Form No.

: 468-a Page 1/11

Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 02.07.2020 Vers.-Nr: 39 Revision: 26.06.2020

1 Identification of the substance/mixture and of the company/undertaking

· 1.1 Product identifier
· Trade name: Transpoxy Masterbond BT pack A
· Article number: 468-a
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
· Application of the substance/preparation: Paint
· 1.3 Details of the supplier of the safety data sheet
· Manufacturer/supplier:
Transocean Coatings
DYO Boya Fabrikalalari Sanayi ve Ticaret A.S.
A.O.S.B. 10003 Sokak No: 2, 35260 Cigli, Izmir, Turkey
Phone; +90-23203280880
www,dyo.com.tr
· 1.4 Emergency telephone number: Manufacturer/Supplier

2 Hazards identification
· 2.1 Classification of the substance or mixture
Flam. Liq. 3 H226 Flammable liquid and vapour.
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2 H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.
· 2.2 Label elements
· GHS label elements
The product is classified and labelled according to the Globally Harmonised System (GHS).
· Hazard pictograms

GHS02 GHS07

· Signal word Warning

· Hazard-determining components of labelling:
reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight =
700)
reaction product: bisphenol A-(epichlorhydrin); epoxy resin (number average molecular weigh >
700)
· Hazard statements
H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H412 Harmful to aquatic life with long lasting effects.
· Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
(Contd. on page 2)
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51.0.2
 Form No.: 468-a Page 2/11
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 02.07.2020 Vers.-Nr: 39 Revision: 26.06.2020

Trade name: Transpoxy Masterbond BT pack A

(Contd. of page 1)
P241 Use explosion-proof [electrical/ventilating/lighting] equipment.
P242 Use non-sparking tools.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin
with water [or shower].
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P321 Specific treatment (see on this label).
P337+P313 If eye irritation persists: Get medical advice/attention.
P403+P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container in accordance with local/regional/national/
international regulations.
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

3 Composition/information on ingredients
· 3.2 Chemical characterisation: Mixtures
· Description: Mixture of substances listed below with nonhazardous additions.
· Dangerous components:
CAS: 25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin ≥10-<25%
NLP: 500-033-5 (number average molecular weight = 700)
Aquatic Chronic 2, H411; Skin Irrit. 2, H315; Eye Irrit. 2,
H319; Skin Sens. 1, H317
CAS: 25036-25-3 reaction product: bisphenol A-(epichlorhydrin); epoxy resin 10-25%
NLP: 500-033-5 (number average molecular weigh > 700)
Skin Sens. 1, H317
CAS: 1330-20-7 xylene, mixture of isomers ≥2,5-<10%
EINECS: 215-535-7 Flam. Liq. 3, H226; Acute Tox. 4, H312; Acute Tox. 4,
H332; Skin Irrit. 2, H315
CAS: 71-36-3 butan-1-ol ≥1-≤2,5%
EINECS: 200-751-6 Flam. Liq. 3, H226; Eye Dam. 1, H318; Acute Tox. 4,
H302; Skin Irrit. 2, H315; STOT SE 3, H335-H336
CAS: 107-98-2 1-methoxy-2-propanol ≤2,5%
EINECS: 203-539-1 Flam. Liq. 3, H226; STOT SE 3, H336
CAS: 64742-94-5 Solvent naphtha (petroleum), heavy arom. ≥0,25-<2,5%
EINECS: 265-198-5 Asp. Tox. 1, H304; Aquatic Chronic 2, H411; STOT
SE 3, H336
· Additional information: For the wording of the listed hazard phrases refer to section 16.
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(Contd. on page 3)

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 Form No.: 468-a Page 3/11
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 02.07.2020 Vers.-Nr: 39 Revision: 26.06.2020

Trade name: Transpoxy Masterbond BT pack A

(Contd. of page 2)

4 First aid measures

· 4.1 Description of first aid measures
· After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing: If symptoms persist consult doctor.
· 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

5 Firefighting measures
· 5.1 Extinguishing media
· Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.
· 5.2 Special hazards arising from the substance or mixture
No further relevant information available.
· 5.3 Advice for firefighters
· Protective equipment: No special measures required.

