Page 1 / 13

SAFETY DATA SHEET

_____________________________________________________________________________________________

SDS # : 080100
CERAN XM 220
Issuing date: 2016-12-30 Revision Date: 2019-07-05 Version 1.02

1. IDENTIFICATION OF THE SUBSTANCE OR MIXTURE AND OF THE SUPPLIER

Product identifier

Product name CERAN XM 220

Other means of identification

Number 4KF
Substance/mixture Mixture

Recommended use of the chemical and restrictions on use

Identified uses Lubricating grease.

Uses advised against Do not use for any purpose other than the one for which it is intended.

Details of the supplier of the safety data sheet

Supplier TOTAL LUBRIFIANTS

562 Avenue du Parc de L'ile
92029 Nanterre Cedex
FRANCE
Tel: +33 (0)1 41 35 40 00
Fax: +33 (0)1 41 35 84 71

Importer PT. Arthamas Sejahtera Mulia

Rukan Grand Aries Niaga
Jl. Taman Aries Blok E1 No.1-E
Meruya Utara, Kembangan
Jakarta 11620, Indonesia
Tel : +6221 2931 9555
Fax : +6221 2931 9229

For further information, please contact:

Contact Point HSE
E-mail Address ms.ap-sds@total.com

Emergency telephone

Indonesia: 007 803 011 0293 (toll-free in country)

Asia-Pacific: +65 3158 1074

2. HAZARDS IDENTIFICATION
Classification of the substance or mixture

Serious eye damage/eye irritation - Category 2A

Version IGHS
 Page 2 / 13

SAFETY DATA SHEET

_____________________________________________________________________________________________

SDS # : 080100
CERAN XM 220
Issuing date: 2016-12-30 Revision Date: 2019-07-05 Version 1.02

_____________________________________________________________________________________________

GHS Label elements, including precautionary statements

Signal word WARNING

Hazard Statements
H319 - Causes serious eye irritation

Precautionary Statements - Prevention

•Washf ace,handsandanyex posedskinthor
oughl
yafterhandl
i
ng
•Wearpr otect
ivegl ov
es/
prot ecti
veclothi
ng/
eyeprot
ect
ion/f
aceprot
ect
ion

Precautionary Statements - Response

•IFINEYES:Ri nsecaut i
ousl ywit
hwaterforsever
alminut
es.Remov
econt
actl
enses,i
fpr
esentandeasyt
odo.Cont
inuer
insi
ng
•Ifeyeirr
it
ati
onper sist
s:Getmedi caladvi
ce/at
tent
ion

Other hazards which do not result in classification

Physical-Chemical Properties Contaminated surfaces will be extremely slippery.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Mixture

Chemical nature Mineral oil of petroleum origin

Chemical Name CAS-No EC-No Weight %

Benzenesulfonic acid, C10-16-alkyl 68584-23-6 271-529-4 5-<10
derivs., calcium salts
Sulfonic acids, petroleum, calcium salt 61789-86-4 263-093-9 1-<3
Benzenesulfonic acid, 70024-69-0 274-263-7 1-<3
mono-C16-24-alkyl derivs., calcium
salts
Benzenesulfonic acid, C10-13-alkyl ^ 932-231-6 1-<2.5
derivs., Ca Salt
C14-16-18 Alkyl phenol ^ 931-468-2 0.1-<1

Additional information Product containing mineral oil with less than 3% DMSO extract as measured by IP 346

Version IGHS
 Page 3 / 13

SAFETY DATA SHEET

_____________________________________________________________________________________________

SDS # : 080100
CERAN XM 220
Issuing date: 2016-12-30 Revision Date: 2019-07-05 Version 1.02

_____________________________________________________________________________________________

4. FIRST AID MEASURES

Description of necessary first-aid measures

General advice IN CASE OF SERIOUS OR PERSISTENT CONDITIONS, CALL A DOCTOR OR

EMERGENCY MEDICAL CARE.

Eye contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and
continue flushing for at least 15 minutes. Keep eye wide open while rinsing.

Skin contact Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes. Wash contaminated clothing before reuse. High pressure jets may
cause skin damage. Take victim immediately to hospital.

Inhalation Remove casualty to fresh air and keep at rest in a position comfortable for breathing. If not
breathing, give artificial respiration.

Ingestion Clean mouth with water. Do NOT induce vomiting. Never give anything by mouth to an
unconscious person. Call a physician or Poison Control Center immediately.

Protection of First-aiders First aider needs to protect himself. See Section 8 for more detail. Do not use
mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial
respiration with the aid of a pocket mask equipped with a one-way valve or other proper
respiratory medical device.

