Safety Data Sheet

Date: 11/14/2019
Product Number: 50-0001-01 Revision: B
Product Name: Cleaner, MEK

Based upon Regulation (EC) No 1907/2006, as amended by Regulation (EU) 2015/830

Section 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product Identifier

Product Name: Cleaner, MEK

Product Code: 50-0001-01
1.2 Relevant identified uses of the substance or mixture and uses advised against
Product Use: Printing ink for use in BestCode CIJ
1.3 Details of the supplier of the safety data sheet
BestCode
3034 SE Loop 820
Fort Worth, TX 76140
817-349-8555
For further information, please contact Customer Service:
Customer Service: 817-349-8555
Email: Info@Bestcode.co
1.4 Emergency telephone number
Emergency Contact: Local Poison Information Center
Chem Tel. Inc. Toll Free 800-255-3924
International 813-248-0585

Section 2: Hazards identification

2.1 Classification of the mixture in accordance with Article 40 of Regulation (EC) No 1272/2008
GHS Rating:

Flammable Liquids, Category 2

Serious Eye Damage/Eye Irritation, Category 2
Specific Target Organ Toxicity (single exposure), Category 3
2.2 Label elements

Signal word: Danger

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Product Number: 50-0001-01 Revision: B
Product Name: Cleaner, MEK

Hazard statements:

H225 - Highly flammable liquid and vapor.

H319 - Causes serious eye irritation.
H335 - May cause respiratory irritation.
Precautionary statements:

P233 - Keep container tightly closed.

P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P240 - Ground/bond container and receiving equipment.
P241 - Use explosion-proof electrical/ventilating/lighting/.../ equipment.
P243 - Take precautionary measures against static discharge.
P242 - Use only non-sparking tools.
P264 - Wash hands thoroughly after handling.
P261 - Avoid breathing dust/fume/gas/mist/vapors/spray.
P271 - Use only outdoors or in a well-ventilated area.
P370+378 - In case of fire, use carbon dioxide, dry chemical powder or appropriate foam to extinguish.
P303+361+353 - IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse
skin with water/shower.
P305+351+338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P337+313 - If eye irritation persists, get medical advice/attention.
P304+340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing.
P312 - Call a POISON CENTER/doctor if you feel unwell.
P403+235 - Store in cool/well-ventilated place.
P501 - Dispose of contents/container in accordance with local regulations.
P403+233 - Store container tightly closed in well-ventilated place.
P405 - Store locked up.

2.3 Other Hazards

Adverse Human Health Effects and Symptoms:

Chronic: Chronic inhalation may cause effects similar to those of acute inhalation. Prolonged or
repeated skin contact may cause defatting and dermatitis. Animal studies have reported that fetal
effects/abnormalities may occur when maternal toxicity is seen. hronic overexposure to vapors may
cause lung damage.

Inhalation:
Causes respiratory tract irritation. Inhalation of vapors may cause drowsiness and dizziness. May cause
central nervous system effects such as nausea and headache. Neurobehavioural effects of exposure to
MEK (200 ppm for 4 hrs) were studied with 137 volunteers. There were no statistically significant
effects observed in biochemical, psychomotor, sensorimotor and psychological tests.

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Product Number: 50-0001-01 Revision: B
Product Name: Cleaner, MEK

Skin Contact:
May be absorbed through the skin in harmful amounts. Repeated or prolonged exposure may cause
drying and cracking of the skin. Only one human case of skin sensitization was located. Negative results
were obtained in an animal test; MEK did not produce skin sensitization in the mouse ear thickness
test.

Eye Contact:
Causes eye irritation. Vapors may cause eye irritation. Animal evidence suggests that MEK is a
moderate to severe eye irritant.

Ingestion:
May cause irritation of the digestive tract. Possible aspiration hazard. May cause central nervous
system depression. Animal evidence suggests that MEK can be aspirated (inhaled) into the lungs during
ingestion or vomiting.

