SAFETY DATA SHEET Date of issued : 03-01-2019

K – 404 CG Suspended : -

SECTION 1 : PRODUCT & COMPANY IDENTIFICATION

PRODUCT NAME : KARMAND K – 404 CG

OTHER NAME : Cold galvanize compound

RECOMMENDED USE : Protective coating, that against corrosion on all iron, steel structures, steel
tanks, pipework, ducting cars, boats and general marine applications.

COMPANY : PT. KARMAND MITRA ANDALAN

Jl. Jemursari II no. 16, Jemur Wonosari, Wonocolo
Surabaya
Indonesia
Telp : (031) 8418726/8418686
Fax : (031) 8418726

SECTION 2 : HAZARD IDENTIFICATION

GHS CLASSIFICATION
Flammable liquids : Category 3
Acute dermal toxicty : Category 4
Acute inhalation toxicity, Vapor : Category 4
Skin corrosion/irritation : Category 2
Serious eye damage/eye irritation : Category 2
Organ toxicity (single exposure) : Category 3
Organ toxicity (repeated exposure): Category 2
Aspiration toxicity : Category 1

GHS LABELS ELEMENTS

Hazards Pictogram :

Signal Word : DANGER

PRECAUTIONARY STATEMENTS
Prevention : Wear protective gloves/protective clothing/eye protection/face protection. Use
only outdoors or in a well-ventilated area. Wash face, hands and any exposed
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KARMAND K – 404 CG
 skin thoroughly after handling. Do not breathe
dust/fume/gas/mist/vapors/spray. Keep away from heat/sparks/open
flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond
container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting/equipment. Use only non-sparking tools. Take
precautionary measures against static discharge. Keep cool.
Response : Get medical attention/advice if you feel unwell Inhalation. IF INHALED: Remove
victim to fresh air and keep at rest in a position comfortable for breathing. Call
a POISON CENTER or doctor/physician if you feel unwell. Call a POISON CENTER
or doctor/physician if you feel unwell. If skin irritation occurs: Get medical
advice/attention. IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water/shower. Wash contaminated clothing before
reuse IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation
persists: Get medical advice/ attention. IF SWALLOWED: Immediately call a
POISON CENTER or doctor/physician. Do NOT induce vomiting. In case of fire:
Use CO2, dry chemical, or foam for extinction
Storage : Store locked up. Store in a well-ventilated place. Keep container tightly closed.
Disposal : Dispose of contents/ container to an approved waste disposal plant.

SECTION 3 : COMPOSITION/INFORMATION INGRIDIENTS

PURE/MIXTURE

Chemical Name CAS Concentration

Xylene 95-47-6
Pigment
Resin

SECTION 4 : FIRST AID MEASURES

Eye Contact Immediately flush eye with plenty water for at least 15 to 20 minutes. Get medical attention
immediately.

Skin Contact Immediately flush skin with plenty water for at least 15 minutes. Change contaminated clothing.
Cold water may be used. Wash clothing before reuse. Get medical attention immediately.

Swallowed Do not induce vomiting unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband.
Get medical attention immediately.

Inhaled If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical attention immediately.

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KARMAND K – 404 CG
 SECTION 5 : FIRE FIGHTING MEASURES

Flammability of The Product Flammable

Suitable Extinguish Media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Cool
closed containers exposed to fire with water spray.

Unstable Extinguish Media Do not use a solid water stream as it may scatter and spread fire.

SECTION 6 : ACCIDENTAL RELEASE MEASURES

General Information Use proper personal protective equipment as indicated in Section 8.

Spills/Leaks Provide ventilation. Do not let this chemical enter the environment. Collect
spillage. Do not flush into surface water or sanitary sewer system.

SECTION 7 : HANDLING AND STORAGE

Handling Wear personal protective equipment. Do not get in eyes, on skin, or on

clothing. Avoid ingestion and inhalation. Ensure adequate ventilation. Keep
away from open flames, hot surfaces and sources of ignition. Use only non-
sparking tools. Take precautionary measures against static discharges.

Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Keep
away from heat and sources of ignition. Flammables area.

SECTION 8 : EXPOSURE CONTROL/PERSONAL PROTECTION

Personal Protective Equipment

Eyes: Wear chemical splash goggles and face shield.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.

SECTION 9 : PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Liquid
Color : Grey ( Zinc )
Odor : Sweet, characteristic
Flash point : 25 °C / 77 °F a pensky, close cup.
Specific gravity : ± 1,10
Non volatile : 49 ± 2 %

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KARMAND K – 404 CG
 SECTION 10 : STABILITY AND REACTIVITY

Chemical stability Stable under normal conditions.

Incompatible materials Strong oxidizing agents, Strong acids

SECTION 11 : TOXICOLOGICAL INFORMATION

Acute oral toxicity : LD50 rat: 3608 mg/kg

Acute inhalation toxicity : LC50 rat: 4330 ppm, 6 hrs

Acute dermal toxicity : LD50 rabbit: 14100 mg/kg

Skin corrosion/irritation : No data available

Serious eye : No data available

damage/eye irritation

Respiratory or : No data available

skin sensitization

SECTION 12 : ECOLOGICAL INFORMATION

Toxicity to fish : LC50 fish: 16,1 mg/L, 96 hrs

Toxicity to daphnia and other: EC daphnia: 2,61 – 5,59 mg/L, 48 hrs

aquatic invertebrates

Toxicity to algae : EC50 alga: 4,2 mg/L, 72 hrs

SECTION 13 : DISPOSAL CONSIDERATIONS

Waste disposal recommendations: handle with care. safe handling: see section 7. handling and storage. collect
and dispose of waste product at an authorised disposal facility. refer to manufacturer/supplier for information on
recovery/recycling. dispose of contaminated materials in accordance with current regulations.

SECTION 14 : TRANSPORT INFORMATION

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KARMAND K – 404 CG
Transport hazard class(es) (ADR) : 3

Packing group (ADR) : II

Dangerous for the environment : No

SECTION 15 : REGULATORY INFORMATION

National regulation
Regulations regarding the management of hazardous and toxic substances use B3 list
Decisions about controlling chemicals in the workplace not apply
Safety regulations for hazardous substances for human health not apply
Regulations regarding the procurement, distribution and control of hazardous substances not apply
Regulations concerning the control of production and use of hazardous materials for industry not apply
SECTION 16 : OTHER INFORMATION

Abbreviations and acronyms:

LC50 = MEDIAN LETHAL CONCENTRATION
LD50 = MEDIAN LETHAL DOSE
LL50 = MEDIAN LETHAL LEVEL
EC50 = MEDIAN EFFECTIVE CONCENTRATION
EL50 = MEDIAN EFFECTIVE LEVE

DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the
information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of
handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and
other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in
any way connected with the handling, storage, use or disposal of the product. This SDS was prepared and is to be used only
for this product. If the product is used as a component in another product, this SDS information may not be applicable.

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KARMAND K – 404 CG