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    11th Atkins Physical Chemistry Student Solutions Manual-1

    Uploaded by

    Javier Palomino Garate
    This document contains information about the properties of gases including: 1. Details about perfect gases and how to calculate various properties like pressure, volume, amount using the ideal gas law. 2. Details about the kinetic model of gases and concepts like root mean square speed and average molecular speed. 3. Information about real gases and how their properties deviate from ideal gas behavior. Concepts discussed include van der Waals equation of state and critical properties. 4. Various calculations related to gas properties like pressure, volume, temperature are presented along with sample data for different gases.

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    11th Atkins Physical Chemistry Student Solutions Manual-1

    Uploaded by

    Javier Palomino Garate
    393 views2 pages
    This document contains information about the properties of gases including: 1. Details about perfect gases and how to calculate various properties like pressure, volume, amount using the ideal gas law. 2. Details about the kinetic model of gases and concepts like root mean square speed and average molecular speed. 3. Information about real gases and how their properties deviate from ideal gas behavior. Concepts discussed include van der Waals equation of state and critical properties. 4. Various calculations related to gas properties like pressure, volume, temperature are presented along with sample data for different gases.

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    This document contains information about the properties of gases including: 1. Details about perfect gases and how to calculate various properties like pressure, volume, amount using the ideal gas law. 2. Details about the kinetic model of gases and concepts like root mean square speed and average molecular speed. 3. Information about real gases and how their properties deviate from ideal gas behavior. Concepts discussed include van der Waals equation of state and critical properties. 4. Various calculations related to gas properties like pressure, volume, temperature are presented along with sample data for different gases.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    393 views2 pages

    11th Atkins Physical Chemistry Student Solutions Manual-1

    Uploaded by

    Javier Palomino Garate
    This document contains information about the properties of gases including: 1. Details about perfect gases and how to calculate various properties like pressure, volume, amount using the ideal gas law. 2. Details about the kinetic model of gases and concepts like root mean square speed and average molecular speed. 3. Information about real gases and how their properties deviate from ideal gas behavior. Concepts discussed include van der Waals equation of state and critical properties. 4. Various calculations related to gas properties like pressure, volume, temperature are presented along with sample data for different gases.

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    1

    1 The properties of gases

    1A The perfect gas


    E1A.1(a) 810 Torr 0.962 atm
    E1A.2(a) no 24.4 atm
    E1A.3(a) 3.42 bar 3.38 atm
    E1A.4(a) 30 lb in−2 .
    E1A.5(a) 0.0427 bar 4.27 × 105 Pa
    E1A.6(a) S8 .
    E1A.7(a) 6.2 kg
    E1A.8(a) x O2 = 0.240 x N2 = 0.760 p O2 = 0.237 bar p N2 = 0.750 bar x N2 = 0.780
    x O2 = 0.210 p N2 = 0.770 bar p O2 = 0.207 bar
    E1A.9(a) 0.169 kg mol−1
    E1A.10(a) θ = −273 ○ C
    E1A.11(a) x H2 = 23 x N2 = 13 p H2 = 2.0×105 Pa p N2 = 1.0×105 Pa p tot = 3.0×105 Pa
    P1A.1 1.15 × 105 Pa 8.315 J K−1 mol−1
    P1A.3 0.082062 atm dm3 mol−1 K−1
    P1A.5 p = ρRT/M 45.94 g mol−1
    P1A.7 24.5 Pa 9.14 kPa 24.5 Pa
    P1A.9 between 0.27 km3 and 0.41 km3
    P1A.11 −2 Pa 0.25 atm
    P1A.13 c CCl3 F = 1.1 × 10−11 mol dm−3 c CCl2 F2 = 2.2 × 10−11 mol dm−3 c CCl3 F = 8.0 ×
    10−13 mol dm−3 c CCl2 F2 = 1.6 × 10−12 mol dm−3

    1B The kinetic model


    E1B.1(a) 9.975
    E1B.2(a) υ rms,H2 = 1.90 km s−1 υ rms,O2 = 478 m s−1
    E1B.3(a) 6.87 × 10−3
    E1B.4(a) 1832 m s−1
    E1B.5(a) υ mp = 333 m s−1 υ mean = 376 m s−1 υ rel = 531 m s−1
    E1B.6(a) 1.7 × 1010 s−1
    E1B.7(a) 475 m s−1 82.9 nm 8.10 × 109 s−1
    E1B.8(a) 0.20 Pa
    E1B.9(a) 1.4 × 10−6 m = 1.4 µm
    P1B.3 υmean, new ≈ 0.493 υmean
    P1B.5 3.02 × 10−3 for n = 3 4.89 × 10−6 for n = 4
    P1B.7 1.12 × 104 m s−1 5.04 × 103 m s−1
    2

    P1B.9 0.0722 at 300 K 0.0134 at 1000 K


    P1B.11 9.7 × 1010 s−1

    1C Real gases
    E1C.1(a) 0.99 atm 1.8 × 103 atm
    E1C.2(a) a = 0.0761 kg m5 s−2 mol−2 b = 2.26 × 10−5 m3 mol−1
    E1C.3(a) 0.88 1.2 dm3 mol−1
    E1C.4(a) 140 atm
    E1C.5(a) 50.7 atm 35.2 atm 0.695
    E1C.6(a) 1.78 atm dm6 mol−2 0.0362 dm3 mol−1 153 pm
    E1C.7(a) 1.41 × 103 K 175 pm
    E1C.8(a) 8.7 atm 3.6 × 103 K 4.5 atm 2.6 × 103 K 0.18 atm 47 K
    E1C.9(a) 4.6 × 10−5 m3 mol−1 0.66
    P1C.1 1.62 atm
    P1C.3 0.929 0.208 dm3 mol−1
    P1C.5 501.0 K
    P1C.7 0.1353 dm3 mol−1 0.6957 0.5914
    P1C.9 0.0594 dm3 mol−1 5.849 atm dm6 mol−2 . 20.48 atm
    P1C.11 0.03464 dm3 mol−1 1.262 atm dm6 mol−2
    P1C.13 Vm = 3C/B T = B 2 /3CR p = B 3 /27C 2
    P1C.15 B = 0.0868 atm
    ′ −1
    B = 2.12 dm mol−1
    3
    bp
    P1C.19 1 + 1.11
    RT
    P1C.21 −0.01324 dm3 mol−1 1.063 × 10−3 dm6 mol−2
    P1C.23 Vm = 13.6 dm3 mol−1 2%
    2RT 1/2
    I1.1 υ = ( )
    M
    3
    I1.3 0.071 dm mol−1

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