Safety Data Sheet

DuPont™ Canopy® Herbicide

Version 3.0

Issue Date : 03/18/2019 Ref. 130000028928

Revision Date : 02/11/2019

This SDS adheres to the standards and regulatory requirements of the United States and may not meet the regulatory
requirements in other countries.

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : DuPont™ Canopy® Herbicide

Tradename/Synonym : CANOPY 75DF
DPX-L8347
METRIBUZIN: 4-Amino-6-(1,1-dimethylethyl)-3-(methylthio)-1,2,4-triazin-
5(4H)-one
CHLORIMURON ETHYL: Ethyl 2-[[[[(4-chloro-6-methoxypyrimidin-2-
yl)amino]carbonyl]amino]sulfonyl]benzoate

Product Use : Herbicide

Restrictions on use : Do not use product for anything outside of the above specified uses.

Manufacturer/Supplier : DuPont
974 Centre Road
Wilmington, DE 19805, USA

Product Information : 1-800-441-7515 (outside the U.S. 1-302-774-1000)

Medical Emergency : 1-800-441-3637 (outside the U.S. 1-302-774-1139)
Transport Emergency : +1-800-424-9300 (outside the U.S. +1-703-527-3887)

SECTION 2. HAZARDS IDENTIFICATION

Product hazard category

Acute toxicity (Oral) Category 4
Skin irritation Category 2
Serious eye damage/eye irritation Category 2B
Specific target organ toxicity - Category 3
single exposure

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Safety Data Sheet

DuPont™ Canopy® Herbicide

Version 3.0

Issue Date : 03/18/2019 Ref. 130000028928

Revision Date : 02/11/2019

Label content
Pictogram :

Signal word : Warning

Hazardous warnings : Harmful if swallowed.

Causes skin and eye irritation.
May cause respiratory irritation.
May cause drowsiness or dizziness.

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Safety Data Sheet

DuPont™ Canopy® Herbicide

Version 3.0

Issue Date : 03/18/2019 Ref. 130000028928

Revision Date : 02/11/2019

Hazardous prevention : Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
measures Wash skin thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
Wear protective gloves.
IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
IF ON SKIN: Wash with plenty of soap and water.
IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
Call a POISON CENTER/doctor if you feel unwell.
Rinse mouth.
If skin irritation occurs: Get medical advice/ attention.
If eye irritation persists: Get medical advice/ attention.
Take off contaminated clothing and wash before reuse.
Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
Dispose of contents/ container to an approved waste disposal plant.

Other hazards
Information presented in Section 2 conforms to the requirements of the Occupational Safety and Health
Administration (OSHA) Hazard Communication Standard of 2012. See Section 15 for applicable information
conforming to the requirements of the Federal Insecticide Fungicide and Rodenticide Act (FIFRA), as required by
the US Environmental Protection Agency (EPA), or by state Regulatory Agencies.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component CAS-No. Concentration

Metribuzin 21087-64-9 64.3 %

Chlorimuron ethyl 90982-32-4 10.7 %

Other Ingredients 25 %

SECTION 4. FIRST AID MEASURES

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Safety Data Sheet

DuPont™ Canopy® Herbicide

Version 3.0

Issue Date : 03/18/2019 Ref. 130000028928

Revision Date : 02/11/2019

General advice : Have the product container or label with you when calling a poison control
center or doctor, or going for treatment.
For medical emergencies involving this product, call toll free 1-800-441-3637.
See Label for Additional Precautions and Directions for Use.
Information presented in Section 4 conforms to the requirements of the
Occupational Safety and Health Administration (OSHA) Hazard Communication
Standard of 2012. See Section 15 for applicable information conforming to the
requirements of the Federal Insecticide Fungicide and Rodenticide Act (FIFRA),
as required by the US Environmental Protection Agency (EPA), or by state
Regulatory Agencies.

Inhalation : Move to fresh air. If person is not breathing, call 911 or an ambulance, then
give artificial respiration, preferably mouth-to-mouth, if possible. Call a poison
control center or doctor for treatment advice.