6 Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
· 6.2 Environmental precautions:
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
· 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

7 Handling and storage

· 7.1 Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
· Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
(Contd. on page 4)
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51.0.2
 Form No.: 468-a Page 4/11
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 02.07.2020 Vers.-Nr: 39 Revision: 26.06.2020

Trade name: Transpoxy Masterbond BT pack A

(Contd. of page 3)

· 7.2 Conditions for safe storage, including any incompatibilities

· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Keep container tightly sealed.
· 7.3 Specific end use(s) No further relevant information available.

8 Exposure controls/personal protection

· Additional information about design of technical facilities: No further data; see item 7.
· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
1330-20-7 xylene, mixture of isomers
MMSD (Turkey) Short-term value: 442 mg/m³, 100 ppm
Long-term value: 221 mg/m³, 50 ppm
Deri
107-98-2 1-methoxy-2-propanol
MMSD (Turkey) Short-term value: 568 mg/m³, 150 ppm
Long-term value: 375 mg/m³, 100 ppm
Deri
· DNELs
1330-20-7 xylene, mixture of isomers
Dermal long term DNEL 108 mg/kg/d (General Population)
180 mg/kg/d (Workers)
Inhalative long term DNEL 14,8 mg/m3 (General Population)
77 mg/m3 (Workers)
71-36-3 butan-1-ol
Oral long term DNEL 3.125 mg/kg/d (General Population)
Inhalative long term DNEL 55 mg/m3 (General Population)
310 mg/m3 (Workers)
107-98-2 1-methoxy-2-propanol
Oral long term DNEL 3,3 mg/kg/d (General Population)
Dermal long term DNEL 18,1 mg/kg/d (General Population)
50,6 mg/kg/d (Workers)
Inhalative long term DNEL 43,9 mg/m3 (General Population)
369 mg/m3 (Workers)
Acute DNEL 553,5 mg/m3 (Workers)
· PNECs
1330-20-7 xylene, mixture of isomers
PNEC STP 6,58 mg/l (water treatment plant)
PNEC aqua 327 ug/l (freshwater)
327 ug/l (marine water)
PNEC sediment 12,46 mg/kg (freshwater)
12,46 mg/kg (marine water)
(Contd. on page 5)
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 Form No.: 468-a Page 5/11
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 02.07.2020 Vers.-Nr: 39 Revision: 26.06.2020

Trade name: Transpoxy Masterbond BT pack A

(Contd. of page 4)
PNEC soil 2,31 mg/kg (Soil)
71-36-3 butan-1-ol
PNEC STP 2.476 mg/l (water treatment plant)
2,25 mg/l (intermittent release)
PNEC aqua 8,2 ug/l (marine water)
PNEC sediment 0,178 mg/kg (freshwater)
0,0178 mg/kg (marine water)
PNEC soil 0,015 mg/kg (Soil)
107-98-2 1-methoxy-2-propanol
PNEC STP 100 mg/l (water treatment plant)
PNEC aqua 10.000 ug/l (freshwater)
PNEC sediment 41,6 mg/kg (freshwater)
4,17 mg/kg (marine water)
PNEC soil 2,47 mg/kg (Soil)
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer
exposure use self-contained respiratory protective device.
· Protection of hands:

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the
preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the
preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks
of quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore
to be checked prior to the application.
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and
has to be observed.
(Contd. on page 6)
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51.0.2
 Form No.: 468-a Page 6/11
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 02.07.2020 Vers.-Nr: 39 Revision: 26.06.2020

Trade name: Transpoxy Masterbond BT pack A

(Contd. of page 5)
· Eye protection:

Tightly sealed goggles

9 Physical and chemical properties

· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Fluid
Colour: According to product specification
· Odour: Characteristic
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in condition
Melting point/freezing point: Undetermined.
Initial boiling point and boiling range: 140 °C
· Flash point: 25 °C
· Flammability (solid, gas): Not applicable.
· Ignition temperature: >300 °C
· Decomposition temperature: Not determined.
· Auto-ignition temperature: Product is not selfigniting.
· Explosive properties: Product is not explosive. However, formation of
explosive air/vapour mixtures are possible.
· Explosion limits:
Lower: Not determined.
Upper: Not determined.
· Vapour pressure: Not determined.
· Density at 20 °C: 1,51851 g/cm³
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
water: Not miscible or difficult to mix.
· Partition coefficient: n-octanol/water: Not determined.
· Viscosity:
Dynamic at 20 °C: 2.000 mPas
Kinematic: Not determined.
· Solvent content:
VOC (EC) 210,6 g/l
(Contd. on page 7)
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 Form No.: 468-a Page 7/11
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 02.07.2020 Vers.-Nr: 39 Revision: 26.06.2020

Trade name: Transpoxy Masterbond BT pack A

(Contd. of page 6)

· 9.2 Other information No further relevant information available.

10 Stability and reactivity

· 10.1 Reactivity No further relevant information available.
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions No dangerous reactions known.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: No further relevant information available.
· 10.6 Hazardous decomposition products: No dangerous decomposition products known.

11 Toxicological information
· 11.1 Information on toxicological effects
· Acute toxicity
· LD/LC50 values relevant for classification:
25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average
molecular weight = 700)
Oral LD50 >5.000 mg/kg (rat)
LC50/ 96 hr 1,5 mg/l (fish)
Dermal LD50 >2.000 mg/kg (rat)
25036-25-3 reaction product: bisphenol A-(epichlorhydrin); epoxy resin (number average
molecular weigh > 700)
Oral LD50 >2.000 mg/kg (rat)
Dermal LD50 >2.000 mg/kg (rabbit)
Inhalative LC50/4 h >4.000 mg/l (rat)
1330-20-7 xylene, mixture of isomers
Oral LD50 >2.000 mg/kg (rat)
LC50/ 96 hr (static) 2,6 mg/l (Rainbow trout (Oncorhynchus mykiss)) (OESO 203 or
equivalent)
Dermal LD50 >2.000 mg/kg (rabbit)
Inhalative LC50/4 h >20 mg/l (rat)
71-36-3 butan-1-ol
Oral LD50 2.292 mg/kg (rat)
LC50/ 96 hr 1.376 mg/l (fish)
Dermal LD50 3.400 mg/kg (rabbit)
Inhalative LC50/4 h 17,76 mg/l (rat)
107-98-2 1-methoxy-2-propanol
Oral LD50 4.016 mg/kg (rat)
LC50/ 96 hr 6.812 mg/l (fish)
Dermal LD50 2.000 mg/kg (rabbit)
Inhalative LC50/4 h 6 mg/l (rat)
(Contd. on page 8)
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 Form No.: 468-a Page 8/11
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 02.07.2020 Vers.-Nr: 39 Revision: 26.06.2020

Trade name: Transpoxy Masterbond BT pack A

(Contd. of page 7)
64742-94-5 Solvent naphtha (petroleum), heavy arom.
Oral LD50 >2.000 mg/kg (rat)
Dermal LD50 >2.000 mg/kg (rat)
· Primary irritant effect:
· Skin corrosion/irritation Irritant to skin and mucous membranes.
· Serious eye damage/irritation Irritating effect.
· Respiratory or skin sensitisation Sensitisation possible through skin contact.
· Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU
Classification Guidelines for Preparations as issued in the latest version:
Irritant

