26 1655 01 Solutions Automotive Appearance Applications

AU TO C ARE
Reliable solutions from Dow

for automotive appearance
Formulation guide
Contents
Formulating tips and resources Exterior trim protection
Auto care formulation information: general auto polish Exterior plastic/rubber enhancers – Liquid
and formulation tips
Exterior plastic/rubber enhancers – Sheen finish
Automotive appearance chemicals application selector
Exterior plastic/rubber enhancers – Aerosol product
and product comparison guide
Exterior plastic/rubber enhancers – Gel
Dow C.A.R.B.-Compliant solutions for automotive surfaces
Premium protectant lotion (Low odor)
Tip sheet for California Regulations for Auto
Appearance Products Glass cleaner
Auto care raw material explanations Glass care – Screenwash
Glass care – Cleaner
Product formulations
Glass cleaner with ammonia and citric glass cleaner
Automotive wax
Anti-fog glass cleaner
Emulsion hard wax
Hard wax
Interior protection
Cockpit enhancers – Aerosol product
Wax conditioner
Cockpit enhancers – Liquid
Low-voc polish
Cockpit enhancers – Sheen finish
Car polish
Leather conditioner lotion
Paintable polish
Vinyl protectant
Spray-and-wipe polish
Creamy vinyl surface protectant
Instant car polish
Fabric water repellent
Low-solvent liquid polish
Multi-surface medium shine dressing
Polish
Premium protectant lotion (Low odor)
Car wash
Leather conditioner lotion
Standard shampoo
Cockpit enhancer – Sheen finish
Protective shampoo – Formulation I
Protective shampoo – Formulation II
Polymer sealant
Polymer sealant liquid
Dry washer
Pre-softened polymer sealant paste – Formulation I
Shampoo for use in professional detailing Pre-softened polymer sealant paste – Formulation II
Concentrated Wax/Sealant – tunnel applied wax-sealant Scratch concealer
USL-CW-200
Scratch concealer
Concentrated wax/sealant featuring DOWSIL™
3055 Resin Solvent-free polish
Drying agent Solvent-free polish
Final rinse formula for automatic car wash (concentrate) Tire care
Durable polish Multi-surface medium shine dressing
Automotive cream wax – durable polish Tire enhancer foam spray
Automotive cream wax Solvent-based liquid tire surface protectant
High-gloss automotive cream wax for Tire dressing
professional detailing
Cream tire dressing
Automotive cream wax for professional detailing
Fast dry premium shine tire dressing
Durable, high-gloss paste polish
Spray and walk away tire dressing
Detergent-resistant cleaner paste polish
Spray and wipe low-cost tire dressing
Extremely Durable Liquid Polish
Water-based tire shine
Hybrid Ceramic Sealant/Wax
pg 2
Auto care formulation information
General auto polish and formulation tips
1. Introduction
The word “polish” is a non-specific name but may be defined
as any product that enhances and protects the painted surface
of an automobile by depositing a thin layer or film of material.
More specifically, the name polish is assigned to a product with
particular properties, as listed below. Polishes may contain
many different ingredients and come in various forms that
contribute to a range of final product properties. It is essential
to choose the correct ingredients and form to satisfy customers’
needs for specific applications. The following information
should assist in making those choices.
Silicones are used to improve a number of auto polish
properties, including:
• Ease of application
• Polish cleaning ability
• Ease of buffing
Durability ranges from temporary (a few weeks) to durable
• Gloss
films that remain after numerous detergent washes or months
• Color intensity (formerly called “polymer sealants”). To the user, durability is
• Durability and detergent resistance typically judged by a polish’s ability to sustain water beading.
• Water repellency 3. Active ingredients

The best choice of silicone will depend on the relative importance The term “active ingredient,” as used here, is defined as that
of the properties above. This is because a polish is essentially a part of the polish left behind in the form of a film on the polished
compromise of all the properties. surface after application.
2. Polish types 3.1 Silicones

Polishes can be described in terms of their physical form, carrier A variety of silicones, including polydimethylsiloxanes,
system, ability to clean and durability. Physical forms of polishes aminofunctional silicones and silicone resins, are used as active
include pastes, pre-softened pastes (non-flowing emulsions), ingredients in polish formulations. Silicone emulsifiers, waxes
liquids and gels. There are three types of carrier system: and volatile silicones are also used in polish formulations and
will be addressed in other sections.
2.1. Water-free polishes
Polydimethylsiloxane is a nonreactive linear silicone fluid,
Where the active ingredients are dissolved in a compatible
which is supplied in a number of viscosities. In the auto polish
carrier such as a hydrocarbon solvent.
industry the convention is to classify polydimethylsiloxane
2.2. Emulsion polishes as either “intermediate” (350-1000 mm2/s) or “high” (above
Combining two incompatible phases (hydrocarbon solvent + 1000 mm2/s) viscosity.
water) by incorporating a surfactant to form a bridge between Intermediate-viscosity polydimethylsiloxanes are lower in
the two phases. molecular weight. They provide excellent application ease and
2.3. Solvent-free polishes rubout, as well as streak resistance. Due to their low surface
tension, they can improve polish cleaning abilities by increasing
Using pre-emulsified materials with the carrier being water. the surface wettability. This enables a more direct contact
The ability of a polish to clean depends on the presence of between the powder and the painted surface. They are very
powders and solvents. Powders clean physically by removing good at spreading and thus provide excellent film continuity. The
the oxidation layer and smoothing the surface. Solvents clean film provided by intermediate-viscosity polydimethylsiloxanes,
chemically by dissolving the films and dirt present on the surface. especially at (1000 mm2/s, provides high shine.
Powder-free polishes, typically referred to as paint conditioners High-viscosity polydimethylsiloxanes are much higher in
and glazes, are used strictly to provide gloss and protection. molecular weight. They provide improvements in durability and
They should be applied only to non-oxidized painted surfaces. provide excellent shine characteristics. However, they are more
A polish may also be described by its level of durability. likely to cause streaking. In general, solvent-in-water polishes
pg 3
use 50-1000 mm2/s polydimethylsiloxane, while water-in- detergent resistance and weathering abilities, especially when
solvent polishes enable higher-viscosity polydimethylsiloxanes combined with functionalized silicones. They provide a dry
to be used. In polish formulations it is advantageous to use a film that improves the resistance to dirt pickup, while retaining
combination of high-and intermediate-viscosity fluids favoring the application ease, spreading characteristics and shine
the following broad spectrum: associated with softer waxes.
3 : 1 : 1 3.3 Solvents
350 1000 12,500 Solvents are another component of most polish systems and
This helps to optimize shine and durability in comparison to can have an impact on the overall formulation performance.
ease of use and film continuity. The purpose of the solvent in a polish is to carry the active
ingredients; to “wet” the surface so a uniform film is produced;
Aminofunctional silicone fluids are also used extensively in and to clean the surface. In choosing a solvent, drying rates,
polishes in both curable (crosslinking) and noncurable forms. combustibility, compatibility with the surface and compatibility
They provide properties similar to the polydimethylsiloxanes, with the packaging must be considered.
but with enhanced durability and detergent resistance,
particularly with the curable forms. It is important to optimize the solvent choice to provide
appropriate drying time for the specific application and actives
One advantage of aminofunctional silicones is that they contain in the formulation. Too little or too much drying time for a
a polar amine group that provides excellent deposition or specific formulation may lead to poor performance by leaving
surface affinity. This effectively anchors the product to the streaks or a discontinuous film finish. Aliphatic hydrocarbons
substrate. In the case of the curable amine silicones, a reactive with Kauri-Butanol values of less than 32 are recommended for
alkoxy group undergoes a condensation reaction that provides polishes. Examples of these include de-aromatized and Isopar
a crosslinked film on the substrate. Aminofunctional silicones rafinic solvents. Solvents that contain aromatic substances are
are available with different viscosities, which allow optimization not recommended for use in these products because they may
of properties for a particular application. They are compatible damage the surface and may raise flammability, health and
with other silicone fluids and resins and therefore may be environmental issues.
blended to create the desired polish performance. Fatty acids
may be combined with aminofunctional silicones to improve Volatile silicones are an alternative to these traditional solvents.
the corrosion resistance of a polish film. Stearic or lauric acid Volatile silicones provide some unique application properties
is often used for this purpose. These can also crosslink with such as better spreading and lubrication properties due to
acid waxes through the amino group. their lower surface tension, and improved compatibility with
silicones. Different evaporation rates can be achieved by
Silicone resins may also be used in polish formulations. These blending. This allows even deposition of other ingredients,
networked silicones are available either bodied or linear and while their cleaning ability for various deposits is comparable
provide intermediate durability to the polish film. When used in to traditional solvents. It has been shown that volatile silicones
conjunction with polydimethylsiloxanes, they provide improved do not contribute to tropospheric ozone formation. Therefore,
durability with excellent leveling while maintaining similar ease- volatile silicones are not classified as VOCs in the USA.
of-use, shine and water-repellent characteristics.
3.4 Powders
3.2 Waxes
Powders or polishing agents provide physical surface
Waxes are commonly found in polish formulations. A wide preparation and cleaning, and aid leveling of the deposited
variety of different waxes are available, including naturally film. The ability of a powder to clean and smooth out surface
occurring (carnauba), synthetic (silicone wax, polyethylene) and imperfections depends on the particle size, its shape and
refined (paraffin) waxes. If properly selected, a wax may reduce hardness. The larger and less uniform the powder particle
smear, improve film continuity (or uniformity), provide durability the greater the cleaning ability to remove the oxidized paint
and promote stability by acting as a thickener. layer. Milder powders are composed of more uniform, smaller
Most waxes may be described as either soft or hard wax. particles, which polish more and clean less, giving greater gloss.
Hard waxes, such as carnauba and polypropylene, tend to have These are better suited to surfaces with little or no oxidation.
higher melting points. They provide a harder film finish and For cars less than one year old, it may not be necessary to
promote good gloss, color intensity and durability. However, include powders in the formulation. Most powders contain
they are often more difficult to apply and buff out. kaolin clays, diatomaceous earths and hydrated aluminas such
as Sillitin, Kaopolite, Diafil and Alcan grades.
Softer waxes, such as paraffin and beeswax, tend to be better at
lubricating, providing better application in terms of rubout ease 3.5 Emulsifiers
and improved spreading. However, soft waxes provide less shine A polish emulsion may be described by either its emulsion
to the system. In most formulations, it is best to blend a hard wax system or its ionic character.
with a soft wax to optimize their benefits in the formulation.
An oil-in-water (o/w) emulsion is a system in which the water
A recent innovation has been the introduction of silicone waxes is the external or continuous phase and the oil is in the form
into auto polishes. These provide a different combination of suspended droplets. These can give a better shine than the
of properties to that of the traditional waxes. While having other emulsion type, are less flammable and may be considered
a low melting point, they can provide a film with increased safer for skin contact.
pg 4
Water-in-oil (w/o) polishes are popular due to easier processing 3.7 Biocides
in some cases and better cleaning properties. Here the
Microbes can spoil polishes, causing breakdown of the product
oil is the continuous phase, with the water suspended as
as indicated by a color change or offensive odor. Microbes
droplets. Emulsifiers for this type of system have a hydrophilic/
can also affect the packaging of the polish by distorting the
hydrophobic balance favoring the oil phase, e.g., silicone
container. Microbial testing must be undertaken to verify
emulsifiers. For best results, the water and oil phases are
whether the product needs protecting.
blended separately, and then the water phase is slowly added
to the oil phase using a mixer that provides high shear. With 3.8 Miscellaneous
some formulations it is possible to blend the phases in a certain Other additives may be added to the polish as desired. For
order in one vessel. example, coloring agents can be added to shade the polish, while
Silicone emulsifiers represent a unique material for use in water- fragrances give an attractive smell. Both are typically incorporated
in-oil polish formulations. These lipophilic materials produce at 0.1-0.2% by weight (higher levels of fragrance can affect
very stable, shear-thickened emulsions. In addition, they are stability). In other situations the coloring agent (pigment or dye)
thixotropic, providing excellent application ease. The inherent is added in larger amounts to create “colored polishes.” Other
lubricating nature of the silicone improves rubout. As emulsifiers resins, such as acrylic and polyurethane, can be incorporated
they can provide better shine than their organic counterparts due at low levels to increase the immediate water resistance (not
to compatibility with active residual material in the polish film. repellency). However, compatibility needs to be determined.
Emulsions defined by their ionic character are either anionic, 4. Formulation tips
nonionic or cationic. An anionic emulsion particle shows a
4.1 Stability problems
net negative charge typical of the formulations, based on the
saponification of a fatty acid such as oleic acid and an alkali. 4.1.1 Oil-in-water polishes
Nonionic emulsions show no net charge and are typical of the Many different stability problems occur in oil-in-water polishes,
emulsions, based on alcohol ethoxylates. Cationic emulsion but the most common ones can be remedied fairly easily. One
particles have a net positive charge similar to the alkyl such problem occurs when the emulsifying system is the reaction
quaternary compounds, giving good wetting and substantivity product of a reactive amine source with a fatty acid. If there is
properties as well as synergy with silicones. interference with this reaction, there will be insufficient surfactant
The key to making stable polishes is using the right level of to emulsify the internal phase. It is advisable to combine the
emulsifier, correct HLB value and chemical type for the system reactants in the same phase (usually the oil phase) and allow
– with the ingredients added in the proper order. Oleic acid and them to pre-react before adding reactive ingredients such as
a volatile amine can be used together because this combination aminofunctional silicones or neutralizing agents. Problems also
leaves no residual surfactant on the surface and therefore occur when the amine content of silicones or other ingredients
avoids re-emulsification. Substituting a higher-molecular- is too great as this tends to favor water-in-oil emulsions and can
weight fatty acid, such as stearic, for the oleic can increase the actually prevent oil-in-water polishes from forming properly.
emulsion viscosity and improve stability. If the emulsion forms, but is prone to settling or breaking,
3.6 Thickeners thickening the emulsion will often enhance the stability. This
may be accomplished by thickening the external phase with
A variety of thickeners are commonly used in polish gums or acrylic acid polymers.
formulations to provide better stability and improved
consistency. For maximum efficiency, the external phase should 4.1.2 Water-in-oil polishes
be thickened with no more thickener used than necessary.
Probably the most common type of instability in water-in-oil
In a water-in-oil system, a solvent-based thickener such as polishes is “oiling out” of the phases. This condition occurs
bentonite clay can be used. This will increase the viscosity and because of the natural tendency of the less dense solvents to
improve the product consistency as well as reduce the phase collect at the top of the polish, but can normally be redispersed
separation. The presence of aminofunctional silicones provides by agitation such as shaking. To eliminate this tendency, the
a richer, thicker end product with this emulsion type. emulsion can be made extra thick to reduce the mobility of the
With oil-in-water formulations, the aqueous phase may be phases. Alternatively, steps can be taken to make the phases more
thickened with natural gums, cellulose gums or acrylic acid compatible, for example by adding a hydrophilic co-surfactant.
polymers. Magnesium aluminium silicates provide minimum Also, applying more shear will reduce the particle size of
thickening, but tend to reduce powder settlement. This is of the emulsion and thicken the polish. It is possible however
particular benefit in spray-and-wipe formulations where lower to overshear the polish and make the particles too small,
viscosity is desired. consuming the surfactant and contributing to instability. When
using silicone emulsifiers, adding 0.5-1.0 of a water-soluble
electrolyte, such as sodium citrate, in the water phase can
substantially enhance stability.
pg 5
4.2 Performance issues high-viscosity actives. The choice and level of powders can
4.2.1 Streaking problems play a significant part in the amount of material left behind on
the surface. This can be optimized by trying to incrementally
Streaking is generally defined as marks or imperfections in the
increase or decrease powder and active levels, but this too
polish film that are immovable, or hard to move, with simple
is a bit of a balancing act and requires perseverance. Every
rubbing. In extreme cases streaking appears as harder swirl
ingredient added or subtracted in a formulation can affect the
marks where the polish was originally applied. Generally there
final properties and physical form of a polish.
are two main causes for streaking:
4.2.3 Gloss and color
• The film-forming ingredients cannot level and spread well.
These properties are a function of several factors of a
• The film-forming ingredients interfere with each other.
formulation as well as the conditions and surface where it is
The first cause is usually manifested by insufficient drying time, applied. Gloss can be measured by reflectance properties and
improper solvent choice or improper application conditions. clarity of image, while color is assessed from such factors as
Allowing too little or too much drying time can have negative hue, lightness and saturation.
effects on the polish film. It is important to choose appropriate
“Clarity of image” is how well the finish shows details of the
solvents as well as the proper phase ratios (water phase versus
reflected image. A common way to assess clarity is to hold a
oil phase) to provide a drying time that allows the polish active
ruler or printed page perpendicular to the surface of the paint
ingredients to wet out to a thin, uniform film.
and observe the reflected markings and letters on the paint.
Polishes that dry too quickly tend to leave a film that varies in This is usually affected by how smooth the surface is. A film-
thickness over the surface. This creates a film with poor gloss former that is smeary can cause unevenness in the image and
properties because the actives do not have time to wet out prior can distort the image. However, a film-former that is too rigid,
to solvent evaporation. This is especially the case for higher- or one that dried too quickly, can cause a spotty or mottled
viscosity and reactive silicones. deposition, also resulting in distortion. Clarity can be improved
Polishes that are left to dry for too long may also yield a non- by blending different film-formers; by choosing slower- or
uniform film with poor gloss and color enhancement. This faster-drying solvents; or by using a very fine grade of powder
is because after the solvent has evaporated, the remaining to polish the surface to a smooth finish.
actives cannot be buffed to a smooth finish – especially if the Color intensity is often referred to as “jetting” or “wet look” and
materials have begun to crosslink and anchor to the surface. is influenced by the type of film-former used. Thicker films (e.g.,
Environmental conditions (primarily temperature and humidity) higher-viscosity silicones) will usually help the jetting but this can
affect the required drying times; on warm surfaces the solvent be carried too far and result in smearing. Hard waxes have the
evaporates too quickly for reactive polymers to wet out. It same benefits and problems as high-viscosity silicones but have
is important to consider these factors when choosing the the disadvantage of being difficult to buff. In some instances,
solvent or solvent blend for your formulation. In most cases where a high level of reactive silicones or hard waxes is used, it
a polydimethylsiloxane will be more flexible than a reactive is possible for some of the powder residues to be trapped in the
polymer, and can accommodate a variety of drying times. If film and left on the surface. This reduces the wet look.
these measures do not eliminate the problem, then a wetting
4.2.4 Durability versus ease of use
agent should be tried at low dosage levels, typically 0.1-0.3%.
Silicone polyethers are effective wetting agents used in small Waxes were the first reasonably durable polish components
quantities; they reduce the tendency to re-emulsify, and avoid and were applied from solvent over the surface, then buffed
incompatibility problems. to a smooth appearance. The harder the wax the better the
durability but the harder it was to buff. Polydimethylsiloxanes
The second cause of streaking (i.e., the film-forming ingredients
were introduced to help lubricate waxes and allowed easier
interfering with each other) can be more difficult to resolve.
buffing, but these compromised durability. The solution was
An approach would be to eliminate each ingredient in turn to
curable silicones, which allow easy application, spreading and
determine the source of the interference. Sometimes the final
buffing. They then cure in place and become more durable.
film may be compatible, but in getting to that film, there may be
stages where ingredients interfere with each other and cause The curable silicones used in automotive polishes are normally
streaking. In this case, choosing coalescing solvents that help aminofunctional ones. The requirement is to apply as much
solubilize all of the active ingredients can help. as needed for good durability while retaining good gloss and
ease of use. Low-viscosity aminofunctional silicones are more
Finally, it must be said that streaking is not an easy problem to
reactive and more durable, but do not provide significant
solve, so plenty of persistence is required.
levels of gloss or lubricity. By blending with higher-viscosity
4.2.2 Smearing aminofunctional silicones or polydimethylsiloxanes, the best
Smearing is the tendency of a polish film to be too mobile. balance of durability and ease of use can be achieved.
This can contribute to a more hazy appearance, and show The typical ratio of reactive amino-silicones used in traditional
fingerprints or an oily look. Smearing is usually caused by polishes is 4 to 6 parts high viscosity to 1 part lower viscosity.
overdeposition of higher-viscosity active ingredients. One This balance can be adjusted to affect ease of application,
solution is to reduce the level of high-viscosity ingredients such buffing, gloss and durability. Small, incremental changes are
as silicones and other materials, or change the ratio of low and best, because altering one property can affect another.
pg 6
5. Notes on formulations shown
Condition of painted surface
5.1. Unless stated, all quantities are in percentage parts
by weight. Slightly
New Good
weathered
5.2. All formulations are for illustrative purposes only and have
been subjected to limited stability tests. You should perform
Abrasive 0-5% 5-12% 10-15%
your own stability and performance tests.
5.3. While Dow endeavors to provide up-to-date information
Durable Wax conditioner Poly sealant liquid Poly sealant paste
on all the toxicological aspects of its products, it cannot
provide such information on other ingredients mentioned
in the formulations. As the formulations themselves have Semi-durable Hard wax “Polish” -
not been subjected to safety tests, formulators must satisfy