Skin contact : Take off all contaminated clothing immediately. Rinse skin immediately with
plenty of water for 15-20 minutes. Call a poison control center or doctor for
treatment advice.

Eye contact : Hold eye open and rinse slowly and gently with water for 15-20 minutes.
Remove contact lenses, if present, after the first 5 minutes, then continue
rinsing eye. Call a poison control center or doctor for treatment advice.

Ingestion : Call a poison control center or doctor for treatment advice. Have person sip a
glass of water if able to swallow. DO NOT induce vomiting unless directed to do
so by a physician or poison control center.

Most important : No applicable data available.

symptoms/effects, acute
and delayed
Protection of first-aiders : No applicable data available.
Notes to physician : No applicable data available.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Water spray, Foam, Dry chemical, Carbon dioxide (CO2)

Unsuitable extinguishing : High volume water jet, (contamination risk)

media

Specific hazards : Not a fire or explosion hazard. Under severe dusting conditions, this material
may form explosive mixtures in air.
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Safety Data Sheet

DuPont™ Canopy® Herbicide

Version 3.0

Issue Date : 03/18/2019 Ref. 130000028928

Revision Date : 02/11/2019

Special protective equipment : Wear full protective clothing and self-contained breathing apparatus.
for firefighters

Further information : Evacuate personnel and keep upwind of fire. Runoff from fire control may be
a pollution hazard. Control Runoff.
(on small fires) If area is heavily exposed to fire and if conditions permit, let
fire burn itself out since water may increase the area contaminated. Cool
containers/tanks with water spray.

SECTION 6. ACCIDENTAL RELEASE MEASURES

NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with clean-up.
Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up.

Safeguards (Personnel) : Evacuate personnel, thoroughly ventilate area, use self-contained breathing
apparatus. Use personal protective equipment.

Environmental precautions : Prevent material from entering sewers, waterways, or low areas.

Spill Cleanup : Dike spill. Sweep up and shovel into suitable containers for disposal. If spill
area is on ground near valuable plants or trees, remove top 2 inches of soil
after initial cleanup.

Accidental Release Measures : Never return spills in original containers for re-use. Dispose of in accordance
with local regulations.
Follow applicable Federal, State/Provincial and Local laws/regulations.

SECTION 7. HANDLING AND STORAGE

Handling (Personnel) : Wash hands thoroughly with soap and water after handling and before eating,
drinking, chewing gum, using tobacco, or using the toilet. Remove
clothing/PPE immediately if material gets inside. Wash thoroughly and put on
clean clothing. Remove personal protective equipment immediately after
handling this product. Wash the outside of gloves before removing. As soon
as possible, wash thoroughly and change into clean clothing.

Handling (Physical Aspects) : Keep away from heat and sources of ignition.
Avoid dust formation.
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Safety Data Sheet

DuPont™ Canopy® Herbicide

Version 3.0

Issue Date : 03/18/2019 Ref. 130000028928

Revision Date : 02/11/2019

Dust explosion class : No applicable data available.

Storage : Store in original container. Do not contaminate water, other pesticides,
fertilizer, food or feed in storage. Store in a cool, dry place. Keep out of the
reach of children.

Storage period : No applicable data available.

Storage temperature : No applicable data available.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering controls : Use only with adequate ventilation. When handlers use closed systems,
enclosed cabs, or aircraft in a manner that meets the requirements listed in
the Worker Protection Standard (WPS) for agricultural pesticides [40 CFR
170.240 (d)(4-6)], the handler PPE requirements may be reduced or modified
as specified in the WPS. IMPORTANT: When reduced PPE is worn because
a closed system is being used, handlers must be provided all PPE specified
for "Applicators and Other Handlers" and have such PPE immediately
available for use in an emergency, such as a spill or equipment breakdown.
Information presented in Section 8 conforms to the requirements of the
Occupational Safety and Health Administration (OSHA) Hazard
Communication Standard of 2012. See Section 15 for applicable information
conforming to the requirements of the Federal Insecticide Fungicide and
Rodenticide Act (FIFRA), as required by the US Environmental Protection
Agency (EPA), or by state Regulatory Agencies.

