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Solution to 2024-JEE Advanced Full Test-1 |Paper-2

PHYSICS
1.(6) Time of flight (T)
1
S  ut  at 2
2
1
20  0  gT 2
2
T  2sec
Range (R)
R  5T
R  10
R  D  D  x0
10  2D  x0
10  16  x0
x0  6m

2.(5) Let the SHM equations for the two particles be given by
 2 
x1  5sin  (t  1) 
 6 
 2 
x2  5sin  t 
 6 
    t  
| x2  x1 |  5 sin  t    sin   
 3 3  3 
d | x2  x1 | 5  t   5  t 
 cos     cos  
dt 3  3 3  3  3
 t    t 
0  cos     cos  
 3 3  3
t  t t  t
   2n     2  [Putting n 1 ]
3 3 3 3 3 3
2t  5
  2   2t  6 1  t
3 3 2
  5    5     
 | x2  x1 |  5 sin     sin      5   sin  sin 
  6 3  6   6 6

 1
 5  2  sin  5  2   5cm
6 2

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3.(5) Since collision is elastic

Vx
e 1  Vx  v0
v0
 J x  2 mv0
Also J y   Ndt  J x  mV y

 2mv0
 vy   2v0  v0
m
2v 2
R  0  5m
g

1 x

4.(3) For x1 B A
1
 30 ms  30ms 1
If collision does not take place, the final velocities of both should be same.
30 30 9t 21
 v f  30  t  30  3(t 1)  t  3t  3 or  3  t  
7 7 7 9
The negative of t indicates that both comes in rest before collision. The distance moved by bus B
302
before coming to rest is s1   30  1 180 m
2 3
302 30  7
The distance moved by bus A before coming to rest is s2    105 m
30 2
2
7
 x1  s1  s2  180  105  75 m
A B
 30 m / s  30m / s

x2

30 30 30 9 30 
10
For x2 : v f  30  (t  1)  30  3t or t  3t or t t s
7 7 7 7 7 3
The positive value of t indicates that before collision, velocities of both buses are non-zero but same.
2
 10  1 30  10 
So, the distance moved by A before collision is s1  30  1  30    1     1
 3  2 7  3 
265
s1  m
3
2
10 1  10  50 250
Distance moved by B before collision is : s2  30    3     100  
3 2  3 3 3
265 250 15 x1 75
x2  s1  s2     5m or  3
3 3 3 5 x2 25

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  
5.(5) vm,b  vm  vb ...(i )
Applying equation (1) to x-and y-components of velocity, we obtain
( vmb ) x   vb and ( vmb ) y  vm
From work-energy theorem in ( x, y) coordinate system , y
W  KE
Stopping d
1
mgd   m(vm2  vb2 ) where d is the stopping distance point
2 vm

1 x
d (vm2  vb2 ) vb
vb m
2g
In the ( x, y) coordinate system

vb vb vm2  vb2

x   d cos    d 
vm2  vb2 2g
vm v
y  d sin   d  m vm2  vb2
v 2  v 2 2g
m b
The particle has a constant retardation of magnitude g in both the reference frames, as these are
inertial. Therefore time taken to stop can be determined from the equation.
0   vm2  vb2   gt
 
1
t vm2  vb2
g
We may convert the stopping distance to a fixed coordinate system by the following equations
x  x  vb t , y  y 
v vm
x  b vm2  vb2 ; y vm2  vb2
2g 2g
1 1
Now, xy   5
5 xy

6.(6) Power absorbed by earth = power emitted by earth.

e(4 Rs2 ) Ts4 Rs Rs
 2
 Re2  e (4 Re2 ) Te4  Te  Ts  Ts
4r 2r 2  200 Rs
T
 Te  s  300 K  n 6
20

7.(3) Here given

 glass  9 106 K 1   glass  27 106 K 1
 0.27 10 4 K 1
And  mercury  1.8 104 K 1 Now, Vglass  Vair  Vmercury
Given Vair  0  Vglass  Vmercury
 glass
  glass t Vglass  Vmercury   mercury  t  Vmercury  Vglass
 mercury

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 glass x x
  [Given Vmercury  Vglass ]
 mercury 20 20
0.27 10 4  20 5.4
 4
x  x 3
1.8 10 1.8

