Safety Data Sheet: Kolliphor® CSL

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Safety data sheet

Page: 1/13
BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 09.08.2017 Version: 1.1
Product: Kolliphor® CSL
(ID no. 30554435/SDS_GEN_00/EN)
Date of print 10.08.2017

1. Identification
Product identifier

Kolliphor® CSL
Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses: Bases for creams and ointments

Details of the supplier of the safety data sheet

Company:
BASF SE
67056 Ludwigshafen
GERMANY
Operating Division Nutrition and Health

Telephone: +49 621 60-48434


E-mail address: EN-global-safety-data@basf.com

Emergency telephone number

International emergency number:


Telephone: +49 180 2273-112

2. Hazards Identification

Classification of the substance or mixture

According to UN GHS criteria

Eye Dam./Irrit. 2A

For the classifications not written out in full in this section the full text can be found in section 16.
Page: 2/13
BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 09.08.2017 Version: 1.1
Product: Kolliphor® CSL
(ID no. 30554435/SDS_GEN_00/EN)
Date of print 10.08.2017

Label elements

Globally Harmonized System (GHS)

Pictogram:

Signal Word:
Warning

Hazard Statement:
H319 Causes serious eye irritation.

Precautionary Statements (Prevention):


P280 Wear eye/face protection.
P264 Wash with plenty of water and soap thoroughly after handling.

Precautionary Statements (Response):


P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P337 + P311 If eye irritation persists: Call a POISON CENTER or doctor/physician.

Other hazards

According to UN GHS criteria

Avoid dust development and deposition - dust explosion risk. Take precautionary measures against
static discharges. The product does not contain a substance fulfilling the PBT
(persistent/bioaccumulative/toxic) criteria or the vPvB (very persistent/very bioaccumulative) criteria.

3. Composition/Information on Ingredients
Substances

Not applicable

Mixtures

Chemical nature

Blend based on: Alcohols, C16-18, Sulfuric acid, C12-18 (even numbered) alkyl esters, sodium salts

For the classifications not written out in full in this section the full text can be found in section 16.
Page: 3/13
BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 09.08.2017 Version: 1.1
Product: Kolliphor® CSL
(ID no. 30554435/SDS_GEN_00/EN)
Date of print 10.08.2017

4. First-Aid Measures
Description of first aid measures
Remove contaminated clothing.

If inhaled:
Keep patient calm, remove to fresh air.

On skin contact:
Wash thoroughly with soap and water.

On contact with eyes:


Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an
eye specialist.

On ingestion:
Rinse mouth and then drink 200-300 ml of water.

Most important symptoms and effects, both acute and delayed


Symptoms: The most important known symptoms and effects are described in the labelling (see
section 2) and/or in section 11., Further important symptoms and effects are so far not known.

Indication of any immediate medical attention and special treatment needed


Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.

5. Fire-Fighting Measures
Extinguishing media
Suitable extinguishing media:
carbon dioxide, foam, dry powder, water spray

Unsuitable extinguishing media for safety reasons:


water jet

Special hazards arising from the substance or mixture


carbon oxides, sulfur oxides, harmful vapours
May form flammable dust-air mixture. Evolution of fumes/fog.

Advice for fire-fighters


Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.

Further information:
If exposed to fire, keep containers cool by spraying with water.
Page: 4/13
BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 09.08.2017 Version: 1.1
Product: Kolliphor® CSL
(ID no. 30554435/SDS_GEN_00/EN)
Date of print 10.08.2017

6. Accidental Release Measures


Avoid the formation and build-up of dust - danger of dust explosion. Avoid dispersal of dust in the air
(i.e., clearing dust surfaces with compressed air).

Personal precautions, protective equipment and emergency procedures


Avoid contact with skin and eyes. Use personal protective clothing.

Environmental precautions
Do not discharge into drains/surface waters/groundwater.

Methods and material for containment and cleaning up


For small amounts: Sweep/shovel up.
For large amounts: Sweep/shovel up.
Dispose of absorbed material in accordance with regulations. Avoid raising dust.

