Articles 187
Articles 187
Articles 187
Abstract
This paper gives an overview of the current legal and standard specifications to be taken into
account while designing and using fuel cell systems. This overview embraces both stationary
and mobile applications at European and international level. Current and under construction
IEC and ISO standard are browsed. So are the one from the US, Canada and Europe.
The world-wide regulation project for vehicles is presented as well as the current legal situa-
tion for vehicle approval. Concerning stationary applications, this paper highlights the legal
frame for both construction and use of these systems. A focus is made on France and Ger-
many.
As a conclusion, the need for demonstration projects is indicated so as to gain experience.
This newly acquired experience shall push towards relevant and tailor made regulations and
standards that ensure homogeneous risk control.
For one H 2 mole at the standard temperature T0 = 298 K and H 2 O in gaseous state, the en-
thalpy, entropy and Gibbs energy of the reaction are :
∆ r H 0 = −241,8 kJ ⋅ mol −1
∆ r S 0 = −44,3 J ⋅ mol −1 ⋅ K −1
∆ r G 0 = −228,6 kJ ⋅ mol −1
This means that with one mole of hydrogen (2 grams), it is possible to obtain 241,8 kJ of heat
or in the ideal case of a reversible transformation 228,6 kJ of mechanical or electrical energy
without any pollutant emission.
In fact real transformations are far from the ideal case and the mechanical or electrical energy
is much lower then 228,6 kJ/molH2. If we define the energetic efficiency η of an engine as
the real electrical or mechanical energy provided reported to the maximum physically possi-
ble ∆ r G 0 , we can calculate the real hydrogen consumption necessary for a given energetic
need. The table 1 gives for different efficiencies the hydrogen mass and volume (gaseous at
293 K, under 1 atmosphere, 25 MPa, 35 MPa and 70 Mpa) to obtain 1 kWh (3,6 MJ) of us-
able energy (mechanical or electrical).
Table 1 : Hydrogen mass and volume to obtain 1 kWh with efficiency from 20 to 100%
Table 2 gives a comparison of mass and volume energy density for Hydrogen and conven-
tional fuels. It can be seen that hydrogen is very competitive for mass energy density but not
for volume energy density.
2
Paper Ref.CO5/147 – Oral presentation
Table 2 : Comparison of mass and volume energy density for various fuels
As a conclusion, the use of hydrogen to replace conventional fuel has the very important ad-
vantage to produce mechanical or electrical energy without any local pollution. The main
drawbacks are its low volume energy density and the safety problems due to its flammability
and explosivity. Additionally, the high pressure storage which is a method to increase the vol-
ume energy density can generate additional safety problems.
As a consequence, hydrogen use can be technically difficult and safety requirements have to
be seriously considered. So the need for accurate technical standards to ensure a good concep-
tion of products and the need for regulations to guarantee user safety are key points in the
hydrogen energy development.
Compliance with regulations is compulsory. Whereas standards are followed on a voluntary
basis. Regulations usually set objectives whereas standards propose means to reach these ob-
jectives. Standard enforcement is sometimes a mean to comply with related regulations (har-
monised standards). It also indicates that state of the art has been taken into account while
designing a system.
3
Paper Ref.CO5/147 – Oral presentation
• The vehicle motion which makes it come across with many different environments
such as circulation in towns, tunnels crossing, underground car parks, etc. Each of
these various environment feature its own type of risks.
• The high speed motion which induces a potentially highly energetic collision hazard.
• The building of urban hydrogen service-stations for car refuelling. These service-
stations have to store large quantity of hydrogen. They also have to be able to transfer
liquid hydrogen or compressed hydrogen to vehicles at high rate.
Standards erection favours homogeneous safety levels. It suggests good practices.
In most countries certification is required to put a new car into service. These regulations set
safety objectives to be satisfied.
In a regulatory framework, the manufacturer has to prove that he has used all adapted techni-
cal means to prevent accidents or to limit their consequences. On the other hand, the manufac-
turer has only to show that its product is in agreement with a given standard.