8.(5) Now F.B.D. of each cylinder could be shown as

  f1 R  I 
a
   f1R  I . . . (i)
r
f2 R  I 
a
 f2 R  I . . . (ii)
r
f1  f 2  ma
Putting the given values, we get
100  f1  0.5 a
f 2  0.5a
f1  f 2  3a
Solving these three equations for a we get
a  25m / s 2  a  5  5 m / s2
 n 5

9.(AD) Suppose blocks A and B move together. Applying NLM on C, A + B and D respectively
60  T  6a
T  18  T   9a T  10 1a
Solving a  2m / s 2
To check slipping between A and B, we have to find friction force in this case. If it is less than limiting
static friction, then there will be no slipping between A and B.
Applying NLM on A
T  f  6 2
As T  48 N f  36 N
And f x max .  42 N hence A and B move together.

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GMm 3 GMm 1 2 GM
10.(ABD)  0   mv  v 
R 2 R 2 R
1 GM 3 GM
 velocity after collision  v  ev   J m
2 R 2 R
Had the tunnel been across the earth, the particle would have executed SHM
R
Then when y 
2
T
t1 
6
T T T t1 2
 time taken for the II half is t2     
4 6 12 t2 1
3 GMm 1 2 3GM
 mve  0  ve 
2 R 2 R
11.(BC) Case I : Particle moves on an ellipse
Bx
Case II : Particle performing SHM along y 
A
GM
12.(BC) g
R2
G (M / 2) g
g P (at surface)  2

(4 R) 32
g / 32 g 16 g
g P (above height R )    
 R  32 25 50
1  4R 
 
g  R / 2  7g
g P (below thesurface)  1  
32  4 R  256
1 a
13.(ABCD) Let acceleration of rocket be a after 1 sec, height of rocket  a(1)2 
2 2
Velocity of rocket = a
a
For bolt : U B  a, aB  10, sB  ,T 2
2
a 1 5a
 a(2)  ( 10)(4) ; 20   a  8 m / s2
2 2 2
Fuel of the rocket is finished after 5 sec.
1 1
h  at 2  (8)(25)  100m
2 2
Speed is also maximum at this moment Vmax  a(5)  40 m / s
After this, rocket undergoes free fall as fuel is exhausted. To find its time of flight after this, use
1
100  40t  (10)t 2  t 2  8t  20  0  t  10sec
2
Total air time = 5 + 10 = 15 sec.

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14.(AC)New buoyant force  V ( g  a )

As the value of g effective is less than g
F
15.(C) Stress  , is same for all points
A
Y
Yx  Y0  0 x
L
Let extension in dx is dy
F  Y  dy
Then   Y0  0 x 
A  L  dx
L FL dx L FL
0 A   x   0 dy ; AY0 l n2  L
Y0 1  
 L
16.(C) 5  v cos  . . .(1)
v sin   5  v cos  . . . (2)
v sin  10 . . .(3)
On squaring and adding (1) and (3)
v 2 125 ; v  5 5 m / s ; tan   2 ;   tan 1 2

17.(B) When plate is moving to right :

Molecules bounce back with speed V  2u
 Change in momentum of one molecule ; P1  m(V  2u )  ( mV )  2mV  2 mu
Number of molecule hitting per unit time n1  A(V  u ) n
 F1  n1P1  An(V  u )2m(V  u )  2mnA(V  u ) 2
When plate is moving to left :
Molecule bounce back with speed V  2u
 Change in momentum of one molecule ; P2  m(V  2u )  ( mV )  2mV  2mu
And number of molecule hitting per unit time
n2  A(V  u )  n ; F2  n2 P2  An(V  u )2m(V  u )  2 mAn(V  u ) 2
 F2  F1  2mnA[(V  u ) 2  (V  u ) 2 ]  8mn AV  u

dy dx dx
18.(C)  3  4x
dt dt dt
2
d2y d 2x d 2x  dx 
2
 3 2
 4 x  4 
dt dt dt  dt 
dx
1 ,
dt
dy
 3
dt

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CHEMISTRY
1.(4)

2.(3) SO2 , SO3 , N(SiH3 )3

3.(6)

all are aromatic compounds having sp2 hybridized atoms.