Reference to other sections


Information regarding exposure controls/personal protection and disposal considerations can be
found in section 8 and 13.

7. Handling and Storage


Precautions for safe handling
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with the skin,
eyes and clothing.

Protection against fire and explosion:


Avoid dust formation. Avoid all sources of ignition: heat, sparks, open flame. Take precautionary
measures against static discharges.

Conditions for safe storage, including any incompatibilities

Suitable materials for containers: High density polyethylene (HDPE)


Further information on storage conditions: Keep container tightly sealed.

Protect from temperatures above: 30 °C


The packed product must be protected against exceeding the indicated temperature.

Specific end use(s)


For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be
observed.

8. Exposure Controls/Personal Protection


Control parameters
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BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 09.08.2017 Version: 1.1
Product: Kolliphor® CSL
(ID no. 30554435/SDS_GEN_00/EN)
Date of print 10.08.2017
Components with occupational exposure limits

No occupational exposure limits known.

Exposure controls
Personal protective equipment
Respiratory protection:
Breathing protection if dusts are formed. Particle filter with low efficiency for solid particles (e.g. EN
143 or 149, Type P1or FFP1)

Hand protection:
Chemical resistant protective gloves (EN 374)
Manufacturer's directions for use should be observed because of great diversity of types.

Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)

Body protection:
Body protection must be chosen based on level of activity and exposure.

General safety and hygiene measures


Handle in accordance with good industrial hygiene and safety practice. Hands and/or face should be
washed before breaks and at the end of the shift.

9. Physical and Chemical Properties


Information on basic physical and chemical properties

Form: pastilles
Colour: white
Odour: faint specific odour
Odour threshold:
not determined
pH value: 6,5 - 8,0 (DIN 19268)
(20 °C)
Melting point: 50,0 - 54,0 °C (DGF C-IV 3C)
Boiling point:
not determined
Flash point: 183 °C (DIN EN 22719; ISO 2719)
Evaporation rate:
The product is a non-volatile solid.
Flammability: not highly flammable (UN Test N.1 (ready
combustible solids))
Lower explosion limit:
For solids not relevant for
classification and labelling.
Page: 6/13
BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 09.08.2017 Version: 1.1
Product: Kolliphor® CSL
(ID no. 30554435/SDS_GEN_00/EN)
Date of print 10.08.2017
Upper explosion limit:
For solids not relevant for
classification and labelling.
Vapour pressure:
not determined
Density: 0,8 - 1,0 g/cm3
(60 °C)
Relative vapour density (air):
not applicable
Solubility in water: insoluble, dispersible
(20 °C)
Partitioning coefficient n-octanol/water (log Kow):
not applicable
Thermal decomposition: No decomposition if stored and handled as prescribed/indicated.
Explosion hazard: not explosive
Fire promoting properties: not fire-propagating

Other information

Self heating ability: It is not a substance capable of


spontaneous heating according to
UN transport regulations class 4.2.

Bulk density: approx. 450 kg/m3


(approx. 20 °C)
Other Information:
If necessary, information on other physical and chemical parameters is indicated in this section., No
further information available.

10. Stability and Reactivity


Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.

Chemical stability
The product is stable if stored and handled as prescribed/indicated.

Possibility of hazardous reactions


None if used for intended purpose.

Conditions to avoid
Avoid dust formation. See MSDS section 7 - Handling and storage.

Incompatible materials

Substances to avoid:
oxidizing agents, strong acids, bases
Page: 7/13
BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 09.08.2017 Version: 1.1
Product: Kolliphor® CSL
(ID no. 30554435/SDS_GEN_00/EN)
Date of print 10.08.2017
Hazardous decomposition products

:
No hazardous decomposition products if stored and handled as prescribed/indicated.

