H2S Analyser & VPP SA4000-3

H2S in Liquid Petroleum Products & Crude Oil

ASTM D7621; IP 570; ISO 8217

• Measurement of potential H2S

in the liquid phase
• No wet chemistry involved
• Small lab bench footprint
• Critical measurement for
product safety and release

Crude Oil • Marine Fuel

Stanhope-Seta, London Street, Chertsey, Surrey, KT16 8AP, UK

t: +44 (0) 1932 564391 | e: sales@stanhope-seta.co.uk | www.seta-analytics.co.uk
 Hydrogen Sulfide
Marine Fuel Testing
Hydrogen Sulfide in Marine Fuel
Hydrogen sulfide is a natural component in crude oils and a by-
product of residual fuel manufacture.H2S is extremely toxic both in the
liquid and vapour phase and is very harmful to humans, animals and
aquatic life. In addition to this, there are long term impacts associated
with H2S, such as; corrosion. H2S is initially contained within the liquid,
from where it can slowly be released as gas into the vapour space
and can concentrate within the head spaces and venting systems of
storage tanks.

Consequently a reliable test method for the detection of H2S conent at

any point in the distribution system is essential.
IP 570/14a introduced a mandated verification procedure for
IP 570; ASTM D7621; ISO 8217
apparatus performance, details of the IP 570 PTS can be found on
IP 570 covers the testing of H2S content of fuel oils including marine the back page. The method also allowed the inclusion of samples
residual fuels, distillates and blend stocks in the liquid phase. containing FAME to be analysed.

Procedure A: If fuel is subject to interferences from Methyl mercaptan, Who should test for hydrogen sulfide?
dimethyl sulphide or larger mercaptan molecules, then Procedure A
will remove the interferences by using the Vapour Phase Processor. • Barge suppliers
The advantage is that the Sensor is protected from aromatics and • Inspection test laboratories
there are no disputes over interferences affecting results. • Bunker fuel suppliers/providers
Procedure B: If measurements are always below 2mg/kg Procedure • Marine fuel suppliers
B could be adopted without use of the Vapour Phase Processor.
• Tank storage terminals
However, if the Sensor is exposed to interferences it will become
• Refineries & fuel blending locations
damaged and test results can be elevated.

Hydrogen Sulfide in Crude Oil

Managing H2S is a challenge at every stage of hydrocarbon
production, refining and transportation. Crude oil considered to
contain high levels of H2S may be refused by the operator and
devalued by the customer. A primary objective for testing and
treatment of crude oil is the reduction of H2S content in the liquid
phase to typically 7ppm or less (equivalent to a cargo headspace
content of typically 70ppm or less).

ASTM D7621 Appendix X1

Stanhope-Seta, with support from the Industry, undertook a study
to show that IP 570/ASTM D7621 can be modified to measure the
concentration of H2S in stabilised crude oil. As a result of this study, a
Crude Oil Appendix has been added to ASTM D7621 Appendix X1.

Principles of Operation
To perform a test, the ‘support bracket’ for the Test Vessel is mounted
outside the H2S Analyser. The sample is then dispensed from the
Pipette provided in the Crude Oil Test Kit.

Sample identity, operator name and

weights of empty/charged syringe
are input via the menu display and
The Seta Oil Test Kit combined with the H2S Analyser & Vapour Phase
keys on the front membrane panel.
Proccessor, offers a simple cost effective solution to determine the
Users simply press start to begin
presence of H2S in accordance with ASTM D7621 Appendix X1.
then test results are automatically
• 15 minute test duration
populated by the instrument and will
• Measures 0-250 mg/kg (0-250 ppm) in the liquid phase appear on screen both as a figure to
• Repeatable results ppm (mg/kg) and graph.