94 10  4
4.(4) N 2  Bond order  2.5 CN  Bond order  3
2 2
10  4 10  4
CO  Bond order  3 NO  Bond order  3
2 2
10  5 10  4
O 2  Bond order   2.5 N2  Bond order  3
2 2
64 10  5
B2  Bond order  1 N 2  Bond order   2.5
2 2
10  5
NO  Bond order   2.5
2
C O , C N  , N O  , N 2 has bond order equal to 3

5.(6) (i) Temperature (ii) Pressure (iii) Specific heat capacity

(iv) Density (v) Molar heat capacity (vi) Molar enthalpy
rH 2 M O2 32
6.(4)   4
rO 2 M H2 2

x
rH 2 x x
 t  ; 4  20  4x  x  5x  20  x = 4m
rO 2 5x 5x 5x
t
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1  1 1 
7.(4)  R H Z2   , Z = 1 (for hydrogen atom)
 2 2
 n1 n 2 
1 1 1  3
 R H (1)2     R H
2
 1 22  4
4
 2  1(For H atom) 
3R H
1  1 1  
 R H Z2   , Z = 2 (for He )
 2 2
 n1 n 2 
1 1 1  1
 R H (2) 2    ,  
2 n  2 (for He  )
 2 n2  1 1 
4R H   2  2 
2 n 
1 1  3
4R H     R H
 4 n2  4
1 1 3 43 1
2
    , n=4
n 4 16 16 16

8.(4) PCl3F2 , CCl4 , SF6 , C2 H4 have zero dipole moment.

9.(ABCD)
N aO H  N aH CO 3  
 Na 2 C O 3  H 2 O
1 mol 1 mol 1 mol
So we have 50 m mole of Na 2 CO 3 in 50 mL solution.
With phenolphthalein : Na 2 CO 3  HCl   NaHCO 3  NaCl
 50 mM of Na2 CO3 can be neutralized by 50 mM of HCl. Hence statement B is correct.
With methyl orange : Na 2 CO 3  2HCl  
 2 NaCl  H 2 CO 3
 by 50 mM of Na 2 CO 3 can be neutralized by 100 mM of HCl on using methyl orange as the
indicator.
With methyl orange after first end point with phenolphthalein :
phenolphthalein methyl orange
Na 2CO3  HCl 
 NaHCO3  NaCl 
HCl

 NaCl  H2CO3
(for second step)
 After achieving the phenolphthalein end point 50 mM of HCl will be sufficient to achieve the
methyl orange end point.
1 mole Na2CO3 in 1000 ml
 50×10–3 moles in 50 ml solution  50 millimoles

10.(BD)

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11.(ABCD)
Given, 25 mL of 0.2 N KMnO4 in acidic medium.
milli gm eq. of KMnO4  N  V  0.2  25  5
(A) milli gm eq. FeSO4 , M  V  n f  0.1 50  1  5
(B) milli gm eq. SnCl2 , M  V  n f  0.05  50  2  5
(C) milli gm eq. H3AsO3 , M  V  n f  0.1 25  2  5
(D) milli gm eq. H2O2 , M  V  n f  0.1 25  2  5
12.(BD) No effect of addition of inert gas at constant volume but entropy increases
13.(ABCD)
Constitutional isomers have same molecular formulae but different connectivity of functional groups
or atoms. Geometrical isomers [cis-trans, E–Z are diastereomers]
14.(ABCD)

15.(D) (A)

(B)

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(C)

(D)

16.(C) H 2SO4  H2C2O4  impurity  3.185g

Let, in 1000 mL x mmole y mmole
x y
For 10 mL solution m mole m mole
100 100
milli gm eq. of NaOH = milli gm eq. of H2SO4  milli gm eq. of H2C2O4
2x 2y
3  0.1  
100 100
2x  2y  0.3  100
2x  2y  30 …… (i)
For 100 mL solution
milli gm eq. of KMnO 4  milli gm eq. of H2C2O4
7
 Mn 2
K Mn O4  nf  5
3 4
H 2 C 2 O 4 
 CO 2 nf  2
2y
4  0.02  5   y2
10
On putting the value of y in eq. (i)
2x  4  30  x  13
milimoles of H 2 SO 4  13
13 103  98
Mass of H 2SO4  13  103  98g Mass % of H 2SO4   40 %
3.185
17.(D)

E  12.75eV ; En 2  En1  12.75 ; E 4  E1  12.75 , so n  4

18.(A) Oxidation state of S in H2SO4   6 , H2SO3   4 , H2S   2

So order of oxidation state of S : H 2SO4  H2SO3  H2S

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MATHEMATICS
1.(8) PA  PR  8  a
So PQ  8  a  b

Also QD  QS  8  b
So QP  8  b  a
8a b  8b a
 ab
PQ  8
1  3 1  3  32 3n  1
2.(8) Sn  1   .............  
2! 3!  3  1 n !
1 n 3r  1 1  3r 1 
 
2 r 1 r !
   
