Gold T1
Gold T1
Gold T1
Found in nature in a comparatively pure form. The history of gold is unequaled by that of any other
metal because of its perceived value from earliest times.
Dense lustrous yellow precious metal of Group 11 (Ib), Period 6, of the periodic table of the
elements.
Gold is one of the densest of all metals. It is a good conductor of heat and electricity. It is also soft
and the most malleable and ductile of the elements; an ounce (31.1 grams; gold is weighed in troy
ounces) can be beaten out to 187 square feet (about 17 square meters) in extremely thin sheets
called gold leaf.
Gold is widespread in low concentrations in all igneous rocks. Its abundance in Earth’s crust is
estimated at about 0.005 part per million. It occurs mostly in the native state, remaining chemically
uncombined except with tellurium, selenium, and bismuth. The element’s only naturally occurring
isotope is gold-197. Gold often occurs in association with copper and lead deposits, and, though
the quantity present is often extremely small, it is readily recovered as a by-product in the refining
of those base metals. Large masses of gold-bearing rock rich enough to be called ores are
unusual. Two types of deposits containing significant amounts of gold are known: hydrothermal
veins, where it is associated with quartz and pyrite (fool’s gold); and placer deposits, both
consolidated and unconsolidated, that are derived from the weathering of gold-bearing rocks.
Because pure gold is too soft to resist prolonged handling, it is usually alloyed with other metals to
increase its hardness for use in jewelry, goldware, or coinage. Most gold used in jewelry is alloyed
with silver, copper, and a little zinc to produce various shades of yellow gold or with nickel, copper,
and zinc to produce white gold. The colour of these gold alloys goes from yellow to white as the
proportion of silver in them increases; more than 70 percent silver results in alloys that are white.
Alloys of gold with silver or copper are used to make gold coins and goldware, and alloys with
platinum or palladium are also used in jewelry. The content of gold alloys is expressed in 24ths,
called karats; a 12-karat gold alloy is 50 percent gold, and 24-karat gold is gold that is more than
99 percent pure.
Because of its high electrical conductivity (71 percent that of copper) and inertness, the largest
industrial use of gold is in the electric and electronics industry for plating contacts, terminals,
printed circuits, and semiconductor systems. Thin films of gold that reflect up to 98 percent of
incident infrared radiation have been employed on satellites to control temperature and on space-
suit visors to afford protection. Used in a similar way on the windows of large office buildings, gold
reduces the air-conditioning requirement and adds to the beauty. Gold has also long been used for
fillings and other repairs to teeth.
Gold is one of the noblest—that is, least chemically reactive—of the transition elements. It is not
attacked by oxygen or sulfur, although it will react readily with halogens or with solutions containing
or generating chlorine, such as aqua regia. It also will dissolve in cyanide solutions in the presence
of air or hydrogen peroxide. Dissolution in cyanide solutions is attributable to the formation of the
very stable dicyanoaurate ion, [Au(CN)2]−.
Like copper, gold has a single s electron outside a completed d shell, but, in spite of the similarity
in electronic structures and ionization energies, there are few close resemblances between gold on
the one hand and copper on the other.