Most important symptoms/effects, acute and delayed

Skin contact Not classified based on available data. May produce an allergic reaction. High pressure
injection of the products under the skin may have very serious consequences even though
no symptom or injury may be apparent.

Eye contact Causes serious eye irritation.

Inhalation Not classified based on available data. Inhalation of vapors in high concentration may
cause irritation of respiratory system.

Ingestion Not classified based on available data. Ingestion may cause gastrointestinal irritation,
nausea, vomiting and diarrhea.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media

Version IGHS
 Page 4 / 13

SAFETY DATA SHEET

_____________________________________________________________________________________________

SDS # : 080100
CERAN XM 220
Issuing date: 2016-12-30 Revision Date: 2019-07-05 Version 1.02

_____________________________________________________________________________________________

Suitable Extinguishing Media Carbon dioxide (CO 2). ABC powder. Foam. Water spray or fog.

Unsuitable Extinguishing Media Do not use a solid water stream as it may scatter and spread fire.

Specific hazards arising from the chemical

Special Hazard Incomplete combustion and thermolysis may produce gases of varying toxicity such as
carbon monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot. These may
be highly dangerous if inhaled in confined spaces or at high concentration. Combustion
products include sulphur oxides ( SO2 and SO3 ) and Hydrogen sulphide H2S, Nitrogen
oxides (NOx), Mercaptans, Silicon dioxide.

Advice for fire-fighters

Special protective equipment for Wear self-contained breathing apparatus and protective suit.
fire-fighters

Other information Cool containers / tanks with water spray. Fire residues and contaminated fire extinguishing
water must be disposed of in accordance with local regulations.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

General Information Do not touch or walk through spilled material. Contaminated surfaces will be extremely
slippery. Use personal protective equipment. Ensure adequate ventilation. Remove all
sources of ignition.

Environmental precautions

General Information Do not allow material to contaminate ground water system. Prevent entry into waterways,
sewers, basements or confined areas. Local authorities should be advised if significant
spillages cannot be contained.

Methods and material for containment and cleaning up

Methods for containment If necessary dike the product with dry earth, sand or similar non-combustible materials.

Methods for cleaning up Dispose of contents/container in accordance with local regulation. In case of soil
contamination, remove contaminated soil for remediation or disposal, in accordance with
local regulations.

Other information

Personal Protective Equipment See Section 8 for more detail.

Waste treatment See section 13.

7. HANDLING AND STORAGE

Version IGHS
 Page 5 / 13

SAFETY DATA SHEET

_____________________________________________________________________________________________

SDS # : 080100
CERAN XM 220
Issuing date: 2016-12-30 Revision Date: 2019-07-05 Version 1.02

_____________________________________________________________________________________________

Precautions for safe handling

Advice on safe handling For personal protection see section 8. Use only in well-ventilated areas. Avoid contact with
skin, eyes and clothing.

Prevention of fire and explosion Take precautionary measures against static discharges.

Hygiene measures Ensure the application of strict rules of hygiene by the personnel exposed to the risk of
contact with the product. When using, do not eat, drink or smoke. Wash hands before
breaks and immediately after handling the product. Provide regular cleaning of equipment,
work area and clothing. Do not use abrasives, solvents or fuels. Do not dry hands with rags
that have been contaminated with product. Do not put product contaminated rags into
workwear pockets.

Conditions for safe storage, including any incompatibilities

Technical measures/Storage Keep away from food, drink and animal feedingstuffs. Keep in a bunded area. Keep
conditions container tightly closed. Keep preferably in the original container. Otherwise reproduce all
indication of the regulation label on the new container. Do not remove the hazard labels of
the containers (even if they are empty). Design the installations in order to avoid accidental
emissions of product (due to seal breakage, for example) onto hot casings or electrical
contacts. Store at room temperature. Protect from moisture.

Materials to Avoid Strong oxidizing agents.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure limits Mineral oil mist:

USA: OSHA (PEL) TWA 5 mg/m3, NIOSH (REL) TWA 5 mg/m3, STEL 10 mg/m3, ACGIH
(TLV) TWA 5 mg/m3 (highly refined)

Appropriate engineering controls

Engineering Measures Apply technical measures to comply with the occupational exposure limits. Ensure
adequate ventilation, especially in confined areas. When working in confined spaces (tanks,
containers, etc.), ensure that there is a supply of air suitable for breathing and wear the
recommended equipment.

