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SAFETY DATA SHEET

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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by

Commission Regulation (EU) 2015/830

SAFETY DATA SHEET

231751 BK POM UV SMARTBATCH

SECTION 1: Identification of the substance/mixture and of the

company/undertaking
1.1 Product identifier

Product name : 231751 BK POM UV SMARTBATCH

REACH Registration number

Not applicable (mixture)
Product code : CC10231751BG
Product type : Pellets.
Other means of identification : Not available.

1.2 Relevant identified uses of the substance or mixture and uses advised against

Product use : Industrial applications. Plastics.

1.3 Details of the supplier of the safety data sheet

POLYONE CORPORATION
19 Route de Bastogne, L-9638 Pommerloch, Luxembourg
Product Stewardship +352 26 90 50 85

e-mail address of person : reach@polyone.com

responsible for this SDS

1.4 Emergency telephone number

National advisory body/Poison Center

Telephone number : Not available.

Supplier

Telephone number : Product Stewardship +352 26 90 50 85

Hours of operation : 08:00 AM - 4:30 PM GMT+1

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SECTION 2: Hazards identification

This mixture has not been evaluated as a whole. Information provided on the health effects of this product is
based on individual components. All ingredients are bound and potential for hazardous exposure as shipped is
minimal. However, some vapors may be released upon heating and the end-user (fabricator) must take the
necessary precautions (mechanical ventilation, respiratory protection, etc.) to protect employees from exposure.

2.1 Classification of the substance or mixture

Product definition : Mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

The product is classified as hazardous according to Regulation (EC) 1272/2008 as amended.

Eye Dam./Irrit. 1, H318

Aquatic Chronic 3, H412

See Section 16 for the full text of the H statements declared above.
See Section 11 for more detailed information on health effects and symptoms.

2.2 Label elements

Label requirements: Not applicable.As the substances are embedded in the polymer matrix and are not likely to
migrate, labeling of the finished good is not mandatory (according to regulation 1272/2008/EC article 23d).

Hazard pictograms : Not applicable.

Signal word : Not applicable.

Hazard statements : Not applicable.

Precautionary statements

General : Not applicable.

Prevention : Not applicable.
Response : Not applicable.
Storage : Not applicable.
Disposal : Not applicable.
Hazardous ingredients : bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate

Supplemental label elements : Not applicable.

Annex XVII - Restrictions on the : Not applicable.

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manufacture, placing on the

market and use of certain
dangerous substances, mixtures
and articles
2.3 Other hazards

Substance meets the criteria for : See Sections 3 and 15 for details.
PBT according to Regulation
(EC) No. 1907/2006, Annex XIII

Substance meets the criteria for : See Sections 3 and 15 for details.
vPvB according to Regulation
(EC) No. 1907/2006, Annex XIII

Other hazards which do not : None known.

result in classification

SECTION 3: Composition/information on ingredients

3.2 Mixtures : Mixture

Classification

Product/ingredient name Identifiers % Type

Regulation (EC) No. 1272/2008 [CLP]

Decanedioic acid, >0 - Eye Dam./Irrit. 1, H318 [1]

EC:258-207-9 Aquatic Acute 1, H400
bis(2,2,6,6-tetramethyl-4- <=10
CAS : 52829-07- Aquatic Chronic 2, H411
piperidinyl) ester 9

Index:
Type
[1] Substance classified with a physical, health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern

See Section 16 for the full text of the H statements declared above.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
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concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

