The Columnar To Equiaxed Transition in Solidification

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The Columnar to Equiaxed Transition

in Solidification

David Browne
Phase Transformation Research Group
School of Mechanical & Materials Engineering
University College Dublin

The Columnar-Equiaxed Transition 1


Advanced Materials Processing
Modes of Metal Solidification

Pure Metal Alloy


Columnar √ √
Equiaxed √ √

liquid

solid

Columnar (directional) Equiaxed (non-directional)


constrained unconstrained or free
Columnar-to-Equiaxed Transition (CET)

Grain morphology refers to the shape characteristics of individual


grains

Cast/solidified components are typically required to have a single


morphology throughout the entire macrostructure.

Several different morphologies may be present in a single


Columnar turbine
component, depending on alloy and process parameters – most blade
importantly, CET

CET can be considered a defect during casting, and thus is the


subject of continued study and investigation.

It is also important in metal alloy welding and additive manufacturing.

Fine equiaxed
grained aluminium
engine block
Mechanical and Materials Engineering - Semester I
Columnar-to-Equiaxed Transition (CET)

Different morphologies have different


associated advantages as well as
disadvantages, depending on application
Columnar Equiaxed
Columnar turbine
High toughness, blade
ductility, and
High temperature
Advantage isotropic
creep resistance
mechanical
strength

Anisotropic Low resistance to


Disadvantage mechanical creep at high
strength temperatures

Fine equiaxed
grained aluminium
engine block
Mechanical and Materials Engineering - Semester II
Columnar-to-Equiaxed Transition (CET)

CET

Equiaxed
Dendrites

Chill
H.B. Dong and P.D. Lee, Acta
Crystals Mater. 53 (2005) 659-668.

Columnar
Dendrites CET

Fully Columnar Fully Equiaxed Columnar-to-


Morphology Morphology Equiaxed Transition
Mechanical and Materials Engineering - Semester I
Al-5%Si
Superheat 100oC
Mould preheat 400oC

Al-10%Si
Superheat 150oC
Mould preheat 200oC

The Columnar-Equiaxed Transition 6


Advanced Materials Processing
The Columnar-Equiaxed Transition (CET)
For an alloy, assume the solid/liquid interface is dendritic. The “growth” undercooling is critical:
DT = TL – T*
liquidus temperature of growing s/l interface,
temperature or dendrite tip.

DT is mostly due to solutal (or constitutional) effects, i.e. for a pure metal there is very little undercooling
DT (and we can even achieve planar growth). But for alloys DT can be significant, and we usually get
columnar dendrites during directional solidification.

Directional
solidification

Let us now look at the detail of the leading


edge (tip) of one such dendrite:

7
The Columnar-Equiaxed Transition (CET)

solutal gradient

For low G, we get a large undercooled


region, in which equiaxed nuclei can
grow, which may possibly block columnar
growth, leading to CET.

T* is the tip temperature

DT(z) is solutal undercooling

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