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T5300 Titan Superflex White

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Safety data sheet


according to 1907/2006/EC, Article 31
Printing date 24.05.2012 Version number 1 Revision: 24.05.2012

1 Identification of the substance/mixture and of the company/undertaking


· Product identifier
· Trade name: T5300 TITAN SUPERFLEX WHITE
· Relevant identified uses of the substance or mixture and uses advised against
· Application of the substance / the preparation
Titan Superflex is a self-priming flexible coating that forms a durable film, which reflect ultraviolet light and
prevent the passage of water and water vapor, recommended for both interior and exterior concrete surfaces. It
cures to an adherent film on property prepared surfaces capable of bridging hairline cracks on vertical walls.
The smooth nature of the film minimizes dirt pick-up and ensures long term durability and color retention.
· Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Pacifc Paint (Boysen) Phils., Inc.
292 D. Tuazon St., Quezon City
1115 Philippines
· Further information obtainable from: Product safety department
· Emergency telephone number:
Telephone Nos.: +63 2 364 3505; +63 2 365 0561
Facsimile Nos.: +63 2 367 8878; +63 2 364 0472
Email Address : inquiry@boysen.com.ph
Website Address : www.boysen.com.ph

2 Hazards identification
· Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008

GHS07

Skin Sens. 1 H317 May cause an allergic skin reaction.


· Classification according to Directive 67/548/EEC or Directive 1999/45/EC
Xi; Sensitising

R43: May cause sensitisation by skin contact.


· Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
· Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literature
data.
· Label elements
· Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous
Materials.
· Code letter and hazard designation of product:

Xi Irritant

(Contd. on page 2)
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Page 2/8
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 24.05.2012 Version number 1 Revision: 24.05.2012

Trade name: T5300 TITAN SUPERFLEX WHITE

(Contd. of page 1)

· Hazard-determining components of labelling:


mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2Hisothiazol-3-one [EC
no. 220-239-6] (3:1) mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-4-
isothiazolin-3-one [EC no. 220-239-6] (3:1)
· Risk phrases:
43 May cause sensitisation by skin contact.
· Safety phrases:
2 Keep out of the reach of children.
23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).
24 Avoid contact with skin.
29/56 Do not empty into drains, dispose of this material and its container at hazardous or special waste
collection point.
37 Wear suitable gloves.
46 If swallowed, seek medical advice immediately and show this container or label.
· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description: Mixture of substances listed below with nonhazardous additions.
· Dangerous components:
CAS: 13463-67-7 titanium dioxide 10-25%
EINECS: 236-675-5 substance with a Community workplace exposure limit
CAS: 471-34-1 calcium carbonate 10-25%
EINECS: 207-439-9 substance with a Community workplace exposure limit
CAS: 111-46-6 2,2'-oxybisethanol ≤ 2.5%
EINECS: 203-872-2 Xn R22
Acute Tox. 4, H302
CAS: 55965-84-9 mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2- ≤ 2.5%
methyl-2Hisothiazol-3-one [EC no. 220-239-6] (3:1) mixture of: 5-chloro-2-
methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-4-isothiazolin-3-
one [EC no. 220-239-6] (3:1)
T R23/24/25; C R34; Xi R43; N R50/53
Acute Tox. 3, H301; Acute Tox. 3, H311; Acute Tox. 3, H331; Skin
Corr. 1B, H314; Aquatic Acute 1, H400; Aquatic Chronic 1, H410; Skin
Sens. 1, H317
· Additional information:
For the wording of the listed risk phrases refer to section 16.
CAS: 7732-18-5 water, distilled, conductivity or of similar purity 25-50%
EINECS: 231-791-2
PH
(Contd. on page 3)

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 24.05.2012 Version number 1 Revision: 24.05.2012

Trade name: T5300 TITAN SUPERFLEX WHITE


(Contd. of page 2)

4 First aid measures


· Description of first aid measures
· After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing: If symptoms persist consult doctor.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.

5 Firefighting measures
· Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· Special hazards arising from the substance or mixture No further relevant information available.
· Advice for firefighters
· Protective equipment: No special measures required.

6 Accidental release measures


· Personal precautions, protective equipment and emergency procedures Not required.
· Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Dilute with plenty of water.
Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

7 Handling and storage


· Handling:
· Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
· Information about fire - and explosion protection: No special measures required.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Not required.
(Contd. on page 4)
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Page 4/8
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 24.05.2012 Version number 1 Revision: 24.05.2012

Trade name: T5300 TITAN SUPERFLEX WHITE

(Contd. of page 3)
· Further information about storage conditions: None.
· Specific end use(s) No further relevant information available.