themselves that their final products are safe and compliant Temporary Instant - -
with current legislation.
5.4. Note that these are representative formulations only and products can be water- or solvent-based. Protectants are
are not commercialized products. Information and data typically water-based products. Silicone emulsions made of
contained in the formulations are based on information polydimethylsiloxane fluids can be combined to achieve desired
Dow believes to be reliable, but Dow does not warrant gloss levels. It is recommended to start with emulsions made
merchantability, fitness for use, performance or efficacy. of intermediate-viscosity fluids and use emulsions made of
It is the formulator’s obligation to test any application and high-viscosity fluids to improve depth of gloss. Aminofunctional
to conclude satisfactory performance and safety tests silicone emulsions can be incorporated to impart durability
before commercialization. Suggestions of uses should not to these products. Notice that some aminofunctional silicone
be taken as inducements to infringe any particular patent. emulsions have cationic surfactants. Choose nonionic or
5.5. Please note that certain aminofunctional siloxanes can cationic emulsions when combining with these emulsions.
display acute toxicity via aerosol inhalational exposure. The recommended silicone actives content for tire dressings
Safety data sheets should be referred to before handling and protectants formulations is 15-25%.
and formulating with these products.
Silicone polyethers such as XIAMETER™ OFX-5211 Fluid can
5.6. Soft water should be used for all formulations. be utilized to enhance wetting properties for these products.
5.7. Biocides have not been shown but all formulations should The recommendation is to use 0.1-0.3% depending on how
be subjected to microbial testing. Coloring agents and difficult to wet the surface is.
fragrances may also be included at low addition levels. Elastomer emulsions and dispersions, silicone polyethers and
The developed polishes presented by Dow have been silicone waxes can help to create innovative look and feel
formulated to satisfy one of the requirements in the table below: finishes such as soft or dry feel. These types of silicones can
help to formulate non-oily-feel products.
6. Tire care and protectants
Solvent-based tire dressings can be formulated following the
Tire dressings, also known as tire renovators, and protectants, recommended ratios found in section 3.1 (Silicones). The same
also known as vinyl dressings, have the purpose of enhancing principles found in polishes on how to achieve different levels of
the appearance of rubber and plastic surfaces. These gloss apply to tire dressings.
pg 7
Table I: Application selector guide
Target application →
Exterior wax, conditioner
Benefit ↓ Wash and rinse aid and sealant Exterior trim protectant Upholstery care
Gloss
DOWSIL™ FZ-4658 Emulsion XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0349 Emulsion
XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0346 Emulsion XIAMETER™ MEM-0346 Emulsion XIAMETER™ MEM-0349 Emulsion
XIAMETER™ MEM-1473 Emulsion XIAMETER™ MEM-0039 Emulsion
Durability
XIAMETER™ MEM-8035 Emulsion
XIAMETER™ MEM-8035 Emulsion XIAMETER™ MEM-8035 Emulsion DOWSIL™ HV 496 Emulsion
DOWSIL™ FZ-4658 Emulsion DOWSIL™ BY 22-749 SR Emulsion XIAMETER™ MEM-0062 Emulsion PS
Ease of use
XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0349 Emulsion

Water beading
DOWSIL™ FZ-4658 Emulsion
XIAMETER™ MEM-8035 Emulsion DOWSIL™ BY 22-749 SR Emulsion XIAMETER™ MEM-8035 Emulsion
Water-based
Leveling
Paintability

DOWSIL™ 2418 Release Emulsion DOWSIL™ 2418 Release Emulsion
Wetting
XIAMETER™ MEM-0062 Emulsion PS
Slip
Color enhancement
DOWSIL™ HV 496 Emulsion DOWSIL™ HV 496 Emulsion
pg 8
Interior trim renovator Leather conditioner Glass care Vinyl protectant Tire care

XIAMETER™ MEM-0346 Emulsion XIAMETER™ OFX-0193 Fluid XIAMETER™ MEM-0039 Emulsion

DOWSIL™ BY 22-729 EX Emulsion
DOWSIL™ HV 496 Emulsion
DOWSIL™ HV 496 Emulsion XIAMETER™ MEM-8035 Emulsion DOWSIL™ HV 496 Emulsion
XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0062 Emulsion PS

XIAMETER™ MEM-0062 Emulsion PS XIAMETER™ MEM-8035 Emulsion

XIAMETER™ OFX-0193 Fluid XIAMETER™ MEM-0346 Emulsion

DOWSIL™ 2418 Release Emulsion
DOWSIL™ 2418 Release Emulsion

XIAMETER™ OFX-5211 Fluid
XIAMETER™ MEM-0346 Emulsion XIAMETER™ MEM-0346 Emulsion XIAMETER™ MEM-0062 Emulsion PS
XIAMETER™ MEM-8035 Emulsion XIAMETER™ MEM-0062 Emulsion PS XIAMETER™ MEM-1101 Emulsion

XIAMETER™ MEM-8035 Emulsion XIAMETER™ MEM-0062 Emulsion PS XIAMETER™ MEM-1101 Emulsion
XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0062 Emulsion PS
DOWSIL™ HV 496 Emulsion DOWSIL™ HV 496 Emulsion XIAMETER™ MEM-1101 Emulsion

XIAMETER™ MEM-1101 Emulsion XIAMETER™ MEM-1101 Emulsion DOWSIL™ HV 496 Emulsion
pg 9
Target application →
Exterior wax, conditioner
Benefit ↓ Wash and rinse aid and sealant Exterior trim protectant Upholstery care
Gloss XIAMETER™ PMX-200 Silicone Fluid
(350-1,000 cSt) XIAMETER™ PMX-200 Silicone Fluid
(350-1,000 cSt)
DOWSIL™ 3527 Release Agent
DOWSIL™ 2-1912 Fluid
DOWSIL™ 2-5088 Wax
Durability XIAMETER™ OFX-0536 Fluid

DOWSIL™ 3527 Release Agent DOWSIL™ 3527 Release Agent
XIAMETER™ OFX-8630 Fluid DOWSIL™ 2-1912 Fluid DOWSIL™ 593 Fluid
DOWSIL™ 593 Fluid DOWSIL™ 2-1912 Fluid
Ease of use
XIAMETER™ PMX-200 Silicone Fluid XIAMETER™ PMX-200
(50-1,000 cSt) Silicone Fluid (50-1,000 cSt)
XIAMETER™ OFX-0531 Fluid XIAMETER™ OFX-0531 Fluid
Water beading XIAMETER™ PMX-0245

DOWSIL™ 593 Fluid
Cyclopentasiloxane
DOWSIL™ 2-1912 Fluid XIAMETER™ OFX-0531 Fluid
XIAMETER™ PMX-200
XIAMETER™ PMX-0531 Silicone Fluid XIAMETER™ OFX-0536 Fluid DOWSIL™ FBL-0563 Formulated Blend
Silicone Fluid
XIAMETER™ OFX-8630
XIAMETER™ PMX-200 Silicone Fluid
Silicone Fluid XIAMETER™ PMX-200 Silicone Fluid
Solvent-based
Leveling
XIAMETER™ PMX-0245 XIAMETER™ PMX-200 Silicone Fluid

Cyclopentasiloxane DOWSIL™ 593 Fluid
Paintability
Dry finish
Wetting
XIAMETER™ PMX-0245
XIAMETER™ PMX-200 Silicone Fluid XIAMETER™ PMX-200 Silicone Fluid XIAMETER™ PMX-200 Silicone Fluid
Cyclopentasiloxane
Slip
XIAMETER™ PMX-200
XIAMETER™ PMX-200 Silicone Fluid XIAMETER™ PMX-200 Silicone Fluid
Silicone Fluid
Color enhancement
XIAMETER™ PMX-200 Silicone Fluid XIAMETER™ PMX-200
(10,000-60,000 cSt) Silicone Fluid (10,000-60,000 cSt)
pg 10
Interior trim renovator Leather conditioner Glass care Vinyl protectant Tire care
XIAMETER™ PMX-200
XIAMETER™ PMX-200 Silicone Fluid (350-1,000 cSt) XIAMETER™ PMX-200 Silicone Fluid XIAMETER™ PMX-200 Silicone Fluid
Silicone Fluid (350-1,000 cSt) (350-1,000 cSt) (350-1,000 cSt)

(12,500-60,000 cSt)
DOWSIL™ 593 Fluid
XIAMETER™ PMX-200
XIAMETER™ PMX-200 XIAMETER™ PMX-200 Silicone Fluid XIAMETER™ PMX-200 Silicone Fluid
Silicone Fluid
Silicone Fluid (50-1,000 cSt) (50-1,000 cSt) (50-1,000 cSt)
(50-1,000 cSt)
DOWSIL™ 593 Fluid

DOWSIL™ 593 Fluid
DOWSIL™ 3527 Release Agent DOWSIL™ 2-5088 Wax DOWSIL™ 3527 Release Agent XIAMETER™ PMX-200 Silicone Fluid
XIAMETER™ PMX-200
Silicone Fluid
Cyclotetrasiloxane
XIAMETER™ PMX-200 XIAMETER™ PMX-200 XIAMETER™ PMX-0245
Silicone Fluid Silicone Fluid Cyclopentasiloxane
DOWSIL™ OS-2 Silicone
Cleaner and Solvent

DOWSIL™ 2-5088 Wax XIAMETER™ OFX-0230 Fluid
Cyclotetrasiloxane
XIAMETER™ PMX-200 XIAMETER™ PMX-200 Cyclopentasiloxane
Silicone Fluid Silicone Fluid
XIAMETER™ PMX-0345 Siloxane Blend
DOWSIL™ OS-2 Silicone Cleaner & Solvent
(10,000-60,000 cSt) (10,000-60,000 cSt) (10,000-60,000 cSt)
pg 11
Table II: Water-based product comparison
Comparison ratings1
Currently
available in these Functions, benefits and
Description Geographic areas Product recommendations Shine Durability
Silicone Fluid Emulsion Americas, Asia XIAMETER™ MEM-0349 Emulsion Preferred for water-based formulations, •••• •••
these emulsions and microemulsions
Americas, Asia XIAMETER™ MEM-0039 Emulsion offer significant advantages when •• ••
formulating flexibility is desirable; good
Americas XIAMETER™ MEM-0062 PS Emulsion compatibility; good surface abrasion •• •••
characteristics; good gloss, minimum
smear; for use in automotive polishes
and rubber/vinyl protectant formulations,
Americas XIAMETER™ MEM-1101 Emulsion ••• ••
cleaning properties; provide proven
performance, reliable quality and speed
Europe XIAMETER™ MEM-0346 Emulsion •••• •••
to market; the small particle size of the
microemulsion products offers better
Europe XIAMETER™ MEM-1473 Emulsion penetration, improved wetting out, more •••• •••
consistent coatings.
Global XIAMETER™ MEM-0347G Emulsion ••• ••
Global DOWSIL™ HV 496 Emulsion •••• ••••
Amino Functional Global XIAMETER™ MEM-8035 Emulsion Provide outstanding bonding and ••• ••••
Silicone Emulsion adhesion properties to automotive
finishes, allowing repeated washings
and adverse weather conditions.
Alkylaryl Functional Global XIAMETER™ MEM-5009 Emulsion Have properties similar to intermediate- •• ••
Silicone Emulsion viscosity fluids, but with alkyl
functionality; serve as actives for
leather conditioners; provide preferred
Europe DOWSIL™ 2418 Release Emulsion technologies to formulate products for ••• •••
body shop use.
Amino Microemulsion Japan DOWSIL™ FZ-4658 Emulsion Provides durable water repellency to ••• ••••
shampoo for automated car washes; the
small particle size prevents blockage in
the pipes of the washing mechanism.
1. C
omparison Ratings (••••• = Best, • = Moderate). Note: Ratings are a preliminary guideline only. See product data sheets for detailed information.
All tested products have been tested at 5% actives on automotive panels using a suitable solvent.
2. There are restrictions under TASCA applicable in the U.S
pg 12
Compliant
with European
Viscosity, cSt2 Free of detergent
(‡polymer viscosity for Emulsifier APEO regulations EC
Ease of use Wetting Slip the emulsion products) % Actives type surfactants 648/2004 Notes
•••• ••• •• 350‡ 60 Nonionic Yes Yes
••• •• • 350‡ 35 Nonionic Yes Yes
••• ••• •• 1,000‡ 60 Slightly Yes Emulsifiers

cationic are readily
biodegradable
••• ••• ••• 125,000‡ 60 Anionic Yes
•••• ••• •• 350‡ 60 Nonionic Yes Yes
••• ••• • 400 50 Nonionic Yes Yes
•••• ••• • OH Functional 60 Nonionic Yes Yes
• ••• •• 100,000‡ 35 Anionic Yes Yes
•• • •••• - 35 Cationic Yes Yes
••• ••• •• - 50 Nonionic Yes Emulsifiers

