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Safety Data Sheet

complying with Regulation 1907/2006/EC (REACH Regulation),
EU 2015/830 and Regulation No 1272/2008/EC (CLP)
Printing date 15.04.2016 Version number 1 Revision: 15.04.2016

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Trade name: GRANIT SYN SHPD PLUS 10W-40
1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
Application of the substance / the mixture: Lubricant
1.3 Details of the supplier of the safety data sheet
Manufacturer/Supplier:
LPC S.A.
Megaridos Avenue 124
Aspropyrgos - Attica , 193 00
Tel.: 210 - 809 3900
Fax: 210 - 809 3999
e-mail: technical@cyclon.gr
1.4 Emergency telephone number:

Emergency telephone number: 112

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation EC No 1272/2008 CLP:

GHS07

Eye Irrit. 2 H319 Causes serious eye irritation.

Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.
2.2 Label elements
Labelling according to Regulation EC No 1272/2008 CLP:
The product is classified and labelled according to the CLP regulation.
Hazard pictograms:

GHS07

Signal word: Warning

Hazard statements:
H319 Causes serious eye irritation.
H412 Harmful to aquatic life with long lasting effects.
(Contd. on page 2)
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Safety Data Sheet
complying with Regulation 1907/2006/EC (REACH Regulation),
EU 2015/830 and Regulation No 1272/2008/EC (CLP)
Printing date 15.04.2016 Version number 1 Revision: 15.04.2016

Trade name: GRANIT SYN SHPD PLUS 10W-40

(Contd. of page 1)

Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P273 Avoid release to the environment.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
Additional information:
EUH208 Contains Benzenesulfonic acid, mono-C16-24-alkyl derivs., calcium salts. May produce an allergic
reaction.
2.3 Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.

SECTION 3: Composition/information on ingredients

3.2 Chemical characterisation: Mixtures

Description: Mixture
Ingredients according Regulation (EU) 830/2015:
CAS: 72623-87-1 Lubricating oils (petroleum), C20-50, hydrotreated neutral 25-50%
EINECS: 276-738-4 oil-based
Index number: 649-483-00-5 Baseoil - unspecified
Asp. Tox. 1, H304
CAS: 84605-29-8 Phosphorodithioic acid, mixed esters , zinc salt 0.1-2.5%
EINECS: 283-392-8 Eye Dam. 1, H318; Aquatic Chronic 2, H411; Skin
Reg.nr.: 01-2119493626-26-XXXX Irrit. 2, H315
CAS: 70024-69-0 Benzenesulfonic acid, mono-C16-24-alkyl derivs., calcium 0.1-<1%
EINECS: 274-263-7 salts
Reg.nr.: 01-2119492616-28-ΧΧΧΧ Skin Sens. 1B, H317
CAS: 121158-58-5 Phenol, dodecyl-, branched 0.1-2.5%
EC number: 310-154-3 Repr. 2, H361f; Aquatic Acute 1, H400 (M=1); Aquatic
Reg.nr.: 01-2119513207-49-ΧΧΧΧ Chronic 1, H410 (M=10); Skin Irrit. 2, H315; Eye Irrit. 2,
H319
Ingredients
CAS: 36878-20-3 bis(nonylphenyl)amine Aquatic Chronic 4, H413 0.1-2.5%
EINECS: 253-249-4
Reg.nr.: 01-2119488911-28-XXXX
Additional information:
The classification as a carcinogen does not need to apply because the substance Lubricating oils (petroleum),
C20-50 hydrotreated neutral oil-based (cas number: 72623-87-1) contains less than 3 % DMSO extract.

SECTION 4: First aid measures

4.1 Description of first aid measures

General information: Take affected persons out into the fresh air.
(Contd. on page 3)
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Safety Data Sheet
complying with Regulation 1907/2006/EC (REACH Regulation),
EU 2015/830 and Regulation No 1272/2008/EC (CLP)
Printing date 15.04.2016 Version number 1 Revision: 15.04.2016

Trade name: GRANIT SYN SHPD PLUS 10W-40

(Contd. of page 2)
After inhalation: Seek medical treatment in case of complaints.
After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
After eye contact:
Rinse opened eye for at least 15 minutes under running water.
Seek immediate medical advice.
After swallowing:
Drink plenty of water and provide fresh air. Call for a doctor immediately.
Seek immediate medical advice.
4.2 Most important symptoms and effects, both acute and delayed Not known or expected results.
4.3 Indication of any immediate medical attention and special treatment needed
No special measures are required.

