CEMENT REMOVER

Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
Date of issue: 11/10/2001 Revision date: 31/01/2020 Supersedes: 7/08/2012 Version: 10.0

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Product form : Mixtures
Product name : CEMENT REMOVER
Product code : UNIM011
Type of product : Acid cleaning product, descaling agent
Product group : Blend

1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Main use category : Industrial use,Professional use
Industrial/Professional use spec : For professional use only
Industrial
Function or use category : Cleaning/washing agents and additives
Title Use descriptors
X
SU3, PC35, PROC5, ERC2

Full text of use descriptors: see section 16

1.2.2. Uses advised against

No additional information available

1.3. Details of the supplier of the safety data sheet

UNIMARINE SERVICES INC.
60 MARKET SQUARE
BELIZE CITY
T +35725331054
info@unimarine-services.com

1.4. Emergency telephone number

Emergency number : +35725331054

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures: SDS < 2015 : Show CLP information only
Skin corrosion/irritation, Category 1B H314
Serious eye damage/eye irritation, Category 1 H318
Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation H335
Full text of H statements : see section 16

Adverse physicochemical, human health and environmental effects

May cause respiratory irritation. Causes severe skin burns and eye damage. Causes serious eye damage.

2.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display
Hazard pictograms (CLP) :

GHS05 GHS07
Signal word (CLP) : Danger
Hazardous ingredients : Phosphoric acid; Hydrochloric acid
Hazard statements (CLP) : H314 - Causes severe skin burns and eye damage
H335 - May cause respiratory irritation
Precautionary statements (CLP) : P260 - Do not breathe vapours
P280 - Wear eye protection, protective clothing, protective gloves
P301+P330+P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting
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CEMENT REMOVER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water/shower
P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing

2.3. Other hazards

No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substances
Not applicable

3.2. Mixtures

Name Product identifier % Classification according to Classification according to

Directive 67/548/EEC Regulation (EC) No.
1272/2008 [CLP]
Citric acid monohydrate (CAS No) 5949-29-1 15 - 30 Xi; R36 Eye Irrit. 2, H319
(EC No) 201-069-1
(REACH-no) 01-
2119457026-42
Phosphoric acid (CAS No) 7664-38-2 15 - 20 C; R34 Skin Corr. 1B, H314
(EC No) 231-633-2 Eye Dam. 1, H318
(EC Index No) 015-011-00-
6
(REACH-no) 01-
2119485924-24
Hydrochloric acid (CAS No) 7647-01-0 5 - 10 C; R34 Skin Corr. 1B, H314
(EC No) 231-595-7;231- Xi; R37 Eye Dam. 1, H318
596-7 STOT SE 3, H335
(EC Index No) 017-002-01-
X
(REACH-no) 01-
2119484862-27

Full text of R- and H-statements: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures
First-aid measures general : If medical advice is needed, have product container or label at hand.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Call a poison center or a
doctor if you feel unwell.
First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Call a
physician immediately.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. Call a physician immediately.
First-aid measures after ingestion : Rinse mouth. Do not induce vomiting. Call a physician immediately.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation : May cause respiratory irritation.
Symptoms/injuries after skin contact : Burns.
Symptoms/injuries after eye contact : Serious damage to eyes.
Symptoms/injuries after ingestion : Burns or irritation of the linings of the mouth, throat, and gastrointestinal tract.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1. Extinguishing media
Suitable extinguishing media : carbon dioxide (CO2), foam, water spray, powder.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Not flammable.
Hazardous decomposition products in case of : Corrosive vapours. Chlorine.
fire
5.3. Advice for firefighters
Precautionary measures fire : Evacuate area.

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CEMENT REMOVER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

Firefighting instructions : Exercise caution when fighting any chemical fire.

Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
No additional information available
6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. For further information
refer to section 8: "Exposure controls/personal protection".
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Take up liquid spill into absorbent material.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
For further information refer to section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Precautions for safe handling : Use only outdoors or in a well-ventilated area. Avoid contact with skin and eyes. Do not breathe
vapours. Wear personal protective equipment.
Hygiene measures : Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product.
Always wash hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Store locked up. Store in a well-ventilated place. Keep container closed when not in use. Keep
cool.
Incompatible materials : aluminium. Metals.
7.3. Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Phosphoric acid (7664-38-2)
EU Local name Orthophosphoric acid
EU IOELV TWA (mg/m³) 1 mg/m³
EU IOELV STEL (mg/m³) 2 mg/m³
Belgium Local name Acide phosphorique
Belgium Limit value (mg/m³) 1 mg/m³
Belgium Short time value (mg/m³) 2 mg/m³
Germany Local name Orthophosphorsäure
Germany TRGS 900 Occupational exposure limit value (mg/m³) 2 mg/m³
Germany Remark (TRGS 900) DFG,EU,AGS,Y
Italy Local name Acido ortofosforico
Italy OEL TWA (mg/m³) 1 mg/m³
Italy OEL STEL (mg/m³) 2 mg/m³
Netherlands Local name Fosforzuur
Netherlands Grenswaarde TGG 8H (mg/m³) 1 mg/m³
Netherlands Grenswaarde TGG 15MIN (mg/m³) 2 mg/m³
Spain Local name Ácido ortofosfórico
Spain VLA-ED (mg/m³) 1 mg/m³
Spain VLA-EC (mg/m³) 2 mg/m³

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CEMENT REMOVER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

Phosphoric acid (7664-38-2)

Spain Notes VLI (Agente químico para el que la U.E. estableció en
su día un valor límite indicativo. Todos estos agentes
químicos figuran al menos en una de las directivas de
valores límite indicativos publicadas hasta ahora (ver
Anexo C. Bibliografía). Los estados miembros
disponen de un tiempo fijado en dichas directivas para
su transposición a los valores límites de cada país
miembro. Una vez adoptados,estos valores tienen la
misma validez que el resto de los valores adoptados
por el país.), s (Esta sustancia tiene prohibida total o
parcialmente su comercialización y uso como
fitosanitario y/o como biocida. Para unainformación
detallada acerca de las prohibiciones consúltese:Base
de datos de productos
biocidas:htthttp://www.msssi.gob.es/ciudadanos/produ
ctos.do?tipo=plaguicidasBase de datos de productos
fitosanitarios:http://www.magrama.gob.es/agricultura/p
ags/fitos/registro/fichas/pdf/Lista_sa.pdf)
Hydrochloric acid (7647-01-0)
EU Local name Hydrogen chloride
EU IOELV TWA (mg/m³) 8 mg/m³
EU IOELV TWA (ppm) 5 ppm
EU IOELV STEL (mg/m³) 15 mg/m³
EU IOELV STEL (ppm) 10 ppm
Belgium Local name Hydrogène (chlorure d’) # Waterstofchloride
Belgium Limit value (mg/m³) 8 mg/m³
Belgium Limit value (ppm) 5 ppm
Belgium Short time value (mg/m³) 15 mg/m³
Belgium Short time value (ppm) 10 ppm
France Local name Chlorure d'hydrogène (Acide chlorhydrique)
France VLE (mg/m³) 7,6 mg/m³
France VLE (ppm) 5 ppm
France Note (FR) Valeurs règlementaires contraignantes
Germany Local name Hydrogenchlorid
Germany TRGS 900 Occupational exposure limit value (mg/m³) 3 mg/m³
Germany TRGS 900 Occupational exposure limit value (ppm) 2 ppm
Germany Remark (TRGS 900) DFG,EU,Y
Italy Local name Acido cloridrico
Italy OEL TWA (mg/m³) 8 mg/m³
Italy OEL TWA (ppm) 5 ppm
Italy OEL STEL (mg/m³) 15 mg/m³
Italy OEL STEL (ppm) 10 ppm
Spain Local name Cloruro de hidrógeno
Spain VLA-ED (mg/m³) 7,6 mg/m³
Spain VLA-ED (ppm) 5 ppm
Spain VLA-EC (mg/m³) 15 mg/m³
Spain VLA-EC (ppm) 10 ppm
Spain Notes VLI (Agente químico para el que la U.E. estableció en
su día un valor límite indicativo. Todos estos agentes
químicos figuran al menos en una de las directivas de
valores límite indicativos publicadas hasta ahora (ver
Anexo C. Bibliografía). Los estados miembros
disponen de un tiempo fijado en dichas directivas para
su transposición a los valores límites de cada país
miembro. Una vez adoptados, estos valores tienen la
misma validez que el resto de los valores adoptados
por el país).