are readily
biodegradable
••• ••• • - 50 Nonionic Yes No
•••• ••• ••• 15 Nonionic Yes Yes Translucent gray
pg 13
Table III: Solvent-based product comparison
Currently
available in these
Description Geographic areas Product Functions, benefits and recommendations
Volatile Global XIAMETER™ PMX-200 Volatile, low-viscosity fluids designed for use as carriers, high-performance non-VOC3
Silicone Silicone Fluid, 0.65 cSt solvents and cleaning aids in a wide range of automotive polish formulations; effective
wetting properties deliver actives to the automotive surface; slip, water repellency and gloss
Global DOWSIL™ OS-2 Silicone
characteristics are present for a limited time; replace mineral seal oil in rinse aids; effective
Cleaner and Solvent
microemulsions can be achieved when combined with silicone surfactants.
Global XIAMETER™ PMX-1184
Silicone Fluid
Cyclotetrasiloxane
Cyclopentasiloxane
Cyclosiloxane Blend
Silicone Fluid Global XIAMETER™ PMX-200 High-viscosity fluids provide excellent depth of gloss and improvements in durability and
Silicone Fluid water resistance; useful in solvent-based formulations; blend of intermediate- and high-
viscosity fluids recommended to achieve a good balance in gloss, application ease and
rub-out; a 3:1:1 ratio of 350, 1,000 and 12,500 cSt products optimizes shine and durability;
products are available in emulsion form.
Amino Global XIAMETER™ OFX-0531 Fluid Offering enhanced durability, detergent resistance and corrosion resistance; offered in
Functional crosslinkable (curable) and non-crosslinkable versions; curable products produce a
Global XIAMETER™ OFX-0536 Fluid continuous film; non-crosslinkable products offer excellent stability and shelf life; deposit
Silicone
and adhere strongly to automobile finishes, chrome and aluminum surfaces.
Global XIAMETER™ OFX-8630 Fluid
Alkylaryl Global XIAMETER™ OFX-0203 Fluid Have properties similar to intermediate-viscosity fluids, but with alkyl functionality; serve
Functional as actives for leather conditioners; provide preferred technologies to formulate products for
Fluid body shop use.
Silicone Global DOWSIL™ 2-5088 Wax Serves as active for leather conditioners; provides preferred technologies to formulate
Wax products for body shop use; serves as an ingredient for hard waxes, paintable polishes,
wax conditioners, polishes and polymer sealants.
Emulsifier Global XIAMETER™ OFX-0190 Fluid Cleaning and wetting properties; lubricity in glass cleaners; ability to be used in water-in-
Wetting oil and water-in-silicone emulsions makes them unique to formulate non-VOC products;
Global XIAMETER™ OFX-0193 Fluid XIAMETER™ OFX-0190 Fluid, XIAMETER™ OFX-0193 Fluid and XIAMETER™ OFX-3667
Agent
Global DOWSIL™ 5225C Fluid are suited for cosurfactants; XIAMETER™ OFX-0193 Fluid for anti-fog applications;
Formulation Aid DOWSIL™ 5225C Formulation Aid for water-in-silicone emulsions; DOWSIL™ 5200
Formulation Aid for water-in-oil emulsions.
Global DOWSIL™ 5200 Formulation Aid
Silicone Resin Global DOWSIL™ 593 Fluid Long-lasting water durability and repellency that protects automotive surfaces;
preferred when enhanced water beading is desired; some can be reacted with catalyst
Global DOWSIL™ FBL-0563
agents to formulate fabric water repellents.
Formulated Blend
Global DOWSIL™ 2-1912 Fluid
Global DOWSIL™ 3527 Release Agent
1. C
omparison Ratings (••••• = Best; • = Moderate). Note: Ratings are a preliminary guideline only. See product data sheets for detailed information. All tested products have
been tested at 5% actives on automotive panels using a suitable solvent.
2. The above information is not intended for use in preparing product specifications. Contact Dow before writing specifications.
3. VOC = Volatile Organic Compounds, according to the U.S. Clean Air Act. Contact Dow for product compliance in your area.
4. California Air Resources Board.
pg 14
Comparison Ratings1
Shine Durability Ease of use Wetting Slip Viscosity, cSt2 % Actives Notes
••••• ••••• 0.65 100 Volatile carrier; CARB4 compliant
•••• 0.78 100
1.6 100 Not tested for comparison ratings
2.5 100 Volatile carrier; CARB4 compliant; not tested

for comparison ratings
•••• •• •••• •••• ••••• 50 - 1,000 100
•••• •••• •• • •••• 10,000 - 60,000 100
••••• ••• ••• •• • 160 50
•• ••••• ••• • •• 40 100
• •••• ••• •• •• 500 100
••• ••• ••• ••• • 1,200 100 Not tested for comparison ratings
1,125 - 1,645 100
•••• •••• •• • - 100 Melt at 70°C prior to use
2,000 100 Not tested for comparison ratings
• ••••• ••••• • 400 100

• • ••• ••• • 700 100
200 - 500 100 Not tested for comparison ratings

•••• • •• •• • 2,500 100
•• •• •••• •••• ••• 700 100

7 42 Air-drying, air-curing; imparts a high degree
of water repellency on natural and synthetic
fabrics; not tested for comparison ratings
•••• •• •••• •••• ••• 700 100
••• ••• ••• ••• •• 2,000 100
pg 15
Reformulate your tire and vinyl dressings with
products from Dow and avoid costly fines
Dow C.A.R.B. – Compliant solutions for automotive surfaces
Failure to comply with the California Air Resources Board’s There are many ways to reformulate, including cost-inviting
(C.A.R.B.’s) volatile organic compound (VOC) limits could water-based formulas and VOC-exempt solvent alternatives.
cost you up to $50,000 per day in fines. However, many of these solutions come with trade-offs. The
The good news is that Dow can help you easily reformulate decision to switch from your current solvent to slow-drying
your products to meet C.A.R.B. requirements. Isopar affin solvents, for example, could short-change your
product (and your customers) in critical performance benefits.
A challenging task
Dow offers solutions that can help you
Effective January 1, 2003, non-aerosol automotive rubber and vinyl
protectants sold in the state of California required a maximum VOC • Control your wetting properties and drying time
limit of 3 percent. (To learn more about how C.A.R.B. regulations • Enhance color for that new-car showroom look
impact your business, read our Tip Sheet on California regulations
• Modify shine and durability
for auto appearance products.) Today’s consumers enjoy
beautifying their vehicles and making them look like new. And they • Make your product easier to apply
rely on your vinyl and tire dressings to help them do just that. We We have prepared sample formulations to show you how easy
understand how difficult it can be to reformulate solvent-based it is to formulate a VOC-exempt Fast Dry tire dressing using
dressings that comply with environmental regulations without DOWSIL™ OS-2 Fluid. Compare the outstanding results Dow
sacrificing the performance your customers have come to expect. delivers (Figure 1) to the results obtained using an Isopar affin-
based formula (Figure 2).
Reliable solutions
Dow can offer you reliable solutions that deliver both high
performance and C.A.R.B. compliance.
pg 16
Or, if a water-based formula is an option for you, try the
XIAMETER™ MEM-0349 Emulsion multi-surface dressing Keep your business moving forward.
formulation with vertical clinging properties (Figure 3). Save money, time, and trouble with
Compare the alternatives Dow Service Solutions.
The drying-time chart (Figure 4) lets you compare the
performance of Dow’s volatile siloxanes vs. common organic- Figure 4: Drying-Time Chart –
based solvents. As you can see, an organic-based VOC- VOC-exempt solvents are shown in purple
exempt solvent may not meet your formulation requirements.
Dow’s VOC-exempt fluids, on the other hand, can give you the Comparison of volatile siloxanes and common solvents
thin-film drying time on metal surface
flexibility you need to formulate compliant products that live up
to your customers’ expectations. 100
DOWSIL™ OS-2 Silicone
Need to know if your product or proposed formulation will stand Cleaner & Solvent
IPA
up to a C.A.R.B. inspection? 80
Isopar H
% Weight Remaining
O.M. SPIRITS
Dow Analytical Services has the capability to analyze for water 60
XIAMETERTM PMX-0245
Cyclopentasiloxane
content, ammonium content, prohibited compounds, ketones, XIAMETER™ PMX-0345
Cyclosiloxane Blend
and alcohols to help you determine if you are meeting the 40
XIAMETER™ PMX-200
C.A.R.B. guidelines for volatile content. There is a fee for these Silicone Fluid, 2 cSt
Isopar M
services, but they can save you money, time, and trouble by 20 XIAMETER™ PMX-200
Silicone Fluid, 5 cSt
helping you avoid violations and costly fines.
0
Copies of our California regulations Tip Sheet and C.A.R.B.- 0 20 40 60 80 100 120 140
compliant prototype formulations are available from your Time (minutes)

See product datasheet for more information.
Dow representative.
Figure 3: Tire treated with Water-Based Tire Dressing

Figure 1: Tire treated with Tire Dressing Formula TP-750 Figure 2: Tire treated with Tire Dressing Formula TP-770
Formula IP-580 (XIAMETER™ MEM-0349 Emulsion), Form
(XIAMETER™ PMX-1077 Fluid), Form No. 26-1613 (Isopar affin), Form No. 26-1615
No. 26-1616
pg 17
Tip sheet for california regulations
for auto appearance products
The California Air Resources Board (C.A.R.B.) has a Consumer New York:
Products Compliance Program that implements regulations
• www.dec.ny.gov/regs/2492.html
and ensures compliance for the amount of volatile organic
compounds (VOCs) in consumer products. • www.dec.ny.gov/regs/4201.html
WHO is impacted by these regulations? New Jersey:

Companies that manufacture, distribute and/or sell consumer Subchapter 24: Prevention of Air Pollution from Consumer
products for both retail sales and institutional sales in the state Products and Subchapter 16: Control and Prohibition of Air
of California. Pollution by Volatile Organic Compounds
Because both retail sales and institutional use are included in • www.state.nj.us/dep/aqm/rules.html#27
these regulations, it is important to know the difference between
these categories. Pennsylvania:
In retail sale the end formula is purchased for personal use by • www.dep.state.pa.us/dep/deputate/airwaste/aq/regs/
a consumer at a retail store, such as a gas station, retail chain regs.html
or auto specialty store. Whereas with institutional use the end • www.pacode.com/secure/data/00.25/chapter130/
formula is purchased by a company such as a car dealership, s130.211.html
body shop, rental car agency or car wash and the user is an
employee of that company. Virginia
9VAC5-40-7270. Standard for volatile organic compounds
WHAT auto products are affected and
• http://leg1.state.va.us/cgi-bin/legp504.
WHEN do the regulations become effective? exe?000+reg+9VAC5-40-7270
The table on page 19 is a partial list from the Consumer
Products Program. Delaware
Regulation No. 1141: Limiting Emissions of Volatile Organic
WHERE can I find more information about Compounds from Consumer and Commercial Products
these regulations?
• http://regulations.delaware.gov/AdminCode/
Visit www.arb.ca.gov for more information on the Consumer title7/1000/1100/1141.shtml
Products Program of the California Air Resources Board
(C.A.R.B.). District of Columbia
Chapter 7 – Volatile Organic Compounds
WHY are some solvents classified as
• http://ddoe.dc.gov/ddoe/frames.asp?doc=/ddoe/lib/ddoe/
“VOC-exempt”?
information2/air.reg.leg/chapter7revised.pdf
There are two ways a solvent can be classified as “VOC-
exempt” for the California Consumer Products Program. Maine
First, if a solvent is a low vapor pressure or high boiling point Bureau of Air Quality
compound, it is considered exempt. These solvents are called Chapter 152: Control of Emissions of Volatile Organic
“LVP-VOC” compounds and are dramatically slower to dry than Compounds from Consumer Products
traditional solvents used in auto appearance products (such
as odorless mineral spirits). Second, there is a small family of • www.maine.gov/dep/air/regulations/docs/CHAP152%20
fast-drying solvents that have been exempted by the California Consumer%20Products%202007.pdf
Consumer Products Program. Dow volatile methyl siloxanes are Chapter 159: Control of Volatile Organic Compounds from
recognized as being non-ozone-depleting; they are exempt Adhesives and Sealants
from U.S. EPA VOC regulations and are also exempt by the
• www.maine.gov/dep/air/regulations/recentlyadopted.htm
California Consumer Products Program.
Maryland
ARE OTHER STATES adopting these
or similar standards? Code of Maryland Regulations 26.11.32 Control of Emissions
of Volatile Organic Compounds from Consumer Products
YES, various states in the country are or have already adopted
these standards. Consult the specific state regulations on air • www.mde.state.md.us/ResearchCenter/laws_regs/
quality or air resources of your concern. Below, we offer links procreg_26_11_32_033007.asp
to assist you. • www.mde.state.md.us/ResearchCenter/laws_regs/index.asp
pg 18
HOW can auto appearance products be
formulated to meet these requirements? VOC
Effective standard
Look at the following examples: Product category date (maximum)
• Clear (solvent-based) rubber and vinyl protectants can be Automotive rubbing or 01/01/2005 17%
modified to include VOC-exempt solvents. polishing compounds
• The type of rubber and vinyl protectant formula can change
to a white water-based emulsion. Automotive wax/polish/
sealant/glaze
• Liquid polishes or hard pastes (water-in-solvent emulsions) Instant detailers 01/01/2001 3%
can be modified to include a mixture of a VOC-exempt solvent Hard paste wax 01/01/2005 45%
and a traditional solvent (such as odorless mineral spirits). All other forms 01/01/2005 15%
Dow supplies VOC-exempt volatile methyl siloxanes with a
variety of drying times to meet your needs for solvent-based Brake cleaners 12/31/2010 10%
formulas or for water-in-solvent emulsions (liquid polishes or
Bug and tar remover 01/01/2002 40%
hard pastes). A few of our products include XIAMETER™
PMX-0245 Cyclopentasiloxane, XIAMETER™ PMX-0345 Engine degreasers
Cyclosiloxane Blend and DOWSIL™ OS-2 Silicone Cleaner Aerosols 12/31/2010 10%
and Solvent. See your Dow representative for a comparison Non-aerosols 12/31/2004 5%
of volatile methyl siloxanes from Dow versus other common
solvents with which you may already be familiar. Fabric protectants
Dow also supplies a variety of silicon-based actives in emulsion aerosols 01/01/1997 60%
non-aerosols 12/31/2010 1%
form for direct formulation into your water-based formulas. See
Dow’s prototype formulations for a variety of choices and ideas
Rubber and vinyl protectant
for protectants for rubber, vinyl, and tire surfaces.
Aerosols 01/01/2005 10%
Contact your local distributor or Dow directly for formulation non-aerosols 01/01/2003 3%
ideas and product recommendations that match your interests.
pg 19
Auto care raw material explanations
Raw material Function Supplier
Acetic acid An acid used to solubilize aminofunctional silicones. Various
Acrylic thickener A polyacrylic acid polymer thickener used to increase viscosity and The Lubrizol Corporation
give stability (e.g., Carbopol ETD 2001). lubrizol.com
Alcan SF7 An aluminum trihydroxide powder with a very fine particle size used Alcan Chemicals
to give extremely gentle polishing action. The function is to remove alcan.com
light oxidization and minor surface blemishes from paintwork. The
powder also aids in leveling of the polish film during buffing and helps
promote high shine.
Alkamuls PSMO 20 PEG-20 Sorbitan oleate. ALKAMULS® PSMO-20 acts as a non-ionic Solvay
surfactant with HLB 14.9 with 60 moles of EO. It is a versatile o/w
emulsifier and co-emulsifier with sorbitan esters for parafinic oils
Alkamuls SMO UNBL Non-ionic emulsifier also described as sorbitan monooleate. Useful to Solvay
form W/O emulsions.
Amadol 511 Non-ionic/Alkanolamide surfactant. Nouryon

https://www.nouryon.com/
Bentone 38 Rheological additive used to modify viscosity. Elementis
www.elementis.com
Bio-soft NI-7 Alcohol ethoxylate. A biodegradable surfactant used to replace Stepan Co.
Makon 10, a nonylphenylethoxylate. stepan.com
Brij LT4 A non-ionic emulsifier with the chemical name ethoxy (4) synthetic Croda Inc.
C12-C13 alcohols. www.crodapersonalcare.com
Brij O10 A non-ionic surfactant with the chemical name alcohol ethoxylate, Croda Inc.
based on tridecanol and used for detergency. www.crodapersonalcare.com
Cabosil EH-5 Fumed silica used as a thickener for organic solvents. Cabot Corporation
cabot-corp.com
Calfoam ES-702 A sodium salt of lauryl alcohol ethoxy sulfate containing an average of Pilot Chemical Company
2 moles of ethylene oxide. www.pilotchemical.com
Cellulose thickener Hydroxyethyl cellulose thickener used to increase viscosity and Ashland Inc.
stabilize the formulation. ashland.com
Carnauba wax An organic wax used to give a hard film with good shine. Various
Crodamet T8 A non-ionic emulsifier with the chemical name ethoxy (8) tallow amine. Croda Inc.
croda.com
Crodasinic LS35 An emulsifier with the chemical name sodium Croda Inc.
lauroyl sarcosine. croda.com
Dimethylamino ethanol Reacts with oleic acid to form a salt, which acts as Various
an emulsifier.
DOWSIL™ HV 496 Emulsion A polymer, non-ionic emulsion of 60,000 cSt dimethyl fluid (OH Dow
terminated) that offers excellent color improvement and good dow.com
durability to auto polish and vinyl/tire protectants.
DOWSIL™ RSN-9118 Resin A silicone resin in a volatile fluid that provides durability and shine Dow
when formulated into auto polishes and tire/vinyl protectants. dow.com
DOWSIL™ 593 Fluid A silicone resin in dimethyl fluid that provides very good leveling Dow
properties to auto polishes. dow.com
Disclaimer:
The formulation provided herein is made available by Dow in good faith, by mere liberality, and portrays a combination of ingredients commonly used in the industry, based on Dow’s experience. Considering that the recipient of it
might use such formulation to different applications and in different conditions, being subject to different regulations, which may differ from one location to another and may change over time, the recipient is responsible for determining
whether such formulation is appropriate and applicable to the recipient’s specific needs. Dow does not guarantee, implicitly or explicitly, that such formulation is correct, adequate, complete or fits any specific use, thus assuming no
obligation or responsibility arising from the use of such formulation by anyone. The suggested formulation contains a Brazilian genetic resource product, named “carnauba”. Such species is endemic from Brazil and part of the Brazilian
genetic heritage and therefore, the use of it might be under the scope of Law No. 13.123/2015. The recipient of such formulation shall evaluate the applicability of such law to the activities to be performed using the formulation. The
recipient shall be exclusively liable to guarantee its product compliance with applicable access and benefit sharing regulation. Dow has already complied with applicable law, registering the formulation before SISGEN and does not
assume any liability resulting from recipient's failure to comply with any applicable access and benefit sharing regulation. For further information please contact flarprs@dow.com.
pg 20
DOWSIL™ 2-1912 Fluid A silicone resin in dimethyl fluid that imparts shine, durability and Dow
ease of use to auto polishes and tire/vinyl protectants. dow.com
DOWSIL™ 2200 A silicone antifoam used to slowly collapse generated foam. Dow
Antifoam dow.com
DOWSIL™ 5225C A silicone polyether used as an emulsifier. Dow