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing agents: CO2, powder or water spray. Fight larger fire with foam.
5.2 Special hazards arising from the substance or mixture
In case of fire, the following can be released:
Carbon monoxide (CO)
Carbon dioxide (CO2)
5.3 Advice for firefighters
Protective equipment:
Mouth respiratory protective device.
Wear fully protective suit.
Additional information Collect contaminated fire fighting water separately. It must not enter the sewage system.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures:

Avoid contact with oxidising agents.
Wear protective equipment. Keep unprotected persons away.
6.1.1 For non-emergency personnel
Keep away from ignition sources.
Caution for slippery surfaces.
Avoid contact with skin and eyes.
6.1.2 For emergency responders
Use chemicals resistant gloves.
Use antistatic and slip resistant boots.
6.2 Environmental precautions:
Do not allow to enter sewers/ surface or ground water.
Do not allow to penetrate the ground/soil.
Prevent from spreading (e.g. by damming-in or oil barriers).
6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust, silica gel).
6.4 Reference to other sections:
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
GB
(Contd. on page 4)

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Safety Data Sheet
complying with Regulation 1907/2006/EC (REACH Regulation),
EU 2015/830 and Regulation No 1272/2008/EC (CLP)
Printing date 15.04.2016 Version number 1 Revision: 15.04.2016

Trade name: GRANIT SYN SHPD PLUS 10W-40

(Contd. of page 3)

SECTION 7: Handling and storage

7.1 Precautions for safe handling Avoid contact with skin, eyes and clothing.
Information about fire - and explosion protection:
Keep away from sources of ignition and flammable materials.
7.2 Conditions for safe storage, including any incompatibilities
Storage: Store in cool, dry conditions in well sealed receptacles.
Requirements to be met by storerooms and receptacles:
Store in a cool location.
Prevent any seepage into the ground.
Information about storage in one common storage facility: Not required.
Further information about storage conditions: Protect from heat and direct sunlight.
7.3 Specific end use(s) No further relevant information available.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the workplace.
8.2 Exposure controls
8.2.1. Appropriate engineering controls Use of local ventilation is advised.
Personal protective equipment
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
Respiratory protection: Not required.
Protection of hands:

Protective gloves

Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a mixture of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The determined penetration times according to EN 374 part III are not performed under practical conditions.
Therefore a maximum wearing time, which corresponds to 50% of the penetration time, is recommended.
Eye protection:

Safety glasses

(Contd. on page 5)
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Safety Data Sheet
complying with Regulation 1907/2006/EC (REACH Regulation),
EU 2015/830 and Regulation No 1272/2008/EC (CLP)
Printing date 15.04.2016 Version number 1 Revision: 15.04.2016

Trade name: GRANIT SYN SHPD PLUS 10W-40

(Contd. of page 4)
Body protection:

Protective work clothing

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Colour: brown
Odour: Oil
Odour threshold: Not determined
pH value: Not determined
Melting point/Melting range: Not determined
Boiling point/Boiling range: Not determined
Flash point: 220 °C
Flammability (solid, gaseous): Not applicable
Auto-ignition temperature: Not determined
Decomposition temperature: Not determined
Self-igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined
Upper: Not determined
Vapour pressure: Not determined
Density: 0.866 g/cm³
Relative density Not determined
Vapour density Not determined
Evaporation rate Not determined
Solubility in / Miscibility with
water: Not miscible
aliphatic hydrocarbons: Fully miscible.
aromatic hydrocarbons: Fully miscible.
Partition coefficient (n-octanol/water): Not determined
Viscosity:
Dynamic: Not determined
Kinematic at 40 °C: 93,7 cSt
Kinematic viscosity at 100 °C 14 cSt
9.2 Other information No further relevant information available.
GB
(Contd. on page 6)

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Safety Data Sheet
complying with Regulation 1907/2006/EC (REACH Regulation),
EU 2015/830 and Regulation No 1272/2008/EC (CLP)
Printing date 15.04.2016 Version number 1 Revision: 15.04.2016

Trade name: GRANIT SYN SHPD PLUS 10W-40

(Contd. of page 5)

