Conforms to Regulation (EC) No.

1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU)

2015/830 - Europe

SAFETY DATA SHEET

PERBUNAN 3445 F
06427251
SECTION 1: Identification of the substance/mixture and of the company/
undertaking
1.1 Product identifier
Product name : PERBUNAN 3445 F
1.2 Relevant identified uses of the substance or mixture and uses advised against
Suitable uses : crude product for the production of technical rubber articles
1.3 Details of the supplier of the safety data sheet
Supplier : ARLANXEO Deutschland GmbH
Alte Heerstraße 2
41540 Dormagen / Germany

Telephone: +49 221 8885 2288

E-mail: infosds@arlanxeo.com
1.4 Emergency telephone number
Telephone number : +49 214 30 99300 (Sicherheitszentrale CHEMPARK Leverkusen)

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification : Not classified.

2.2 Label elements

Hazard pictograms : Not applicable.
Signal word : No signal word.
Hazard statements : No known significant effects or critical hazards.
Precautionary statements
Prevention : Not applicable.
Response : Not applicable.
Storage : Not applicable.
Disposal : Not applicable.
2.3 Other hazards
Other hazards which do : None known.
not result in classification

SECTION 3: Composition/information on ingredients

Product definition (REACH) : Polymer
butadiene-acrylonitrile-rubber (NBR). CAS No.: 9003-18-3
Within the present knowledge of the supplier, this product does not contain any hazardous ingredients in
quantities requiring reporting in this section, in accordance with EU or national regulations.
Occupational exposure limits, if available, are listed in Section 8.

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SECTION 4: First aid measures

4.1 Description of first aid measures
Skin contact : Get medical attention if irritation develops.
Eye contact : Get medical attention if irritation occurs.
4.2 Most important symptoms and effects, both acute and delayed
See Section 11 for more detailed information on health effects and symptoms.
4.3 Indication of any immediate medical attention and special treatment needed
See Section 11 for more detailed information on health effects and symptoms.

SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing : In case of fire, use water spray (fog), foam, dry chemical or CO₂.
media
Unsuitable extinguishing : None known.
media

5.2 Special hazards arising from the substance or mixture

Hazards from the : No specific fire or explosion hazard.
substance or mixture
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
nitrogen oxides

5.3 Advice for firefighters

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves)
conforming to European standard EN 469 will provide a basic level of protection for
chemical incidents.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency : No special measures required.
personnel
For emergency responders : No special measures required.

6.2 Environmental : No special measures required.

precautions

6.3 Methods and material for containment and cleaning up

Small spill : Take up mechanically.
Large spill : Take up mechanically.

6.4 Reference to other : See Section 1 for emergency contact information.

sections See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

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SECTION 7: Handling and storage

7.1 Precautions for safe handling
Protective measures : Provided good ventilation and/or local exhaust systems are used, the Occupational
Exposure Limit(s) stated in Chapter 8 should not be exceeded.

Avoid inhaling vapours. Avoid inhaling dust. Grease skin. Wash hands, forearms
and face thoroughly after handling compounds and before eating, smoking and using
the lavatory and at the end of the day. When using do not eat, drink or smoke.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment
before entering eating areas. See also Section 8 for additional information on
hygiene measures.

7.2 Conditions for safe storage, including any incompatibilities

Conditions for safe : Do not store above the following temperature: 35°C (95°F). Store in a dry place.
storage, including any
incompatibilities

7.3 Specific end use(s)

Recommendations : Not available.
Industrial sector specific : Not available.
solutions
Remarks : Keep away from direct sunlight or strong incandescent light.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
Exposure limit values : Not available. Polymer.

acrylonitrile, 1,3-butadiene:
No workplace limit value(OEL) fixed. Additional protective measures must be complied with, in particular:
- Measurements for the early detection of increased exposure as a result of an unforeseen incident;
- Cordoning off of the hazardous areas and display of warning and hazard signs, including a sign saying "Smoking
prohibited", in areas where exposure is possible;
- Extracted air must not be returned to the system without being treated first.

Recommended monitoring : If this product contains ingredients with exposure limits, personal,
procedures workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control
measures and/or the necessity to use respiratory protective
equipment. Reference should be made to monitoring standards,
such as the following: European Standard EN 689 (Workplace
atmospheres - Guidance for the assessment of exposure by
inhalation to chemical agents for comparison with limit values and
measurement strategy) European Standard EN 14042 (Workplace
atmospheres - Guide for the application and use of procedures for
the assessment of exposure to chemical and biological agents)
European Standard EN 482 (Workplace atmospheres - General
requirements for the performance of procedures for the
measurement of chemical agents) Reference to national guidance
documents for methods for the determination of hazardous
substances will also be required.
8.2 Exposure controls
Appropriate engineering : Use process enclosures, local exhaust ventilation or other engineering controls to
controls keep airborne levels below recommended exposure limits. If user operations
generate dust, fumes or mist, use ventilation to keep exposure to airborne
contaminants below the exposure limit.
Individual protection measures

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SECTION 8: Exposure controls/personal protection