Formulation Aid dow.com
DOWSIL™ 3527 A silicone resin in dimethyl fluid that imparts shine, durability and ease Dow
Release Agent of use to auto polishes and tire/vinyl protectants. dow.com
DOWSIL™ 5200 A silicone polyether used as an emulsifier. Dow
Formulation Aid dow.com
DOWANOL™ DPM A solvent to remove road film, with the chemical name dipropylene Dow
Glycol Ether glycol methyl ether. dow.com
DOWANOL™ DPnB A coalescing agent with the chemical name dipropylene glycol Dow
Glycol Ether n-butyl ether. dow.com
DOWANOL™ PM A fast-evaporating solvent to remove road film, with the chemical Dow
Glycol Ether name propylene glycol methyl ether. dow.com
DOWANOL™ PnB A coalescing agent with the chemical name propylene glycol Dow
Glycol Ether n-butyl ether. dow.com
ECOSURF™ EH-9 A water soluble, biodegradable nonionic surfactant with low odor. Dow
Readily biodegradable. Provides performance equal to alkylphenol dow.com
ethoxylate (APE) surfactants, and better than primary alcohol
ethoxylate (PAE) surfactants in many applications. EU Ecolabel
Empicol ESB 70 An anionic surfactant with the chemical name sodium lauryl ethoxy Innospec
sulphate. Used for detergency and quick foaming. innospec.com
Empilan 2502 A non-ionic surfactant with the chemical name coconut Alfa Chemicals
diethanolamide. Used to increase viscosity and improve alfa-chemical.co.uk
foam generation.
Exxsol D40 A medium-evaporating solvent, used as a carrier for actives Mineral Spirits – ExxonMobil
(Low aromatic solvent (silicones). This solvent also has cleaning properties and can exxonmobilchemical.com
160/190°C) (also known as remove tar, etc.
Mineral Spirits)
Exxsol D80 A slow-evaporating solvent, used as a carrier for actives (wax and ExxonMobil
(Low aromatic solvent silicones). This solvent also has cleaning properties for tar, etc. exxonmobilchemical.com
200/250°C)
Heptane A fast-evaporating aliphatic solvent used as a carrier for silicone Univar

actives. Chemcentral.com
Isopropanol A fast-evaporating solvent used for its cleaning and anti-freeze Various
properties.
Kaopolite SF Anhydrous aluminum silicate powders used for removing oxidized IMERYS
Kaopolite AB paintwork and very minor surface blemishes. Also aid in leveling of www.imerys-performance-minerals.com
Kaopolite 1152 the polish film during buffing.
KATHON LX A preservative agent. DuPont

dupont.com
pg 21
Lanolin Oil An oil to help restore and maintain Various
the suppleness of leather.
Makon TD-12 A non-ionic surfactant, tridecyl alcohol ethoxylate, POE-12. Stepan Co.
stepan.com
Ninol 49-CE A coconut DEA. Stepan Co.
stepan.com
Norpar 6 A very fast-evaporating aliphatic solvent, used as a carrier for actives ExxonMobil Chemical
(silicones). exxonmobilchemical.com
Oleic acid An acid that reacts with dimethylamino ethanol to form a salt that acts as Various
an emulsifier.
Paraffin wax A softer organic wax that gives less durability and shine than carnauba; Various
however, it is easily buffable.
CARBOWAX™ Polyethylene High-molecular-weight polymer of ethylene oxide, used as an emulsifier in Dow
Glycol (PEG) 6000 waxes and polishes. dow.com
Pine oil A wetting and cleaning agent. Various
Polawax GP200 A blend of fatty acids with non-ionic surfactants that functions as an Croda Inc.
emulsifier. Forms oil/water emulsions, which can convert to water/oil on croda.com
application.
Polyethylene wax An organic wax that gives hardness and durability to films. Also has Various
solvent-binding ability.
Propylene glycol A slow-evaporating water-miscible solvent that assists to deposit a Dow

uniform film, anti-freeze property. dow.com
Rhodapex ESB 70 An anionic surfactant with the chemical name sodium lauryl ethoxy Rhodia Inc.
sulphate. Used for detergency and quick foaming. rhodia.com
Rust inhibitor Sodium benzoate or similar to eliminate rusting of aerosol can. Emerald
Sillikolloid P87 Quartz and kaolinite filler. Hoffmann Mineral

hoffmann-mineral.com
Sillitin Z86 Quartz and kaolinite filler. Hoffmann Mineral
hoffmann-mineral.com
Span 80 A non-ionic emulsifier with the chemical name sorbitan trioleate. Croda Inc.
croda.com
Span 120 (formerly Crill 6) A non-ionic emulsifier with the chemical name sorbitan monoisostearate. Croda Inc.
croda.com
Syncrowax AWI A hard wax (blend of C18-C36 acids), used for protection. Croda Inc.
croda.com
Syncrowax ERL An ethylene glycol ester of C18-C36 fatty acids that can be buffed to a Croda Inc.
high gloss. croda.com
pg 22
TERGITOL™ 15-S-12 Surfactant Readily biodegradable, rapid wetting & spreading on hard surfaces, lower Dow
aqueous surface tension than other ethoxylated surfactants, fast foam dow.com
collapse rates for easy rinsing, Dissolves easily in aqueous solutions,
Narrow gel range, Non-APE based.
Tomamine Amphoteric L Cocoamidopropyl betaine. An amphoteric surfactant used for detergency Evonik
and foam generation. evonik.com
Tomamine AO-728 An amine oxide-type amphoteric surfactant used as a foam booster/foam Evonik
stabilizer. evonik.com
Tomamine Emulsifier Four An emulsifier with the chemical name cationic dialkyl quaternary ammonium Evonik
chloride, used to aid water repellency. evonik.com
Tomamine Q-17-2 A cationic surfactant with the chemical name isotridecylcyloxypropyl Evonik
dihydroxyethyl methyl ammonium chloride that is used to enhance evonik.com
detergency performance.
Triethanolamine Used as part of emulsifier system/thickener system. Dow
dow.com
Tween 80 A non-ionic emulsifier with the chemical name polyoxyethylene (20) Croda Inc.
sorbitan monooleate. croda.com
Veegum Pro Gum thickener (amine-modified hydrated magnesium aluminum silicate). Vanderbilt Mineral
www.vanderbiltminerals.com
Wax emulsion A 25% active blend of soft/hard wax, with a particle size such that a non- Michelman Inc.
Michem Lube 155 level film is created that scatters light, causing the sheen effect. michem.com
Wax Emulsion 7619 Carnauba/beeswax blend to aid gloss and water repellency. Marlin Chemicals
marlinchemicals.co.uk
XIAMETER™ MEM-0039 A non-ionic emulsion of intermediate-viscosity dimethyl fluid that improves Dow
Emulsion the leveling and ease of use of auto polish formulations. Also imparts gloss dow.com
to both polishes and tire/vinyl protectants.
XIAMETER™ MEM-0062 A cationic silicone emulsion (55% active silicone) of 1,000 cSt dimethyl fluid. Dow
Emulsion PS The emulsion promotes gloss and improves wet-out characteristics of vinyl dow.com
and tire dressings.
XIAMETER™ MEM-8035 A cationic aminosilicone emulsion that provides shine and protection when Dow
Emulsion formulated into polishes and vinyl/tire protectants. dow.com
XIAMETER™ OFX-0193 Fluid A silicone polyether surfactant that acts as a wetting and foam-boosting Dow
agent. This polyether also has moderate cleaning properties and acts as a dow.com
surface tension depressant, wetting agent, emulsifier and foam builder.
pg 23
XIAMETER™ OFX-0203 Fluid An alkylaryl polysiloxane fluid that imparts gloss and ease of use to polish Dow
formulations. This fluid also offers the benefit of paintability. dow.com
XIAMETER™ OFX-0531 Fluid An aminofunctional silicone fluid that provides good gloss in polish Dow
formulations. This fluid works in conjunction with XIAMETER™ OFX-0536 dow.com
Fluid to plasticize it.
XIAMETER™ OFX-0536 Fluid An aminofunctional silicone fluid that gives excellent durability and Dow
protection properties. This fluid works in conjunction with XIAMETER™ dow.com
OFX-0531 Fluid.
XIAMETER™ OFX-3667 Fluid A silicone polyether emulsifier. Dow
dow.com
XIAMETER™ PMX-0245 A volatile cyclic siloxane fluid that promotes water removal when used Dow
Cyclopentasiloxane in rinse aid formulations. Also can be used as a VOC-exempt solvent in dow.com
XIAMETER™ PMX-0246 protectant formulations.
Cyclohexasiloxane
XIAMETER™ PMX-200 Silicone A low-viscosity dimethyl fluid that promotes leveling of auto polishes, Dow
Fluid, 350 cSt provides gloss and improves ease of use. dow.com
XIAMETER™ PMX-200 Silicone An intermediate-viscosity dimethyl fluid that gives high gloss, aids rubout Dow
Fluid, 1,000 cSt and improves ease of use when incorporated into polish formulations. dow.com
XIAMETER™ PMX-200 Silicone An intermediate-viscosity dimethyl fluid that enhances color and shine Dow
Fluid, 12,500 cSt when formulated into auto polishes. Also provides protection against minor dow.com
scratches.
XIAMETER™ PMX-200 Silicone A high-viscosity dimethyl fluid that gives excellent color enhancement and Dow
Fluid, 60,000 cSt protection properties when formulated into automotive polishes. dow.com
pg 24
Prototype formulation for automotive wax
Emulsion hard wax Description

Formulation reference: PW-310 This formulation features a blend of silicones to promote shine and water beading. Also,
this product contains a much lower solvent level than traditional hard-wax formulations.
Ingredient Weight (%) Supplier

Phase A
1. Low aromatic solvent 160/190°C 20.0 Odorless mineral spirits
2. XIAMETER™ PMX-200 Silicone Fluid, 1.1 Dow

350 cSt
1,000 cSt
4. Syncrowax AWI 1.5 Croda Ltd.

5. DOWSIL™ 2-5088 Wax 1.5 Dow
6. Crill 6 1.4 Croda Ltd.
7. Polawax GP200 0.9 Croda Ltd.
8. Triethanolamine 0.9 Dow
9. 50% sodium citrate in water 2.0
Phase B
10. Water 72.0
Procedure
1. Mix Phase A ingredients in the main vessel using
low-speed stirring while heating to 70°C.
2. In an auxiliary vessel, heat Phase B ingredient to 70°C

and then add to Phase A with high-shear mixing.
3. Stir slowly while cooling.
Typical properties / additional information

Suggestions for adjusting the formulation:
• To improve color: Incorporate XIAMETER™ PMX-200 Silicone Fluid,
12,500 cSt, at 0.4%
• To improve durability: Incorporate DOWSIL™ RSN-9118 Resin or
XIAMETER™ OFX-8630 Fluid at 1.0%
pg 25
Hard wax Description

Formulation reference: PW-320 This is a traditional product for the preservation of new and good-condition paintwork.
The formulation provides shine and ease of use due to its thin consistency.

Phase A
2. Low aromatic solvent 200/250°C 10.0 Low odor base solvent
or #460 solvent
Phase B
3. Carnauba Wax 0.5
350 cSt
12,500 cSt
7. DOWSIL™ 593 Fluid 1.0 Dow
8. DOWSIL™ RSN-9118 Resin 1.0 Dow
Procedure
1. Add ingredients 1-4 to the vessel and heat to 85°C with low-speed stirring
until the waxes have dissolved.
2. Start cooling and add ingredients 5-8 with continuous stirring.

• To improve gloss: Incorporate 0.5-1.0% XIAMETER™ PMX-200 Silicone
Fluid, 1,000 cSt
• To improve ease of use: Increase level of XIAMETER™ PMX-200 Silicone
Fluid, 350 cSt, to 1.0%
• To improve durability: Increase levels of DOWSIL™ RSN-9118 Resin and
DOWSIL™ 2-5088 Wax to 2.0% or incorporate XIAMETER™ OFX-0536 Fluid
at 1.0%
• If a single silicone resin is desired, choose either DOWSIL™ 593 Fluid or
DOWSIL™ RSN-9118 Resin. Look for the product that provides the best
leveling and durability.
Disclaimer:
pg 26
Wax conditioner Description

Formulation reference: PW-390 This formulation produces a traditional high-wax-content polish, typically used by
classic car owners. This polish is suitable for cleaned paintwork, but also can be used
on wood dashboards and chrome bumpers. The silicone wax contributes to durability
of the product, with the silicone resin aiding leveling characteristics.

Phase A
2. Low aromatic solvent 200/250°C 18.6 Low-odor base solvent
or #460 solvent
3. Carnauba Wax 6.4
5. Rocsol C wax 2.0 Croda Ltd.
6. Polyethylene wax AC 629 1.7 Allied Corp. Int.
Procedure
1. Add all products to a vessel and heat to 110°C with slow-speed stirring.
Mix until uniform.
2. Cool to filling temperature.

• To improve gloss: Incorporate XIAMETER™ PMX-200 Silicone Fluid, 1,000 cSt,
instead of DOWSIL™ 593 Fluid
• To improve ease of use: Incorporate 1-3.0% XIAMETER™ PMX-200 Silicone
Fluid, 350 cSt, or increase level of DOWSIL™ 593 Fluid
• To improve color intensity: Incorporate 0.5-1.0% XIAMETER™ PMX-200
Silicone Fluid, 12,500 cSt
• To improve durability: Increase level of DOWSIL™ 2-5088 Wax, reducing the
level of the paraffin wax by the same amount, or incorporate XIAMETER™
OFX-0536 Fluid or DOWSIL™ RSN-9118 Resin as a replacement for
DOWSIL™ 593 Fluid
Disclaimer:
pg 27
Prototype formulation for low-VOC polish
Low-VOC polish Description

Formulation reference: PW-400 This polish is a detergent-resistant cleaner designed for automotive surfaces.
The product exhibits little phase separation and provides easy rub-out, excellent
gloss, very good durability and resistance to detergent washings.
Solvent was replaced with a VOC-exempt silicone solvent, XIAMETER™ PMX-
0245 Cyclopentasiloxane, to target a VOC level of 14% for this formula as defined
by California A.R.B.
This formula passes five cycles of freeze/thaw stability testing.

Phase A
1. DI water 59.0
2. KAOPOLITE XDA 6.6 Kaopolite, Inc.
3. KAOPOLITE 1152 3.4 Kaopolite, Inc.
4. Amadol (Witcamide) WE 1.0 Akzo Nobel
5. Kerosene/mineral spirits 3.5
6. XIAMETER™ PMX-0245
11.0 Dow
Cyclopentasiloxane (VOC-exempt)
7. Sodium chloride 1.0
Phase B
8. Kerosene/mineral spirits 7.24
9. BENTONE 38 Thickener 0.6 Rheox, Inc.
Phase C
10. XIAMETER™ OFX-0531 Fluid 5.5 Dow
12. Isopropanol 0.15
Procedure
1. Load Phase A ingredients in the order shown into a vessel and mix well.
2. Mix Phase B ingredients in a separate container.
3. Add Phase B to the production vessel and mix well.
4. Add Phase C ingredients to the production vessel and mix well.

• After Phase A mixing, the material forms a thick paste emulsion.
• After Phase B mixing, the material is a similar thick paste emulsion.
• After Phase C mixing, the alcohols activate Bentone 38 Thickener. Polish
continues to thicken over several days.
• Ensure high-flow (turnover) mixing exists to prevent the abrasive from settling
at the vessel bottom. If agitation is stopped on the mixing vessel during Phase
A or Phase B, KAOPOLITE XDA Abrasive will settle to the bottom.
Observe precautions for handling XIAMETER™ products as indicated on the
safety data sheets.
pg 28
Prototype formulation for car polish
Paintable polish Description

Formulation reference: PP-930 This paintable polish is specifically formulated for use in garages and body shops
where polydimethylsiloxanes could give rise to recoatability problems.

Phase A
1. Low aromatic solvent 160/190°C 30.0 Exxon Chemicals Ltd./Shell
Chemicals Ltd.
2. Paraffin wax 0.5 Suter & Co Ltd.

4. Alkamuls SMO UNBL 0.4 Solvay
Phase B
6. Water 50.6
7. SILLITIN Z.86 5.0 Hoffmann Minerals
8. Alcan SF7 7.0 Alcan Chemicals
9. Alkamuls PSMO 20 1.1 Solvay
Phase C
10. Cellulose thickener 0.9 Hercules Ltd.
Procedure
1. Heat ingredients 1-3 to 70°C in an auxiliary vessel to dissolve the wax with
low-speed stirring.
2. Add ingredients 4 and 5.
3. In the main vessel, mix Phase B ingredients while heating to 70°C.
4. Add Phase A to Phase B with high shear, then start to cool.
5. Add Phase C ingredient under low shear.

• To improve ease of use: Increase XIAMETER™ OFX-0203 Fluid to 1.0%
• To improve durability: Increase DOWSIL™ 2-5088 Wax to 4.0%
• Alcan SF7 can be replaced by other aluminum trihydroxides such as Almatis
Hydral 710.
pg 29
Spray-and-wipe polish Description

Formulation reference: PW-306 This is a no-wax spray-and-wipe polish formulation designed to provide good
gloss to an automotive surface. The product has good application ease and
rub-out with limited durability.

Phase A
1. XIAMETER™ MEM-0349 Emulsion or

6.0 Dow
Phase B
2. Water 90.0
3. VEEGUM Pro 0.8 R.T. Vanderbilt Co.
4. KAOPOLITE AB 0.2 Kaopolite, Inc.
Phase C
5. KAOPOLITE SF 3.0 Kaopolite, Inc.
Procedure
1. Blend Phase B ingredients (thickening water first)
until uniform.
2. Add Phase A ingredients and mix until uniform.
3. Add Phase C ingredient and mix lightly until uniform.
Typical properties/additional information

• To improve durability, add XIAMETER™ MEM-8035
Emulsion at 2–3%.
• Other gum thickeners may be used.
pg 30
Instant car polish Description

Formulation reference: PW-330 The blend of fluids in this formulation yields high gloss in an easy-touse
product form.