Section 3: Composition/information on ingredients

3.1 Substances:

3.2 Mixtures:

CAS # EC # Hazardous components / REACH Concentration GHS Classification

Registration No.
78-93-3 201-159-0 Methyl Ethyl Ketone 60.0 – 100.0% Flam. Liq. 2: H225;
Eye Irrit. 2: H319;
STOT SE 3: H336;
EUH066

Section 4: First Aid Measures

4.1 Description of first aid measures

Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing
is difficult, give oxygen. Get medical aid.

Eyes: In case of contact, immediately flush eyes with plenty of water for a t least 15
minutes. Get medical aid.

Skin: In case of contact, flush skin with plenty of water. Remove contaminated clothing and
shoes. Get medical aid if irritation develops and persists. Wash clothing before reuse.

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Product Number: 50-0001-01 Revision: B
Product Name: Cleaner, MEK

Ingestion: Potential for aspiration if swallowed. Get medical aid immediately. Do not induce
vomiting unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. If vomiting occurs naturally, have victim lean
forward.

4.2 Most Important symptoms and effects, both acute and delayed

Inhalation No Data Available

Eye contact No Data Available
Skin contact No Data Available
Ingestion No Data Available

4.3 Indication of any immediate medical attention and special treatment needed

Notes to doctor: Treat symptomatically and supportively.

Section 5: Fire Fighting Measures

5.1 Extinguishing media

In case of fire, use carbon dioxide, dry chemical powder or appropriate foam. Water may be ineffective
because it will not cool material below its flash point.

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefighters

As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved

or equivalent), and full protective gear. Extremely flammable liquid and vapor. Vapor may cause flash
fire. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can
spread along the ground and collect in low or confined areas.

Section 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

6.1.1 For non-emergency personnel

Evacuate

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Product Name: Cleaner, MEK

6.1.2 For emergency responders

Use proper personal protective equipment as indicated in Section 8.

6.2 Environmental Precautions

Avoid release to the environment.

6.3 Methods and material for containment and cleaning up

6.3.1 For Containment:

Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.

6.3.2 Clean up and disposal of spill:

Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean
up spills immediately, observing precautions in the Protective Equipment section.

Section 7: Handling and storage

7.1 Precautions for safe handling

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Ground and
bond containers when transferring material. Use spark-proof tools and explosion proof equipment.
Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame.
Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or
open flames. Use only with adequate ventilation. Avoid breathing vapor.

7.2 Conditions for safe storage, including any compatibilities

Keep away from sources of ignition. Store in a cool, dry, well-ventilated area away from
incompatible substances. Flammables-area.

7.3 Specific end use(s)

Fluid delivery to BestCode Series 8 CIJ. Follow safety instructions outlined in 7.1 & 7.2 while handling.
Observe warnings provided with BestCode Series 8 CIJ system when installing and handling fluids.

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Product Number: 50-0001-01 Revision: B
Product Name: Cleaner, MEK

Section 8: Exposure control/personal protection

8.1 Control parameters

CAS # Hazardous components ACGIH TLV Australia Austria

78-93-3 Methyl Ethyl Ketone TLV: 200 ppm TWA: 295 mg/m3 TWA: 445 mg/m3
STEL: 300 ppm (100 ppm) (150 ppm)
STEL: 590 mg/m3 STEL: 890 mg/m3
(200 ppm) (300 ppm)

CAS # Hazardous components Belgium OEL California, USA Ontario, CA

78-93-3 Methyl Ethyl Ketone TWA: 600 mg/m3 TWA: 590 mg/m3 TWA: 200 ppm
(200 ppm) (200 ppm) STEL: 300 ppm
STEL: 900 mg/m3 STEL: 885 mg/m3
(300 ppm) (300 ppm)

CAS # Hazardous components China Québec, CA German AGS

78-93-3 Methyl Ethyl Ketone TWA: 300 mg/m3 TWA: 150 mg/m3 TWA: 600 mg/m3
STEL: 600 mg/m3 (50 ppm) (200 ppm)
(15 min) STEL: 300 mg/m3 STEL: 600 mg/m3
(100 ppm) (200 ppm) (15 min)

CAS # Hazardous components Germany MAK/TRK Denmark OEL Spain OEL

78-93-3 Methyl Ethyl Ketone TWA: 295 mg/m3 TWA: 145 mg/m3 TWA: 600 mg/m3
(100 ppm) (50 ppm) (200 ppm)
STEL: 600 mg/m3 STEL: 290 mg/m3 STEL: 900 mg/m3
(200 ppm) (30min) (100 ppm) (300 ppm)
(4x)