Individual protection measures, such as personal protective equipment (PPE)

Personal Protective Equipment

Version IGHS
 Page 6 / 13

SAFETY DATA SHEET

_____________________________________________________________________________________________

SDS # : 080100
CERAN XM 220
Issuing date: 2016-12-30 Revision Date: 2019-07-05 Version 1.02

_____________________________________________________________________________________________

General Information Protective engineering solutions should be implemented and in use before personal
protective equipment is considered. These recommendations apply to the product as
supplied.

Respiratory protection None under normal use conditions. When workers are facing concentrations above the
exposure limit they must use appropriate certified respirators. Respirator with combination
filter for vapour/particulate (EN 14387): Type A/P1. Warning ! filters have a limited use
duration. The use of breathing apparatus must comply strictly with the manufacturer's
instructions and the regulations governing their choices and uses.

Eye Protection Safety glasses with side-shields. EN 166.

Skin and body protection Wear suitable protective clothing. Protective shoes or boots. Long sleeved clothing. Type
4/6.

Hand Protection Hydrocarbon-proof gloves: Fluorinated rubber, Nitrile rubber. In case of prolonged contact
with the product, it is recommended to wear gloves complying with EN 420 and EN 374
standards, protecting at least for 480 minutes and having a thickness of 0,38 mm at least.
These values are indicative only. The level of protection is provided by the material of the
glove, its technical characteristics, its resistance to the chemicals to be handled, the
appropriateness of its use and its replacement frequency. Please observe the instructions
regarding permeability and breakthrough time which are provided by the supplier of the
gloves. Also take into consideration the specific local conditions under which the product is
used, such as the danger of cuts, abrasion, and the contact time.

9. PHYSICAL AND CHEMICAL PROPERTIES

General Information
Color light brown
Physical State @20°C solid
Odor Characteristic
Odor Threshold No information available

Important health safety and environmental information

Property Values Remarks Method

pH Not applicable
Melting point/range No information available

Boiling point/boiling range Not applicable

Flash point Not applicable

.

Version IGHS
 Page 7 / 13

SAFETY DATA SHEET

_____________________________________________________________________________________________

SDS # : 080100
CERAN XM 220
Issuing date: 2016-12-30 Revision Date: 2019-07-05 Version 1.02

_____________________________________________________________________________________________

Evaporation rate No information available

Flammability Limits in Air

upper No information available

Lower No information available
Vapor Pressure No information available
Vapor density No information available
Relative density 0.900 @ 20 °C
Density 900 kg/m3 @ 20 °C
Water solubility Insoluble
Solubility in other solvents No information available
logPow No information available

Autoignition temperature No information available

Decomposition temperature No information available
Viscosity, kinematic Not applicable

Explosive properties Not explosive

Oxidizing Properties Not applicable
Possibility of hazardous reactions None under normal processing

Other information
Freezing Point No information available

10. STABILITY AND REACTIVITY

Reactivity None under normal processing.

Chemical stability Stable under recommended storage conditions.

Possibility of hazardous reactions No dangerous reaction known under conditions of normal use.

Conditions to avoid Keep away from open flames, hot surfaces and sources of ignition. Keep away from heat
and sparks.

Materials to Avoid Strong oxidizing agents.

Hazardous Decomposition Products Incomplete combustion and thermolysis may produce gases of varying toxicity such as
carbon monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot. Combustion
products include sulphur oxides ( SO2 and SO3 ) and Hydrogen sulphide H2S, Mercaptans,
Nitrogen oxides (NOx), Silicon dioxide.

Version IGHS
 Page 8 / 13

SAFETY DATA SHEET

_____________________________________________________________________________________________

SDS # : 080100
CERAN XM 220
Issuing date: 2016-12-30 Revision Date: 2019-07-05 Version 1.02

_____________________________________________________________________________________________

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Inhalation Not classified based on available data. Inhalation of vapors in high concentration may
cause irritation of respiratory system.

Ingestion Not classified based on available data. Ingestion may cause gastrointestinal irritation,
nausea, vomiting and diarrhea.

Skin contact Not classified based on available data. May produce an allergic reaction. High pressure
injection of the products under the skin may have very serious consequences even though
no symptom or injury may be apparent.

Eye contact Causes serious eye irritation.

Symptoms related to the physical, chemical and toxicological characteristics

Symptoms No information available.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Acute toxicity - Product Information

Oral Not classified based on available data.

ATEmix (oral) > 5,000.00 mg/kg
0 % of the mixture consists of ingredient(s) of unknown acute oral toxicity

Dermal Not classified based on available data.

ATEmix (dermal) > 5,000.00 mg/kg
1.79 % of the mixture consists of ingredient(s) of unknown acute dermal toxicity

Inhalation Not classified based on available data.

