CBSE Physics Class 12

Sample Paper 3 Page 1

CBSE Sample Paper 3

Class XII 2022-23
Chemistry
Time: 3 Hours Max. Marks: 70
General Instructions:
1. There are 35 questions in this question paper with internal choice.
2. SECTION A consists of 18 multiple-choice questions carrying 1 mark each.
3. SECTION B consists of 7 very short answer questions carrying 2 marks each.
4. SECTION C consists of 5 short answer questions carrying 3 marks each.
5. SECTION D consists of 2 case-based questions carrying 4 marks each.
6. SECTION E consists of 3 long answer questions carrying 5 marks each.
7. All questions are compulsory.
8. Use of log tables and calculators is not allowed.

SECTION-A

Directions (Q.Nos.1-18) : The following questions are multiple-choice questions with one correct answer.
Each question carries 1 mark. There is no internal choice in this section.

1. Electrolytic reduction of nitrobenzene in strongly acidic medium gives the final product:
(a) p -aminophenol (b) azobenzene
(c) aniline (d) phenyl hydroxyl amine

2. In reaction A $ B , the rate of reaction is doubled on increasing the concentration of the

reactants four times. The order of the reaction is :
(a) 12 (b) 2
(c) 4 (d) Zero

3. Which of the following does not reduce Fehling’s solution?

(a) CH3CHO (b) HCHO
(c) CH3COOH (d) HCOOH

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Page 2 Sample Paper 3 CBSE Physics Class 12

4. Metallic radii of some transition elements are given below:

Element Fe Co Ni Cu
Metallic radii/pm 126 125 125 128
Which of these elements will have highest density ?
(a) Cu (b) Fe
(c) Ni (d) Co

5. Consider the following reaction:

1. HBr
CH 3 − CH = CH 2 2. aq. KOH

The major end product is :

(a) CH 3 - CH - CH 3 (b) CH 3 - CH - CH 3
; ;
Br OH
(c) CH 3 - CH 2 - CH 2 - Br (d) CH 3 - CH 2 - CH 2 - OH

6. Williamson’s synthesis of preparing dimethyl ether is an :

(a) SN2 reaction
(b) SN1 reaction
(c) Elimination reaction
(d) Nucleophilic addition reaction

7. The molar conductivity of KCl solutions at different concentrations at 298 K is shown in the
graph:

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CBSE Physics Class 12 Sample Paper 3 Page 3

Determine the value of /c m for KCl using the graph.

(a) 151.2 S cm2 mol–1 (b) 149.9 S cm2 moL–1
(c) 150.0 S cm2 mol–1 (d) 152.0 S cm2 mol–1

8. The reaction between RNH2 + CHCl3 + KOH (alc.) is known as:

(a) Coupling reaction (b) Carbylamine reaction
(c) Hoffmann bromamide reaction (d) Schmidt reaction

9. How much ethyl alcohol must be added to 1L of water so that the solution will freeze at –14°C?
( K f for water = 1.86°C/mol)
(a) 10.5 mol (b) 9.5 mol
(c) 7.5 mol (d) 8.5 mol

10. The value of rate constant for a first order reaction is 2.303 # 10-2 s-1 . What will be the time
required to reduce the concentration to 1/10th of its initial concentration ?
(a) 10 s (b) 2303 s
(c) 23.03 s (d) 100 s

11. Long time nitration of phenol with mixture of conc. HNO3 and concentrated H2SO4 gives:
(a) picric acid (b) o -nitrophenol
(c) nitrobenzene (d) p -nitrophenol

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12. Which of the following energy level diagram for [FeF6]3– is correct on the basis of crystal field
theory?

13. According to Arrhenius equation rate constant k is equal to Ae-E /RT . Which of the following
a

options represents the graph of ln k vsT1 ?

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14. In the reaction

Compound Y is :

Directions (Q. Nos. 15-18) : Each of the following questions consists of two statements, one is Assertion
and the other is Reason. Give answer:

15. Assertion : (CH3)3COH when heated with conc. H2SO4 gives iso-butylene as the main product
and not di-tertiary butyl ether.
Reason : All alcohols readily dehydrates with conc. H2SO4.
(a) Both Assertion and Reason are true but Reason is not the correct explanation of Assertion.
(b) Both Assertion and Reason are true and Reason is the correct explanation of Assertion.
(c) Assertion is false but Reason is true.
(d) Assertion is true but Reason is false.

16. Assertion : In presence of enzyme, substrate molecule can be attacked by the reagent effectively.
Reason : Active sites of enzymes hold the substrate molecule in a suitable position.
(a) Both Assertion and Reason are true but Reason is not the correct explanation of Assertion.
(b) Both Assertion and Reason are true and Reason is the correct explanation of Assertion.
(c) Assertion is false but Reason is true.
(d) Assertion is true but Reason is false.

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17. Assertion : Cu cannot liberate hydrogen from acids.

