECIFIC HAZARDS
    Fire creates: Toxic gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2).
    PROTECTIVE MEASURES IN FIRE
    Wear self contained breathing apparatus

    6 ACCIDENTAL RELEASE MEASURES


    2 / 4
    REVISION DATE: October 2010 SDS NO.: 14514

    MATRIX 500
    PERSONAL PRECAUTIONS
    Avoid skin and eye contact. Wear personal protective equipment. Avoid breathing vapour
    SPILL CLEAN UP METHODS
    Wear necessary protective equipment. Stop leak if possible without risk. DO NOT touch spilled material. Do not contaminate water
    sources or sewer. Absorb in vermiculite, dry sand or earth and place into containers. Flush with plenty of water to clean spillage area. Do
    not let washing down water contaminate ponds or waterways.

    7 HANDLING AND STORAGE

    USAGE PRECAUTIONS
    Avoid spilling, skin and eye contact. Persons susceptible to allergic reactions should not handle this product.
    STORAGE PRECAUTIONS
    Store at moderate temperatures in dry, well ventilated area. Do not store in direct sunlight.
    STORAGE CLASS
    Chemical storage.

    8 EXPOSURE CONTROLS/PERSONAL PROTECTION

    Name Std TWA - 8 hrs STEL - 15 min Notes

    DIPHENYLMETHANE-4,4'-DI-ISOCYANATE WEL 0.02 0.07


    mg/m3(Sen) mg/m3(Sen)
    ISOPHORONE DI-ISOCYANATE WEL 0.02 0.07
    mg/m3(Sen) mg/m3(Sen)

    WEL = Workplace Exposure Limit.

    INGREDIENT COMMENTS
    WEL = Workplace Exposure Limits
    PROTECTIVE EQUIPMENT

    PROCESS CONDITIONS
    Use engineering controls to reduce air contamination to permissible exposure level.
    RESPIRATORY EQUIPMENT
    Respiratory protection may be required.
    HAND PROTECTION
    Protective gloves must be used if there is a risk of direct contact or splash.
    EYE PROTECTION
    Wear splash-proof eye goggles to prevent any possibility of eye contact.
    OTHER PROTECTION
    Wear appropriate clothing to prevent repeated or prolonged skin contact.
    HYGIENE MEASURES
    Wash promptly if skin becomes contaminated. Wash at the end of each work shift and before eating, smoking and using the toilet.
    Promptly remove non-impervious clothing that becomes wet or contaminated. Use appropriate skin cream to prevent drying of skin.

    9 PHYSICAL AND CHEMICAL PROPERTIES

    APPEARANCE Paste
    ODOUR Solvent.
    SOLUBILITY Insoluble in water Soluble in: Esters Aromatic solvents Ketones
    RELATIVE DENSITY 1.3 FLASH POINT (°C) > 56

    10 STABILITY AND REACTIVITY

    STABILITY
    Stable under normal temperature conditions.
    CONDITIONS TO AVOID
    Avoid heat, flames and other sources of ignition.
    3 / 4
    REVISION DATE: October 2010 SDS NO.: 14514

    MATRIX 500
    MATERIALS TO AVOID
    Amines. Acids Alkalis
    HAZARDOUS DECOMPOSITION PRODUCTS
    Fire creates: Toxic gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2).

    11 TOXICOLOGICAL INFORMATION

    GENERAL INFORMATION
    Preparation contains small volumes of isocyanate which may cause allergic reaction and irritation of respiratory system.
    INHALATION
    Vapour may irritate respiratory system or lungs.
    INGESTION
    May cause discomfort if swallowed.
    SKIN CONTACT
    Liquid may irritate skin.
    EYE CONTACT
    Spray and vapour in the eyes may cause irritation and smarting.
    OTHER HEALTH EFFECTS
    Carcinogen Category 3.
    MEDICAL CONSIDERATIONS
    Skin disorders and allergies. Chronic respiratory and obstructive airway diseases.

    12 ECOLOGICAL INFORMATION

    ECOTOXICITY
    The product contains a substance which is harmful to aquatic organisms and which may cause long term adverse effects in the aquatic
    environment.

    13 DISPOSAL CONSIDERATIONS

    GENERAL INFORMATION
    This material is not classified as special waste as defined by Special Waste Regulations 1996.
    DISPOSAL METHODS
    Dispose of waste and residues in accordance with local authority requirements. Recover and reclaim or recycle, if practical.

    14 TRANSPORT INFORMATION

    GENERAL The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,
    ADR/RID).
    No transport warning sign required.

    15 REGULATORY INFORMATION

    LABELLING

    Harmful

    CONTAINS DIPHENYLMETHANE-4,4'-DI-ISOCYANATE

    RISK PHRASES
    R20 Harmful by inhalation.
    R40 Limited evidence of a carcinogenic effect.
    R42/43 May cause sensitisation by inhalation and skin contact.
    R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
    environment.
    SAFETY PHRASES
    S23 Do not breathe vapour/spray.
    S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
    S38 In case of insufficient ventilation, wear suitable respiratory equipment.
    4 / 4
    REVISION DATE: October 2010 SDS NO.: 14514

    MATRIX 500
    S45 In case of accident or if you feel unwell, seek medical advice immediately (show label
    where possible).
    S60 This material and its container must be disposed of as hazardous waste.
    P4 Contains isocyanates. See information supplied by the manufacturer.
    STATUTORY INSTRUMENTS
    The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Control of Substances Hazardous to
    Health.
    APPROVED CODE OF PRACTICE
    Safety Data Sheets for Substances and Preparations. Classification and Labelling of Substances and Preparations Dangerous for Supply.
    GUIDANCE NOTES
    CHIP for everyone HSG(108). Workplace Exposure Limits EH40.

    16 OTHER INFORMATION

    GENERAL INFORMATION
    This product should be used as directed by Bostik Ltd. For further information consult the product data sheet or contact Technical Services.
    INFORMATION SOURCES
    This safety data sheet was compiled using current safety information supplied by distributor of raw materials.
    REVISION COMMENTS
    NOTE: Lines within the margin indicate significant changes from the previous revision. This safety data sheet supersedes all previous
    issues and users are cautioned to ensure that it is current. Destroy all previous data sheets and if in doubt contact Bostik Limited.
    ISSUED BY
    Approved LJ
    REVISION DATE October 2010
    REV. NO./REPL. SDS GENERATED 6
    DATE August 2003

    RISK PHRASES IN FULL


    R10 Flammable.
    R20 Harmful by inhalation.
    R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
    R65 Harmful: may cause lung damage if swallowed.
    R36/37/38 Irritating to eyes, respiratory system and skin.
    R37 Irritating to respiratory system.
    R40 Limited evidence of a carcinogenic effect.
    R42/43 May cause sensitisation by inhalation and skin contact.
    R66 Repeated exposure may cause skin dryness or cracking.
    R23 Toxic by inhalation.
    R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
    R67 Vapours may cause drowsiness and dizziness.

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