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    DOMINGO

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    CyberR.Domingo

    Copyright:

    © All Rights Reserved
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    DOMINGO

    Uploaded by

    CyberR.Domingo
    17 views2 pages

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    17 views2 pages

    DOMINGO

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    CyberR.Domingo

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    © All Rights Reserved
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    of 2

    Saint Louis University

    School of Engineering and Architecture


    _____________________________________________________________________________

    CHE 3231 SOLUTION THERMODYNAMICS


    Prelims Examination 2nD Sem Ay 2021-2022
    Domingo, Cyber R.
    FULL NAME:__________________________________

    I. MODIFIED TRUE OR FALSE. Write TRUE if the statement is correct. If the


    statement is FALSE, change the underlined word/s to make the statement true. (2 pts
    each)

    Above saturated liquid curve On a T-x-y plot for a mixture, the single vapor phase exists below the
    ________________1.
    saturated liquid curve.
    True
    ________________2. On a P-x-y plot for a mixture, the pressure is constant.
    True
    ________________3. In a closed non-reacting binary system with vapor-liquid equilibrium,
    the degree of freedom F is equal to 2.
    Chemical Potenial
    ________________4. The change in the Gibbs free energy of a system when a small amount
    of component i is added to the system is indicated by the critical point.
    2
    ________________5. In the saturated vapor curve, the number of phases is equal to 1.

    II. MULTIPLE CHOICE. Write the letter of the correct answer. (1 pt each)

    B 1. Which of the following systems is/are well-modelled by Raoult’s Law?

    A. n-pentane and methanol at T = 426K


    B. n-hexane and n-pentane at 101.325 kPa
    C. Ethanol/toluene at T =65 0C
    D. All of the above systems

    C 2. Following Duhem’s theorem and Gibbs Phase Rule, if F = 2, how many more
    extensive variables have to be specified to completely determine the equilibrium state
    of the system?

    A. 0
    B. 1
    C. 2
    D. 3

    B 3. The Modified Raoult’s law is applicable to ____________ pressures.

    A. High
    B. Low to moderate
    C. Negative
    D. A and B
    Saint Louis University
    School of Engineering and Architecture
    _____________________________________________________________________________

    D 4. In the P-x1-y1 plot of a binary system (species 1 and 2), the pure-species vapor
    pressure of ____________ is located at the coordinates x1 = 0.0, y1 = 0.0.

    A. Species 1
    B. Species 2
    C. Species 1 and 2
    D. Cannot be determined

    C 5. In a binary system that follows Raoult’s law, the _________plot is linear.

    A. P-T
    B. T vs x1
    C. P vs x1
    D. B and C

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