2  r ! r ! 
1 3 1
lim  Sn  
n  2   
e  1   e  1   e3  e   8.59
 2 
 Sn   8
3.(1) Equation of chord whose mid-point is (t, K – t)
2
tx  K  t  y t 2  K  t 
   …(i)
8 2 8 2
 2, 1 satisfy (i)


 5t 2   6  8 K  t  4 K 2  K  0 
For two distinct chords, D  0

 6  8K 2  4.4.5  K 2  K   0
 4K 2  4K  9  0
 1  10 1  10 
K   ,   a  b 1
 2 2 

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b b
4.(4) Let f  x   ax 2  c f   x   2ax  d
x x2
1 2
 b 3  b 3 b 27 ab 2
f   x   0, x     a    1
c  4
 2a   2a  c3
 b 3
 
 2a 
5.(8) x  y  z 1
 y  z    z  x   x  y   2
Let y  z  A, z  x  B, x y C
1  x 1  y 1  z    B  C  C  A A  B 
 1  x 1  y 1  z   8  x  y  x  z  z  x  …..(i)

As,  x  y  y  z  z  x   1  x 1  y 1  z 

 1   x  y  z    xy  yz  zx   xyz  xy  yz  zx  xyz

1 1 1 
 x  y  y  z  z  x   xyz     1  xyz  x 1  y 1  z 1  1
 x y z   
1
x 1  y 1  z 1  x  y  z 
Now  
3  3 
  x  y  y  z  z  x   8 xyz …..(ii)

 1  x 1  y 1  z   8.8 xyz

 1  1  1 
1   1   1    64
 x  y  z 

cos3  sin 3 
6.(7)   3
9a 5b
9a 5b
  56
cos  sin 
9a 5b
1
 1
 56
  9a  3   5b  3

2 2 3
 3 3
 9 a  3   5b  3    56    56 
 

Code A | JEE-2024 | Solutions | Paper - 2 12 JEE Adv. Full Test-1 (Gen 1 & 2)
 Vidyamandir Classes: Innovating For Your Success

 2
7.(4) Any point on the curve xy  4 is  2t , 
 t
 2 1
Slope of the tangent at  2t ,  is  2  equation of tangent is x  t 2 y  4t  0
 t t
Since it is tangent to x 2  y 2  8 also

4t
 2 2 i.e. t2  1
4
1 t
 equation of the tangent is x  y  4
Since the intercepts are positive  the tangent is x  y  4

8.(8) Centre of circles c1, c2 , c3 are in A.P.

General term for abscissa of centres  1   n  1 .3  3n  2  centre of c5 is (13, 0)
Radius of circles are in G.P.
 Rn  1.2n1  2n1  R3  4 and centre of c3 is (7, 0)
Tangents of circle c3 intersect each other at (13, 0) equation of any line passing through (13, 0) is

7 m  0  13m
y  0  m( x  13)  mx  y  13m  0 now it will be required tangents if 4
m2  1
2
 36m 2  16m 2  16  20m2  16  m 
5
2 2
Let m1  , m2    10 m1m2  8
5 5
(15 r ) r
9.(BC)  Tr 1  15Cr x 4    
x 3  15Cr x 60 7 r
(A) for the term independent of x, 60  70r  0  r is not an integer.
 there is no term independent of x.
(B) n = 15 is odd
n 1 n 1
 nCr will be maximum if r  or r  i.e. r  7 or r  8
2 2
 binomial coefficient of 8th and 9th terms will be greatest
(C) for the coefficient of x32 ; 60  7 r  32  r  4

 coefficient of x32 is  15C4

for the coefficient. of x 17 ; 60  7 r  17; r  11

 coefficient of x 17 is  15C11  15C4  (C) is correct.

