Scribd Logo
Upload

Welcome to Scribd!

  • 20 views

    2020 CHEE2001 Week 10 Tutorial Sheet

    Uploaded by

    Muntaha Manzoor
    Tutorial helpful information regarding the process principle course to get a head start in your learning experience.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    2020 CHEE2001 Week 10 Tutorial Sheet

    Uploaded by

    Muntaha Manzoor
    20 views5 pages
    Tutorial helpful information regarding the process principle course to get a head start in your learning experience.

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Tutorial helpful information regarding the process principle course to get a head start in your learning experience.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    20 views5 pages

    2020 CHEE2001 Week 10 Tutorial Sheet

    Uploaded by

    Muntaha Manzoor
    Tutorial helpful information regarding the process principle course to get a head start in your learning experience.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    You are on page 1of 5

    CHEE2001 2020 Tutorial Week 10

    Mass and Energy Balances with Reaction


    1. Introduction to heats of reaction

    1.1 Consider the reaction 2A -> B. If the ΔHro = -40 kJ/mol:


    a) what is the value of the ratio kJ/mol A reacted?
    b) is the reaction exothermic or endothermic at 25 ̊C and 1 atm?
    c) If the reactor is adiabatic (Q =0), would the products leave the reactor at a higher
    or lower temperature than the entering reactants?

    1.2 Consider the following reactions


    C6H14(l) + 19/2 O2(g) -> 6 CO2(g) + 7 H2O(l): ΔHro = -4 163 kJ/mol
    C6H14(g) + 19/2 O2(g) -> 6 CO2(g) + 7 H2O(l): ΔHro = -4 195 kJ/mol

    The standard states of reaction are 25 ̊C and 1 atm. What is the physical significance
    of the difference between the two values of ΔHro ?

    2. Heats of reaction from heats of formation


    Using heats of formation, calculate the standard heat of reaction (25 C̊ and 1atm) in
    kJ/mol for the following reactions.
    a) CH4(g) + 2O2(g) -> CO2(g) + 2H2O(g)
    b) 2CH4(g) + 4O2(g) -> 2CO2(g) + 4H2O(g)
    c) CH4(g) + 2O2(g) -> CO2(g) + 2H2O(l)
    d) Explain the difference in value between a) and c)
    e) These heats of reaction are expressed as specific values (energy/mol). How do you
    determine the total heat generated in a process?

    3. Methane-fired boiler
    A methane-fired boiler creates steam for use in a process plant.
    50 mol/s of methane enters the boiler at 25 ˚C and burns with 50% excess air preheated
    at 150 ˚C. The hot gases from the combustion chamber then pass through a heat
    exchanger to generate 10 bar saturated steam from process water.
    a) Determine the heat content of the boiler combustion gases leaving the combustion
    chamber in MW (assume that the boiler operates adiabatically),
    b) Assuming that 75% of the heat in the combustion gases is recovered to generate
    steam, calculate the amount of 10 bar saturated steam (kg/s) that is produced.
    Assume an inlet process water temperature of 30 ˚C.

    Show the full systematic method


    CHEE2001 2020 Tutorial Week 10

    Heats of formation
    CHEE2001 2020 Tutorial Week 10

    SATURATED STEAM TABLES (ref: T = 0 ̊C and P = 1 atm)


    CHEE2001 2020 Tutorial Week 10

    Table B.6 Felder & Rousseau (Ref: T= 0 ̊C, P = 1 atm)


    CHEE2001 2020 Tutorial Week 10

    Enthalpies of selected gases – Table B.8 Felder & Rousseau

    You might also like