11. Toxicological Information


Information on toxicological effects

Acute toxicity

Assessment of acute toxicity:


Virtually nontoxic after a single ingestion. Virtually nontoxic after a single skin contact. The product
has not been tested. The statement has been derived from the properties of the individual
components.

Experimental/calculated data:
ATE (oral): > 5.000 mg/kg
No data available.

ATE (dermal): > 5.000 mg/kg


No data available.

Information on: Alcohols, C16-18

Experimental/calculated data:
LD50 rat (oral): > 10.000 mg/kg
Limit concentration test only (LIMIT test).
----------------------------------

Information on: Alcohols, C16-18


Experimental/calculated data:
LD50 rabbit (dermal): > 8.000 mg/kg
----------------------------------

Irritation

Assessment of irritating effects:


May cause slight irritation to the eyes. Not irritating to the skin. The product has not been tested. The
statement has been derived from the properties of the individual components.

Information on: Alcohols, C16-18


Experimental/calculated data:
Skin corrosion/irritation rabbit: non-irritant (OECD Guideline 404)
Literature data.
----------------------------------

Information on: Alcohols, C16-18


Experimental/calculated data:
Page: 8/13
BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 09.08.2017 Version: 1.1
Product: Kolliphor® CSL
(ID no. 30554435/SDS_GEN_00/EN)
Date of print 10.08.2017
Serious eye damage/irritation rabbit: non-irritant (OECD Guideline 405)

Information on: Sulfuric acid, mono-C16-18-alkyl esters, sodium salts


Experimental/calculated data:
Serious eye damage/irritation rabbit: Irritant. (OECD Guideline 405)

Serious eye damage/irritation rabbit: moderately irritating (OECD Guideline 405)

Information on: Sulfuric acid, mono-C12-18-alkyl esters, sodium salts


Experimental/calculated data:
Serious eye damage/irritation rabbit: irreversible damage (OECD Guideline 405)
The product has not been tested. The statement has been derived from substances/products of a
similar structure or composition. Analogous: Assessment derived from products with similar chemical
character.
----------------------------------

Respiratory/Skin sensitization

Assessment of sensitization:
No sensitizing effect. The product has not been tested. The statement has been derived from the
properties of the individual components.

Information on: Alcohols, C16-18


Experimental/calculated data:
Guinea pig maximization test guinea pig: Non-sensitizing. (OECD Guideline 406)
----------------------------------

Germ cell mutagenicity

Assessment of mutagenicity:
The substance was not mutagenic in bacteria. The product has not been tested. The statement has
been derived from substances/products of a similar structure or composition. The data on toxicology
refer to the active ingredient.

Carcinogenicity

Assessment of carcinogenicity:
Based on the ingredients there is no suspicion of a carcinogenic effect in humans.

Reproductive toxicity

Assessment of reproduction toxicity:


No data available.

Specific target organ toxicity (single exposure)

Remarks: No data available.

Repeated dose toxicity and Specific target organ toxicity (repeated exposure)

Assessment of repeated dose toxicity:


Page: 9/13
BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 09.08.2017 Version: 1.1
Product: Kolliphor® CSL
(ID no. 30554435/SDS_GEN_00/EN)
Date of print 10.08.2017
No data available.

Aspiration hazard

No aspiration hazard expected.

12. Ecological Information


Toxicity

Assessment of aquatic toxicity:


The inhibition of the degradation activity of activated sludge is not anticipated when introduced to
biological treatment plants in appropriate low concentrations. The product has not been tested. The
statement has been derived from the properties of the individual components.

Information on: Alcohols, C16-18


Assessment of aquatic toxicity:
There is a high probability that the product is not acutely harmful to aquatic organisms. The inhibition
of the degradation activity of activated sludge is not anticipated when introduced to biological
treatment plants in appropriate low concentrations.