ATEmix (inhalation-gas) > 20,000.00 ppm
12.112 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (gas)
ATEmix (inhalation-vapor) > 20.00 mg/l
12.112 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (vapor)
ATEmix (inhalation-dust/mist) 65.80 mg/l
4.364 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (dust/mist)

Acute toxicity - Component Information

Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation

Benzenesulfonic acid, C10-16-alkyl > 5000 mg/kg (Rat - OECD 401) > 5000 mg/kg bw (rabbit - OECD > 1.9 mg/l (Rat - aerosol-OECD
derivs., calcium salts 402) 403)
Sulfonic acids, petroleum, calcium > 16000 mg/kg bw (rat) > 4000 mg/kg (rabbit) LC50(4h) > 1.9 mg/l (rat - aerosol)
salt

Version IGHS
 Page 9 / 13

SAFETY DATA SHEET

_____________________________________________________________________________________________

SDS # : 080100
CERAN XM 220
Issuing date: 2016-12-30 Revision Date: 2019-07-05 Version 1.02

_____________________________________________________________________________________________

Benzenesulfonic acid, LD50 > 5000 mg/kg (Rat - OECD LD50 > 5000 mg/kg (Rabbit - OECD
mono-C16-24-alkyl derivs., calcium 401) 402)
salts
Benzenesulfonic acid, C10-13-alkyl LD50 4445 mg/kg bw (rat) LD50 2000 mg/kg bw (rat)
derivs., Ca Salt
C14-16-18 Alkyl phenol LD50 2000 mg/kg bw (rat) LD50 2000 mg/kg bw (rat)

Skin corrosion/irritation Not classified based on available data.

Serious eye damage/eye irritation Causes serious eye irritation.

Sensitization Not classified based on available data. Contains sensitizer(s). May produce an allergic
reaction. The supplier of one of the components contained within this formulation has
indicated that they have data, which confirms that at the concentration used, no
sensitisation classification is required .

Carcinogenicity Not classified based on available data.

Germ Cell Mutagenicity Not classified based on available data.

Reproductive toxicity Not classified based on available data.

Target Organ Effects (STOT) None known.

STOT - single exposure Not classified based on available data.

STOT - repeated exposure Not classified based on available data.

Aspiration hazard Not classified based on available data.

Other adverse effects Characteristic skin lesions (pimples) may develop following prolonged and repeated
exposures (contact with contaminated clothing).

12. ECOLOGICAL INFORMATION

Ecotoxicity

Not classified based on available data.

Acute aquatic toxicity - Product Information

No information available.

Acute aquatic toxicity - Component Information

Chemical Name Toxicity to algae Toxicity to daphnia and Toxicity to fish Toxicity to

Version IGHS
 Page 10 / 13

SAFETY DATA SHEET

_____________________________________________________________________________________________

SDS # : 080100
CERAN XM 220
Issuing date: 2016-12-30 Revision Date: 2019-07-05 Version 1.02

_____________________________________________________________________________________________

other aquatic invertebrates microorganisms

Benzenesulfonic acid, EL50(72h) > 1000 mg/l EL50(48h) > 1000 mg/l LL50(96h) > 10000 mg/l
C10-16-alkyl derivs., calcium (Pseudokirchneriella (Daphnia magna) (Cyprinodon variegatus -
salts subcapitata) OECD 203)
68584-23-6
Sulfonic acids, petroleum, EC50(72h) > 1000 mg/l EC50(48h) > 1000 mg/l LC50(96h) > 10000 mg/l
calcium salt (Pseudokirchnerella (Daphnia magna - OECD (Cyprinodon variegatus -
61789-86-4 subcapitata) 202) OECD 203)
Benzenesulfonic acid, EC50 (72h) > 1000 mg/l EC50 (48h) > 1000 mg/l LL50 (96h) > 10000 mg/l
mono-C16-24-alkyl derivs., (Pseudokirchnerella (Daphnia magna - static) (Cyprinodon variegatus -
calcium salts subcapitata - static) OECD 203)
70024-69-0
Benzenesulfonic acid, EC50 (96h) 29 mg/l EC50 (48 h) 2.9 mg/l LC50 (96h) >1 - <10 mg/l
C10-13-alkyl derivs., Ca Salt Pseudokirchneriella EC50 (24 h) 3.58 mg/l (OECD 203)
^ subcapitata) (Daphnia magna - OECD
202)
C14-16-18 Alkyl phenol EC50(48h) > 100 mg/l
^ (Daphnia magna - static -
OECD202)

Chronic aquatic toxicity - Product Information

No information available.

