Cambridge IGCSE™

*2244180806*

CHEMISTRY 0620/62
Paper 6 Alternative to Practical October/November 2022

1 hour

You must answer on the question paper.

No additional materials are needed.

INSTRUCTIONS
● Answer all questions.
● Use a black or dark blue pen. You may use an HB pencil for any diagrams or graphs.
● Write your name, centre number and candidate number in the boxes at the top of the page.
● Write your answer to each question in the space provided.
● Do not use an erasable pen or correction fluid.
● Do not write on any bar codes.
● You may use a calculator.
● You should show all your working and use appropriate units.

INFORMATION
● The total mark for this paper is 40.
● The number of marks for each question or part question is shown in brackets [ ].

This document has 12 pages. Any blank pages are indicated.

m
co
e.
at

IB22 11_0620_62/2RP
-m

© UCLES 2022 [Turn over

m
xa
.e
w
w
w
 2

1 A mixture of three coloured compounds was separated using the apparatus shown in the diagram.

lid

paper

baseline

(a) Give the name of the item of apparatus labelled A.

.............................................................................................................................................. [1]

(b) One drop of the mixture of coloured compounds was placed on the paper and some solvent
was poured into A.

Draw on the diagram:

●  spot(●)toshowwherethedropofthemixtureofcolouredcompoundsshouldbeplaced
a
on the paper at the start of the experiment

● a line to show the level of the solvent in A at the start of the experiment.
[2]

(c) Name an item of apparatus that should be used to place a drop of the mixture of coloured
compounds onto the paper.

.............................................................................................................................................. [1]

(d) State when the paper should be removed from the solvent in A.

.............................................................................................................................................. [1]

(e) Name this method of separation of coloured compounds.

.............................................................................................................................................. [1]

[Total: 6]
m
co
e.
at
-m
m
xa

© UCLES 2022 0620/62/O/N/22

.e
w
w
w
 3

2 A student investigated the temperature change when two different aqueous solutions of
sodium hydroxide, solution G and solution H, reacted with dilute hydrochloric acid.

Two experiments were done.

(a) Experiment 1
● A burette was rinsed with distilled water and then with dilute hydrochloric acid.
● The burette was filled with the dilute hydrochloric acid. The hydrochloric acid was then run
out through the tap until the level was on the 0.00 cm3 mark.
● A 50 cm3 measuring cylinder was used to pour 20 cm3 of solution G into a beaker.
● A thermometer was used to measure the initial temperature of solution G.
● 5 cm3 of dilute hydrochloric acid was added from the burette into the beaker.
● The mixture in the beaker was stirred using the thermometer and the temperature of the
mixture was measured.
● Another 5 cm3 of dilute hydrochloric acid was added from the burette into the beaker.
● The mixture in the beaker was stirred using the thermometer and the temperature of the
mixture was measured.
● 5 cm3 portions of dilute hydrochloric acid continued to be added and the temperature
measured until a total of 35 cm3 of dilute hydrochloric acid had been added.

Experiment 2
● Experiment 1 was repeated using solution H instead of solution G.

m
co
e.
at
-m
m
xa

© UCLES 2022 0620/62/O/N/22 [Turn over

.e
w
w
w
 4

Use the thermometer diagrams to complete the table.

Experiment 1 using solution G Experiment 2 using solution H

total volume
temperature temperature
of dilute thermometer temperature thermometer temperature
change change
hydrochloric diagram / C diagram / C
since start since start
acid added
/ C / C
/ cm3

30 30

0 25 25

20 20
30 30

5 25 25

20 20
30 30

10 25 25

20 20
30 30

15 25 25

20 20
30 30

20 25 25

20 20
30 30

25 25 25

20 20
30 30

30 25 25

20 20
30 30

35 25 25

20 20
m
co
e.

[5]
at
-m
m
xa

© UCLES 2022 0620/62/O/N/22

.e
w
w
w
 5

(b) Complete a suitable scale on the y-axis and plot the results from Experiments 1 and 2 on the
grid.

 Drawtwosmoothlinegraphs.Bothcurvesmuststartat(0,0).Clearlylabelyourlines.

temperature
change / C

0
0 5 10 15 20 25 30 35
total volume of dilute hydrochloric acid added / cm3

[5]

(c) From your graph, deduce the temperature change obtained when a total volume of 13 cm3 of
dilute hydrochloric acid is added in Experiment 1.

Show clearly on the grid how you worked out your answer.

temperature change = .............................. °C [2]

(d) Explain why the temperature change decreases towards the end of each experiment.

....................................................................................................................................................

.............................................................................................................................................. [1]
m
co
e.
at
-m
m
xa

© UCLES 2022 0620/62/O/N/22 [Turn over

.e
w
w
w
 6

(e) Explain what conclusion about the concentrations of solution G and solution H can be made
from the results of Experiments 1 and 2.

