Drying Curve: M.Sc. II Sem Unit Opeartion (ICM-2001)

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Drying Curve

M.Sc. II sem
Abu Mustafa Khan
Unit Opeartion
(ICM-2001) Department of Chemistry
A.M.U. Aligarh
Content
• Types of moisture
• Drying curve
• Typical drying rate curve
• Constant rate period
• Falling rate period
• First falling rate period
• Second falling rate period
• Moisture content Vs drying time curve
Types of Moisture
Moisture content of a substance which exerts as equilibrium vapour pressure less than of the
pure liquid at the same temperature is referred to as bound moisture.

Moisture content of the solid which exerts an equilibrium vapour pressure equal to that of
pure liquid at the given temperature is the unbound moisture.

The moisture content of solid in excess of the equilibrium moisture content is referred as free
moisture. During drying, only free moisture can be evaporated. The free moisture content of a
solid depends upon the vapour concentration in the gas.

The moisture contents of solid when it is in equilibrium with given partial pressure of vapour
in gas phase is called as equilibrium moisture content.

Moisture content at which the constant rate drying period ends and the falling rate drying
period starts is called critical moisture content.
Drying curve

Drying curve is the plot of the drying rate Φ or N versus the


remaining water content X. Water content X is expressed as
kg of water per kg of dry matter. Drying process of a
material can be described as a series of steps in which drying
rate plays a key role.
typical
drying
rate
curve
Constant rate period
• Point A’ or A to B is called preheating period.
• Point B represents equilibrium temperature conditions of the product
surface.
• Section B to C of the curve, known as the constant rate periods,
represents removal of unbound water from the product.
• The water acts as if the solid is not present. The surface of the product is
very wet and water. And the water activity is equal to one.
• The constant rate period continues as long as the amount of water
evaporates is equal to the amount of water supplied to surface by capillary
action.
• There is no change in the temperature of the material.
Falling rate period

• The falling rate period is reached when the


drying rate starts to decrease, and the
surface water activity falls to less than one.
• The rate of drying is governed by the
internal flow of liquid or vapour. This point
is represented by C in the figure.
• This point there is not enough water on the
surface to maintain a water activity value of
one.
Falling rate period can be
divided into two steps.

First Second
falling falling
drying rate drying rate
First falling drying rate period

A first falling drying rate occurs when wetted


spots in the surface continually diminish until
the surface is dried (Point D)

.
Heat required for moisture removal is transferred
through the solid to the vaporization of moisture in
the solid and the vapour moves through the solid
Second falling drying rate

• Second falling rate period begins at point D when the surface is completely
dry. The plane of evaporation recedes from the surface
• The amount water removed in this period can be relatively small compared to
the constant rate and first falling rate period.
• However this period may take much longer time than constant rate period
because the drying is slow.

In the sufficiently porous materials there is no discrimination between first and second falling rate
period.
Moisture
content
Vs
Drying
time
curve
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