60 7 r
(D) If x  2, Tr 1  15Cr 2 2
 for rational terms r  0, 2, 4, 6,...... 14

Code A | JEE-2024 | Solutions | Paper - 2 13 JEE Adv. Full Test-1 (Gen 1 & 2)
 Vidyamandir Classes: Innovating For Your Success

10.(BD) Let S  x 2  y 2  2 gx  2 fy  c  0

 it cuts x 2  y 2  4 orthogonally
 c4
Moreover 2 g  2 f  9  0
( ( g ,  f ) satisfy the given equation)

 S  x 2  y 2  2 gx  2 fy  4  0
 x 2  y 2   2 f  9  x  2 fy  4  0

 
 x2  y 2  9x  4  2 f  x  y   0
It is of the form S  P  0 and hence passes through the intersection of S = 0 and P = 0 which when
solved give  1/ 2,1/ 2  ,  4, 4  .
az  b ax  b  aiy (ax  b  aiy )(( x  1)  iy )
11.(BD)  
z 1 ( x  1)  iy ( x  1) 2  y 2
 az  b  (ax  b ) y  ay ( x  1) ( a  b) y
 Im    y
 z 1  2
( x  1)  y 2
( x  1)2  y 2
 a b 1
2
  x  1  y 2  1  x  1  1  y 2

12.(AD) Given, x1 and x2 are roots of  x 2  x    0 .


 x1  x2  and x1 x2  1

Also, | x1  x2 |  1
2
 x1  x2  1   x1  x2 2  1 or  x1  x2 2  4 x1x2  1
1 1
 2
 4  1 or 5
 2
 5 2  1  0 or  5  1 
5  1  0

 1   1 
    ,   , …(i)
 5  5 
Also, D0
 1 1
 1  4 2  0 or     ,  …(ii)
 2 2
From Eqs. (i) and (ii), we get
 1 1   1 1 
 ,  , 
 2 5   5 2
Code A | JEE-2024 | Solutions | Paper - 2 14 JEE Adv. Full Test-1 (Gen 1 & 2)
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13.(ABD) Let z   be a real root. Then  3   3  2i     1  ia   0

 3  3  1  i  a  2   0  3  3  1  0 and    a / 2

a3 3a
   1 0  a3  12a  8  0
8 2
Let f  a   a 3  12a  8  f  1  0 f  0   0 f  2   0 f 1  0 and f  3   0
Hence, a   1 0  or a   2 1 or a   2 3 

14.(AC) | z |  | z  cos   i sin  || z |  | z  ei |  | z  ( z  ei ) |  | ei |  1  | z |  | z  ei |  1

 4 17 
15.(C) Equation of BC is x  y  7 so B   , 
3 3 

m2 2 1
Let slope of AB is m so, 
1  2m 1  2
1
m
7
So equation of AB is 3 x  21 y  123  0
 17 21   67 131 
So A   ,  mid-point of AB   , 
 4 4  24 24 
Equation of median through C is 7 x  y  25

16.(C)
1  x n  1  x n  nc0  n c2 x 2  nc4 x 4  ...... ….(i)
2
1  ix n  1  ix n  nc0  nc2 x 2  n c4 x 4 ........ …(ii)
2
Adding (i) & (ii)
n n n n
1  1  x   1  x  1  ix   1  ix 
     n c0  n c4 x 4  .....
2

2 2   

 n

n n  2 2 cos n 
1 2 n
1  i   1  i   1  n1 4 
Put x = 1, we get    2 
2 2 2  2 2 
   
 

Code A | JEE-2024 | Solutions | Paper - 2 15 JEE Adv. Full Test-1 (Gen 1 & 2)
 Vidyamandir Classes: Innovating For Your Success

17.(D) Foot of perpendicular from focus on any tangent lies of tangent at the vertex.
Normal through given point be the axis of parabola,
y  2  4  x  1
4x  y  6

18.(B) f6  cos    cos 6  2 cos 2 3  1

2

 2 4 cos3   3cos    1  32 cos6   48 cos 4   18 cos 2   1

Code A | JEE-2024 | Solutions | Paper - 2 16 JEE Adv. Full Test-1 (Gen 1 & 2)