SECTION 4: First aid measures

4.1 Description of first aid measures

Eye contact : Get medical attention immediately. Call a poison center or physician.
Immediately flush eyes with plenty of water, occasionally lifting the
upper and lower eyelids. Check for and remove any contact lenses.
Continue to rinse for at least 10 minutes. Chemical burns must be
treated promptly by a physician.
Inhalation : Get medical attention immediately. Call a poison center or physician.
Remove victim to fresh air and keep at rest in a position comfortable
for breathing. If it is suspected that fumes are still present, the rescuer
should wear an appropriate mask or self-contained breathing
apparatus. If not breathing, if breathing is irregular or if respiratory
arrest occurs, provide artificial respiration or oxygen by trained
personnel. It may be dangerous to the person providing aid to give
mouth-to-mouth resuscitation. If unconscious, place in recovery
position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
In case of inhalation of decomposition products in a fire, symptoms
may be delayed. The exposed person may need to be kept under
medical surveillance for 48 hours.
Skin contact : Get medical attention immediately. Call a poison center or physician.
Flush contaminated skin with plenty of water. Remove contaminated
clothing and shoes. Wash contaminated clothing thoroughly with
water before removing it, or wear gloves. Continue to rinse for at
least 10 minutes. Chemical burns must be treated promptly by a
physician. Wash clothing before reuse. Clean shoes thoroughly
before reuse.
Ingestion : Get medical attention immediately. Call a poison center or physician.
Wash out mouth with water. Remove dentures if any. Remove victim
to fresh air and keep at rest in a position comfortable for breathing. If
material has been swallowed and the exposed person is conscious,
give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the
head should be kept low so that vomit does not enter the lungs.
Chemical burns must be treated promptly by a physician. Never give
anything by mouth to an unconscious person. If unconscious, place in
recovery position and get medical attention immediately. Maintain an
open airway. Loosen tight clothing such as a collar, tie, belt or
waistband.
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Protection of first-aiders : No action shall be taken involving any personal risk or without
suitable training. If it is suspected that fumes are still present, the
rescuer should wear an appropriate mask or self-contained breathing
apparatus. It may be dangerous to the person providing aid to give
mouth-to-mouth resuscitation. Wash contaminated clothing
thoroughly with water before removing it, or wear gloves.

4.2 Most important symptoms and effects, both acute and delayed

Potential acute health effects

Eye contact : Causes serious eye damage.

Inhalation : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.

Over-exposure signs/symptoms

Eye contact : Adverse symptoms may include the following:

pain
watering
redness

Inhalation : No specific data.

Skin contact : Adverse symptoms may include the following:

pain or irritation
redness
blistering may occur

Ingestion : Adverse symptoms may include the following:

stomach pains

4.3 Indication of any immediate medical attention and special treatment needed

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms

may be delayed. The exposed person may need to be kept under
medical surveillance for 48 hours.
Specific treatments : No specific treatment.

SECTION 5: Firefighting measures

5.1 Extinguishing media

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Suitable extinguishing media : In case of fire, use water spray (fog), foam, dry chemical or CO₂.
Unsuitable extinguishing media : None known.

5.2 Special hazards arising from the substance or mixture

Hazards from the substance or : This material is harmful to aquatic life with long lasting effects. Fire
mixture water contaminated with this material must be contained and
prevented from being discharged to any waterway, sewer or drain.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
nitrogen oxides

5.3 Advice for firefighters

Special protective actions for : Promptly isolate the scene by removing all persons from the vicinity
fire-fighters of the incident if there is a fire. No action shall be taken involving
any personal risk or without suitable training.
Special protective equipment for : Fire-fighters should wear appropriate protective equipment and self-
fire-fighters contained breathing apparatus (SCBA) with a full face-piece
operated in positive pressure mode. Clothing for fire-fighters
(including helmets, protective boots and gloves) conforming to
European standard EN 469 will provide a basic level of protection for
chemical incidents.
Additional information : Not available.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures

For non-emergency personnel : No action shall be taken involving any personal risk or without
suitable training. Evacuate surrounding areas. Keep unnecessary and
unprotected personnel from entering. Do not touch or walk through
spilled material. Provide adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Put on appropriate personal
protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note
of any information in Section 8 on suitable and unsuitable materials.
See also the information in "For non-emergency personnel".

6.2 Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil,
waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil
or air). Water polluting material. May be harmful to the environment
if released in large quantities.