Personal protective equipment

Skin and body protection : Applicators and other handlers must wear:
Long sleeved shirt and long pants
Chemical resistant gloves made of any waterproof material, such as
polyethylene or polyvinyl chloride.
Shoes plus socks
PPE required for early entry to treated areas that is permitted under the
Worker Protection Standard and that involves contact with anything that has
been treated, such as plants, soil, or water, is:
Coveralls
Chemical resistant gloves made of any waterproof material, such as
polyethylene or polyvinyl chloride.
Shoes plus socks

Protective measures : Discard clothing and other absorbent materials that have been drenched or
heavily contaminated with this product. Do not reuse them. Follow
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Safety Data Sheet

DuPont™ Canopy® Herbicide

Version 3.0

Issue Date : 03/18/2019 Ref. 130000028928

Revision Date : 02/11/2019

manufacturer's instructions for cleaning/maintaining PPE. If no such

instructions for washables exist, use detergent and hot water. Keep and
wash PPE separately from other laundry.

Exposure Guidelines
Exposure Limit Values
Metribuzin
TLV (ACGIH) 5 mg/m3 TWA
REL (NIOSH) 5 mg/m3 Time-weighted average concentration
for up to a 10-hour workday during a
40-hour workweek
PEL (Permissible (OSHA) 5 mg/m3 TWA
Exposure Limit)
AEL * (DuPont) 5 mg/m3 8 & 12 hr. TWA

Chlorimuron ethyl
AEL * (DuPont) 10 mg/m3 8 & 12 hr. TWA
AEL * (DuPont) 5 mg/m3 8 & 12 hr. TWA

* AEL is DuPont's Acceptable Exposure Limit. Where governmentally imposed occupational exposure limits which are
lower than the AEL are in effect, such limits shall take precedence.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance
Physical state : solid
Form : solid, granules
Color : brown

Odor : slight

Odor threshold : No applicable data available.

pH : 7 - 7.6

Melting point/range : No applicable data available.

Boiling point/boiling range : No applicable data available.

Flash point : No applicable data available.

Evaporation rate : No applicable data available.

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Safety Data Sheet

DuPont™ Canopy® Herbicide

Version 3.0

Issue Date : 03/18/2019 Ref. 130000028928

Revision Date : 02/11/2019

Flammability (solid, gas) : No applicable data available.

Upper explosion limit : No applicable data available.

Lower explosion limit : No applicable data available.

Vapour Pressure : No applicable data available.

Vapour density : No applicable data available.

Specific gravity (Relative : No applicable data available.

density)

Water solubility : dispersible

Solubility(ies) : No applicable data available.

Partition coefficient: n- : No applicable data available.

octanol/water

Auto-ignition temperature : No applicable data available.

Decomposition temperature : No applicable data available.

Viscosity, kinematic : No applicable data available.

Viscosity, dynamic : No applicable data available.

SECTION 10. STABILITY AND REACTIVITY

Reactivity : No applicable data available.

Chemical stability : Stable under recommended storage conditions.

Possibility of hazardous : Polymerization will not occur.

reactions
Conditions to avoid : No applicable data available.
Incompatible materials : None reasonably foreseeable.

Hazardous decomposition : Decomposition will not occur.

products

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Safety Data Sheet

DuPont™ Canopy® Herbicide

Version 3.0

Issue Date : 03/18/2019 Ref. 130000028928

Revision Date : 02/11/2019

SECTION 11. TOXICOLOGICAL INFORMATION

DuPont™ Canopy® Herbicide

Inhalation 4 h LC50 : > 5.3 mg/l , Rat

Dermal LD50 : > 5,000 mg/kg , Rat

Skin irritation : Skin irritation, Rabbit

Eye irritation : Mild eye irritation, Rabbit

Sensitisation : Did not cause sensitisation on laboratory animals., Guinea pig

Further information : Information presented in this Section conforms to the requirements of

the Occupational Safety and Health Administration (OSHA) Hazard
Communication Standard of 2012. See Section 15 for applicable
information conforming to the requirements of the Federal Insecticide
Fungicide and Rodenticide Act (FIFRA), as required by the US
Environmental Protection Agency (EPA), or by state Regulatory
Agencies.
Metribuzin
Oral LD50 : 1,030 mg/kg , Rat
Target Organs: Central nervous system
Central nervous system effects

Repeated dose toxicity : Inhalation

Rat
- 21 d
dust/mist
NOAEL: 0.72 mg/l
LOAEL: > 0.72 mg/l
No toxicologically significant effects were found.