Chronic aquatic toxicity - Component Information

Chemical Name Toxicity to algae Toxicity to daphnia and Toxicity to fish Toxicity to
other aquatic invertebrates microorganisms
Benzenesulfonic acid, NOEC (96h) 500 µg/l NOEC (48h) 379 µg/l NOEC (72h) 0.23 mg/l
C10-13-alkyl derivs., Ca Salt LOEC (96h) 1 mg/l LOEC (48h) 5.6 mg/l
^ (Daphnia magna)
NOEC (21d) 1.18 mg/l

Effects on terrestrial organisms No information available.

Persistence and degradability

No information available.

Bioaccumulative potential

Product Information No information available.

logPow No information available

Component Information

Version IGHS
 Page 11 / 13

SAFETY DATA SHEET

_____________________________________________________________________________________________

SDS # : 080100
CERAN XM 220
Issuing date: 2016-12-30 Revision Date: 2019-07-05 Version 1.02

_____________________________________________________________________________________________

Mobility

Soil Given its physical and chemical characteristics, the product has no soil mobility.
Air Loss by evaporation is limited.
Water The product is insoluble and floats on water.

Other adverse effects

General Information No information available.

13. DISPOSAL CONSIDERATIONS

Waste from Residues / Unused Should not be released into the environment. Do not empty into drains. Dispose of in
Products accordance with all applicable national environmental laws and regulations.

Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or
disposal.

Other information Refer to section 8 for safety and protective measures for disposal personnel.

14. TRANSPORT INFORMATION

ADR/RID Not regulated

IMDG/IMO Not regulated

ICAO/IATA Not regulated

ADN Not regulated

15. REGULATORY INFORMATION

International Inventories All the substances contained in this product are listed or exempted from listing in the
following inventories:
Australia (AICS)
Canada (DSL/NDSL)
China (IECSC)
Europe (EINECS/ELINCS/NLP)
Japan (ENCS)
Korea (KECL)
U.S.A. (TSCA)

Version IGHS
 Page 12 / 13

SAFETY DATA SHEET

_____________________________________________________________________________________________

SDS # : 080100
CERAN XM 220
Issuing date: 2016-12-30 Revision Date: 2019-07-05 Version 1.02

_____________________________________________________________________________________________

Further information

No information available

National regulatory information

Indonesia

•Accor
dingt
oOr
derNo.04/
BIM/
PER/
1/2014

16. OTHER INFORMATION

Issuing date: 2016-12-30

Revision Date: 2019-07-05

Revision Note
No information available.

Abbreviations, acronyms
ACGIH = American Conference of Governmental Industrial Hygienists
bw = body weight
bw/day = body weight/day
EC x = Effect Concentration associated with x% response
GLP = Good Laboratory Practice
IARC = International Agency for Research of Cancer
LC50 = 50% Lethal concentration - Concentration of a chemical in air or a chemical in water which causes the death of 50% (one
half) of a group of test animals
LD50 = 50% Lethal Dose - Chemical amount, given at once, which causes the death of 50% (one half) of a group of test animals
LL = Lethal Loading
NIOSH = National Institute of Occupational Safety and Health
NOAEL = No Observed Adverse Effect Level
NOEC = No Observed Effect Concentration
NOEL = No Observed Effect Level
OECD = Organization for Economic Co-operation and Development
OSHA = Occupational Safety and Health Administration
UVCB = Substance of unknown or Variable composition, Complex reaction products or Biological material
Legend
Section 8
ACGIH - American Conference of Governmental Industrial Hygienists
TWA - Time Weight Average
STEL - Short Term Exposure Limits
S* - Skin notation Ceiling: Maximum limit value
_____________________________________________________________________________________________
This safety data sheet serves to complete but not to replace the technical product sheets. The information contained
herein is given in good faith and is accurate to the best of knowledge at the date indicated above.It is understood by the
user that any use of the product for purposes other than those for which it was designed entails potential risk.The
information given herein in no way dispenses the user from knowing and applying all provisions regulating his

Version IGHS
 Page 13 / 13

SAFETY DATA SHEET

_____________________________________________________________________________________________

SDS # : 080100
CERAN XM 220
Issuing date: 2016-12-30 Revision Date: 2019-07-05 Version 1.02

_____________________________________________________________________________________________

activity.The user bears sole liability for the precautions required when using the product.The regulatory texts indicated
herein are intended to aid the user to fulfil his obligations. This list is not to be considered complete and exhaustive.It is
the user's responsibility to ensure that he is subject to no other obligations than those mentioned.

End of the Safety Data Sheet

Version IGHS