6.3 Methods and materials for containment and cleaning up

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Small spill : Move containers from spill area. Avoid dust generation. Using a
vacuum with HEPA filter will reduce dust dispersal. Place spilled
material in a designated, labeled waste container. Dispose of via a
licensed waste disposal contractor.
Large spill : Move containers from spill area. Approach release from upwind.
Prevent entry into sewers, water courses, basements or confined
areas. Avoid dust generation. Do not dry sweep. Vacuum dust with
equipment fitted with a HEPA filter and place in a closed, labeled
waste container. Dispose of via a licensed waste disposal contractor.

6.4 Reference to other sections : See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective
equipment.
See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Protective measures : Put on appropriate personal protective equipment (see Section 8). Do
not get in eyes or on skin or clothing. Do not ingest. Avoid release to
the environment. If during normal use the material presents a
respiratory hazard, use only with adequate ventilation or wear
appropriate respirator. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed
when not in use. Empty containers retain product residue and can be
hazardous. Do not reuse container.
Advice on general occupational : Eating, drinking and smoking should be prohibited in areas where
hygiene this material is handled, stored and processed. Workers should wash
hands and face before eating, drinking and smoking. Remove
contaminated clothing and protective equipment before entering
eating areas. See also Section 8 for additional information on hygiene
measures.

7.2 Conditions for safe storage, : Store in accordance with local regulations. Store in original
including any incompatibilities container protected from direct sunlight in a dry, cool and well-
ventilated area, away from incompatible materials (see Section 10)
and food and drink. Store in a well-ventilated place. Keep container
tightly closed and sealed until ready for use. Containers that have
been opened must be carefully resealed and kept upright to prevent
leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination.

7.3 Specific end use(s)

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Recommendations : Not available.

Industrial sector specific : Not available.
solutions

SECTION 8: Exposure controls/personal protection

The information in this section contains generic advice and guidance. Information is provided based on typical
anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could
significantly increase worker exposure or environmental releases.

8.1 Control parameters

Occupational exposure limits

No exposure limit value known.
Recommended monitoring : If this product contains ingredients with exposure limits, personal,
procedures workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control
measures and/or the necessity to use respiratory protective
equipment. Reference should be made to monitoring standards, such
as the following: European Standard EN 689 (Workplace
atmospheres - Guidance for the assessment of exposure by
inhalation to chemical agents for comparison with limit values and
measurement strategy) European Standard EN 14042 (Workplace
atmospheres - Guide for the application and use of procedures for
the assessment of exposure to chemical and biological agents)
European Standard EN 482 (Workplace atmospheres - General
requirements for the performance of procedures for the
measurement of chemical agents) Reference to national guidance
documents for methods for the determination of hazardous
substances will also be required.

DNEL/DMEL Summary : Not available.

PNEC Summary : Not available.

8.2 Exposure controls

Appropriate engineering controls : If user operations generate dust, fumes, gas, vapor or mist, use
process enclosures, local exhaust ventilation or other engineering
controls to keep worker exposure to airborne contaminants below
any recommended or statutory limits.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical
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products, before eating, smoking and using the lavatory and at the
end of the working period. Appropriate techniques should be used to
remove potentially contaminated clothing. Wash contaminated
clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be
used when a risk assessment indicates this is necessary to avoid
exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be worn, unless the
assessment indicates a higher degree of protection: chemical splash
goggles and/or face shield. If inhalation hazards exist, a full-face
respirator may be required instead.

Skin protection

Hand protection : Chemical-resistant, impervious gloves complying with an approved

standard should be worn at all times when handling chemical
products if a risk assessment indicates this is necessary. Considering
the parameters specified by the glove manufacturer, check during
use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material
may be different for different glove manufacturers. In the case of
mixtures, consisting of several substances, the protection time of the
gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based
on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures
should be selected based on the task being performed and the risks
involved and should be approved by a specialist before handling this
product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator
that meets the appropriate standard or certification. Respirators must
be used according to a respiratory protection program to ensure
proper fitting, training, and other important aspects of use.
Environmental exposure controls : Emissions from ventilation or work process equipment should be
checked to ensure they comply with the requirements of
environmental protection legislation. In some cases, fume scrubbers,
filters or engineering modifications to the process equipment will be
necessary to reduce emissions to acceptable levels.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

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Appearance

Physical state : solid [Pellets.]