Phase A
1. Low aromatic solvent 160/190°C 25.0 Exxon Chemicals Ltd./
Shell Chemicals Ltd.
2. XIAMETER™ PMX-200 Silicone 1.4 Dow
Fluid, 350 cSt
Fluid, 1,000 cSt
4. DOWSIL™ 5200 Formulation Aid 2.0 Dow
Phase B
5. Water 57.6
6. Sillikolloid P.87 8.5 Hoffmann Minerals
7. Wax Emulsion 76191 2.5 Marlin Chemicals
8. 50% sodium citrate in water 2.0
Wax Emulsion – 35% active blend of soft/hard waxes
1
Procedure
1. Blend Phase A ingredients in the main vessel under
low shear.
2. In the auxiliary vessel, add Phase B ingredients in the order listed.

Mix with low shear.
3. Add Phase B to Phase A very slowly under high shear until the emulsion
begins to form. The remainder of Phase B can then be added at a faster rate.
4. When addition is complete, mix with high shear.

• To improve color: Incorporate XIAMETER™ PMX-200 Silicone Fluid, 12,500
cSt, at 0.4%
• To improve durability: Incorporate DOWSIL™ 3527 Release Agent
or XIAMETER™ OFX-0531 Fluid at 1.0% and reduce the level of the
XIAMETER™ PMX-200 Silicone Fluids by 0.5%
• The low aromatic solvent can be partially replaced with XIAMETER™
PMX-0245 Cyclopentasiloxane to comply with California Air Resources
Board regulations
pg 31
Low-solvent liquid polish Description

Formulation reference: PW-340 This low-solvent liquid polish uses a blend of silicone fluids to achieve shine and
ease of use. The silicone resin helps to improve water repellency.

Phase A
1. Low aromatic solvent 200/250°C 9.0 Exxon Chemicals Ltd./Shell
Chemicals Ltd.
Fluid, 350 cSt
Fluid, 1,000 cSt
Fluid, 12,500 cSt
Phase B
8. Water 71.3 Hoffmann Minerals
9. KAOPOLITE SF 11.6 Alcan Chemicals
11. Acrylic thickener 0.2 Dow
Phase C
Procedure
1. Mix phase A ingredients with heat to 70°C in an auxiliary vessel using
low shear.
2. Mix phase B ingredients in the main vessel at 70°C with

low shear.
3. Add phase A to phase B under high shear and cool.
4. Add phase C ingredient with low shear.

• To improve durability: Replace DOWSIL™ 593 Fluid with DOWSIL™
RSN-9118 Resin at 2.0% or XIAMETER™ OFX-8630 Fluid at 1.0%
pg 32
Polish Description
Formulation reference: PW-350 The combination of silicone fluids and a silicone resin gives an easy-to-use
polish product that resists weathering. This product also features excellent
gloss and color.

Phase A
Fluid, 350 cSt
Fluid, 1,000 cSt
5. DOWSIL™ 3527 Release Agent 1.6 Dow
Phase B
7. Water 57.0
8. ALCAN SF7 12.4 Alcan Chemicals
9. CRODAMET T8 1.3 Croda Ltd.
10. Cellulose thickener 0.9 Hercules Ltd.
Procedure
1. Heat Phase A ingredients to 70°C in an auxiliary vessel using low shear.
2. Add ingredients 7-9 to the main vessel, heating to 70°C with low shear.
3. Slowly add ingredient 10 and stir until dispersed.
4. Add Phase A and Phase B with high shear.
5. Cool to ambient temperature.

• To improve gloss: Increase XIAMETER™ PMX-200 Silicone Fluid, 1,000 cSt,
to 1.0%.
cSt, at 0.5%.
• To improve durability: Incorporate DOWSIL™ RSN-9118 Resin at 2.0%
instead of DOWSIL™ 3527 Release Agent.
• ALCAN SF7 can be replaced by other aluminum trihydroxides such as
Almatis Hydral 710.
pg 33
Prototype formulation for shampoo
Standard shampoo Description

Formulation reference: CW-101 The silicone surfactant provides wetting effects, while the amino-functional silicone
can deposit onto the surface to enhance the polish film for gloss/water repellency.

Phase A
Rhodapex ESB 70 FEA/
1. Sodium lauryl ethoxy sulfate 10.0 Rhodia Inc or Calfoam
ES-702 / Pilot Chemical
2. Soft water 78.7
Phase B
3. TERGITOL™ 15-S-12 Surfactant or Dow
MAKON TD-12 5.5 Stepan Co.
NINOL 49-CE
4. Coconut diethanolamide 3.5 Stepan Co.
5. XIAMETER™ MEM-8035 Emulsion 1.5 Dow
Phase C
7. Hydroxyethyl cellulose thickener 0.5 Ashland Inc.
Procedure
1. Dissolve ingredient 1 in ingredient 2. Add Phase B ingredients with low-speed
mixing until fully dispersed.
2. Sprinkle in the Phase C ingredient and mix until completely dissolved,

approximately 60 minutes.
3. Pour down and package appropriately.

• To improve gloss and color, add DOWSIL™ HV 496 Emulsion at 1.0%.
pg 34
Protective shampoo Description

Formulation reference: CW-102 This formulation produces a product that is an intermediate between a
standard shampoo and a polish that enhances gloss and provides a longer-
lasting protective silicone film. The product can be applied the same as normal
shampoo, or it can be poured directly onto a water-soaked sponge and wiped
over a surface.

Phase A
1. Water 60.0
2. ECOSURF™ EH-9 Surfactant or 1.0 Dow
BIO-SOFT N1-7 Stepan Co.
Phase B
4. Low aromatic solvent 160/190°C 30.0
Exxon Chemicals Ltd.
Exxsol D40
1.5
5. Carnauba Wax
6. XIAMETER™ PMX-200 Silicone Fluid, 1.0

Dow
350 cSt
7. Pine oil 1.0
Phase C
Procedure
1. Put Phase A ingredients into the main vessel. Heat to 70°C with low-shear mixing.
2. In a separate vessel, load ingredients 4 and 5. Heat to 70°C, then add ingredi-
ents 6 and 7 while mixing at low shear.
3. Add Phase B to Phase A with high shear. Start cooling to room temperature.
4. Add the Phase C ingredient slowly and mix until dissolved, approximately
45 minutes.

• To improve color, incorporate XIAMETER™ PMX-200 Silicone Fluid,
12,500 cSt, at 0.5%.
• To improve gloss, substitute XIAMETER™ PMX-200 Silicone Fluid, 1,000 cSt,
for XIAMETER™ PMX-200 Silicone Fluid, 350 cSt.
• To improve durability, reduce the level of XIAMETER™ PMX-200 Silicone
Fluid, 350 cSt, to 0.6% and the emulsifier level to 0.8%
Disclaimer:
pg 35
Protective shampoo Description

Formulation reference: CW-120 This formulation produces a product that is an intermediate between a standard
shampoo and a polish that enhances gloss and provides a longer-lasting protective
silicone film. The product can be applied the same as normal shampoos, or it can be
poured directly onto a water-soaked sponge and wiped over a surface.

Phase A
1. Water 60.0
2. Crodamet T8 1.0 Croda Ltd.
Phase B
30.0 Exxon Chemicals Ltd./
3. Low aromatic solvent 160/190°C
5. XIAMETER™ PMX-200 Silicone 1.0
Dow
Fluid, 350 cSt
6. Pine oil 1.0
Phase C
8. Cellulose thickener 0.8 Hercules-Aqualon
Procedure
1. Add ingredient 2 to ingredient 1 with low-speed stirring in the main vessel,
heating to 70°C.
2. In phase B, add ingredients 3 and 4 to an auxiliary vessel, heat to 70°C,

and add ingredients 5 – 7 with low-speed stirring.
3. Add phase B to phase A with high shear. Start cooling.
4. Add the phase C ingredient slowly and mix until dissolved.

cSt, at 0.5%
• To improve gloss: Substitute XIAMETER™ PMX-200 Silicone Fluid, 1,000 cSt,
for XIAMETER™ PMX-200 Silicone Fluid, 350 cSt
• To improve durability: Reduce the level of XIAMETER™ PMX-200 Silicone
Fluid, 350 cSt, to 0.6% and the emulsifier level to 0.8%
pg 36
Prototype formulation for dry washer
Dry washer Description

Formulation reference: CW-140 This formulation exhibits the dual function of cleaning and adding shine to
automotive metallic surfaces. XIAMETER™ MEM-0039 Emulsion provides gloss
and XIAMETER™ OFS-6124 Silane ensures an excellent adherence factor, making it
more resistant and shiny and providing surface cleaning with no water.

1. Water 90.2
2. KELTROL F 0.5 CP Kelco
4. Ethanol 3.0
5. Sodium ricinoleate at 35% 2.0
6. XIAMETER™ OFS-6124 Silane 1.0 Dow
7. Aluminum silicate 500 # 0.2
8. Glutaraldehyde 0.1
Procedure
1. Add ingredient 2 to ingredient 1 in the main vessel.
2. When completely dispersed, add ingredient 3 and

stir for 10 minutes.
3. Add ingredients 4 and 5 and stir for 10 minutes.
4. Add ingredient 6 and stir for 10 minutes.

Directions: Apply the final product with a soft cloth or cotton wool over dust or
grime with circular movements, one small area at a time. Remove the product with
a dry and clean cloth.
Do not apply this product over sand-covered surfaces.
The ethanol helps to clean the surface and ensures the compatibility of XIAMETER™
OFS-6124 Silane in the formulation.
The ethanol may be replaced by isopropanol.
The final formulation will have a pH between 8.0-9.5 because of the presence of
the sodium ricinoleate. The xanthan gum helps to stabilize the formulation
pg 37
Shampoo for use in Description

professional detailing This is an automotive shampoo that stands out among similar products because
Formulation reference: CW-150 XIAMETER™ OFS-6124 Silane, in addition to providing excellent grime and
grease removal, imparts shine and adheres to metal surfaces.

1. Water 88.4
2. CELLOSIZE™ QP-100M-H Hydroxyethyl Cellulose 0.4 Dow
3. Sulfonic acid 5.0
4. Sodium hydroxide at 50% 0.6
6. Cocamide DEA 1.0
7. Dioctyl succinate at 70% 2.0
8. Isopropanol 1.0
9. XIAMETER™ OFS-6124 Silane 1.0 Dow
10. Glutaraldehyde 0.1
pH at 10% dilution: 6.5-7.5
Procedure
1. Add ingredient 2 to ingredient 1 in the main vessel
and stir until the solution is transparent and viscous.
3. Slowly add ingredient 4 and stir for 10 minutes.
5. Check the pH. It should be between 6.5 and 7.5.

Use ingredient 3 or 4 to correct the pH, if necessary.
8. Add ingredient 10 and stir for 10 minutes more.

Directions: In a shaded area, apply a 10% dilution of the final product on a
cold metallic surface with a soft sponge. The resulting foam should be left for 2
minutes and then removed with water. Dry the vehicle with a soft towel.
pg 38
Prototype formulation for tunnel wash wax/sealant
Concentrated Wax/Sealant Description

Formulation reference: USL-CW-200 This wax sealant is designed for Tunnel Car Wash applications. It provides
gloss and water beading properties. NOTE: A version of this formulation can be
incorporated into a rinse aid formulation for excellent water break and gloss effect.
2. Accoquat CS 4000 10.0 Abitec
3. TERGITOL™ 15-S-7 Surfactant 7.0 Dow
5. Glycol Ether EB 11.0 Eastman
6. Water 52.5
Application notes: For tunnel wash applications dilution ratio is 1000:1 as the most ideal
but can go as high as 2000:1
Procedure
Slowly mix in the listed order until homogeneous. After that, adjust pH to 5.9 using
glacial acetic acid which will clear the solution.

Application notes: For tunnel wash applications dilution ratio is 1000:1 as the most
ideal but can go as high as 2000:1.
Courtesy of Univar Solutions Inc.

pg 39
Prototype formulation Concentrated Wax/Sealant
featuring DOWSIL™ 3055 Resin
Concentrated Wax/Sealant Description

Formulation reference: USL-CW-210 This this wax/sealant concentrate provides high durability with very good
water beading.
2. DOWSIL™ 3055 Resin 4.2 Dow
3. Accoquat CS 4000 8.8 Abitec
4. Glycol Ether EB 13.3 Eastman
5. Water 71.7
Adjust pH with glacial acetic acid to pH 5.9 to clear.
Procedure
Divide the water in three equal parts. Add and mix until homogeneous the first 4
ingredients with one part of water. Add the second part of water and then add 5,
keep mixing and then add the third part of water. After that, adjust pH to 5.9 using
glacial acetic acid which will clear the solution.

Application notes: For tunnel wash applications dilution ratio is 300-500:1. 300:1
is most ideal.

pg 40
Prototype formulation for drying agent
Final Rinse Formula for Description

Automatic Car Wash This formulation can be used for the final rinse cycle for automatic car wash
(Concentrate) systems. The silicone ingredient provides water sheeting and quicker runoff.
Formulation reference: RA-210 A dilute solution is sprayed on the vehicle after cleaning, with blowers aiding
removal of water droplets.
The concentrate product is diluted with water 50:1 at the car wash facility.
The product/water mixture is diluted further 6:1 to 10:1 while spraying through
the car wash machinery.

Phase A
1. XIAMETER™ PMX-0245 10.0
Dow
Cyclopentasiloxane
2. DOWANOL™ DPnP Glycol Ether 10.0 Dow
4. Tomamine Emulsifier Four1 or 20.0 Air Products, Inc.
Accoquat CS-4000 Abitec
Phase B
5. Water 50.0
1
Contact Air Products, Inc., (www.airproducts.com) to obtain information on this product.
Procedure
1. Add Phase A ingredients in the order shown under low-shear mixing.
2. Add water under low shear. The final mixture should be transparent.
pg 41
Prototype formulation for durable polish
Automotive cream wax – Description

durable polish This automotive cream wax was created and balanced with XIAMETER™ silicone
Formulation reference: PW-301 fluids, resulting in a high-gloss and easy-to-apply product. The XIAMETER™
silicone fluids leave a soft film on a metallic surface. XIAMETER™ OFX-0531 Fluid
adds long-lasting protection to the wax film. This wax is appropriate for consumers
and professionals.

1. Water 62.0
2. Xanthan gum 0.3
3. Stearic acid 2.0
4. Polyethylene glycol stearate PEG 6000 or 1.0 Cutina DSP 6B/Cognis
CARBOWAX™ PEG-6000 Dow
6. Kerosene 15.0
7. Citric fragrance 0.2 D-Limonene
8. Carnauba wax – emulsion at 50% 4.0
Dow
100 cSt
Dow
1,000 cSt
12. Silicon dioxide 300# 1
8.0
13. Glutaraldehyde 0.1 Dow
1
The silicon dioxide can be replaced with aluminum silicate 350#
or 500# for better cleaning properties.
Procedure
1. Place ingredient 1 in a vessel.
2. Add ingredient 2 to the main vessel at room temperature and stir until uniform.
3. Add ingredients 3 and 4 and heat to 65°C to reach the melting point.
4. Add ingredient 5 under agitation and cool to 35°C
6. Add ingredients 7-12 under agitation in the listed order one at a time until uniform.

• The fragrance provides a pleasant citric odor.
• For good results, apply the product in circles. Do one section at a time. When
haze appears, buff with a soft and clean cloth or cotton.
• If paste-like consistency is required, the xanthan gum can be replaced with
acrylic polymer Carbopol 941 from Lubrizol (Noveon division or Dow's Acusol,
consult with Dow Technical Service).
Disclaimer:
pg 42
Automotive cream wax Description

Formulation reference: PW-303 This automotive cream wax was created and balanced with XIAMETER™ silicone
fluids, resulting in a high-gloss and easy-to-apply product. In addition, this product
exhibits cleaning and high wetting properties, leaving a soft film on the metallic
surface. XIAMETER™ OFX-0531 Fluid adds long-lasting protection to the wax film.
This wax is appropriate for consumers and professionals.

1. Water 62.0
2. Xanthan gum 0.3
3. Stearic acid 2.0
4. HallStar PEG 6000 DS 1.0 Hallstar
6. Kerosene 15.0
7. Fragrance 0.2 D-Limonene
8. Carnauba wax emulsion at 35% 4.0
Dow
Fluid, 100 cSt
Dow
Fluid, 1,000 cSt
13. KATHON LX 0.1 DuPont
Procedure
4. Add ingredient 5 under agitation and cool to 35°C.
6. Add ingredients 7-12 under agitation in the listed order one at a time
until uniform.

• For good results, apply the product in circles. Do one section at a time.
When haze appears, buff with a soft and clean cloth or cotton.
acrylic polymer Carbopol 941 from Lubrizol (Noveon division)
Disclaimer:
pg 43
High-gloss automotive cream Description

wax for professional detailing This automotive cream wax was created and balanced with XIAMETER™ silicone
Formulation reference: PW-304 fluids resulting in a high-gloss, durable, and easy-to-apply wax. In addition, this
product exhibits cleaning and high-wetting properties leaving a soft film on a
metallic surface. XIAMETER™ OFX-0531 Fluid adds long-lasting protection to the
wax film. DOWSIL™ 3037 Intermediate is a phenyl resin that provides outstanding
and persistent shine. This formula is appropriate for professionals.

1. Water 62.2
3. Stearic acid 2.0
6. Kerosene 15.0
Dow
Fluid, 100 cSt
9. DOWSIL™ 3037 Intermediate 2.0 Dow
Procedure
2. Add ingredient 2 to the vessel at room temperature and stir until uniform.
6. Add ingredients 7–11 under agitation in the listed order one at a time
until uniform.