CAS # Hazardous components Europe Finland OEL France VL

78-93-3 Methyl Ethyl Ketone TWA: 600 mg/m3 STEL: 300 mg/m3 TWA: 600 mg/m3
(200 ppm) (100 ppm) (15 min) (200 ppm)
STEL: 900 mg/m3 STEL: 900 mg/m3
(300 ppm) (300 ppm)

CAS # Hazardous components Hungary OEL Ireland OEL Italy OEL

78-93-3 Methyl Ethyl Ketone TWA: 600 mg/m3 TWA: 600 mg/m3 TWA: 600 mg/m3
STEL: 900 mg/m3 (200 ppm) (200 ppm)
STEL: 900 mg/m3 STEL: 900 mg/m3
(300 ppm) (15 min) (300 ppm)

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Product Number: 50-0001-01 Revision: B
Product Name: Cleaner, MEK

CAS # Hazardous components South Korea Latvia OEL Mexico OEL

78-93-3 Methyl Ethyl Ketone TWA: 590 mg/m3 TWA: 200 mg/m3 TWA: 590 mg/m3
(200 ppm) (67 ppm) (200 ppm)
STEL: 885 mg/m3 STEL: 900 mg/m3 STEL: 885 mg/m3
(300 ppm) (300 ppm) (15 min) (300 ppm)

CAS # Hazardous components Malaysia OEL NIOSH Netherlands OEL

78-93-3 Methyl Ethyl Ketone TWA: 590 mg/m3 TWA: 200 ppm TWA: 590 mg/m3
(200 ppm) STEL: 300 ppm STEL: 900 mg/m3

CAS # Hazardous components New Zealand OSHA PELs Poland

78-93-3 Methyl Ethyl Ketone TWA: 445 mg/m3 PEL: 200 ppm TWA: 450 mg/m3
(150 ppm) STEL: 900 mg/m3
STEL: 890 mg/m3
(300 ppm)

CAS # Hazardous components Sweden OEL Singapore Britain EH40

78-93-3 Methyl Ethyl Ketone TWA: 150 mg/m3 TWA: 590 mg/m3 TWA: 600 mg/m3
(50 ppm) (200 ppm) (200 ppm)
STEL: 300 mg/m3 STEL: 885 mg/m3 STEL: 899 mg/m3
(100 ppm) (15 min) (300 ppm) (300 ppm)

CAS # Hazardous components Switzerland OEL Japan OEL

78-93-3 Methyl Ethyl Ketone

8.2 Exposure controls:

8.2.1 Appropriate engineering controls:

Facilities storing or utilizing this material should be equipped with an eyewash facility and
a safety shower. Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits. Ventilation fans and other electrical
service must be non-sparking and have an explosion-proof design.

8.2.2 Individual protection measures, such as personal protective equipment

Wear appropriate protective clothing to prevent skin exposure. Choose body protection according to the
amount and concentration of the dangerous substance at the work place.

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Product Number: 50-0001-01 Revision: B
Product Name: Cleaner, MEK

Eye/Face protection: Wear chemical splash goggles.

Skin protection: Wear appropriate protective gloves to prevent skin exposure.

Respiratory protection: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or
European Standard EN 149. Use a NIOSH/MSHA or European Standard
EN 149 approved respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.

Hygienic Practices: DO NOT SMOKE IN WORK AREA! Promptly remove contaminated

clothing. Wash immediately if skin becomes contaminated. Do not eat
or drink in work area while using this product. Wash thoroughly at the
end of the workday, before eating and using the restroom.