SECTION 10: Stability and reactivity

10.1 Reactivity No further relevant information available.

10.2 Chemical stability
Thermal decomposition / conditions to be avoided Stable at environment temperature.
10.3 Possibility of hazardous reactions No dangerous reactions known.
10.4 Conditions to avoid Oxidising agents
10.5 Incompatible materials No further relevant information available.
10.6 Hazardous decomposition products No dangerous decomposition products known.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity Based on available data, the classification criteria are not met.
Skin corrosion/irritation Based on available data, the classification criteria are not met.
Serious eye damage/irritation
Causes serious eye irritation.
Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
Germ cell mutagenicity Based on available data, the classification criteria are not met.
Carcinogenicity Based on available data, the classification criteria are not met.
Reproductive toxicity Based on available data, the classification criteria are not met.
STOT-single exposure Based on available data, the classification criteria are not met.
STOT-repeated exposure Based on available data, the classification criteria are not met.
Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information

12.1 Toxicity
Aquatic toxicity: No further relevant information available.
12.2 Persistence and degradability No further relevant information available.
12.3 Bioaccumulative potential No further relevant information available.
12.4 Mobility in soil No further relevant information available.
Ecotoxical effects:
Remark: Harmful to fish
Additional ecological information:
General notes:
The product contains materials that are harmful to the environment.
Harmful to aquatic organisms
12.5 Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
12.6 Other adverse effects
Uncontrolled release of the product to the environment must be prohibited.
The product floats on water and does not mix with it.
Spillage of the product may form a layer on the water surface which can damage aquatic organism due to lack of
oxygenation.
GB
(Contd. on page 7)

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Safety Data Sheet
complying with Regulation 1907/2006/EC (REACH Regulation),
EU 2015/830 and Regulation No 1272/2008/EC (CLP)
Printing date 15.04.2016 Version number 1 Revision: 15.04.2016

Trade name: GRANIT SYN SHPD PLUS 10W-40

(Contd. of page 6)

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Recommendation
In case of dicarding waste oil, according European Directive 75/439/EEC, recycling of the product is
reccomended. Disposal of large amounts must
carried out from qualified, authorized body.

Dispose according to National Regulations.

Must not be disposed together with household garbage. Do not allow product to reach sewage system.

Contact manufacturer for recycling information.

Uncleaned packaging:
Recommendation:
Disposal must be made according to official regulations.
Packaging may be reused or recycled after cleaning.

SECTION 14: Transport information

14.1 UN-Number Void
14.2 UN proper shipping name Void
14.3 Transport hazard class(es) Void
14.4 Packing group Void
14.5 Environmental hazards:
Marine pollutant: No
14.6 Special precautions for user Not applicable.
14.7 Transport in bulk according to Annex II of
Marpol and the IBC Code Not applicable.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
REACH Regulation 1907/2006/EC
Regulation (EU) 2015/830
CLP Regulation 1272/2008/EC
Directive 2012/18/EU
Named dangerous substances - ANNEX I None of the ingredients is listed.
National regulations: No further information available.
(Contd. on page 8)
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Safety Data Sheet
complying with Regulation 1907/2006/EC (REACH Regulation),
EU 2015/830 and Regulation No 1272/2008/EC (CLP)
Printing date 15.04.2016 Version number 1 Revision: 15.04.2016

Trade name: GRANIT SYN SHPD PLUS 10W-40

(Contd. of page 7)

Other regulations, limitations and prohibitive regulations

Substances of very high concern (SVHC) according to REACH, Article 57
It doesn't contain substances of very high concern (SVHC).
15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information

This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Relevant phrases
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H361f Suspected of damaging fertility.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
Abbreviations and acronyms:
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
PBT: Persistent, Bioaccumulative and Toxic
SVHC: Substances of Very High Concern
vPvB: very Persistent and very Bioaccumulative
Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2
Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1
Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2
Skin Sens. 1B: Sensitisation - Skin, Hazard Category 1B
Repr. 2: Reproductive toxicity, Hazard Category 2
Asp. Tox. 1: Aspiration hazard, Hazard Category 1
Aquatic Acute 1: Hazardous to the aquatic environment - AcuteHazard, Category 1
Aquatic Chronic 1: Hazardous to the aquatic environment - Chronic Hazard, Category 1
Aquatic Chronic 2: Hazardous to the aquatic environment - Chronic Hazard, Category 2
Aquatic Chronic 3: Hazardous to the aquatic environment - Chronic Hazard, Category 3
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