ISO/DPAS155
Airport fuelling facility In progress
94
Vehicle fuel tanks with high pressure gase- Harmonization with EIHP in progress at
ISO/CD15869
ous H2 WP29/GRPE
4
Paper Ref.CO5/147 – Oral presentation
5
Paper Ref.CO5/147 – Oral presentation
Concerning regulations, EIHP2 proposed two draft regulations for vehicles, one concerning
liquid hydrogen [1] and the other one concerning compressed gaseous hydrogen [2]
1
United Nation, Economic Commission for Europe, Working Party 29
2
Group on Pollution and Energy
3
Global Technical Regulation
6
Paper Ref.CO5/147 – Oral presentation
“Fuel cell specific” standards and regulations under development are among others concerned
with the safety of the systems.
7
Paper Ref.CO5/147 – Oral presentation
8
Paper Ref.CO5/147 – Oral presentation
The U.S., Canadian or Japanese Fuel Cell Standards are mostly the basis for the work of the
different WG’s of IEC / TC 105.
9
Paper Ref.CO5/147 – Oral presentation
othe. As such, they would need an approval from local authorities prior to be installed and
used. As an example, we will give a quick overview for France and Germany.
3.3.1. EU regulation
Table 5 gives an overview of all the EU Directives that generally apply to fuel cell systems.
It applies to all machinery and lays down the essential health and safety
requirements. It also apply to safety components placed on the market
separately. For the purposes of this Directive, machinery means an as-
sembly of linked parts or components, at least one of which moves,… .
98/37/EC Machinery
It refers to the ATEX 94/9 CE directive dedicated to equipment and
protective systems intended to be use in potentially explosive atmos-
phere
All these Directives are “new approach directives”. They give some essential safety require-
ments that have to be fulfilled by the manufacturer or the importer of a system..
CE marking is required to market a product in every country of the European Union. Compli-
ance with appropriate EU directives entitles for marking (auto-certification or notified body).
10
Paper Ref.CO5/147 – Oral presentation
Therefore, fuel cell manufacturers (or importers) have to ensure that their systems are in con-
formity with Directives cited in table 5.
In Germany, a rule, namely VP 119, has been edited by manufacturers and end-users to facili-
tate residential fuel cell CE marking. On the basis of this rule fuel cell systems from Vaillant
and Sulzer have been CE marked.
The fuel cell project from EdF (French electricity company) and GdF (French gas company)
in the city of Chelles, near Paris, can be taken as an example of the enforcement of French
regulation to a stationary fuel cell system (200 kWel fuel cell from UTC FC, PAFC technol-
ogy fuelled with natural gas).
The most important learning from this project are as follow:
• application of the French regulation on pressure vessels;
• application of the French regulation on heating appliances;
• application of the French regulation on electrical systems;
• certification by the local authorities of a steam separator (pressure vessel regulation);
11
Paper Ref.CO5/147 – Oral presentation
• non application of the 1415 rubric of the French “ICPE regulation” on the principle that
hydrogen was not industrially produced and was immediately consumed after production;
• special “use approval” by the French Industry Ministry because the unit was not CE
marked.
4. Conclusion
Legal and standardisation frame for both stationary and mobile applications is evolving on an
international and European level. Even though not always facilitated by the current context,
demonstration projects are required to gain experience that is useful to appropriately shape
specifications to come. Standardisation and common regulations shall provide world-wide
homogeneous and relevant safety principles. It shall prevent accidents and associated bad
press.
12
Paper Ref.CO5/147 – Oral presentation
References
[1] EIHP, Proposal for a new draft regulation for the use of liquid hydrogen on motor vehi-
cles, Revision 13, 25 Nov. 2002
[2] EIHP, Proposal for a new draft regulation for the use of compressed gaseous hydrogen
on motor vehicles, Revision 11, 29 March 2003
13
Paper Ref.CO5/147 – Oral presentation
Annex 1
Organisation chart for elaboration
of international hydrogen vehicles regulations
______
Germany
EIHP UNECE - WP29
GRPE
Ad-hoc WG ISO
Hydrogen Vehicles TC197 – TC22
GRPE GRPE/ISO
CGH2 GoE Harmonization
GRPE/ISO GRPE/ISO
CGH2 GoE LH2 GoE
Ad-hoc WG
Hydrogen Vehicles
GRPE
WP29
14
Paper Ref.CO5/147 – Oral presentation
Annex 2
Table of meetings for elaboration of international hydrogen
vehicles regulations since 2001
15