CH 101
CH 101
CH 101
Before starting chemical heat, It is necessary to repeat heating of water and phase change of water by heating or cooling. Lets draw temperature time graph of ice while we give heat to it. Lets start from minus twenty (-20) Celsius degree. Temp.
Liquid Gas Gas 1 Heating of Solid (s) 2 Phase Change (sl) 3 Heating of Liquid (l) 4 Phase Change (lg) 5 Heating of Gas (g)
Liquid
Solid Liquid
Time
Solid
Heating
Q = m
c
x
Areas 1 3 5
Q = m
Phase Change
Areas 2 4
SPECIPIC HEAT
The specific heat is the amount of heat per unit mass required to raise the temperature by one degree Celsius. The relationship between heat and temperature change is usually expressed in the form shown below where c is the specific heat. The relationship does not apply if a phase change is encountered, because the heat added or removed during a phase change does not change the temperature. cice = 0.5 cal/g, cwater = 1 cal/g
Q = m c T
heat added mass
Specific heats and molar heat capacities for various substances at 20 C c in Molar C Substance c in J/g cal/g J/mol K Aluminum 0.900 0.215 24.3 Copper 0.386 0.0923 24.5 Gold 0.126 0.0301 25.6 Lead 0.128 0.0305 26.4 Silver 0.233 0.0558 24.9 Zinc 0.387 0.0925 25.2 Mercury 0.140 0.033 28.3 Ethyl alcohol 2.4 0.58 111 Water 4.186 1.00 75.2 Ice (-10 C) 2.05 0.49 36.9
Problem 1: How many calories are needed to increase the temperature of 250 g ice from - 25 oC to - 5 oC? Problem 2: How many calories are needed to increase the temperature of 250 g water from 10 oC to 95 oC?
CH101
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Heat of Fusion
0C
0 -100
0C
calories/gm
The energy required to change a gram of a substance from the solid to the liquid state without changing its temperature is commonly called it's "heat of fusion". This energy breaks down the solid bonds, but leaves a significant amount of energy associated with the intermolecular forces of the liquid state. Lf = 80 cal/g
Heat of Vaporization
The energy required to change a gram of a liquid into the gaseous state at the boiling point is called the "heat of vaporization". This energy breaks down the intermolecular attractive forces. Lv = 540 cal/g
Problem 3: 36 g of water at 80 oC is converted to steam at 100 oC. Compute the amount of heat required for this process. (cwater = 1 cal/g-oC and Lv = 540 cal/g.) Problem 4: Calculate the total amount of heat absorbed in converting 10 g of ice at -10 o C to 10 g of steam at 120 oC? (cice = 0.5 cal/g, Lf = 80 cal/g, cwater = 1 cal/g, Lv = 540 cal/g) Problem 5: What will be last temperature and phase if we give 9.2 kcal heat to 20 g ice at 20 oC? (cice = 0.5 cal/g, Lf = 80 cal/g, cwater = 1 cal/g, Lv = 540 cal/g)
CH101
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