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Eye/face protection : Protective goggles with side shield or tightly fitting protective goggles
Skin protection
Hand protection : Protective gloves of leather, contaminated or damaged gloves should be replaced.
Other skin protection : Skin covering working clothes; wear dust-proof overalls if large quantities of dust are
generated.
Respiratory protection : In case of dust formation use respiratory equipment with filter type particle filter P1
according to DIN EN 143.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Appearance
Physical state : Solid. [rubber bales]
Colour : Beige. [Light]
Odour : Aromatic. [Slight]
Odour threshold : Not available.
pH : Not available.
Melting point : Not available.
Boiling point : Not available.
Flash point : Not available.
Burning time : Not available.
Burning rate : Not available.
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive : Not available.
(flammable) limits
Vapour pressure : Not available.
Vapour density : Not available.
Density : 0,97 kg/L (20℃)
Relative density : Not available.
Solubility in water : Insoluble in the following materials: cold water
Ignition temperature : >200°C
Partition coefficient: n-octanol/ : Not available.
water
Auto-ignition temperature : Not available.
Decomposition temperature : >200°C (>392°F)
Viscosity : Not available.
Explosive properties : Not available.
Oxidising properties : Not available.
9.2 Other information
No additional information.

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SECTION 10: Stability and reactivity

10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.

10.2 Chemical stability : The product is stable.

10.3 Possibility of : Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions

10.4 Conditions to avoid : No hazardous reactions when used as directed.

10.5 Incompatible materials : No specific data.

10.6 Hazardous : Under normal conditions of storage and use, hazardous decomposition products
decomposition products should not be produced. Caused by smouldering and incomplete combustion toxic
fumes mainly consisting of CO and CO2 may be developed. Degradation products of
the polymers and their additives may also be formed.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Under the recommended processing conditions small amounts of emitted substance (e.g. residual monomers, residual
solvents, decomposition products) may be discharged. According to our experience and information the product has
no harmful effects on health if properly handled.

Potential acute health effects

Eye contact : No known significant effects or critical hazards.
Inhalation : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.

Delayed and immediate effects as well as chronic effects from short and long-term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.

Other information : Not available.

SECTION 12: Ecological information

The product is practically insoluble in water. In view of its consistency and insolubility in water, no ecological problems
are to be expected if the product is properly handled. This product is not readily biodegradable.
12.1 Toxicity
Conclusion/Summary : Not available.

12.2 Persistence and degradability

Conclusion/Summary : Not available.

12.3 Bioaccumulative potential

Not available.

12.4 Mobility in soil

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SECTION 12: Ecological information

Soil/water partition : Not available.
coefficient (KOC)
Mobility : Not available.

12.5 Results of PBT and vPvB assessment

PBT : Not applicable.
vPvB : Not applicable.

12.6 Other adverse effects

Other adverse effects : No known significant effects or critical hazards.
AOX : Not available.

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product
Methods of disposal : The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation and
any regional local authority requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste should not be disposed of
untreated to the sewer unless fully compliant with the requirements of all authorities
with jurisdiction.
Hazardous waste : Within the present knowledge of the supplier, this product is not regarded as
hazardous waste, as defined by EU Directive 2008/98/EC.
Packaging
Methods of disposal
: The generation of waste should be avoided or minimised wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible.
Special precautions : This material and its container must be disposed of in a safe way. Empty containers
or liners may retain some product residues. Avoid dispersal of spilt material and
runoff and contact with soil, waterways, drains and sewers.

SECTION 14: Transport information

ADR/RID ADN IMDG IATA
14.1 UN number - - - -

14.2 UN proper - - - -
shipping name
14.3 Transport - - - -
hazard class(es)/ - - - -
Marks

14.4 Packing group - - - -

14.5 No. No. No No
Environmental
hazards
14.6 Special Not regulated. Not regulated. Not regulated. Not regulated.
precautions for
user/Additional
information

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SECTION 14: Transport information

14.7 Transport in bulk according to Annex : Not available.
II of Marpol and the IBC Code
Hazard notes:
Not dangerous cargo.
Keep separated from foodstuffs.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH)
Annex XIV - List of substances subject to authorisation
Annex XIV
None of the components are listed.
Substances of very high concern
None of the components are listed.
Other EU regulations
Seveso Directive
This product is not controlled under the Seveso III Directive.

15.2 Chemical safety : Not applicable.

assessment

SECTION 16: Other information

Indicates information that has changed from previously issued version.
Abbreviations and acronyms : ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.
1272/2008]
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
PBT = Persistent, Bioaccumulative and Toxic
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
vPvB = Very Persistent and Very Bioaccumulative
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification Justification
Not classified.

Full text of abbreviated H statements

Not applicable.

Full text of classifications [CLP/GHS]

Not applicable.

History
Date of issue : 2016-11-29
Date of previous issue : 2013-10-30
Version : 5
Notice to reader
The data given here is based on current knowledge and experience. The purpose of this Safety Data Sheet and
its Annex [if required according to Regulation (EC) 1907/2006 (REACh)] is to describe the products in terms of
their safety requirements. The given details do not imply any guarantee concerning the composition, properties
or performance.

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