Section 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Appearance: Clear Liquid (Upon aging, clear or colorless fluids may develop a slight yellow tint
which will not affect the product performance).
Odor: Solvent Odor threshold: No data available
pH: No data available Melting point: -87.00C
Boiling range: 80.00 C Flash point: -7°C
Evaporation rate: 5.8 (BuAC=1) Upper Explosive Limit:
Lower Explosive Limit:
Flammability: No data available Vapor Pressure: ~ 94.5 MM_HG at 20.0 C
Vapor density: > Air Relative Density: -0.805
Solubility(ies): Miscible Partition coefficient No data available
n-octanol/water:
Auto-ignition 404.00 C Decomposition No data available
temperature: temperature:
Viscosity: No data available
Explosive properties: > 99.999% Volatile by volume.
Oxidizing properties: No data available
9.2 Other information:

Miscibility: No data available VOC: No data available

Section 10: Stability and reactivity

10.1 Reactivity

No data available.

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Date: 11/14/2019
Product Number: 50-0001-01 Revision: B
Product Name: Cleaner, MEK

10.2 Chemical stability

Stable under normal conditions.

10.3 Possibility of hazardous reactions

Will not occur

10.4 Conditions to avoid:

Ignition sources, Excess heat.

10.5 Incompatible materials:

Strong oxidizing agents, Strong acids, 2-propanol

10.6 Hazardous decomposition products

Carbon monoxide, Carbon dioxide.

Section 11: Toxicological information

11.1 Information on Toxicological effects

Acute toxicity: Acute toxicity, LD50, Intraperitoneal, Mouse, 616.0 MG/KG.

Result:
Lungs, Thorax, or Respiration: Sputum.
Biochemical: Metabolism (Intermediary): Other proteins.
Biochemical: Metabolism (intermediary): Effect on inflammation or mediation
of inflammation.

- Shell Chemical Company. Unpublished Report., Vol/p/yr: -,6, 1961

Acute toxicity, LD50, Skin, Species: Rabbit, 6480. MG/KG.

Result:
Lungs, Thorax, or Respiration: Other changes.
Biochemical: Metabolism (intermediary): Effect on inflammation or mediation
of inflammation.

- Shell Chemical Company., Vol/p/yr: MSDS-5390-,

Acute toxicity, LC50, Inhalation, Mouse, 32.00 MG/M3.
Result:
Brain and Coverings: Other degenerative changes.
Biochemical: Metabolism (intermediary): Effect on inflammation or mediation
of inflammation.

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Product Number: 50-0001-01 Revision: B
Product Name: Cleaner, MEK

Acute toxicity, LD50, Intraperitoneal, Species: Guinea pig, 2.000 GM/KG.

Result:
Immunological Including Allergic: Increase in humoral immune response.

Skin No data available

corrosion/irritation:
Serious eye No data available
damage/irritation:
Respiratory or skin No data available
sensitization:
Germ cell Mutagenic effects have occurred in experimental animals.
mutagenicity:
Carcinogenicity: CAS# 78-93-3: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Reproductive toxicity: No data available

STOT-single exposure: No data available
STOT-repeated No data available
exposure:
Aspiration hazard No data available

11.1.1 Hazard Class information:

No data available
11.1.2 Mixture toxicity:

No data available
11.1.3 Critical studies:

No data available
11.1.4 Non-compliance hazard class:

No data available
11.1.5 Information on likely routes of exposure:

No data available
11.1.6 Symptoms related to the physical, chemical and toxicological characteristics:

No data available
11.1.7 Delayed and immediate effects as well as chronic effects from short and long-term exposure:

No data available
11.1.8 Interactive effects:

No data available
11.1.9 Absence of specific data:

No data available

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Product Name: Cleaner, MEK

11.1.10 Mixtures:

No data available
11.1.11 Mixture vs Substance information:

No data available
11.1.12 Other information:

No data available

Section 12: Ecological information

12.1 Toxicity:

Environmental: Substance evaporates in water with T1/2= 3D (rivers) to 12D (lakes). Substance is not
expected to bioconcentrate in marine life. Physical: Substance photodegrades in air with T1/2 = 2.3
days. Oxidizes rapidly by photo-chemical reactions in air. Readily biodegradable meeting the 10 day
window criterion. Not expected to bioaccumulate significantly.

12.2 Persistence and degradability:

No data available

12.3 Bioaccumulative potential:

No data available
12.4 Mobility in soil:

No data available
12.5 Results of PBT and vPvB assessment:

No data available
12.6 Other adverse effects:

No data available

Section 13: Disposal considerations

13.1 Waste treatment methods:

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous
waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.
Additionally, waste generators must consult state and local hazardous waste regulations to ensure
complete and accurate classification.