2 Stanhope-Seta,
t: +44 (0) 1932 564391 | f: +44 (0) 1932 568363London Street, Chertsey, Surrey, KT16
| e: sales@stanhope-seta.co.uk 8AP, UK
| www.seta-analytics.com
t: +44 (0) 1932 564391 | e: sales@stanhope-seta.co.uk | www.seta-analytics.co.uk
 Hydrogen Sulfide
Marine Fuel Testing
H2S Analyser & VPP (Vapour Phase
Processor)
ASTM D7621; IP 570; ISO 8217
The H2S Analyser was developed with Lloyd’s Register’s Fuel Oil and
Bunker Analysis Service’ (FOBAS) along with support of other major
international oil companies to offer rapid measurement of H2S in
petroleum products.

The H2S Analyser is an excellent tool for supporting product Quality

Control and safety ensuring product is within approved specification.
It is also ideal for both product remediation treatment of feedstock
components and off-spec products with fast repeat sample
measurement capability.

Key Features Operator Sequence

To conduct a test, 20ml of diluent is decanted into the test vessel,
• 15 minute test duration
which is inserted into the heater block. After approximately 5
• Measurement range from 0-250 mg/kg (0-250 ppm H2S) in the
minutes, the diluent has reached 60°C and 1ml of sample is added
liquid phase
to the diluent. Sample identity,operator name, weights of empty/
• Vapour Phase Processor proven to eliminate effects of chemical charged syringe are input via the menu display and keys on the front
interferences membrane panel.
• Fully portable operation
• Small lab bench footprint
Unique Test Vessel Design
• Critical measurement method for product safety and release
• No wet chemistry The H2S Analyser features a specifically designed test vessel which;

• Simplifies sample introduction

Vapour Phase Processor (VPP) • Prevents incorrect orientation
Seta developed the VPP accessory for use with the H2S Analyser to • Reduces operator error
improve precision and accuracy of IP 570.

IP 570 Procedure A gives the The inlet & outlet connections are
marine industry a more robust enhanced making connections to the
specification tool for monitoring instrument quick and easy.
H2S by removing any interfering
chemicals such as toluene, xylene Upgrades to accommodate earlier
or Mercaptans which can damage systems are easy and can be achieved in
the sensor and ‘interfere’ with the field via the Test Vessel Upgrade Kit,
readings. using part number; SA4022-0

How does the VPP What samples can the H2S Analyser measure?
work? • Heavy Residuel Marine Fuels
Gases emitted from the H2S analyser test vessel are passed through • Distillate Marine Fuels
a cooled sorbent cartridge before they are measured by the
• Fuel Oils
electrochemical sensor. Hydrogen Sulfide passes through the sorbent
• Road Transport Diesel Fuels
cartridge whereas methyl mercaptans, dimethyl sulphide and other
volatile chemicals are slowed or trapped by the cartridge. • Stationary Power Fuels
• Refinery Feedstocks
Add View demo video plus a QR code
• Light Distillate Products
• Crude Oils

Stanhope-Seta, London Street, Chertsey, Surrey, KT16 8AP, UK

t: +44 (0) 1932 564391 | f: +44 (0) 1932 568363 | e: sales@stanhope-seta.co.uk | www.seta-analytics.com 3
t: +44 (0) 1932 564391 | e: sales@stanhope-seta.co.uk | www.seta-analytics.co.uk
 Hydrogen Sulfide
Marine Fuel Testing
IP 570 Proficiency Testing Scheme
IP 570/14a
The IP 570 Proficiency Testing Scheme (PTS) is an inter-laboratory,
quality assurance programme which enables users to continually
monitor the performance of their H2S Analyser in accordance with
ISO/IEC 17025. This is achieved by testing a sample with a known, but
undisclosed, H2S concentration.

Aim of Proficiency Testing

Proficiency Testing is defined as an evaluation of participant
performance against pre-established criteria by means of
interlaboratory comparison (ISO/IEC 17043). Proficiency Testing
aids laboratories in achieving accurate and reproducible results and
therefore provides reassurance in the laboratory’s testing.