Reason : Cu has positive electrode potential.
(a) Both Assertion and Reason are true but Reason is not the correct explanation of Assertion.
(b) Both Assertion and Reason are true and Reason is the correct explanation of Assertion.
(c) Assertion is false but Reason is true.
(d) Assertion is true but Reason is false.

18. Assertion : Hoffmann’s bromamide reaction is given by primary amines.

Reason : Primary amines are more basic than secondary amines.
(a) Both Assertion and Reason are true but Reason is not the correct explanation of Assertion.
(b) Both Assertion and Reason are true and Reason is the correct explanation of Assertion.
(c) Assertion is false but Reason is true.
(d) Assertion is true but Reason is false.

SECTION-B

Directions (Q. Nos. 19-25) : This section contains 7 questions with internal choice in two questions. The
following questions are very short answer type and carry 2 marks each.

19. [Fe(CN)6]4– and [Fe(H2O)6]2– are of different colours in dilute solutions. Why?


o
Using IUPAC norms, write the formula for the following :
(i) Sodium dicyanidoaurate(I)
(ii) Tetraamminechtoridonitrito-N-platinum(IV) sulphate.

20. Propose the mechanism of the reaction taking place when :

(i) (–)-2-Bromooctane reacts with sodium hydroxide to form (+)-Octane-2-ol.
(ii) 2-Bromopentane is heated with KOH(alc.) to form alkene.

21. HgO decomposes on heating but MgO does not. Explain with reason.

22. For the reaction 2N 2 O 5 (g) $ 4NO 2 (g) + O 2 (g),

the rate of formation of NO2(g) is 2.8 # 10-3 M s-1 . Calculate the rate of disappearance of N2O5(g).

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CBSE Physics Class 12 Sample Paper 3 Page 7

o
What do you mean by rate of a reaction? For the reaction NO 2 (g) + CO (g) $ CO 2 (g) + NO (g),
the proposed mechanism is as follows :
(i) NO 2 + NO 2 $ NO + NO 3 (slow)
(ii) NO 3 + CO $ CO 2 + NO 2 (fast)
What is the velocity (rate) of reaction?

23. Write the structures of A, B, C and D in the following reactions :

H 2 /Pd − BaSO 4 NaOH (conc.) CH 3 MgBr/H 3 O+
C 6 H 5 COCl [A ] B+C [D ]
Benzoyl chloride

24. In a reaction 2N 2 O 5 (g) $ 4NO 2 (g) + O 2 (g), the concentration of N2O5 decreases from 0.5 mol L–1
to 0.4 mol L–1 in 10 minutes, Calculate the average rate of this reaction and rate of production
of NO2 during this period.

25. What is the effect of denaturation on the structure of proteins?

SECTION-C

Directions (Q. Nos. 26-30) : This section contains 5 questions with internal choice in two questions. The
following questions are short answer type and carry 3 marks each.

26. The following compounds are given to you :

2-Bromopentane, 2-Bromo-2-methylbutane, 1- Bromopentane
(i) Write the compound which is most reactive towards SN2 reaction.
(ii) Write the compound which is optically active.
(iii) Write the compound which is most reactive towards β elimination reaction.

27. What happens when: (Any three)

(i) formic acid reacts with conc. H2SO4.
(ii) acetic acid reacts with Cl2 in the presence of red P ?
(iii) calcium acetate is heated?
(iv) CH 3 - O - CH 3 is heated with HI.

28. (i) At low pressure and high temperature, water evaporates rapidly, why?
(ii) Calculate the molality of a solution when 20 g NaOH is dissolved in 440 g of solvent.

29. A solution of [Ni(H2O)6]2– is green but a solution of [Ni(CN)4]2– is colourless. Explain.

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30. How will you convert (Give only chemical equation):

(i) Propanamide to ethylamine
(ii) Ethyl amine to methane
(iii)
Aniline to acetanilide.


o
Identify A, B and C in the following equations :
Sn/HCl
(i) C 6 H 5 NO 2 6 [H]
(A) + H 2 O
(ii)

SECTION-D

Directions (Q. No. 31-32) : The following questions are case-based questions. Each question has an internal
choice and carries 4 (1+1+2) marks each. Read the passage carefully and answer the questions that follow.

31. Molar conductivity of a solution is the conductance of solution containing one mole of electrolyte,
kept between two electrodes having unit length between them and large cross-sectional area,
so as to contain the electrolyte. In other words, molar conductivity is the conductance of the
electrolytic solution kept between the electrodes of a conductivity cell at unit distance but
having area of cross-section large enough to accommodate sufficient volume of solution that
contains one mole of the electrolyte.
It is denoted by Λ m .
The molar conductivity is related to conductivity as:
Λ m = k # V = 1000 # k = k # 1000
C Molarity
Unity of Λ m (molar conductivity) shall be ohm–1 cm–1 mol–1 or S cm2 mol–1.
Thus, knowing molar concentration (C ) and conductivity (k ), Λ m can be calculated. Λc m is
called molar conductivity at infinite dilution. The molar conductivity of strong electrolytes is
found to vary with concentration according to the equation,
ΛCm = Λc m − A C

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This equation is called Debye-Huckel Onsager equation.