Information on: Sulfuric acid, mono-C12-18-alkyl esters, sodium salts


Assessment of aquatic toxicity:
The inhibition of the degradation activity of activated sludge is not anticipated when introduced to
biological treatment plants in appropriate low concentrations. Acutely toxic for aquatic organisms.
Harmful to aquatic organisms based on long-term (chronic) toxicity study data.
----------------------------------

Persistence and degradability

Assessment biodegradation and elimination (H2O):


Readily biodegradable (according to OECD criteria). The product has not been tested. The
statement has been derived from the properties of the individual components.

Information on: Alcohols, C16-18


Elimination information:
79 - 100 % (28 d) (other) (activated sludge, domestic) other

79 - 100 % BOD of the ThOD (28 d) (ISO 10708) Readily biodegradable.


----------------------------------

Bioaccumulative potential

Assessment bioaccumulation potential:


The product has not been tested.

Mobility in soil

Assessment transport between environmental compartments:


Page: 10/13
BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 09.08.2017 Version: 1.1
Product: Kolliphor® CSL
(ID no. 30554435/SDS_GEN_00/EN)
Date of print 10.08.2017
Adsorption in soil: Adsorption to solid soil phase is possible.

Results of PBT and vPvB assessment

According to Annex XIII of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH): The product does not contain a substance
fulfilling the PBT (persistent/bioaccumulative/toxic) criteria or the vPvB (very persistent/very
bioaccumulative) criteria. Self classification

Other adverse effects

The product does not contain substances that are listed in Regulation (EC) 1005/2009 on
substances that deplete the ozone layer.

13. Disposal Considerations

Waste treatment methods

Incinerate in suitable incineration plant, observing local authority regulations.

Contaminated packaging:
Completely emptied packagings can be given for recycling.
Packs that cannot be cleaned should be disposed of in the same manner as the contents.

14. Transport Information

Land transport

ADR
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user

RID
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Page: 11/13
BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 09.08.2017 Version: 1.1
Product: Kolliphor® CSL
(ID no. 30554435/SDS_GEN_00/EN)
Date of print 10.08.2017
Special precautions for None known
user

Inland waterway transport


ADN
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user:

Transport in inland waterway vessel


Not evaluated

Sea transport

IMDG
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user

Air transport

IATA/ICAO
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user

UN number
Page: 12/13
BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 09.08.2017 Version: 1.1
Product: Kolliphor® CSL
(ID no. 30554435/SDS_GEN_00/EN)
Date of print 10.08.2017
See corresponding entries for “UN number” for the respective regulations in the tables above.

UN proper shipping name


See corresponding entries for “UN proper shipping name” for the respective regulations in the tables
above.

Transport hazard class(es)


See corresponding entries for “Transport hazard class(es)” for the respective regulations in the
tables above.

Packing group
See corresponding entries for “Packing group” for the respective regulations in the tables above.

Environmental hazards
See corresponding entries for “Environmental hazards” for the respective regulations in the tables
above.

Special precautions for user


See corresponding entries for “Special precautions for user” for the respective regulations in the
tables above.

Transport in bulk according to Annex II of MARPOL and the IBC Code


Regulation: Not evaluated
Shipment approved: Not evaluated
Pollution name: Not evaluated
Pollution category: Not evaluated
Ship Type: Not evaluated

15. Regulatory Information


Safety, health and environmental regulations/legislation specific for the substance or
mixture

If other regulatory information applies that is not already provided elsewhere in this safety data
sheet, then it is described in this subsection.

16. Other Information

Full text of classifications, hazard symbols and hazard statements, if mentioned in section 2 or 3:
Eye Dam./Irrit. Serious eye damage/eye irritation

The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. This safety data sheet is neither a
Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification
agreement. Identified uses in this safety data sheet do neither represent an agreement on the
corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the
Page: 13/13
BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 09.08.2017 Version: 1.1
Product: Kolliphor® CSL
(ID no. 30554435/SDS_GEN_00/EN)
Date of print 10.08.2017
responsibility of the recipient of the product to ensure any proprietary rights and existing laws and
legislation are observed.

Vertical lines in the left hand margin indicate an amendment from the previous version.

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