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Chemistry for the IB Diploma

Core Worksheet – Chapter 10

1 Identify the functional groups present in the following molecules: [4]


a c

b d

2 Give the structural formula of an isomer of each of the compounds in question 1 with a
different functional group. [4]

3 State and explain which of the compounds in question 1 has the highest boiling point. [3]

4 Name the following molecules: [4]


a c

b d (CH3)2CHCH(CH3)2

5 Write equations for the following reactions: [2]


a the complete combustion of pentane
b the incomplete combustion of butane producing carbon monoxide

6 a Under what conditions do alkanes react with bromine or chlorine? [1]


b In the reaction between an alkane and a halogen write equations for the
following reactions: [4]
i a propagation step than produces bromoethane
ii a propagation step that produces dichloromethane
iii a termination step that produces butane
iv a termination step that produces 1,2-dibromoethane

Copyright Cambridge University Press 2011. All rights reserved. Page 1 of 2


Chemistry for the IB Diploma

7 a Name the following molecules: [4]


i iii (CH3)2CCHCH3

ii iv

b Write equations, using structural formulas, for the following reactions of the
molecules in question 7a under suitable conditions: [4]
i 7a i + H2
ii 7a ii + HBr
iii 7a iii + H2O
iv 7a iv + Br2
c Describe a chemical test that could be used to distinguish between the molecule in
question 4a and molecule 7a i. [2]

8 a Name and give the formula of a suitable oxidising agent to oxidise propan-1-ol. [2]
b Write balanced chemical equations for the partial and complete oxidation of
propan-1-ol. Use [O] to represent oxygen from the oxidising agent. [2]
c Name the organic compound obtained when each of the following undergoes
complete oxidation: [3]
i ethanol
ii propan-2-ol
iii 2-methylpropan-1-ol

9 a Draw the full structural formulas of the following and classify each as primary,
secondary or tertiary: [6]
i 2-chlorobutane
ii 2-bromo-3-methylpentane
iii 2-bromo-2-methylpentane
b Draw a reaction mechanism using curly arrows to show the reaction between
1-chloropropane and aqueous sodium hydroxide. [4]
c Explain what is meant by an SN1 mechanism. [3]

10 Draw out reaction sequences showing structural formulas and all reagents and conditions
for the following conversions: [9]
a ethene to ethanoic acid
b butane to butan-1-ol
c but-2-ene to butanone

Copyright Cambridge University Press 2011. All rights reserved. Page 2 of 2

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