8.2. Exposure controls

Appropriate engineering controls:
Ensure good ventilation of the work station.

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CEMENT REMOVER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

Hand protection:
protective gloves

Eye protection:
Safety glasses

Skin and body protection:

Wear suitable protective clothing

Respiratory protection:
In case of insufficient ventilation, wear suitable respiratory equipment

Environmental exposure controls:

Avoid release to the environment.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Clear.
Colour : Colourless.
Odour : Acidic.
Odour threshold : No data available
pH : 1-2
Relative evaporation rate (butylacetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : Not applicable
Vapour pressure : No data available
Relative vapour density at 20 °C : No data available
Relative density : No data available
Density : 1,05 - 1,15
Solubility : Soluble in water.
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2. Other information
No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity
Reacts exothermically with (some) bases.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
May react with bases, copper, silver, mercury, magnesium, zinc and their alloys.
10.4. Conditions to avoid
Overheating.
10.5. Incompatible materials
aluminium. metals (e.g. cupper, brass).

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CEMENT REMOVER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

10.6. Hazardous decomposition products

Chlorine.

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Acute toxicity : Not classified

Citric acid monohydrate (5949-29-1)

LD50 oral rat 3000 mg/kg
Skin corrosion/irritation : Causes severe skin burns and eye damage.
pH: 1 - 2
Serious eye damage/irritation : Causes serious eye damage.
pH: 1 - 2
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
STOT-single exposure : May cause respiratory irritation.
STOT-repeated exposure : Not classified
Aspiration hazard : Not classified

SECTION 12: Ecological information

12.1. Toxicity
Ecology - general : Before neutralisation, the product may represent a danger to aquatic organisms.

Citric acid monohydrate (5949-29-1)

LC50 fish 1 440 - 760 mg/l Leucicus idus 96 h
EC50 Daphnia 1 120 mg/l 72 h
EC50 other aquatic organisms 1 > 100000 mg/l Micro-organisme-Pseudomonas putida 16 h

12.2. Persistence and degradability

CEMENT REMOVER
Persistence and degradability This surfactant complies with the biodegradability criteria as laid down in Regulation (EC)
No.648/2004 on detergents. Data to support this assertion are held at the disposal of the
competent authorities of the Member States and will be made available to them, at their direct
request or at the request of a detergent manufacturer.

12.3. Bioaccumulative potential

Citric acid monohydrate (5949-29-1)
Log Pow -1,67
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
No additional information available

12.6. Other adverse effects

No additional information available

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Regional legislation (waste) : Disposal must be done according to official regulations.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN

14.1. UN number
UN-No. (ADR) : 3264
UN-No. (IMDG) : 3264
UN-No. (IATA) : 3264
UN-No. (ADN) : 3264

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CEMENT REMOVER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

UN-No. (RID) : 3264

14.2. UN proper shipping name
Proper Shipping Name (ADR) : CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.
Proper Shipping Name (IMDG) : CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.
Proper Shipping Name (IATA) : Corrosive liquid, acidic, inorganic, n.o.s.
Proper Shipping Name (ADN) : CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.
Proper Shipping Name (RID) : CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.
Transport document description (ADR) : UN 3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Phosphoric acid, Hydrochloric
acid), 8, III, (E)
Transport document description (IMDG) : UN 3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., 8, III
Transport document description (IATA) : UN 3264 Corrosive liquid, acidic, inorganic, n.o.s., 8, III
Transport document description (ADN) : UN 3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., 8, III
Transport document description (RID) : UN 3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., 8, III
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) (ADR) : 8
Danger labels (ADR) : 8

IMDG
Transport hazard class(es) (IMDG) : 8
Danger labels (IMDG) : 8

IATA
Transport hazard class(es) (IATA) : 8
Hazard labels (IATA) : 8

ADN
Transport hazard class(es) (ADN) : 8
Danger labels (ADN) : 8

RID
Transport hazard class(es) (RID) : 8
Danger labels (RID) : 8

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CEMENT REMOVER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

14.4. Packing group

Packing group (ADR) : III
Packing group (IMDG) : III
Packing group (IATA) : III
Packing group (ADN) : III
Packing group (RID) : III
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available

