Scribd Logo
Upload

Welcome to Scribd!

  • 19 views

    Two Salt Analysis PDF

    Uploaded by

    luffyanime121

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    Two Salt Analysis PDF

    Uploaded by

    luffyanime121
    19 views3 pages

    Original Title

    Two Salt Analysis.pdf

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    19 views3 pages

    Two Salt Analysis PDF

    Uploaded by

    luffyanime121

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    You are on page 1of 3

    Never rinse the conical flask with experimental solutions.

    Remove the air gaps from the burette.


    Do not boil the solution.

    Experiment No. 3

    Aim : To detect Acid and Basic Radical In given Unknown Inorganic


    Sample.

    SAMPLE 1

    Experiment Observation Inference


    1. PHYSICAL EXAMINATION
    Colour of the sample is noted White colour Cu2+,Fe2+,Fe3+,Ni2+, Mn2+,Co2+
    are absent
    A little amount of the sample is Pungent smell evolved NH4+ may be present
    rubbed between thumb and
    finger.
    2.Dry Test Tube Heating : Pungent gas evolved along NH4+ ,Cl- may be present
    Heated small amount of the with formation of white
    sample in a dry test tube. sublimate
    3.Flame test was performed. No characteristic colour in Ca2+,Sr2+,Ba2+and Cu2+ may be
    the flame absent.

    4.Small amount of the sample is Effervescence with S2-, NO2-,may be absent.


    treated with dilute H2SO4 and evolution of colourless, CO32- may be present.
    and pass the gas through lime odourless gas
    water
    5.Small amount of the solid Colourless and odourless NO3-, Cl-, Br- may be absent.
    sample is treated with gas evolved with CO32- may be present.
    concentrated H2SO4. effervescence.
    Confirmatory test for acid radicals :
    8.Small amount of the solid Effervescence with CO32- is present and
    sample is treated with Dilute evolution of colourless, confirmed.
    H2SO4 and the evolved gas is odourless gas which turns
    passed through lime water. lime water milky.
    Preparation of aqueous extract :
    Aqueous extract of the sample was prepared and following test for acid radical was
    performed.
    9. Small amount of the sample is Lime water turns milky and CO32- is present and
    treated with dilute H2SO4 and milkiness disappears on confirmed.
    and pass the gas through lime passing excess lime water.
    water
    10. To the aqueous solution of White precipitate was CO32- is present and confirmed
    sample MgSO4 solution was formed
    added.
    Confirmatory test for basic
    radicals :

    11. Heated the solid sample with Colourless gas with pungent NH4+ (Group 0) may be
    NaOH solution in a test tube. smell evolves. present.
    Following test was performed
    with the evolved gas:
    12.A glass rod dipped in HCl White dense fumes NH4+ (Group 0)is present and
    was brought near the mouth of produced confirmed.
    the test tube.
    13.Salt solution + nesslar reagent reddish brown ppt. obtained NH4+ (Group 0) is present and
    confirmed.

    The given salt contains :


    Basic Radical : NH4+
    Acid Radical : CO32-

    Experiment No. 4

    Analysis of Acid and Basic radical in given inorganic


    salt.
    Aim : To detect Acid and Basic Radical In given Unknown Inorganic
    Sample.
    SAMPLE 2

    Experiment Observation Inference


    1. PHYSICAL EXAMINATION
    Colour of the sample is noted White colour Cu2+,Fe2+,Fe3+,Ni2+, Mn2+,Co2+
    are absent
    A little amount of the sample is No pungent smell evolved NH4+, S2- may be absent
    rubbed between thumb and
    finger.
    2.Dry Test Tube Heating : Formation of white sublimate NH4+ may be present
    Heated small amount of the
    sample in a dry test tube.
    3.Flame test was performed. No characteristic colour in the Ca2+,Sr2+,Ba2+and Cu2+ may be
    flame absent.

    4.Small amount of the sample is No gas evolves S2-, NO2-, CO32- may be absent.
    treated with dilute H2SO4 .
    5.Small amount of the solid Pungent smelling gas evolved . Cl- may be present
    sample is treated with It gives dense white fumes with
    concentrated H2SO4. rod dipped in NH4OH.
    6. When this gas comes in contact Blue Litmus paper turns red Cl- may be present
    with blue litmus paper

    Confirmatory test for acid radicals :

    7.Acidified the solution with Curdy White precipitate Cl - is present and confirmed.
    dilute HNO3 and AgNO3 formed which dissoved in
    solution was added. excess NH4OH
    Confirmatory test for basic
    radicals :
    13. Heated the solid sample with Colourless gas with pungent NH4+ (Group 0) may be
    NaOH solution in a test tube. smell evolves. present.

    Following test was performed


    with the evolved gas:
    14.A glass rod dipped in HCl White dense fumes produced NH4+ (Group 0)is present and
    was brought near the mouth of confirmed.
    the test tube.
    13.Salt solution + nesslar reagent reddish brown ppt. obtained NH4+ (Group 0) is present and
    confirmed.

    The given salt contains:


    Basic Radical : NH4+
    Acid Radical : Cl-

    Experiment No. 5
    Preparation Of Ferrous Ammonium Sulphate (Mohr Salt)
    Aim : To Preparare Ferrous Ammonium Sulphate (Mohr Salt)
    Materials Required:
    Beaker, Conical flask(250ml), Funnel, Glass rod, Tripod Stand, Bunsen Burner

    Chemical Required :
    Ferrous Sulphate, Ammonium Sulphate, Dilute H2SO4, Distilled water

    Theory: When a mixture containing equimolar proportions of ferrous sulphate and ammonium sulphate
    is crystallised from its solution, a double salt is formed. The formation of double salt may be
    shown as follows:
    FeSO4 + (NH4)2 SO4 + 6H2O → FeSO4 . (NH4)2 SO4 . 6H2O
    Ferrous ammonium sulphate (Mohr’s salt)
    2+
    Fe and ions undergo hydrolysis, therefore, while preparing aqueous solutions of ferrous sulphate in
    water, 2-3 mL dilute sulphuric acid is added to prevent the hydrolysis of these salts.

    Procedure :
    ➢ Dissolve 3.5 g of ferrous sulphate and 1.7 g of ammonium sulphate (weighed separately), in 5 mL of
    distilled water contained in a 50 mL conical flask by heating.
    ➢ Add about 5 mL of dilute sulphuric acid to the flask and concentrate the solution by heating till the
    crystallization point is reached.
    ➢ Allow the mixture to cool to room temperature slowly.
    ➢ On cooling, light green crystals of ferrous ammonium sulphate separate out.
    ➢ Decant the mother liquor and wash the crystals by shaking with very small amounts of 1:1 cold water
    and alcohol mixture to remove sticking mother liquor.
    ➢ Separate the crystals by filtration wash with alcohol, dry between the folds of a filter paper and record
    the yield.

    Result : Yield of potash alum/Mohr’s salt is 3.8 g.

    Precaution:
    ➢ Cool the solution slowly to get good crystals. Avoid rapid cooling.
    ➢ Do not disturb the solution while cooling.
    ➢ Avoid prolonged heating while preparing crystals of ferrous ammonium sulphate, as it may oxidise
    ferrous ions to ferric ions and change the stoichiometry of the crystals.

    You might also like