Matter Waves, Atomic Models

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S2021

Prof. Dr. M. Ziese

Solutions to Exercises Experimental Physics 4


1. Matter waves, atomic models

1. Matter waves I
A wavelength of λ = 10−5 m and a slit width of d = 10−4 m lead to a first minimum in the
diffraction pattern appearing at
λ
sin αmin = . (1)
d
This yields a typical spread
 
λ
∆α = 2αmin = 2 arcsin = 11.5◦ . (2)
d

2. Mater waves II
The function
 r  
3 2x b
1+ − ≤x≤0


 rb  b  2


ψ(x) = 3 2x 2b (3)
 1− 0≤x≤



 b b x
0 otherwise

yields the probability density


  2
3 2x b
1+ − ≤x≤0


 b b 2


2
P (x) = . (4)

3 2x 2b
 1− 0≤x≤
 b b x



0 otherwise

Let us first check normalization:


Z ∞ Z 0  2 Z 2
b/2 
3 2x 3 2x
P (x)dx = 1+ dx + 1− dx (5)
−∞ b −b/2 b 0 b b
Z b/2  2  3 b/2
6 2x 2x
= 1− dx = − 1 − = 1. (6)
b 0 b b
0

The probability density is indeed normalized.


(a) The conjugated probability is
Z ∞
1
ψ̂(k) = √ ψ(x) exp(−ikx)dx (7)
2π −∞
r ( Z 0   Z b/2   )
3 2x 2x
= 1+ exp(−ikx)dx + 1− exp(−ikx)dx (8)
2πb −b/2 b 0 b
r ( )
2 0 exp(−ikx) 2 b/2 exp(−ikx)
Z Z
3 1 1
= + dx + − dx (9)
2πb −ik b −b/2 ik ik b 0 ik
r  
3 2 1 exp(ikb/2) exp(−ikb/2) 1
= − − + (10)
2πb b k 2 k2 k2 k2
r
3b 4 1 − cos(kb/2)
= (11)
2π b2 k2
r r
3b 1 − cos(kb/2) 3b sin2 (kb/4)
= = . (12)
2π (kb/2)2 8π (kb/4)2
Check normalization:
Z ∞ Z ∞
3b sin4 (kb/4)
|ψ̂(k)|2 dk = dk (13)
−∞ 8π −∞ (kb/4)4
3b 4 ∞ sin4 (z)
Z
= dz (14)
8π b −∞ z4
3 2π
= = 1. (15)
2π 3
Also this probability density is normalized.
(20 P) for Fourier transform
(b) Since both probability densities are symmetric, we have hxi = hki = 0.

(Z )
0 Z b/2
2 3 2 2 2 2
hx i = x (1 + 2x/b) dx + x (1 − 2x/b) dx (16)
b −b/2 0
Z b/2
6
= x2 (1 − 2x/b)2 dx (17)
b 0
Z b/2
8
= x3 (1 − 2x/b)dx (18)
b2 0
Z b/2
4 4 4  5 b/2 b2
= x dx = x = (19)
b3 0 5b3 0 40
p b
∆x = hx2 i = √ . (20)
2 10
(10 P)


sin4 (kb/4) 2
Z
3b
hk 2 i = k dk (21)
8π −∞ (kb/4)4
 3 Z ∞
3b 4 sin4 (z)
= dz (22)
8π b −∞ z2
24 π 12
= = 2 (23)
πb2 2 b√
p 2 3
∆k = hk 2 i = . (24)
b

2
(10 P)
(c) The uncertainty product is
r
3
∆x∆k = ' 0.54772 (25)
10
and about 9.5% larger than the minimum value of 1/2.
(10 P)

3. (a) Since angular momentum is conserved, the Rutherford scattering problem is a two-
dimensional problem. From the lecture we know the value of the angular momentum

L = mr2 ϕ̇ = mbv0 (26)

and the impact parameter

zZe2
b= cot(θ/2) . (27)
4π0 mv02

The energy is conserved and given by


1 1 1 zZe2
E = mv02 = mṙ2 + mr2 ϕ̇2 + (28)
2 2 2 4π0 r
1 2 L2 zZe2
= mṙ + + . (29)
2 2mr2 4π0 r
At the point of closest approach the radial acceleration vanishes: ṙ = 0. This yields
L2 zZe2
E = 2
+ (30)
2mr 4π0 r
2
zZe L2
r2 − − =0 (31)
4π0 E 2mE
 s 
2
zZe2 

8π0 E
r = 1+ 1+ b2  (32)
8π0 E zZe2

zZe2
 q 
2
r = 1 + 1 + cot (θ/2) (33)
8π0 E
zZe2
r = [1 + csc(θ/2)] (34)
8π0 E
(b) The cross section is deviating from the Coulomb scattering value at small angles, since
the α particles start to penetrate the aluminum nuclei. At 54◦ the minimum distance
is just equal to the sum of the radii of the α-particle and the nucleus. With z = 2,
Z = 13, E = 12.75 MeV and rα = 2 fm, one obtains

zZe2
rAl = r − rα = [1 + csc(θ/2)] − rα = 4.7 fm − 2 fm = 2.7 fm . (35)
8π0 E

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