• If paste-like consistency is required, the xanthan gum can be replaced
with acrylic polymer Carbopol 941 from Lubrizol (Noveon division).
Disclaimer:
pg 44
Automotive cream wax for Description

professional detailing This colored, automotive cream wax was created and balanced with XIAMETER™
Formulation reference: PW-305 silicone fluids resulting in a high-gloss, durable, and easy-to-apply wax.
In addition, this product exhibits cleaning and high wetting properties, leaving a
soft film on the metallic surface. XIAMETER™ OFX-0531 Fluid adds long-lasting
protection to the wax film. XIAMETER™ OFS-6124 Silane is added to fix the
pigment on the metallic surface. This wax is appropriate for professionals.

1. Water 62.0
2. KETROL F 0.3 CP Kelco
3. Stearic acid 2.0
6. Kerosene 15.0
8. XIAMETER™ PMX-200 Silicone Fluid, 100 cSt 4.0 Dow
9. XIAMETER™ PMX-200 Silicone Fluid, 1,000 cSt 2.0 Dow
11. XIAMETER™ OFX-6124 Silane 1.0 Dow
13. Pigment 0.1
14. Titanium dioxide 1.6
Procedure
6. Add ingredients 7–11 under agitation in the listed order one at a time until uniform.
7. Add ingredients 12–14 under agitation until uniform.

This formulation was developed with the purpose to cover scratches on
metallic surfaces.
acrylic polymer Carbopol 941 from Lubrizol (Noveon division).
Disclaimer:
pg 45
Durable, high-gloss paste polish Description

Formulation reference: PW-307 This formulation is for a detergent-resistant cleaner paste polish, designed for
automotive surfaces. This formulation provides a product with improved
application ease and rub-out, as well as excellent gloss, due to the use of a
silicone emulsifier. The product also exhibits very good durability and resistance
to multiple detergent washings.

Phase A
1. Odorless mineral spirits 9.5
2. DOWSIL™ 5225C Formulation Aid 7.5 Dow
Phase B
Phase C
5. Water 58.0
6. Kaopolite SF 15.0 Kaopolite, Inc.
Phase D
7. Tween 20 1.0 Croda/Uniqema
Phase E
8. 50% solution of sodium citrate in water 2.0
Procedure
1. Place Phases A and B into a mixing vessel. Start agitation. Mix until uniform.
2. Separately blend Phase C and add it to the top of the vessel with turbulent mixing.
3. Add Phases D and E.
4. Upon complete addition, begin high-speed mixing with a shear blade.
5. Continue shearing the product until the desired consistency is achieved.

Package.

1. The order of addition is critical. Ensure the water phase is added to the top of
the oil phase under turbulent mixing followed by shearing. Variations to this
procedure may yield a thin, unstable product because the emulsion may not
invert to a water-in-oil form.
2. The use of a high-shear homogenizer may improve product consistency

and stability.
3. Many alternative solvents to mineral spirits are acceptable.
4. A reduced level of the polishing agent (Kaopolite SF) may be desirable for use
on clearcoat finishes and may improve application ease and rub-out.
pg 46
Detergent-resistant cleaner Description

paste polish This formulation is for a detergent-resistant cleaner paste polish designed for
Formulation reference: PW-308 automotive surfaces. This formulation provides exceptional application ease and
rub-out, as well as excellent gloss, due to the use of a silicone emulsifier with
the resin/dimethyl fluid blend. The use of volatile silicones improves wet-out, as
well as the application ease of the material. The presence of the amine-functional
material and the resin/dimethyl fluid blend provides excellent durability
and resistance to multiple detergent washings.

Phase A
1. XIAMETER™ PMX-0345 Cyclosiloxane Blend 12.5 Dow
Phase B
3. DOWSIL™ 2-1912 Fluid 3.0 Dow
Phase C
5. Water 58.0
Phase D
Phase E
8. 50% solution of sodium citrate in water 2.0
Procedure
1. Place Phases A and B into a mixing vessel. Start agitation. Mix until uniform.
2. Separately blend Phase C and add it to the top of the vessel with turbulent mixing.
3. Add Phases D and E.
4. Upon complete addition, begin high-shear mixing.
5. Continue high-shear mixing until the desired consistency is achieved. Package.
pg 47
Extremely Durable Description

Liquid Polish Formulation APF 320 is an extremely durable, detergent-resistant cleaner polish
Formulation reference: PW-520 for automotive surfaces. The product provides very good gloss while the resin
improves durability and resistance to multiple detergent washings. This product
may be more difficult to rub out.

Phase A
1. Water 60.00
Phase B
3. WITCAMIDE 511 1.00 Witco Chemical Corp.
4. Odorless Mineral Spirits 19.25
Phase C
Phase D
7. DOWSIL™ RSN-6018 Resin Intermediate 0.50 Dow
8. Anhydrous Ethyl Alcohol 1.50
Phase E
9. BENTONE 38 0.50 Rheox Corp.
Phase F
10. Anhydrous Isopropyl Alcohol 0.24
Procedure
1. Add Phase A, with agitation, into mixing vessel.
2. Add Phase B.
3. When mixture is uniform, add Phase C.
4. Premix Phase D in ethyl alcohol until resin is soluble. Add to formulation.
5. Mix until creamy. Add Phase E.
6. When the above mixture is blended, add Phase F.
7. Mix until uniform. Package.

1. High shear mixing equipment will provide a thicker cream with less
phase separation.
2. Allow sufficient time for DOWSIL™ RSN-6018 Resin Intermediate. Resin to
dissolve. Heating the premix will reduce time needed to dissolve resin, but
use caution due to flash point limitations of alcohol.
3. Use of dimethyl fluid with this formulation may improve rub-out and gloss.
4. BENTONE 38 may be more easily incorporated into the system through the
use of a sifter or screen, particularly with low shear equipment.
5. Lower levels of the polishing agent (KAOPOLITE SF) may be desirable for
dear coat systems.
6. Alternative solvents to the mineral spirits may be considered.
pg 48
Hybrid Ceramic Sealant/Wax Description

Formulation reference: USL-PW-500 This hybrid ceramic sealant provides a durable highly hydrophobic protective
finish with a high degree of depth of gloss. The finish can last for many months!

Phase A
4. Water 40.3
Phase B
3. DOWSIL™ 2-1912 Fluid 3.4 Dow
5. Water 37.8
Procedure
Phase A:
1. Blend the first 3 components using normal shear or mixing.
2. Slowly add water until thoroughly mixed. (Slight milky appearance).
Phase B:
1. Mix DOWSIL™ 2-1912 Fluid with the DOWSIL™ RSN 9118 Resin under
normal shear.
2. Add TERGITOL™ 15-S-3 Surfactant under normal shear shear.
3. Add TERGITOL™ 15-S-7 Surfactant under normal shear.
4. Under high shear add Phase A slowly to above DOWSIL™ 2-1912/9118/
TERGITOL™ 15-S mixture.
5. Slowly add remaining water in Phase B under high shear until a homogenous
mixture is obtained.

Benefits:
• Ease of application: To a washed & rinsed vehicle (do not dry), use a quarter to
half dollar sized amount of Hybrid Ceramic Wax/Sealant on a micro-fiber cloth
or applicator pad and apply onto all surfaces of a quarter panel of the vehicle
(NOTE: Keep surface wet wiith mist of water if it should go dry during app.)
Buff dry completely until glossy & free of smears. Continue this process on all
surfaces of the vehicle.
• Long lasting protection.
• High depth of gloss.
• Can re-apply for future applications without affecting gloss .
• Can be applied over all vehicle surfaces, including glass, without streaking
or smearing.
pg 49
Hybrid Ceramic Sealant/Wax Description

Formulation reference: USL-PW-510 This hybrid ceramic sealant provides a durable highly hydrophobic protective
finish with a high degree of depth of gloss. The finish can last for many months!

Phase A
4. Water 40.3
Phase B
3. DOWSIL™ 2-1912 Solid Resin 3.4 Dow
4. DOWSIL™ MQ 1600 Solid Resin 1.5 Dow
5. Water 40.3
Procedure
Phase A:
1. Blend the first 3 components using normal shear or mixing.
2. Slowly add water until thoroughly mixed. (Slight milky appearance).
Phase B:
1. Mix DOWSIL™ 2-1912 with the DOWSIL™ MQ1600 under high shear to
help solvate.
2. Add TERGITOL™ 15-S-3 Surfactant under high shear to continue to break
down DOWSIL™ MQ 1600.
3. Add TERGITOL™15-S-7 Surfact under high shear.
4. Under high shear add Phase A slowly to above DOWSIL™ 2-1912 Solid
Resin / DOWSIL™ MQ 1600 Solid Resin.
5. Add remaining water in Phase B under high shear until a homogenous
mixture is obtained. Filter final mixture.

Benefits:
• Ease of application: To a washed & rinsed vehicle (do not dry), use a quarter to
half dollar sized amount of Hybrid Ceramic Wax/Sealant on a micro-fiber cloth
or applicator pad and apply onto all surfaces of a quarter panel of the vehicle
(NOTE: Keep surface wet wiith mist of water if it should go dry during app.)
Buff dry completely until glossy & free of smears. Continue this process on all
surfaces of the vehicle.
• Long lasting protection.
• High depth of gloss.
• Can re-apply for future applications without affecting gloss.
• Can be applied over all vehicle surfaces, including glass, without streaking
Courtesy of Univar Solutions Inc. or smearing.
pg 50
Prototype formulation for exterior trim protection
Exterior plastic / rubber Description

enhancers – liquid The combination of an amino-functional silicone fluid and a high-viscosity silicone
Formulation reference: EP-403 fluid gives a durable film to restore faded bumpers and other trim. Reducing the
thickener level enables the product to be packaged in a spray dispenser.
1. Water 83.3
3. DOWSIL™ HV 496 Emulsion 10.0 Dow
4. Cellulose thickener 1.0 Ashland Inc.
Procedure
1. Add ingredients 1–3 in the order listed to an appropriate vessel,while mixing
at low speed.
2. Slowly add ingredient 4 to the vessel. Mix for 30 minutes, or until the product
is completely dissolved and no lumps are present.

• To improve leveling, add XIAMETER MEM-0062 Emulsion PS or XIAMETER™
MEM-0349 Emulsion or XIAMETER™ MEM-0346 Emulsion.
• To improve wetting, add 0.5% of XIAMETER™ OFX-5211 Superwetting Agent
or XIAMETER™ OFX-0309 Fluid.
pg 51

enhancers – sheen finish This product provides a matte, leather-like appearance to exterior surfaces.
Formulation reference: EP-404 Incorporation of a wax emulsion will promote uneven reflection of light, giving a
perceived lower gloss finish. An emulsion of a lower viscosity polydimethylsiloxane
base polymer will give less color intensity.

1. Water 80.4
3. XIAMETER™ MEM-0062 Emulsion PS 8.0 Dow
4. Michem Lube 155 6.0 Michelman Inc.
Consult with Dow on
5. Acrylic thickener 0.4 ACUSOL™ PRO Polymer and
other Acrylic thickeners
Procedure
1. Add ingredients 1–4 into an appropriate vessel. Mix at low speed.
2. Slowly add ingredients 5 and 6. Mix until product is homogeneous.

• To lower the color intensity, substitute XIAMETER™ MEM-0349 Emulsion or
XIAMETER™ MEM-0346 Emulsion for XIAMETER™ MEM-0062 Emulsion PS.
• To give a lower gloss finish, partially replace XIAMETER™ MEM-0062
Emulsion PS with wax emulsion.
• To improve durability, increase the level of XIAMETER™ MEM-8035 Emulsion
and decrease the level of XIAMETER™ MEM-0062 Emulsion PS.
pg 52

enhancers – aerosol product Blending a silicone fluid with a silicone resin shows excellent gloss/color with
Formulation reference: EP-410 durability. Spray application makes for a very quick process.

Exxon Chemicals Ltd. /
2. Heptane 62.5
10.0 Dow
5. Isopar G 15.0 Exxon Chemicals Ltd.
Please read Guidance for Aerosol Applications of Silicone-Based Materials from the Silicones
Environmental, Health and Safety Council of North America (SEHSC) at sehsc.com/science.asp.
Procedure
Mix the ingredients listed with low-speed stirring.

Approximately 70% by weight of this formulation would be used in an aerosol with
the remaining 30% serving as propellant.
• To improve durability, increase the level of DOWSIL™ RSN-9118 Resin.
• Replace DOWSIL™ RSN-9118 Resin with DOWSIL™ 2-1912 Fluid
pg 53

enhancers – gel The thick gel consistency of this formulation enables accurate application to trim
Formulation reference: EP-420 areas only. The silicone fluid gives excellent gloss and color, while the amino-
functional silicone fluid provides durability.

2. CAB-O-SIL EH-5 8.7 Cabot Corp.
6.0 Dow
Procedure
Mix the ingredients in the order listed above with low-shear stirring.

• To increase the color intensity, substitute XIAMETER™ PMX-200 Silicone
Fluid, 60,000 cSt, for XIAMETER™ PMX-200 Silicone Fluid, 12,500 cSt.
• To improve durability, increase the level of XIAMETER™ OFX-0536 Fluid and/
or incorporate DOWSIL™ RSN-9118 Resin.
pg 54
Premium protectant lotion Description

(Low odor) This formula is a water-based protectant lotion that is California A.R.B. compliant.
Formulation reference: IP-590 The combination of XIAMETER™ MEM-0349 Emulsion with XIAMETER™ MEM-0037
Emulsion provides high gloss to interior dashboards, plastic, rubber, interior leather
and tire surfaces and is low odor when applied to surfaces. An easy-to-disperse
thickener that maintains low odor was selected to create this lotion.

Phase A
1. DI or soft water 45.00
2. Carbopol EZ-2 0.70 Lubrizol/Noveon
Phase B
3. Preservative q.s. Dow
Separate Phase C (Premix) Target pH = 8.0–9.0
6. DI water 24.00
7. 20% sodium hydroxide solution q.s.1
Start with 0.010%
1
Procedure
Use a mixer with multiple impellers to give high turnover flow
at sides and bottom of container.
1. Use enough phase A water to reach the effective mixing zone of the vessel.
2. Add Carbopol EZ-2 thickener and disperse under moderate shear (minimum
20 minutes).
3. Add phase B ingredients and mix under moderate shear (minimum 20

minutes). A large increase in thickness will occur.
4. Put phase C DI water in a separate container for the phase C premix.
5. Add 20% sodium hydroxide solution to achieve a pH of 8.0–9.0 for phase

C as measured by a digital pH meter.
6. Add phase C to the formula and continue mixing (minimum of 20 minutes).

Lotion will thin during this step.

DI water or softened water is recommended for this formula. Adjust the amount of
20% sodium hydroxide solution to achieve the target pH. The amount of thickener
can be adjusted to modify the formula from a thin lotion to a thick gel if desired.
pg 55
Prototype formulation for glass cleaner
Glass care – screenwash Description

Formulation reference: GL-802 This silicone surfactant enables rapid coverage of the windscreen promoting contact
between road traffic film and the solution.

1. Water 68.5
2. Crodasinic LS35 0.5 Croda, Inc.
3. DOWANOL™ DPM Glycol Ether 2.0 Dow
4. DOWANOL™ PM Glycol Ether 3.0 Dow
5. Propylene glycol 5.0 Dow
7. Isopropanol 20.0
Procedure
Mix the ingredients in the order listed with low-speed stirring.

• The level of XIAMETER™ OFX-0193 Fluid should be adjusted depending on
the dilution ratio recommended for the product to optimize wetting.
pg 56
Glass care – cleaner Description

Formulation reference: GL-810 This is a cleaning product for removing grease and dirt from windows. The silicone
surfactant aids spreadability and also provides temporary anti-mist properties
without smearing.

1. Water 84.7
2. DOWANOL™ DPM Glycol Ether 5.0 Dow
4. Isopropanol 10.0
Procedure

• At higher levels of incorporation, XIAMETER™ OFX-0193 Fluid can provide an
anti-mist property.
pg 57
Glass cleaner with ammonia Description

and citric glass cleaner These automotive glass cleaners are easy to wipe off because of the lubricity
Formulation reference: GL-840 provided by XIAMETER™ OFX-0193 Fluid.

Phase A
1. Water 66.2
2. Isopropanol 10.0
3. Ethanol 20.0
4. DOWANOL™ PnB Glycol Ether 3.0 Dow
6. Ammonia 0.3
Phase B
1. Water 66.3
2. Isopropanol 10.0
3. Ethanol 20.0
6. D-Limonene 0.2
Procedure

• The ammonia in formulation A acts as a degreaser and the D-Lemonene in
formulation B adds a pleasant citric odor.
pg 58
Anti-fog glass cleaner Description

Formulation reference: GL-860 This is a glass cleaner formulation that is excellent for cleaning automobile
windshields, household windows, refrigerators, stove tops and kitchen counter
surfaces. It removes grease and dirt and is easy to wipe off because of the lubricity
provided by the silicone fluid. This formulation also provides anti-fog properties.

Phase A
4. Isopropanol 10.0
Phase B
5. Deionized Water 84.5
Procedure
1. Mix Phase A ingredients until uniform.
2. Add this solution to Phase B.

• The grease-removing power of this product may be slightly improved by
adding a small amount of organic surfactant.
pg 59
Prototype formulation for interior protection
Cockpit enhancers – Description

aerosol product This formulation provides an easy-to-apply product featuring silicones that give
Formulation reference: IP-501 good gloss/color and that help mask light scratches.

1. Exxon D40 10.0 Exxon Chemical Co.
3. XIAMETER™ PMX-200 Silicone
3.5 Dow
Fluid, 350 cSt
4. XIAMETER™ PMX-200 Silicone

3.5 Dow
Fluid, 1,000 cSt
5. Isopar G 15.0 Exxon Chemical Co.
Procedure
Mix the ingredients in the order listed with-low speed stirring. Approximately 70%
by weight of this formulation would be
used in an aerosol with the remaining 30% being propellant.

