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    Experiment 16

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    Beenu Singh
    The document describes an experiment to detect acidic and basic radicals in a given compound. Tests were performed to identify the radicals, including silver nitrate and manganese dioxide tests to detect chloride ions and reactions involving sodium hydroxide and nessler's reagent to detect ammonium ions. The results showed the compound contained chloride ions as the acidic radical and ammonium ions as the basic radical. Precautions were listed to safely handle the reagents and glassware during the experiment.

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    Experiment 16

    Uploaded by

    Beenu Singh
    36 views3 pages
    The document describes an experiment to detect acidic and basic radicals in a given compound. Tests were performed to identify the radicals, including silver nitrate and manganese dioxide tests to detect chloride ions and reactions involving sodium hydroxide and nessler's reagent to detect ammonium ions. The results showed the compound contained chloride ions as the acidic radical and ammonium ions as the basic radical. Precautions were listed to safely handle the reagents and glassware during the experiment.

    Original Description:

    class 12 chemistry practical

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    The document describes an experiment to detect acidic and basic radicals in a given compound. Tests were performed to identify the radicals, including silver nitrate and manganese dioxide tests to detect chloride ions and reactions involving sodium hydroxide and nessler's reagent to detect ammonium ions. The results showed the compound contained chloride ions as the acidic radical and ammonium ions as the basic radical. Precautions were listed to safely handle the reagents and glassware during the experiment.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    36 views3 pages

    Experiment 16

    Uploaded by

    Beenu Singh
    The document describes an experiment to detect acidic and basic radicals in a given compound. Tests were performed to identify the radicals, including silver nitrate and manganese dioxide tests to detect chloride ions and reactions involving sodium hydroxide and nessler's reagent to detect ammonium ions. The results showed the compound contained chloride ions as the acidic radical and ammonium ions as the basic radical. Precautions were listed to safely handle the reagents and glassware during the experiment.

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    EXPERIMENT-16

    ➢ AIM: To detect the acidic and basic radical in the given compound.

    ➢ APPARATUS REQUIRED: Test-tube, test-tube stand, nessler’s reagent, dilute


    HNO3, manganese dioxide, concentrated H2SO4.
    ➢ PROCEDURE:
     TEST FOR ACIDIC RADICALS -

    EXPERIMENT OBSERVATION INFERENCE


    To the salt add dil. H SO . 2 4 No Reaction. CO32- is absent.
    To the salt add conc. H SO . 2 4 Colourless gas with Cl may be present.
    -

    pungent.
    Confirmatory Test -
    Silver Nitrate Test: Cl- is confirmed.
    Acidify a portion of aqueous A white precipitate is
    solution with dil. HNO boil 3
    formed.
    for some time cool and add
    AgNO solution.
    3

    Manganese Dioxide Test:


    Heat a pinch of salt with a Evolution of greenish Cl- is confirmed.
    small quantity of MnO and 2 yellow gas having a
    Concentrated H SO . 2 4 pungent smell.
    Chromyl Chloride Test:
    Mix a small quantity of salt A yellow precipitate is Cl- is confirmed.
    with a small amount of formed.
    powdered K Cr O . Take it in
    2 2 7

    a test tube and add


    conc.H SO . Heat the test
    2 4

    tube and pass the red vapours


    evolved into the gas detector
    containing NaOH solution.
    To the yellow solution thus
    obtained add dilute acetic
    acid and lead acetate
    solution.
     TEST FOR BASIC RADICAL -

    EXPERIMENT OBSERVATION INFERENCE


    Take solid salt and add Evolution of ammonia NH4+ may be present.
    concentrated solution of gas which has a
    NaOH. characteristic
    ammoniacal smell.
    Confirmatory Test-
    Bring a glass rod dipped in White fumes are NH4+ is confirmed.
    HCl near the mouth of the observed.
    test tube. NH4+ is confirmed.
    Pass the gas with nessler’s Brown precipitate is
    reagent. observed.

    ➢ RESULT:
    Acidic Radical -Chloride (Cl )-

    Basic Radical - Ammonium (NH ) 4


    +

    ➢ PRECAUTIONS:
    1. Handle reagents carefully.
    2. Wash test tube after chemical reaction.
    3. Do not use broken glassware.
    Blank page 1 (In correspondence to 1st page)
    ➢ CHEMICAL REACTIONS:
    • Silver Nitrate Test: (write the following reaction with pencil)
     NaCl + AgNO3 ⟶ AgCl↓ +NaNO3
    (White ppt.)
     AgCl + 2NH4OH ⟶ [Ag (NH3)2] Cl +2H2O
    (Soluble complex)

    • Manganese Dioxide Test: (write the following reaction with pencil)


    • 2NaCl + MNO2 + 3H2SO4 ⟶ 2NaHSO4 + MnSO4 + 2H2O + Cl2 ↑

    • Chromyl Chloride Test: (write the following reaction with pencil)


     4NaCl + K2Cr2O7 + 6H2SO4 ⟶ 4NaHSO4 + 2K5O4 + 2CrO2Cl2 + 3H2O
    (Chromyl chloride)
     CrO2Cl2 + 4NaOH ⟶Na2CrO4 + 2H2O + 2NaCl
    (Sodium chromate)
     Na2CrO4 + (CH3COO)2Pb ⟶ PbCrO4↓ + 2CH3COONa
    Lead chromate
    (Yellow ppt.)

    Blank page 2 (In correspondence to 2nd page)


    • Reactions Involved in Zero Group Analysis: (write the following reaction with
    pencil)
    ∆
     NH4Cl + NaOH → NaCl + N2O + NH3↑

     NH3 + HCl → NH4Cl


    (White fumes)
    • Nessler’s Reagent: (write the following reaction with pencil)
    2K2 [HgI4] + NH3 + 3KOH ⟶ H2N.HgO.HgI↓ + 7KI + 2H2O
    (Brown Precipitate)

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