8 Exposure controls/personal protection


· Additional information about design of technical facilities: No further data; see item 7.
· Control parameters
· Ingredients with limit values that require monitoring at the workplace:
13463-67-7 titanium dioxide
PEL (USA) 15* mg/m³
*total dust
REL (USA) See Pocket Guide App. A
TLV (USA) 10 mg/m³
471-34-1 calcium carbonate
PEL (USA) 15* 5** mg/m³
*total dust **respirable fraction
REL (USA) 10* 5** mg/m³
*total dust **respirable fraction
TLV (USA) TLV withdrawn
111-46-6 2,2'-oxybisethanol
WEEL (USA) 10 mg/m³
· Additional information: The lists valid during the making were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
· Protection of hands:

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
(Contd. on page 5)
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Page 5/8
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 24.05.2012 Version number 1 Revision: 24.05.2012

Trade name: T5300 TITAN SUPERFLEX WHITE

(Contd. of page 4)
· Eye protection: Goggles recommended during refilling

9 Physical and chemical properties


· Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Liquid
Colour: According to product specification
· Odour: Characteristic
· Odour threshold: Not determined.
· pH-value: 8.5 - 9.0
· Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 100°C
· Flash point: Not applicable.
· Flammability (solid, gaseous): Not applicable.
· Ignition temperature:
Decomposition temperature: Not determined.
· Self-igniting: Product is not selfigniting.
· Danger of explosion: Product does not present an explosion hazard.
· Explosion limits:
Lower: Not determined.
Upper: Not determined.
· Vapour pressure at 20°C: 23 hPa
· Density: 1.22 - 1.27 Kg/Li
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
water: Fully miscible.
· Segregation coefficient (n-octanol/water): Not determined.
· Viscosity: 92 -97 KU
· Dynamic: Not determined.
· Kinematic: Not determined.
· Solvent content:
Organic solvents: 0.0 %
Water: 49.0 %
VOC (EC) 0.1 g/Li
Solids content: 30.6 %
· Other information No further relevant information available.
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(Contd. on page 6)

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 24.05.2012 Version number 1 Revision: 24.05.2012

Trade name: T5300 TITAN SUPERFLEX WHITE


(Contd. of page 5)

10 Stability and reactivity


· Reactivity
· Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid No further relevant information available.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: No dangerous decomposition products known.

11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· Primary irritant effect:
· on the skin: Cause mild irritation
· on the eye: No irritating effect.
· Sensitization: Sensitization possible through skin contact.
· Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU Classification
Guidelines for Preparations as issued in the latest version:
Irritant

12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behaviour in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.

13 Disposal considerations
· Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
(Contd. on page 7)
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Page 7/8
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 24.05.2012 Version number 1 Revision: 24.05.2012

Trade name: T5300 TITAN SUPERFLEX WHITE

(Contd. of page 6)
· Recommended cleansing agents: Water, if necessary together with cleansing agents.

14 Transport information
· UN-Number
· ADR, IMDG, IATA Void
· UN proper shipping name
· ADR, IMDG, IATA Void
· Transport hazard class(es)
· ADR, IMDG, IATA
· Class Void
· Packing group
· ADR, IMDG, IATA Void
· Environmental hazards:
· Marine pollutant: No
· Special precautions for user Not applicable.
· Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
· UN "Model Regulation": -

15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· Philippines Inventory of Chemicals and Chemical Substances
13463-67-7 titanium dioxide
471-34-1 calcium carbonate
111-46-6 2,2'-oxybisethanol
7631-86-9 silicon dioxide, chemically prepared
21645-51-2 aluminium hydroxide
25265-77-4 2,2,4-trimethyl-1,3 pentanediol-monoisobutyrate
Texanol
9004-58-4 Ethylhydroxyethyl cellulose
Cellulose Ether
ethyl-2-hydroxyethylether
ethyl-2-hydroxyethyl cellulose
celluloseethylhydroxyethyl
Ethylhydroxyethyl cellulose
Cellulose ethyl hydroxyethyl ether
Etulose
1336-21-6 ammonia
9036-19-5 Polyethylene glycol octylphenyl ether
330-54-1 diuron(ISO)
10605-21-7 carbendazim (ISO)
(Contd. on page 8)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 24.05.2012 Version number 1 Revision: 24.05.2012

Trade name: T5300 TITAN SUPERFLEX WHITE

(Contd. of page 7)
25322-68-3 Polyethylene glycol
26530-20-1 2-octyl-2H-isothiazol-3-one
50-00-0 formaldehyde
10377-60-3 Magnesium nitrate 6-hydrate
Magnesium (II), hexahydrate
Nitric acid, magnesium salt, hexahydrate
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H331 Toxic if inhaled.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
R22 Harmful if swallowed.
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
R34 Causes burns.
R43 May cause sensitisation by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
· Department issuing MSDS:
Safety, Health and Environment Department
Gretchen A. Fontejon - g_fontejon@boysen.com.ph
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the
International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
ICAO: International Civil Aviation Organization
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
VOC: Volatile Organic Compounds (USA, EU)
· * Data compared to the previous version altered. 24.05.2012
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