Color : BLACK
Odor : Faint odor.
Odor threshold : Not available.
pH : Not available.
Melting point/freezing point : Not available.
Initial boiling point and boiling : Not available.
range
Flash point : Not available.
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Burning time : Not available.
Burning rate : Not available.
Upper/lower flammability or : Lower: Not available.
explosive limits Upper: Not available.
Vapor pressure : Not available.
Vapor density : Not available.
Relative density : Not available.
Solubility(ies) : Not available.
Solubility in water : insoluble in water.

Partition coefficient: n- : Not available.

octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Dynamic: Not available.
Kinematic: Not available.
Explosive properties : Not available.
Oxidizing properties : Not available.

9.2 Other information

No additional information.

SECTION 10: Stability and reactivity

10.1 Reactivity : No specific test data related to reactivity available for this product or
its ingredients.

10.2 Chemical stability : Stable under recommended storage and handling conditions (see
Section 7).

10.3 Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions
reactions will not occur.

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10.4 Conditions to avoid : Keep away from extreme heat and oxidizing agents.

10.5 Incompatible materials : Keep away from strong acids.

Oxidizer.

10.6 Hazardous decomposition : Under normal conditions of storage and use, hazardous
products decomposition products should not be produced.

SECTION 11: Toxicological information

This mixture has not been evaluated as a whole for health effects. Exposure effects listed are based on existing
health data for the individual components which comprise the mixture.

11.1 Information on toxicological effects

Acute toxicity

Conclusion/Summary : Mixture.Not fully tested.

Acute toxicity estimates

Not available.

Irritation/Corrosion

Conclusion/Summary
Skin : Mixture.Not fully tested.
Eyes : Mixture.Not fully tested.
Respiratory : Mixture.Not fully tested.

Sensitization

Conclusion/Summary
Skin : Mixture.Not fully tested.
Respiratory : Mixture.Not fully tested.

Mutagenicity

Conclusion/Summary : Mixture.Not fully tested.

Carcinogenicity

Conclusion/Summary : Mixture.Not fully tested.

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Reproductive toxicity

Conclusion/Summary : Mixture.Not fully tested.

Teratogenicity

Conclusion/Summary : Mixture.Not fully tested.

Specific target organ toxicity (single exposure)

Not available.

Specific target organ toxicity (repeated exposure)

Not available.

Aspiration hazard
Not available.

Information on likely routes of : Not available.

exposure

Potential acute health effects

Eye contact : Causes serious eye damage.

Inhalation : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:

pain
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Short term exposure

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Potential immediate effects : Not available.

Potential delayed effects : Not available.

Long term exposure

Potential immediate effects : Not available.

Potential delayed effects : Not available.

Potential chronic health effects

Conclusion/Summary : Mixture.Not fully tested.

General : No known significant effects or critical hazards.

Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

SECTION 12: Ecological information

12.1 Toxicity

Product/ingredient name Result Species Exposure

Decanedioic acid, bis(2,2,6,6-tetramethyl-4-piperidinyl) ester
Acute LC50 4.4 Mg/l Fish - Bluegill 96 h
Acute EC50 8.6 Mg/l Aquatic invertebrates. 48 h
Fresh water Daphnia
Acute EC50 0.705 Mg/l Aquatic plants - Green 72 h
algae
231751 BK POM UV SMARTBATCH
Remarks - Acute - Aquatic Chemicals are not readily available as they are bound within the polymer
invertebrates.: matrix.
Conclusion/Summary : Chemicals are not readily available as they are bound within the
polymer matrix.

12.2 Persistence and degradability

Conclusion/Summary : Chemicals are not readily available as they are bound within the
polymer matrix.