Suggestion for adjusting the formulation:
• To increase the gloss/color, increase ratio of XIAMETER™ PMX-200 Silicone
Fluid, 1,000 cSt to XIAMETER™ PMX-200 Silicone Fluid, 350 cSt; or
incorporate 2% XIAMETER™ PMX-200 Silicone Fluid, 12,500 cSt.
• To provide a drier film, incorporate 3% DOWSIL™ 2-1912 Fluid or DOWSIL™
RSN-9118 Resin and reduce level of other silicones by 1% each.
pg 60
Cockpit enhancers – liquid Description

Formulation reference: IP-502 This product is an emulsion form of a solventless product formulated to provide
shine to interior surfaces.

1. Water 85.0
2. XIAMETER™ MEM-0349 Emulsion or 7.0 Dow
Procedure
1. Put ingredients 1–3 into an appropriate vessel and mix at low speed.
2. Slowly add ingredient 4 while mixing at low speed. Continue to mix for 30
minutes, or until all thickener is dissolved and the product is homogeneous.

• To increase the gloss/color: Incorporate 2% DOWSIL™ HV 496 Emulsion and
reduce the level of other silicones by 1% each.
pg 61
Cockpit enhancers – Description

sheen finish Lowering the silicone level and using a wax emulsion of larger particle size promotes
Formulation reference: IP-503 uneven light reflection, giving a perceived lower gloss finish (as a new look) with
reduced glare.

1. Water 87.3
2. Carbopol Ultrez 0.5 Lubrizol
4. Michem Lube 155 5.0 Michelman Inc.
6. Preservative 0.2
Procedure
1. Put ingredient 1 into the main vessel. Sift in ingredient 2. Mix for 20 minutes at
low speed.
2. Add ingredients 3 and 4 to the main vessel. Mix 10 minutes.
3. Add ingredients 5 and 6 to the main vessel. Mix 30 minutes. Pour down and
package.

• To give a more sheen or matte finish: Increase ratio of wax emulsion to
XIAMETER™ MEM-0349 Emulsion or XIAMETER™ MEM-0346 Emulsion
pg 62
Leather conditioner lotion Description

Formulation Reference: IP-540 This gel product uses a combination of materials to keep leather supple by replacing
Croda derived formulation lost natural oils. The silicone wax helps to protect the leather, while the silicone
fluid aids application.

Phase A
2. SynCroWax ERL 2.0 Croda Ltd.
3. SynCroWax AWI 2.0 Croda Ltd.
4. Lanolin 2.0
5. VOLPO L4 2.5 Croda Ltd.
350 cSt
7. Pine Oil 1.0
Phase B
9. Water 37.0
Phase C
10. Acrylic thickener (2%) solution 15.0 Consult with Dow on
ACUSOL™ PRO
Polymer and other
Acrylic thickeners
11. Water 30.0
12. Isopropanol 5.0
Procedure
1. Mix ingredients 1-8 in the main vessel and heat to 70°C.
2. Heat ingredient 9 to 70°C and add to Phase A under high shear.
3. Prepare a solution of acrylic thickener and water and add this to the
main vessel.
4. Add isopropanol and mix for 5 minutes under high shear, then use
low-speed mixer.

• To increase the gloss or color: Replace XIAMETER™ PMX-200 Silicone Fluid,
350 cSt, with XIAMETER™ PMX-200 Silicone Fluid, 1,000 cSt.
• To reduce the gloss: Replace XIAMETER™ PMX-200 Silicone Fluid, 350 cSt,
with XIAMETER™ PMX-200 Silicone Fluid, 100 cSt.
• To improve water repellency: Replace XIAMETER™ PMX-200 Silicone Fluid,
350 cSt, with DOWSIL™ RSN-9118 Resin.
• To give a drier film: Replace XIAMETER™ PMX-200 Silicone Fluid, 350 cSt,
with DOWSIL™ 593 Fluid, DOWSIL™ 3527 Release Agent or DOWSIL™
RSN-9118 Resin.
pg 63
Vinyl protectant Description

Formulation reference: IP-550 This formulation is a vinyl surface protectant that may be used on various soft
surfaces such as vinyl, leather, rubber, and plastics to impart gloss.

1. Water 79.1
2. CELLOSIZE™ QP-4400H 0.8
Dow
Hydroxyethyl cellulose
Procedure
1. Add ingredient 2 to ingredient 1 and stir to achieve a transparent solution.

Directions: The final product can be applied by spray or with a damp cloth. This
product should not be applied on floors or on vehicle controls.
pg 64
Creamy vinyl surface protectant Description

Formulation reference: IP-560 This is a creamy vinyl and leather cleaner and protectant. It provides excellent
gloss and easy application.

Phase A
3. XIAMETER™ PMX-0245 Cyclopentasiloxane 12.5 Dow
Phase B
4. Water 73.9
6. Sodium chloride 0.1
Procedure
1. Blend Phases A and B separately.
2. Add Phase B to the top of Phase A with turbulent mixing.
3. Once the addition is complete, shear mix to the desired consistency.

• Durability may be improved with the addition of XIAMETER™ OFX-0531 Fluid
in Phase A.
• Witcamide 511 may be used as an alternative emulsifier
• Other electrolytes may be subsituted for sodium chloride
pg 65
Fabric water repellent Description

Formulation reference: IP-570 This formulation is an excellent water repellent treatment for items such as automotive
upholstery and carpet. It may also be used to treat rainwear, snowsuits, mittens,
footwear and upholstery materials.

1. DOWSIL™ FBL-0563 Formulated Blend 5.0 Dow
2. Isopar G Solvent 95.0 Exxon Corp.
Procedure
Blend water repellent with solvent.

• This product could also serve as a concentrate for an aerosol and be used
at a level of 80% with 20% propellant.
• Solvents should be free of moisture to ensure maximum shelf life.
• Alternative solvents, such as aliphatic hydrocarbons, may be used.
pg 66
Multi-surface medium shine Description

dressing This formulation is a water-based protectant that is California A.R.B. compliant.
Formulation reference: IP-580 The formula provides gloss to interior dashboards, plastic, rubber, interior leather,
and tire surfaces. The thickener provides vertical cling when the formula is sprayed.

Phase A
1. Water 30-40
3. Acrylic thickener: Alcogum L-12 1.5 Alco Chemical
or ACUSOL™ 820 Polymer 1.0 Dow
Phase B
5. Additional water to total 63% water 33-23
Procedure
Use a mixer that gives adequate turn over flow at the sides of the bottom of
the container.
1. Load enough water to reach the effective mixing zone of the container.
2. Add the remaining phase A ingredients and mix until uniformly dispersed
(minimum 20 minutes).
3. Premix phase B ingredients and then add to phase A.
XIAMETER™ MEM-0349 Emulsion and 4. Mix until thickener is fully activated (minimum 20 minutes).
XIAMETER™ MEM-0346 Emulsion are 5. Check the formula pH and verify it is in the correct range.
60% polydimethyl-siloxane emulsions
with nonionic surfactants. Additional information to optimize formula
First, adjust the targeted amount of triethanolamine to obtain a final pH of 8.0–9.5
to correctly activate the thickener. This compensates for variations in the source
water pH. If desired, adjust the level of acrylic thickener to modify the formula
viscosity for best performance with your spray bottle.
See Auto Care Raw Material Supplier Reference Sheet for the role of the raw
material and supplier information.
pg 67
Premium protectant lotion Description

(Low odor) This formulation is a water-based protectant lotion that is California A.R.B.
Formulation reference: IP-590 compliant. The combination of XIAMETER™ MEM-0349 Emulsion with
XIAMETER™ MEM-0037 Emulsion provides high gloss to interior dashboards,
plastic, rubber, interior leather and tire surfaces and is low odor when applied to
surfaces. An easy-to-disperse thickener that maintains low odor was selected to
create this lotion.

Phase A
1. DI or soft water 45.0
2. Carbopol EZ-2 0.70 Lubrizol (Noveon
division)
Phase B
Separate Phase C (Premix) Target pH = 8.0–9.0
6. DI water 24.0 Lubrizol
7. 20% sodium hydroxide solution q.s. 1
1
Start with 0.010%.
Procedure
Use a mixer with multiple impellers to give high turnover flow
at the sides and bottom of the container.
1. Load enough water to reach the effective mixing zone of the container.
2. Add Carbopol EZ-2 thickener and disperse under moderate shear (minimum
20 minutes).
3. Add phase B ingredients and mix under moderate shear (minimum 20

minutes). A large increase in thickness will occur.
4. In a separate container, load DI water for the phase C premix.
5. Add 20% sodium hydroxide solution to achieve a pH of 8.0–9.0 for phase C

as measured by a digital pH meter.
6. Add phase C to formula and continue mixing (minimum of 20 minutes). Lotion

will thin during this step.
Additional information to optimize formula

DI water or softened water is recommended for this formula. Adjust the amount of
20% sodium hydroxide solution to achieve the target pH. The amount of thickener
can be adjusted to modify the formula from a thin lotion to a thick gel if desired.
pg 68
Prototype formulation for leather conditioner
Leather conditioner lotion Description

Formulation Reference: IP-600 with A creamy lotion for conditioning leather that appeals to the senses. The formula
DOWSIL™ 2-5088 Wax gives a high shine during initial application that slowly transforms to a surface
with medium shine that feels dry. DOWSIL™ 2-5088 Wax thickens the formula and
provides a dry protective film to the leather. DOWSIL™ 5200 Formulation Aid is an
excellent emulsifier for economical formulas with a high water content where the
oil phase is the continuous phase of the emulsion. The formula VOC content
is less than 0.5 wt %. Contains natural Lanolin Oil for conditioning.

Water Phase
1. DI Water 72.0
2. Sodium Chloride 1.0
Oil Phase
3. Isoparaffin (Isopar M) 17.0 Exxon Mobil
(VOC exempt) or equivalent
4. XIAMETER™ PMX-0245 2.0 Dow
Cyclopentasiloxane
5. Lanolin Oil 2.0 Various
6. White Mineral Oil 1.0 Various
7. DOWSIL™ 5200 Formulation 3.0 Dow
Aid (emulsifier)
Procedure
1. In a separate container suitable for heating, add all oil phase ingredients in the
order shown.
2. Heat the oil phase slowly to 72ºC in a closed container to melt the wax (for
example, in a large oven).
Additional Information
3. Load hot DI Water at 60ºC into the mixing vessel.
Sodium Chloride is a freeze-thaw stabilizer.
XIAMETER™ PMX-0245 Cyclopentasiloxane 4. Add Sodium Chloride and dissolve the salt.
promotes good spreading of all actives.
5. Ensure mixing vessel equipment and Water Phase are between 60-65ºC prior
to adding oil phase.
6. Add hot Oil Phase (72ºC) to mixing vessel while mixing.
7. Allow the formula to begin cooling under moderate shear.
8. When the liquid cools below 55ºC, the material will change to an “oil out”
emulsion and will thicken dramatically.
9. Continue to mix until formula has cooled below 40ºC.
pg 69
Prototype formulation for sheen finish cockpit enhancer
Cockpit enancers – sheen finish Description

Formulation reference: IP-610 This cockpit enhancer uses a silicone emulsion at low dosage. It incorporates a
wax emulsion with large particle size, which gives uneven light reflection. The result
is a perceived lower gloss finish. This is important for light reflection control on
treated surfaces, e.g., dashboards, that can distract the driver from the road.

1. Water 88.0
3. Microspersion 250 5.0 Kromachem Ltd.
4. Cellulose thickener 1.0 Dow
Procedure
Mix the ingredients in the order listed at low stirring speed.
pg 70
Prototype formulation for polymer sealant
Polymer sealant liquid Description

Formulation reference: PW-360 This polymer sealant liquid polish features an amino-functional silicone that gives
long-lasting protection with good color and gloss. Full protection is developed 24
hours after application of the polish.

Phase A
1. Low aromatic solvent 160/190°C 10.0 Exxon Chemicals Ltd. Shell Chemicals Ltd.
2. Low aromatic solvent 200/250°C 12.0 Exxon Chemicals Ltd. Shell Chemicals Ltd.
3. Oleic acid 1.4
4. Dimethylamino ethanol 1.3
Phase B
Phase C
7. Water 55.1
10. Dimethylamino ethanol 0.1
Phase D
11. Wax emulsion 4.3
Procedure
1. Mix phase A ingredients until uniform using low shear in an auxiliary vessel.
2. Add phase B ingredients to phase A with low shear.
3. Add phase C ingredients to the main vessel with low-speed stirring until
fully dispersed.
4. Add the contents of the auxiliary vessel to the main vessel under high shear.
5. Add phase D ingredient to the main vessel with low-speed stirring.

A method used to improve the corrosion resistance of a polish is to react
XIAMETER™ OFX-0536 Fluid with lauric acid. In the example above, the XIAMETER™
OFX-0536 Fluid and lauric acid only would be added to the solvents (ratio 0.3
acid to 1.0 XIAMETER™ OFX-0536 Fluid) and this heated to 45°C for 5 minutes.
Components 3 and 4 would then be added and the polish completed as before.
• To improve gloss: Incorporate 0.5–1.0% XIAMETER™ PMX-200 Silicone Fluid,
1,000 cSt.
• To improve ease of use/leveling: Incorporate 0.5–1.0% XIAMETER™ PMX-200
Silicone Fluid, 350 cSt, or DOWSIL™ 593 Fluid.
• To improve color intensity: Incorporate 0.2–0.5% XIAMETER™ PMX-200
Silicone Fluid, 12,500 cSt.
• To improve gloss, ease of use and color: Incorporate XIAMETER™
PMX-200 Silicone Fluid, 350 cSt; XIAMETER™ P
MX-200 Silicone Fluid, 1,000 cSt; XIAMETER™ PMX-200 Silicone Fluid,
12,500 cSt in a ratio of 3:1:1 at 1% total level.
pg 71
Pre-softened polymer Description

sealant paste This product is formulated to give good detergent resistance by incorporation of
Formulation reference: PW-370 amino-functional silicones and wax. The silicone fluid aids application characteristics.

Phase A
1. Low aromatic solvent 160/190°C 10.0 Exxon Chemicals Ltd.
2. Low aromatic solvent 200/250°C 12.0 Exxon Chemicals Ltd.


6. XIAMETER™ PMX-200 0.8 Dow
Phase B
7. Water 54.5
8. Alcan SF7 8.0 Alcan Chemicals
9. Diafil 830 4.2 Microfine Minerals Ltd.
10. Crodamet T8 1.5 Croda Ltd.
Procedure
1. Place ingredients 1–3 into an auxiliary vessel and heat to 45°C with low-
shear mixing. Maintain the temperature at 40-45°C and add ingredients 4–6
with low shear.
2. In the main vessel, add ingredients 8 and 9 to ingredient 7 with low shear until
dispersed while heating to 50°C.
3. Add ingredients 10 and 11 under low shear.

4. Add phase A and phase B under high shear.
5. Cool to filling temperature.

• To improve gloss: Incorporate 0.5–1.0% XIAMETER™ PMX-200 Silicone Fluid,
1,000 cSt.
• To improve ease of use: Increase level of XIAMETER™ PMX-200 Silicone
Fluid, 350 cSt, to 1.5%.
• To improve color intensity: Incorporate 0.2–0.5% XIAMETER™ PMX-200
• To improve gloss, ease of use, and color: Incorporate XIAMETER™ PMX-200
Silicone Fluid, 350 cSt; XIAMETER™ PMX-200 Silicone Fluid, 1,000 cSt; and
XIAMETER™ PMX-200 Silicone Fluid, 12,500 cSt in a
ratio of 3:1:1 at 1% total level.
pg 72
Pre-softened polymer Description

sealant paste This formulation gives good detergent resistance by incorporation of amino-
Formulation reference: PW-375 functional silicones and wax, while the fluid aids application characteristics.

Phase A
1. Low aromatic solvent 160/190°C 10.0 Exxsol D40/Exxon Chemical Co.
2. Low aromatic solvent 200/250°C 12.0 Exxsol D40/Exxon Chemical Co.
3. Carnauba Wax 3.0
0.8 Dow
Phase B
7. Water 54.4
8. Alcan SF7 8.0 Alcan Inc.
9. Celite Super Floss 4.2 Celite Corp.
10. ECOSURF™ EH-9 Surfactant or Dow
1.5
Procedure
1. Place ingredients 1–3 into an appropriate vessel and heat to 45°C with low-
shear mixing. Maintain the temperature at 40–45°C and add ingredients 4–6.
2. In the main vessel, add ingredients 7–9 and mix with low shear until dispersed
while heating to 50°C.
3. Add ingredients 10 and 11 under low shear. Mix until all ingredients are dis-
persed, approximately 45 minutes.
4. Add Phase A to Phase B under high shear. Cool to filling temperature.

• To improve gloss, incorporate 0.5–1.0% XIAMETER™ PMX-200 Silicone Fluid,
1,000 cSt.
• To improve ease of use, increase level of XIAMETER™ PMX-200 Silicone
Fluid, 350 cSt, to 1.5%.
• To improve color intensity, incorporate 0.2–0.5% XIAMETER™ PMX-200
• To improve gloss, ease of use, and color, incorporate XIAMETER™ PMX-200
Silicone Fluid, 350 cSt; XIAMETER™ PMX-200 Silicone Fluid, 1,000 cSt; and
XIAMETER™ PMX-200 Silicone Fluid, 12,500 cSt in a ratio of 3:1:1 at 1%
total level.
Disclaimer:
pg 73
Prototype formulation for scratch concealer
Scratch concealer Description

Formulation reference: SC-100 DOWSIL™ 3527 Release Agent is easy to apply and provides a durable, smooth,
glossy coating that penetrates imperfections.
Hydral 710 Abrasive works well with polish formulas with a high water content.
Both Kaopolite 1152 and Hydral 710 Abrasives are relatively mild and prevent
additional scratches to auto clear coats.
Isopar M is an organic Isopar affin solvent that is VOC-exempt, very slow to dry and
aids with film formation of active ingredients in the formula.
This formula passes five cycles of freeze/thaw stability testing.

