CH 101

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CHEMISTRY DAILY PLAN

Class: Subject: Heating and Phase Change Date: Time:

Before starting chemical heat, It is necessary to repeat heating of water and phase change of water by heating or cooling. Lets draw temperature time graph of ice while we give heat to it. Lets start from minus twenty (-20) Celsius degree. Temp.
Liquid Gas Gas 1 Heating of Solid (s) 2 Phase Change (sl) 3 Heating of Liquid (l) 4 Phase Change (lg) 5 Heating of Gas (g)

Liquid

Solid Liquid

Time
Solid

Heating

Q = m

c
x

Areas 1 3 5

Q = m
Phase Change

Areas 2 4

SPECIPIC HEAT
The specific heat is the amount of heat per unit mass required to raise the temperature by one degree Celsius. The relationship between heat and temperature change is usually expressed in the form shown below where c is the specific heat. The relationship does not apply if a phase change is encountered, because the heat added or removed during a phase change does not change the temperature. cice = 0.5 cal/g, cwater = 1 cal/g

Heat of Fusion 80 cal/g Heat of Vaporization 540 cal/g

Q = m c T
heat added mass

Specific heats and molar heat capacities for various substances at 20 C c in Molar C Substance c in J/g cal/g J/mol K Aluminum 0.900 0.215 24.3 Copper 0.386 0.0923 24.5 Gold 0.126 0.0301 25.6 Lead 0.128 0.0305 26.4 Silver 0.233 0.0558 24.9 Zinc 0.387 0.0925 25.2 Mercury 0.140 0.033 28.3 Ethyl alcohol 2.4 0.58 111 Water 4.186 1.00 75.2 Ice (-10 C) 2.05 0.49 36.9

specific change in heat temperature

Problem 1: How many calories are needed to increase the temperature of 250 g ice from - 25 oC to - 5 oC? Problem 2: How many calories are needed to increase the temperature of 250 g water from 10 oC to 95 oC?

CH101

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THE PHASE CHANGES OF WATER


Water can exist in all three phases at temperatures commonly found in the atmosphere. In many instances, water changes from one phase to another. In changing from one phase to another, water either absorbs or releases energy into the air. This hidden energy is commonly referred to as latent heat. The two basic types of latent heat are as follows.

Heat of Fusion
0C
0 -100

0C

calories/gm

-200 -300 -400 -500 -600 -700

The energy required to change a gram of a substance from the solid to the liquid state without changing its temperature is commonly called it's "heat of fusion". This energy breaks down the solid bonds, but leaves a significant amount of energy associated with the intermolecular forces of the liquid state. Lf = 80 cal/g

LF 334 J/gm = 79.7 cal/gm LF=heat of fusion of water

Heat of Vaporization

The energy required to change a gram of a liquid into the gaseous state at the boiling point is called the "heat of vaporization". This energy breaks down the intermolecular attractive forces. Lv = 540 cal/g

Boiling Points and Heat of Vaporization


Substance Helium Hydrogen Nitrogen Oxygen Ethyl alcohol Mercury Water Lead Silver Gold Copper Boiling point K 4.216 20.26 77.34 90.18 351 630 373.15 2023 2466 2933 2840 Boiling point C -268.93 -252.89 -195.81 -182.97 78 357 100.00 1750 2193 2660 2567 Heat of vaporization (103 J/kg) 20.9 452 201 213 854 272 2256 871 2336 1578 5069

Melting Points and Heat of Fusion


Substance Helium Hydrogen Nitrogen Oxygen Ethyl alcohol Mercury Water Lead Silver Gold Copper Melting point K 3.5 13.84 63.18 54.36 159 234 273.15 600.5 1233.95 1336.15 1356 Melting point C -269.65 -259.31 -209.97 -218.79 -114 -39 0.00 327.3 960.80 1063.00 1083 Heat of fusion (103 J/kg) 5.23 58.6 25.5 13.8 104.2 11.8 334 24.5 88.3 64.5 134

Problem 3: 36 g of water at 80 oC is converted to steam at 100 oC. Compute the amount of heat required for this process. (cwater = 1 cal/g-oC and Lv = 540 cal/g.) Problem 4: Calculate the total amount of heat absorbed in converting 10 g of ice at -10 o C to 10 g of steam at 120 oC? (cice = 0.5 cal/g, Lf = 80 cal/g, cwater = 1 cal/g, Lv = 540 cal/g) Problem 5: What will be last temperature and phase if we give 9.2 kcal heat to 20 g ice at 20 oC? (cice = 0.5 cal/g, Lf = 80 cal/g, cwater = 1 cal/g, Lv = 540 cal/g)

CH101

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