Method Compliance
Validation of apparatus performance is stated as a mandatory Benefits of Participating in the PT Scheme
requirement at leats every 3 months in IP 570/14a. Participation in
the Seta IP 570 Proficiency Testing Scheme is stated as the preferred • Continual validation of laboratory and apparatus performance
means to achieve this requirement as it enables laboratories to • Ability to demonstrate compliance with laboratory accreditation
evaluate their performance for testing H2S in the liquid phase using requirements (ISO 17025)
the Seta H2S Analyser. • Diagnostic support provided if incorrect results are reported
• Inter-laboratory comparison of test results and performance
• Identifies problems such as inadequate test or measurement
Summary Report Content
processes and procedures
• A table detailing the data reported • Repeat samples available for incorrect and result investigation
• Z-score performance indicators • Easy online result reporting
• An evaluation of the findings • Z-Score performance indicators
• Advice relating to any action required • Identifies problems with the calibration of laboratory test
• A summary of the scheme equipment
• Comments relating to inconsistent data

Quarterly Subscription
Comprises; 4 PT Scheme kits distributed over a 1 year period. Kits are
Z-scores are calculated from taking the ratio of the difference
only distributed in January, April, July and October.
between the mean and the mean test result and the test method
reproducibility standard deviation. The Z-score is an indication of
performance against the published test method precision.

4 t: +44 (0) 1932 564391 | f: +44 Stanhope-Seta,

(0) 1932 568363London Street, Chertsey, Surrey, KT16
| e: sales@stanhope-seta.co.uk 8AP, UK
| www.seta-analytics.com
t: +44 (0) 1932 564391 | e: sales@stanhope-seta.co.uk | www.seta-analytics.co.uk
 Hydrogen Sulfide
Marine Fuel Testing
Calibration & Verification Equipment

Static Calibration & Verification Kit for Sensor

(SA4001-2)
The H2S Static Calibration & Verification Kit enables users to verify and
calibrate the H2S Sensor.

This kit comprises of; traceable verification gas, regulator and

connection hose.

H2S Airflow Calibration & Verification Kit

(SA4011-0)
This kit comprises of; a calibrated flowmeter, stand and tubing. The
flowmeter is easily connected to the instrument to verify and calibrate
the air flow of the instrument.

H2S & VPP Temperature Calibration Kit (SA4019-2)

The H2S & VPP Temperature Calibration Kit allows users to easily
calibrate the temperature.

The kit consists of; a calibrated thermometer, test block and

insulation.

Technical Specification
Measurement Range: 0-250 mg/kg H2S in the liquid phase (0-250ppm H2S)
Operating Limits: 5-40c maximum (80% RH)
Viscosity Range Up to 3000 mm2/s
Principle of Measurement Advanced Electrochemical sensor
Test Duration: 25 minutes with VPP
Sample Size: 1ml, 2ml, 5ml (depending on H2S concentration
Diluent Volume: 20ml
Voltage: 12V DC, supplied with universal A/C transformer
Computer Interface: RS232
H2S Size (HxWxD)/Weight: 210 x 300 x 410 mm / 8kg
VPP Size (HxWxD)/Weight: 400 x 240 x 200 mm / 7.8kg
Voltage / Power: 100 to 250V 50/60Hz / 50W max

Ordering Information
H2S Analyser SA4000-3
H2S Vapour Phase Processor (VPP) SA4015-0
IP 570 PT Scheme Quarterly subscription SA4032-0

H2S Crude Oil Test Kit SA4021-0

Calibration & Verification

Static Calibration & Verification Kit - Sensor SA4001-2
H2S Airflow Calibration & Verification Kit SA4011-0
H2S & VPP Temperature Calibration Kit SA4019-2

t: +44 (0) 1932 564391 Stanhope-Seta, London Street, Chertsey, Surrey, KT16 8AP, UK
t: +44| (0)
f: +44
1932(0) 1932 568363
564391 | f: +44| (0)
e: sales@stanhope-seta.co.uk | www.seta-analytics.com
1932 568363 | e: sales@stanhope-seta.co.uk | www.seta-analytics.com 5
t: +44 (0) 1932 564391 | e: sales@stanhope-seta.co.uk | www.seta-analytics.co.uk