Phase A
1. DI water 68.45
2. Alcoa Hydral 710 Abrasive 3.0 Alcoa Inc.
3. Kaopolite 1152 Abrasive 5.0 Kaopolite, Inc.
4. Amadol (Witcamide) WE 2.0 Akzo Nobel
5. Sodium chloride salt 1.0
6. Stoddard solvent 10.50 Chemcentral or Ashland
Phase B
7. Isopar M (Isoparaffin) 1.00 Exxon Chemicals Ltd.
8. Stoddard solvent 3.0 Chemcentral or Ashland
9. Bentone 38 0.7 Rheox, Inc.
Phase C
10. DOWSIL™ 3527 Release Agent 5.0 Dow
11. Isopropanol 0.35
Procedure
1. Load phase A ingredients in the order shown into a vessel and mix well.
2. Mix phase B ingredients in a separate container.
3. Add phase B to the production vessel and mix well.
4. Add phase C ingredients to the production vessel in

the order shown and mix well.

• Formulas with a water content greater than 75% are problematic (poor
emulsification and do not thicken to a paste) and are not recommended with
this combination of abrasives and emulsifier.
Observe precautions for handling DOWSIL™ products as indicated on the safety
data sheets.
pg 74
Prototype formulation for solvent-free polish
Solvent-free polish Description

Formulation reference: PW-385 This formulation incorporates a range of silicone emulsions of fluid/amino/wax to
provide properties that were achievable historically with solvent-based technologies.

1. Water 60.0
2. ECOSURF™ EH-9 Surfactant Dow
1.0
2.5 Dow
Cyclohexasiloxane
4. Water 30.0
5. XIAMETER™ MEM-0349 Emulsion or

1.5 Dow

Michem Lube 155 /
7. Wax emulsion 1.0
Michelman Inc.
8. Hydroxyethyl Cellulose Thickener 0.8 Ashland Inc.
9. Celite Super Floss 1.0 Celite Corporation
10. Alcan SF7 0.8 Ashland Inc.
Procedure
1. Mix ingredients 1–4 in an appropriate vessel under high shear.
2. Add ingredients 5–7 to the vessel with high shear.
3. Slowly add ingredient 8 while mixing. Continue to mix for 30 minutes; or until
the thickener is dissolved and the product is uniform.
4. Add ingredients 9 and 10 to the above, continuing to mix for an additional

10 minutes.

• To improve gloss, incorporate XIAMETER™ MEM-0062 Emulsion PS at
0.5%; reduce XIAMETER™ MEM-0349 Emulsion or XIAMETER™ MEM-0346
Emulsion to 0.5%.
• To improve durability, increase XIAMETER™ MEM-8035 Emulsion to 2.0%
and the wax emulsion to 5.1%.
pg 75
Prototype formulation for tire care
Tire enhancer foam spray Description

Formulation reference: TP-701 This formulation gives a “new” rather than painted appearance to the tire. The high-
viscosity fluid emulsion increases gloss, while the amino-functional silicone
promotes durability.

1. Water 68.15
2. Polyoxyethylene (20) sorbitan monooleate 0.7 Alkamuls PSMO
20 / Solvay
3. Sorbitan trioleate 0.5 Alkamuls SMO

UNBL / Solvay
7. Sodium benzoate - rust inhibitor 0.2
8. XIAMETER™ AFE-2210 Antifoam Emulsion 0.15 Dow
Procedure
Mix the ingredients in the order listed with low-speed stirring. Approximately 85%
by weight of this formulation will be used in an aerosol fitted with a foaming valve,
with the remaining 15% used in propellant.

• To improve durability, increase ratio of XIAMETER™ MEM-8035 Emulsion to
DOWSIL™ HV 496 Emulsion.
pg 76
Solvent-based liquid tire Description

surface protectant This tire dressing protectant is designed to impart high gloss to the surfaces
Formulation reference: TP-720 of tires.

1. Oderless mineral spirits 85.0
2. X
IAMETER™ PMX-200 SIlicone Fluid, 15.0 Dow
10,000 cSt
Procedure
Blend ingredients until uniform. Ensure adequate mixing at the bottom of the
blending container.
Additional information to optimize formula

• Solvent choice may vary with specific application needs and desired drying time.
• Additional durability and gloss can be achieved by raising amount of
XIAMETER™ PMX-200 Silicone Fluid, 10,000 cSt. Suggested range in
formulation is 10–20 wt %.
pg 77
Prototype formulation for water-based tire dressing
Tire dressing Description

(Lot Number 16788-73) Formulation This formulation is based in XIAMETER™ MEM-1101 Emulsion adds shine, while
reference: TP-730 XIAMETER™ MEM-8035 Emulsion increases durability.
Procedure
4. Water 60.5
Mix the ingredients in the order listed with low stirring and add them slowly.

• To improve gloss, add more XIAMETER™ MEM-1101 Emulsion.
• Explore different levels of gloss by using XIAMETER™ MEM-1664 Emulsion
with XIAMETER™ MEM-1101 Emulsion.
pg 78
Cream tire dressing Description

(Lot Number 16788-75) Formulation This formulation produces a thick cream tire dressing. XIAMETER™ MEM-1101
reference: TP-740 Emulsion adds shine, while XIAMETER™ MEM-8035 Emulsion improves durability.

1. Water 58.85
2. Carbopol Ultrez 10 0.60 Lubrizol
Procedure
1. Put the water into the main vessel and begin mixing at low speed. Slowly
add the carbomer and mix under high shear until all powder has been
wetted, approximately 30 minutes. Add the carbomer slowly to avoid the
formation of lumps.
2. When all the carbomer has been hydrated, add XIAMETER™ MEM-0349
Emulsion, XIAMETER™ MEM-0037, XIAMETER™ MEM-1101 Emulsion and
XIAMETER™ MEM-8035 Emulsion to the main vessel while mixing.
3. Add the triethanolamine and preservative. Stir for another 30 minutes.
4. Pour down and package.

• To improve gloss, increase the amount of XIAMETER™ MEM-1101 Emulsion.
• Explore different levels of gloss using DOWSIL™ HV 496 Emulsion with
XIAMETER™ MEM-1101 Emulsion.
pg 79
Fast dry premium shine Description

tire dressing This formulation is a “spray and walk away” tire dressing that dries extremely fast
Formulation reference: TP-750 and is California A.R.B compliant. The formulation provides premium shine and
premium darkening/color enhancement of tires. Treated tires have a glossy, dark
“car show” appearance.

Phase A
1. DOWSIL™ OS-2 Silicone Cleaner and Solvent 50.0 Dow
Phase B
4. VOC-exempt aliphatic hydrocarbon 20.0 CPChem
solvent (isoparaffin) Soltrol 220
or Exxon
Isopar M
Procedure
1. Add the Phase A ingredients in the order shown into a mixing vessel suitable
for handling flammable liquids and vapors. Use a mixing impeller with ad-
equate turnover flow at the bottom of the container. Rinse the load lines and
any additional containers with the Phase B ingredient while adding it to the
mixing vessel.
DOWSIL™ OS-2 Silicone Cleaner
and Solvent is: Typical properties / additional information
• VOC-exempt DOWSIL™ OS-2 Silicone Cleaner and Solvent is flammable. Review the Safety
Data Sheet and use appropriate cautions during use. The above formulation is
• Non-allergenic flammable (flash point = 27ºF). Follow the appropriate labeling and shipping of
• Low in toxicity packages containing this formula.
• Safe on plastics; non-corrosive Including the isoparaffin solvent prevents the formula from drying before the gloss
to metals agents cover the tire uniformly and also lowers the formula cost.
Formulation performance review results:

• Uniform appearance while drying
• Amount of slippery residue on the ground is four times less than with
15 Minutes 30 Minutes formulation TP-770
after application after application
• Reduced streaks/drips at the tire bottom while drying
• High level of color enhancement and gloss compared to TP-770
Formula was sprayed on the tire surface with no wiping.
Dried appearance
Dried appearance
pg 80
Spray and walk away Description

tire dressing This formulation is a “spray and walk away” tire dressing that is California A.R.B.
Formulation reference: TP-760 compliant. XIAMETER™ PMX-0245 Cyclopentasiloxane improves the spreading
of gloss agents so no wiping is needed. The formulation gives premium shine and
premium darkening/color enhancement of tires. Treated tires have a glossy, dark
“car show” appearance.

Phase A
1. XIAMETER™ PMX-0245 Cyclopentasiloxane 37.0 Dow
1,000 cSt
10,000 cSt
Phase B
4. VOC-exempt aliphatic hydrocarbon solvent 38.0 CPChem Soltrol
(isoparaffin) 220 or Exxon
Isopar M
Procedure
Add the Phase A ingredients in the order shown into a mixing vessel. Use a mixing
impeller with adequate turnover flow at the bottom of the container. Rinse the load
lines and any additional containers with the Phase B ingredient while adding it to
the mixing vessel.
XIAMETER™ PMX-0245 Typical properties / additional information

Cyclopentasiloxane is: If the amount of XIAMETER™ PMX-0245 Cyclopentasiloxane is significantly
• VOC-exempt reduced, then wiping the formula after spraying will be necessary.
• Low in toxicity Increasing the ratio of XIAMETER™ PMX-0245 Cyclopentasiloxane to isoparaffin

solvent in the formula will continue to improve the spreading properties.
• Safe on most plastics or metals
Formulation performance review
Results:
• Uniform appearance while drying
• Amount of slippery residue on the ground is two times less than with
formulation TP-770
• Reduced streaks/drips at the tire bottom while drying
• High level of color enhancement and gloss compared to TP-770
pg 81
Spray and wipe low-cost Description

tire dressing This formulation is a “spray and wipe” tire dressing that is California A.R.B.
Formulation reference: TP-770 compliant and low in cost. Wiping after application to the tires is necessary to
improve the uniformity of shine and to prevent residue on the floor. The blend
of XIAMETER™ PMX-200 Silicone Fluid, 1,000 cSt, and XIAMETER™ PMX-200
Silicone Fluid 10,000 cSt gives high shine.

Phase A
1. VOC-exempt aliphatic hydrocarbon 70.0 CPChem Soltrol 220
solvent (isoparaffin) or Exxon Isopar M
1,000 cSt
10,000 cSt
Phase B
4. VOC-exempt aliphatic hydrocarbon 5.0 CPChem Soltrol 220
solvent (isoparaffin) or Exxon Isopar M
Procedure
Place the Phase A ingredients in the order shown into a mixing vessel. Use a
mixing impeller with adequate turnover flow at the bottom of the container.
Rinse the load lines and any additional containers with the Phase B ingredient
while adding it to the mixing vessel.

The VOC-exempt isoparaffin solvent is very slow to dry compared to volatile
methylsiloxane fluids from Dow. Wipe the tire after treatment to avoid dripping
and residue on the floor.
Untreated tire 15 Minutes Formulation performance review

after application
Results:
• Streaky appearance while drying
• Streaks and drips at the tire bottom while drying
• Low level of color enhancement and gloss compared to TP-750 or TP-760
30 Minutes Dried appearance Formula was sprayed on the tire surface with no wiping.
after application
See Auto Care Raw Material Supplier Reference Sheet (Form No. 26-1064) for
the role of the raw material and supplier information.
pg 82
Water-based tire shine Description

Formulation reference: TP-780 The formulation is a water-based tire shine.

1. Water 67.95
7. Sodium benzoate 0.20
8. XIAMETER™ AFE-2210Antifoam Emulsion 0.15 Dow
Procedure
pg 83
Learn more
Whether you need industry-leading innovation or greater cost
efficiency, Dow can help. Solutions by Dow are dedicated
to meeting your needs for specialty materials, collaborative
problem-solving and innovation support. Learn how we can
help you at www.dow.com/autocare.
Disclaimer:
The formulation provided herein is made available by Dow in good faith, by mere liberality, and portrays a combination of ingredients commonly used in the industry, based
on Dow’s experience. Considering that the recipient of it might use such formulation to different applications and in different conditions, being subject to different regulations,
which may differ from one location to another and may change over time, the recipient is responsible for determining whether such formulation is appropriate and applicable
to the recipient’s specific needs. Dow does not guarantee, implicitly or explicitly, that such formulation is correct, adequate, complete or fits any specific use, thus assuming
no obligation or responsibility arising from the use of such formulation by anyone.
The suggested formulation contains a Brazilian genetic resource product, named “carnauba”. Such species is endemic from Brazil and part of the Brazilian genetic heritage
and therefore, the use of it might be under the scope of Law No. 13.123/2015. The recipient of such formulation shall evaluate the applicability of such law to the activities to
be performed using the formulation. The recipient shall be exclusively liable to guarantee its product compliance with applicable access and benefit sharing regulation. Dow
has already complied with applicable law, registering the formulation before SISGEN and does not assume any liability resulting from recipient's failure to comply with any
applicable access and benefit sharing regulation. For further information please contact flarprs@dow.com.
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51-54 – dow_40458042260; Pages 55-57 – dow_40644247778; Pages 58-60 – dow_40234871966; Page 61 – dow_40145816519; Pages 62-65 – dow_40234871966; Pages 66-79 – dow_40697654713;
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NOTICE: No freedom from infringement of any patent owned by Dow or others is to be inferred. Because use conditions and applicable laws may differ from one location to another and may change
with time, Customer is responsible for determining whether products and the information in this document are appropriate for Customer’s use and for ensuring that Customer’s workplace and disposal
practices are in compliance with applicable laws and other government enactments. The product shown in this literature may not be available for sale and/or available in all geographies where Dow is
represented. The claims made may not have been approved for use in all countries. Dow assumes no obligation or liability for the information in this document. References to “Dow” or the “Company”
mean the Dow legal entity selling the products to Customer unless otherwise expressly noted. NO WARRANTIES ARE GIVEN; ALL IMPLIED WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A
PARTICULAR PURPOSE ARE EXPRESSLY EXCLUDED.
®
™ Trademark of The Dow Chemical Company (“Dow”) or an affiliated company of Dow
© 2021 The Dow Chemical Company. All rights reserved.
2000024121 Form No. 26-1655-01-0223 S2D

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AU TO C ARE

Reliable solutions from Dow

• Water repellency 3. Active ingredients

2. Polish types 3.1 Silicones

not been subjected to safety tests, formulators must satisfy

XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0349 Emulsion

XIAMETER™ MEM-5009 Emulsion XIAMETER™ MEM-5009 Emulsion

XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0349 Emulsion

XIAMETER™ MEM-8035 Emulsion

XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0062 Emulsion PS

XIAMETER™ MEM-0349 Emulsion XIAMETER™ MEM-0349 Emulsion

XIAMETER™ MEM-5009 Emulsion

XIAMETER™ MEM-0349 Emulsion

XIAMETER™ MEM-8035 Emulsion

DOWSIL™ HV 496 Emulsion DOWSIL™ HV 496 Emulsion XIAMETER™ MEM-1101 Emulsion

Durability XIAMETER™ OFX-0536 Fluid

Water beading XIAMETER™ PMX-0245

XIAMETER™ PMX-0245 XIAMETER™ PMX-200 Silicone Fluid

DOWSIL™ 2-5088 Wax

XIAMETER™ PMX-200 Silicone Fluid

DOWSIL™ 593 Fluid

XIAMETER™ OFX-0203 Fluid

DOWSIL™ 2-5088 Wax

Global DOWSIL™ HV 496 Emulsion •••• ••••

••• •• • 350‡ 35 Nonionic Yes Yes

••• ••• •• 1,000‡ 60 Slightly Yes Emulsifiers

•••• ••• •• 350‡ 60 Nonionic Yes Yes

••• ••• • 400 50 Nonionic Yes Yes

•••• ••• • OH Functional 60 Nonionic Yes Yes

• ••• •• 100,000‡ 35 Anionic Yes Yes

•• • •••• - 35 Cationic Yes Yes

••• ••• •• - 50 Nonionic Yes Emulsifiers

••• ••• • - 50 Nonionic Yes No

•••• ••• ••• 15 Nonionic Yes Yes Translucent gray

Global DOWSIL™ 2-1912 Fluid

Global DOWSIL™ 3527 Release Agent

•••• 0.78 100

1.6 100 Not tested for comparison ratings

2.5 100 Volatile carrier; CARB4 compliant; not tested

••••• ••••• 5.0 100 Volatile carrier; CARB4 compliant

•••• •• •••• •••• ••••• 50 - 1,000 100

•••• •••• •• • •••• 10,000 - 60,000 100

••••• ••• ••• •• • 160 50

•• ••••• ••• • •• 40 100

• •••• ••• •• •• 500 100

•••• •••• •• • - 100 Melt at 70°C prior to use

2,000 100 Not tested for comparison ratings

• ••••• ••••• • 400 100

200 - 500 100 Not tested for comparison ratings

•• •• •••• •••• ••• 700 100

••• ••• ••• ••• •• 2,000 100

compliant prototype formulations are available from your Time (minutes)

Figure 3: Tire treated with Water-Based Tire Dressing

WHO is impacted by these regulations? New Jersey:

Amadol 511 Non-ionic/Alkanolamide surfactant. Nouryon

DOWSIL™ 5225C A silicone polyether used as an emulsifier. Dow

Heptane A fast-evaporating aliphatic solvent used as a carrier for silicone Univar

KATHON LX A preservative agent. DuPont

Pine oil A wetting and cleaning agent. Various