Here, A is constant depending upon the type of electrolyte taken and nature of solvent and
temperature.
In the context of given passage, answer the following questions:
(i) The molar conductivity of HCl increases with dilution. Can you suggest what may be the
reason for this?
(ii) Here are given the different molarities of NaCl. Which of them will exhibit the highest
molar conductivity?
0.005 M NaCl, 0.1 M NaCl, 0.5 M NaCl, 0.01 M NaCl .
(iii) Molar conductivity of a solution is 1.26 # 102 Ω−1 cm2 mol−1 . Its molarity is 0.01. What will be
its specific conductivity?

o
(iv) The conductivity of 0.00241 M acetic acid is 7.896 # 10-5 S cm-1 . What shall be the molar
conductivity of the solution in S cm–1 mol–1 ?

32. Amines constitute an important class of organic compounds derived by replacing one or more
hydrogen atoms of ammonia molecule by alkyl/aryl groups. Amines are usually formed from
nitro compounds, halides, amides, etc. They exhibit hydrogen bonding which influences their
physical properties. Alkyl amines are found to be stronger bases than ammonia. In aromatic
amines, electron releasing and withdrawing groups, respectively increase and decrease their
basic character. Reactions of amines are governed by availability of the unshared pair or
electrons on nitrogen. Influence of the number of hydrogen atoms at nitrogen atom on the type
of reactions and nature of products is responsible for identification and distinction between
primary, secondary and tertiary amines. Reactivity of aromatic amines can be controlled by
acylation process.
In the context of given passage, answer the following questions :
(i) Why does aniline not give Friedel-Crafts reaction?
(ii) Arrange the following in the increasing order of their pKb values :
C6H5NH2, NH3, C2H5NH2, (CH3)3N
(iii) How can you distinguish between CH3CH2NH2 and (CH3CH2)2 NH by Hinsberg test?

o
(iv) Write the structures of A and B in the following reactions:

(a)
Br2 /alc. KOH
CH 3 CH 2 CONH 2 A
(b) CH 3 COCl
Pyridine
B

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SECTION-E

Directions (Q. No. 33-35) : The following questions are long answer type and carry 5 marks each. Two
questions have an internal choice.

33. (i) Write the reaction involved in the following :

(a) Etard reaction
(b) Stephan reduction
(ii) How will you convert the following in not more than two steps :
(a) Benzoic acid to Benzaldehyde
(b) Acetophenone to Benzoic acid
(c) Ethanoic acid to 2-hydroxyethanoic acid.


o
(i) An organic compound [A] with molecular formula C8H16O2 was hydrolysed with dilute
sulphuric acid to give a carboxylic acid [B] and an alcohol [C]. Oxidation of [C] with
chromic acid produced [B]. The alcohol [C] on dehydration gave but-1-ene. Write equations
for the reactions involved.
(ii) How many asymmetric carbon atoms are created during the complete reduction of benzil
(PhCOCOPh) with LiAlH4 ? Also write the number of possible stereoisomers formed as
the product.

34. (i) Account for the following :

(a) Copper (I) compounds are white whereas Copper (II) compounds are coloured.
(b) Chromates change their colour when kept in an acidic solution.
(c) Zn, Cd, Hg are considered as d -block elements, but not as transition elements.
(ii) Calculate the spin-only moment of Co2+ (Z = 27) by writing the electronic configuration of
Co and Co2+.


o
(i) Following are the transition metal ions of 3d series :
Ti 4+, V 2+, Mn3+, Cr3+
(Atomic numbers :
Ti = 22, V = 23, Mn = 25, Cr = 24 )
Answer the following :
(a) Which ion is most stable in an aqueous solution and why?
(b) Which ion is a strong oxidising agent and why?
(c) Which ion is colourless and why?
(ii) Complete the following equations :
(a) 2MnO −4 + 16H+ + 5S2− $
heat
(b) KMnO 4

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CBSE Physics Class 12 Sample Paper 3 Page 11

35. (i) Calculate the mass of Ag deposited at cathode when a current of 2 amperes was passed
through a solution of AgNO3 for 15 minutes.
(Given : Molar mass of Ag = 108 g mol−1 , 1F = 96500 C mol−1 )
(ii) What do you mean by fuel cell?
(iii) Write Cu, Na, Mg and Ag in the decreasing order of electrochemical series with the help
of the following reactions:
Cu + 2Ag+ $ Cu2+ + 2Ag
2Na + Mg2+ $ 2Na+ + Mg
Mg + Cu2+ $ Mg2+ + Cu

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