14.6. Special precautions for user

- Overland transport
Classification code (ADR) : C1
Special provisions (ADR) : 274
Limited quantities (ADR) : 5l
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P001, IBC03, LP01, R001
Mixed packing provisions (ADR) : MP19
Portable tank and bulk container instructions : T7
(ADR)
Portable tank and bulk container special : TP1, TP28
provisions (ADR)
Tank code (ADR) : L4BN
Vehicle for tank carriage : AT
Transport category (ADR) : 3
Special provisions for carriage - Packages : V12
(ADR)
Hazard identification number (Kemler No.) : 80
Orange plates :

Tunnel restriction code (ADR) : E

EAC code : 2X
APP code : B

- Transport by sea
Special provisions (IMDG) : 223, 274
Limited quantities (IMDG) : 5L
Excepted quantities (IMDG) : E1
Packing instructions (IMDG) : P001, LP01
IBC packing instructions (IMDG) : IBC03
Tank instructions (IMDG) : T7
Tank special provisions (IMDG) : TP1, TP28
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-B
Stowage category (IMDG) : A
Properties and observations (IMDG) : Causes burns to skin, eyes and mucous membranes.
MFAG-No : 154

- Air transport
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y841
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CEMENT REMOVER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

PCA limited quantity max net quantity (IATA) : 1L

PCA packing instructions (IATA) : 852
PCA max net quantity (IATA) : 5L
CAO packing instructions (IATA) : 856
CAO max net quantity (IATA) : 60L
Special provisions (IATA) : A3
ERG code (IATA) : 8L

- Inland waterway transport

Classification code (ADN) : C1
Special provisions (ADN) : 274
Limited quantities (ADN) : 5L
Excepted quantities (ADN) : E1
Carriage permitted (ADN) : T
Equipment required (ADN) : PP, EP
Number of blue cones/lights (ADN) : 0

- Rail transport
Classification code (RID) : C1
Special provisions (RID) : 274
Limited quantities (RID) : 5L
Excepted quantities (RID) : E1
Packing instructions (RID) : P001, IBC03, LP01, R001
Mixed packing provisions (RID) : MP19
Portable tank and bulk container instructions : T7
(RID)
Portable tank and bulk container special : TP1, TP28
provisions (RID)
Tank codes for RID tanks (RID) : L4BN
Transport category (RID) : 3
Special provisions for carriage – Packages : W12
(RID)
Colis express (express parcels) (RID) : CE8
Hazard identification number (RID) : 80
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations

Contains no REACH substances with Annex XVII restrictions

Contains no substance on the REACH candidate list
Contains no REACH Annex XIV substances

15.1.2. National regulations

Germany
VwVwS Annex reference : Water hazard class (WGK) 1, low hazard to waters (Classification according to VwVwS, Annex
4)
12th Ordinance Implementing the Federal : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Immission Control Act - 12.BImSchV

Netherlands
SZW-lijst van kankerverwekkende stoffen : None of the components are listed
SZW-lijst van mutagene stoffen : None of the components are listed
NIET-limitatieve lijst van voor de voortplanting : None of the components are listed
giftige stoffen – Borstvoeding
NIET-limitatieve lijst van voor de voortplanting : None of the components are listed
giftige stoffen – Vruchtbaarheid
NIET-limitatieve lijst van voor de voortplanting : None of the components are listed
giftige stoffen – Ontwikkeling
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CEMENT REMOVER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product

15.2. Chemical safety assessment

No additional information available

SECTION 16: Other information

Full text of R-, H- and EUH-statements:

Eye Dam. 1 Serious eye damage/eye irritation, Category 1
Eye Irrit. 2 Serious eye damage/eye irritation, Category 2
Skin Corr. 1B Skin corrosion/irritation, Category 1B
STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H319 Causes serious eye irritation
H335 May cause respiratory irritation
R34 Causes burns
R36 Irritating to eyes
R37 Irritating to respiratory system
C Corrosive
Xi Irritant
ERC2 Formulation of preparations
PC35 Washing and cleaning products (including solvent based products)
PROC5 Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or
significant contact)
SU3 Industrial uses: Uses of substances as such or in preparations* at industrial sites

SDS EU (REACH Annex II)

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product

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