12.3 Bioaccumulative potential

Bioaccumulation Potential : Chemicals are not readily available as they are bound within the polymer
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matrix.

12.4 Mobility in soil

Soil/water partition coefficient : Not available.

(KOC)
Mobility : Chemicals are not readily available as they are bound within the
polymer matrix.

12.5 Results of PBT and vPvB assessment

PBT : P: Not available.

B: Not available.
T: Not available.

vPvB : vP: Not available.

vB: Not available.

12.6 Other adverse effects : No known significant effects or critical hazards.

No known significant effects or critical hazards.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Product

Methods of disposal : The generation of waste should be avoided or minimized wherever

possible. Disposal of this product, solutions and any by-products
should at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional local
authority requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste should not
be disposed of untreated to the sewer unless fully compliant with the
requirements of all authorities with jurisdiction.
Hazardous waste : The classification of the product may meet the criteria for a
hazardous waste.

Packaging

Methods of disposal : The generation of waste should be avoided or minimized wherever

possible. Waste packaging should be recycled. Incineration or
landfill should only be considered when recycling is not feasible.

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Special precautions : This material and its container must be disposed of in a safe way.
Care should be taken when handling emptied containers that have
not been cleaned or rinsed out. Empty containers or liners may retain
some product residues. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.

SECTION 14: Transport information

ADR (road) : Not classified as dangerous goods under transport regulations.

ICAO/IATA : Not classified as dangerous goods under transport regulations.

IMO/IMDG (maritime) : Not classified as dangerous goods under transport regulations.

Special precautions for user : Transport within user's premises: always transport in closed
containers that are upright and secure. Ensure that persons
transporting the product know what to do in the event of an accident
or spillage.

Transport in bulk according to Annex II of MARPOL and the IBC Code

Not applicable.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

EU Regulation (EC) No. 1907/2006 (REACH)

Annex XIV - List of substances subject to authorization
Annex XIV: None of the components are listed.

Substances of very high concern: None of the components are listed.

Other EU regulations

Europe inventory : All components are listed or exempted.

Industrial emissions (integrated : Not listed
pollution prevention and control)
- Air
Industrial emissions (integrated : Not listed
pollution prevention and control)
- Water

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Aerosol dispensers : Not applicable.

Seveso Directive

This product is not controlled under the Seveso Directive.

National regulations
Hazard class for water : not available

International regulations
Inventory list
Australia : All components are listed or exempted.
Canada : All components are listed or exempted.
China : All components are listed or exempted.
Europe inventory : All components are listed or exempted.
Japan : All components are listed or exempted.
New Zealand : All components are listed or exempted.
Philippines : All components are listed or exempted.
Republic of Korea : All components are listed or exempted.
Taiwan : All components are listed or exempted.
Turkey : All components are listed or exempted.
United States : All components are listed or exempted.

15.2 Chemical Safety Assessment : Not available.

SECTION 16: Other information

Abbreviations and acronyms : ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation
[Regulation (EC) No. 1272/2008]
DNEL = Derived No Effect Level
DMEL = Derived Minimal Effect Level
EUH statement = CLP-specific Hazard statement
PBT = Persistent, Bioaccumulative and Toxic
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
vPvB = Very Persistent and Very Bioaccumulative
Full text of abbreviated H : H318 Causes serious eye damage.
statements H400 Very toxic to aquatic life.
H411 Toxic to aquatic life with long
lasting effects.

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H412 Harmful to aquatic life with long

lasting effects.
Date of printing : 18.04.2018
Date of issue/ Date of revision : 20.02.2018
Date of previous issue : 18.12.2015
Version : 1.1

Notice to reader

To the best of our knowledge, the information contained herein is accurate. However, neither the above-
named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any material is
the sole responsibility of the user. All materials may present unknown hazards and should be used with
caution. Although certain hazards are described herein, we cannot guarantee that these are the only
hazards that exist. Particularly this information may not be valid for such material used in conjunction
with any other materials or in any process, unless specified in the text.

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