12 Ecological information
· 12.1 Toxicity
· Aquatic toxicity:
25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average
molecular weight = 700)
EC 50 (48 hr) 1,7 mg/l (daphnia)
EC 50 (72 hr) 9,4 mg/l (Algae)
1330-20-7 xylene, mixture of isomers
EC 50 (48 hr) 1-10 mg/l (daphnia)
EC 50 (72 hr) 1-10 mg/l (Algae)
71-36-3 butan-1-ol
EC 50 (48 hr) 1.328 mg/l (daphnia)
107-98-2 1-methoxy-2-propanol
EC 50 (48 hr) 23.300 mg/l (daphnia)
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Ecotoxical effects:
· Remark: Harmful to fish
· Additional ecological information:
· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Harmful to aquatic organisms
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.
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(Contd. on page 9)

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 Form No.: 468-a Page 9/11
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 02.07.2020 Vers.-Nr: 39 Revision: 26.06.2020

Trade name: Transpoxy Masterbond BT pack A

(Contd. of page 8)

13 Disposal considerations
· 13.1 Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage
system.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.

14 Transport information
· 14.1 UN-Number
· ADR, ADN, IMDG Void
· IATA UN1263
· 14.2 UN proper shipping name
· ADR, ADN, IMDG Void
· IATA PAINT
· 14.3 Transport hazard class(es)
· ADR, ADN, IMDG
· Class Void
· IATA

· Class 3 Flammable liquids.

· Label 3
· 14.4 Packing group
· ADR, IMDG Void
· IATA III
· 14.5 Environmental hazards:
· Marine pollutant: No
· 14.6 Special precautions for user Not applicable.
· 14.7 Transport in bulk according to Annex II
of Marpol and the IBC Code Not applicable.
· UN "Model Regulation": Void

15 Regulatory information
· 15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
· GHS label elements
The product is classified and labelled according to the Globally Harmonised System (GHS).
(Contd. on page 10)
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 Form No.: 468-a Page 10/11
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 02.07.2020 Vers.-Nr: 39 Revision: 26.06.2020

Trade name: Transpoxy Masterbond BT pack A

(Contd. of page 9)
· Hazard pictograms

GHS02 GHS07

· Signal word Warning

· Hazard-determining components of labelling:
reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight =
700)
reaction product: bisphenol A-(epichlorhydrin); epoxy resin (number average molecular weigh >
700)
· Hazard statements
H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H412 Harmful to aquatic life with long lasting effects.
· Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof [electrical/ventilating/lighting] equipment.
P242 Use non-sparking tools.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin
with water [or shower].
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P321 Specific treatment (see on this label).
P337+P313 If eye irritation persists: Get medical advice/attention.
P403+P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container in accordance with local/regional/national/
international regulations.
· Directive 2012/18/EU
· Named dangerous substances - ANNEX I None of the ingredients is listed.
· Seveso category P5c FLAMMABLE LIQUIDS
· Qualifying quantity (tonnes) for the application of lower-tier requirements 5.000 t
· Qualifying quantity (tonnes) for the application of upper-tier requirements 50.000 t
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee
for any specific product features and shall not establish a legally valid contractual relationship.
(Contd. on page 11)
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 Form No.: 468-a Page 11/11
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 02.07.2020 Vers.-Nr: 39 Revision: 26.06.2020

Trade name: Transpoxy Masterbond BT pack A

(Contd. of page 10)

· Relevant phrases
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H411 Toxic to aquatic life with long lasting effects.
· Abbreviations and acronyms:
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations
Concerning the International Transport of Dangerous Goods by Rail)
ICAO: International Civil Aviation Organisation
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Flam. Liq. 3: Flammable liquids – Category 3
Acute Tox. 4: Acute toxicity - dermal – Category 4
Skin Irrit. 2: Skin corrosion/irritation – Category 2
Eye Dam. 1: Serious eye damage/eye irritation – Category 1
Eye Irrit. 2: Serious eye damage/eye irritation – Category 2
Skin Sens. 1: Skin sensitisation – Category 1
STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
Asp. Tox. 1: Aspiration hazard – Category 1
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2
Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
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