....................................................................................................................................................

....................................................................................................................................................

....................................................................................................................................................

.............................................................................................................................................. [2]

(f) E
 xplainhowtheresultsobtainedwouldbedifferentifapolystyrenecupisusedinsteadofthe
beaker.

....................................................................................................................................................

....................................................................................................................................................

....................................................................................................................................................

.............................................................................................................................................. [2]

(g) Give an advantage and a disadvantage of using a burette rather than a measuring cylinder to
add the dilute hydrochloric acid to solution G and solution H.

advantage ..................................................................................................................................

....................................................................................................................................................

disadvantage .............................................................................................................................

....................................................................................................................................................
[2]

[Total: 19]

m
co
e.
at
-m
m
xa

© UCLES 2022 0620/62/O/N/22

.e
w
w
w
 7

3 Solid I and solid J were analysed.

Tests were done on each substance.

tests on solid I

tests observations
test 1

Dilute hydrochloric acid was added to a effervescencewasseen,thesoliddissolved

boiling tube containing solid I. to form a colourless solution

Any gas produced was tested. the gas turned limewater milky

test 2

Aflametestwascarriedoutonthesolution aredflamewasseen
formed in test 1.

(a) Identify the gas made in test 1.

.............................................................................................................................................. [1]

(b) Identify solid I.

....................................................................................................................................................

.............................................................................................................................................. [2]

m
co
e.
at
-m
m
xa

© UCLES 2022 0620/62/O/N/22 [Turn over

.e
w
w
w
 8

tests on solid J

Solid J was aluminium chloride.

Solid J was dissolved in water to form solution J. Solution J was divided into four approximately
equalportionsinfourtest-tubes.

(c) A
 queous sodium hydroxide was added dropwise and then in excess to the first portion of
solution J.

observations ..............................................................................................................................

.............................................................................................................................................. [2]

(d) AqueousammoniawasaddeddropwiseandtheninexcesstothesecondportionofsolutionJ.

observations ..............................................................................................................................

.............................................................................................................................................. [2]

(e) A
 bout1cmdepthofdilutenitricacidfollowedbyafewdropsofaqueousbariumnitratewere
added to the third portion of solution J.

observations ........................................................................................................................ [1]

(f) A
 bout1cmdepthofdilutenitricacidfollowedbyafewdropsofaqueoussilvernitratewere
added to the fourth portion of solution J.

observations ........................................................................................................................ [1]

[Total: 9]

m
co
e.
at
-m
m
xa

© UCLES 2022 0620/62/O/N/22

.e
w
w
w
 9

4 Hydrogels are powders that absorb water to form hydrated solids. Hydrogels and the hydrated
solids formed are insoluble in water.

 Plan an investigation to find which hydrogel, hydrogel A or hydrogel B, is able to absorb the
greater mass of water.

You are provided with samples of hydrogel A, hydrogel B, water and common laboratory apparatus.

...........................................................................................................................................................

...........................................................................................................................................................

...........................................................................................................................................................

...........................................................................................................................................................

...........................................................................................................................................................

...........................................................................................................................................................

...........................................................................................................................................................

...........................................................................................................................................................

...........................................................................................................................................................

...........................................................................................................................................................

...........................................................................................................................................................

...........................................................................................................................................................

...........................................................................................................................................................

...........................................................................................................................................................

...........................................................................................................................................................

...........................................................................................................................................................

...........................................................................................................................................................

...........................................................................................................................................................

...........................................................................................................................................................

...........................................................................................................................................................

...........................................................................................................................................................

...........................................................................................................................................................
m

...........................................................................................................................................................
co
e.
at

..................................................................................................................................................... [6]
-m
m
xa

© UCLES 2022 0620/62/O/N/22 [Turn over

.e
w
w
w
 10

BLANK PAGE

m
co
e.
at
-m
m
xa

© UCLES 2022 0620/62/O/N/22

.e
w
w
w
 11

BLANK PAGE

m
co
e.
at
-m
m
xa

© UCLES 2022 0620/62/O/N/22

.e
w
w
w
 12

BLANK PAGE

Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.

To avoid the issue of disclosure of answer-related information to candidates, all copyright acknowledgements are reproduced online in the Cambridge
m

Assessment International Education Copyright Acknowledgements Booklet. This is produced for each series of examinations and is freely available to download
co

at www.cambridgeinternational.org after the live examination series.

e.
at

Cambridge Assessment International Education is part of Cambridge Assessment. Cambridge Assessment is the brand name of the University of Cambridge
-m

Local Examinations Syndicate (UCLES), which is a department of the University of Cambridge.

m
xa

© UCLES 2022 0620/62/O/N/22

.e
w
w
w