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Product Name: Cleaner, MEK

RCRA P-Series: None listed.

RCRA U-Series:

Waste number U159 (Ignitable waste, Toxic waste).

Section 14: Transport information

14.1 UN number: 1210
14.2 Proper shipping name:
US DOT: Printing Ink Related Material
Canadian TDG: Printing ink, [flammable or] Printing ink related material
[(including printing ink thinning or reducing compound),
flammable]
European ADR/RID: Printing ink, [flammable or] Printing ink related material
[(including printing ink thinning or reducing compound),
flammable]
IMDG/IMO: Printing ink, [flammable or] Printing ink related material
[(including printing ink thinning or reducing compound),
flammable]
ICAO/IATA: Printing ink, [flammable or] Printing ink related material
[(including printing ink thinning or reducing compound),
flammable]

14.3 Transport hazard class(es) : 3 - FLAMMABLE LIQUID

14.4 Packing group: II
14.5 Environmental hazards: N/A
14.6 Special precautions for user: N/A
14.7 Transport in bulk according to Annex II of Marpol and the IBC Code:
N/A

Section 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:

EPA SARA (Superfund Amendments and Reauthorization Act of 1986) Lists

CAS # Hazardous components S. 302 (EHS) S. 304 RQ S. 313 (TRI)
78-93-3 Methyl Ethyl Ketone No Yes 5000LB No

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CAS # Hazardous components Canadian NPRI Canadian Canadian DSL

Toxic
78-93-3 Methyl Ethyl Ketone Yes No Yes

CAS # Hazardous components CAA HAP, ODC CWA NPDES TSCA

78-93-3 Methyl Ethyl Ketone No No Yes - Inv

CAS # Hazardous components CA Prop 65 Mexico Australia ICS

INSQ
78-93-3 Methyl Ethyl Ketone No Yes - 1193 Listed

CAS # Hazardous components New Zealand China IECSC Japan ENCS

IOC
78-93-3 Methyl Ethyl Ketone Listed Listed Yes - 2-542

CAS # Hazardous components Japan ISHL Korea ECL Philippines

78-93-3 Methyl Ethyl Ketone Listed Yes KE-24094 Listed

CAS # Hazardous components Taiwan TCSCA Singapore Israel HSL:

HSL
78-93-3 Methyl Ethyl Ketone Listed No No

CAS # Hazardous components Germany Switzerland Switzerland

WHCS Giftliste 1 INNS
78-93-3 Methyl Ethyl Ketone Yes – 150 Yes G-2429 No

CAS # Hazardous components REACH Kyoto GHG Rotterdam

78-93-3 Methyl Ethyl Ketone Yes - (R), (P) No No

CAS # Hazardous components Stockholm

78-93-3 Methyl Ethyl Ketone No

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Date: 11/14/2019
Product Number: 50-0001-01 Revision: B
Product Name: Cleaner, MEK

Canadian WHMIS Classification:

CLASS B, DIVISION 2: Flammable Liquids

CLASS D, DIVISION 2, SUBDIVISION B: Toxic Materials (Mutagenicity, skin sensitization, irritation, etc.)

15.2 Chemical safety assessment

Section 16: Other information

Revision Date: 11/14/19
Revision Notes: Format updated to (EU) 2015/830.
Additional Information:

Company Disclaimer:
The information and recommendations contained herein are, to the best of BestCode's knowledge and belief,
accurate and reliable as of the date issued. Because many factors may affect processing or application/use,
BestCode recommend that you make tests to determine the suitability of a product for your particular purpose
prior to use. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If
buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary
information is included with and/or on the container. Appropriate warnings and safe-handling procedures
should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent
required by law, re-publication or retransmission of this document, in whole or in part, is not-permitted. In no
case shall the descriptions, information, data or designs provided be considered a part of our terms and
conditions of sale. Further, you expressly understand and agree that the descriptions, designs, date and
information furnished by BestCode hereunder are given gratis and BestCode assumes no obligation or liability
for the description, designs, data and information given or results obtained. All such being given and accepted
at your risk.

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