Carcinogenicity : Not classifiable as a human carcinogen.

Animal testing did not show any carcinogenic effects.

Mutagenicity : Animal testing did not show any mutagenic effects.

Did not cause genetic damage in cultured bacterial cells.
Genetic damage in cultured mammalian cells was observed in some
laboratory tests but not in others.

Reproductive toxicity : No toxicity to reproduction

No effects on or via lactation
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Safety Data Sheet

DuPont™ Canopy® Herbicide

Version 3.0

Issue Date : 03/18/2019 Ref. 130000028928

Revision Date : 02/11/2019

Animal testing showed no reproductive toxicity.

Teratogenicity : Animal testing showed effects on embryo-fetal development at levels

equal to or above those causing maternal toxicity.

Chlorimuron ethyl
Oral LD50 : 4,102 mg/kg , Rat

Repeated dose toxicity :

The following effects occurred at levels of exposure that significantly
exceed those expected under labeled usage conditions.

Dermal
Rabbit
-
No toxicologically significant effects were found.

Oral
Dog
-
No toxicological effects warranting significant target organ toxicity
classification were seen below the recommended guidance values for
classification., Abnormal decrease in number of red blood cells

Oral
Rat
-
No adverse effect has been observed in chronic toxicity tests.

Carcinogenicity : Not classifiable as a human carcinogen.

Animal testing did not show any carcinogenic effects.

Mutagenicity : Tests on bacterial or mammalian cell cultures did not show mutagenic
effects.
Animal testing did not show any mutagenic effects.

Reproductive toxicity : No toxicity to reproduction

Teratogenicity : Animal testing showed effects on embryo-fetal development at levels

equal to or above those causing maternal toxicity.

Carcinogenicity
The carcinogenicity classifications for this product and/or its ingredients have been determined according to
HazCom 2012, Appendix A.6. The classifications may differ from those listed in the National Toxicology
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Safety Data Sheet

DuPont™ Canopy® Herbicide

Version 3.0

Issue Date : 03/18/2019 Ref. 130000028928

Revision Date : 02/11/2019

Program (NTP) Report on Carcinogens (latest edition) or those found to be a potential carcinogen in the
International Agency for Research on Cancer (IARC) Monographs (latest edition).

Material IARC NTP OSHA

Titanium dioxide 2B

SECTION 12. ECOLOGICAL INFORMATION

Aquatic Toxicity
Metribuzin
96 h LC50 : Oncorhynchus mykiss (rainbow trout) 74.6 mg/l

72 h EC50 : Desmodesmus subspicatus (green algae) 0.022 mg/l

48 h EC50 : Daphnia magna (Water flea) 98.5 mg/l

21 d : NOEC Oncorhynchus mykiss (rainbow trout) 5.6 mg/l

21 d : NOEC Daphnia magna (Water flea) 0.32 mg/l

Chlorimuron ethyl
96 h LC50 : Oncorhynchus mykiss (rainbow trout) > 1,000 mg/l

96 h LC50 : Lepomis macrochirus (Bluegill sunfish) > 100 mg/l

72 h EC50 : Pseudokirchneriella subcapitata (green algae) 0.001 mg/l

48 h EC50 : Daphnia magna (Water flea) > 1,000 mg/l

Additional ecological information : Environmental Hazards: Do not apply directly to water, or to areas
where surface water is present, or to intertidal areas below the mean
high water mark. Do not apply where/when conditions favour runoff.
Do not contaminate water when cleaning equipment or disposing of
equipment washwaters or rinsate.

SECTION 13. DISPOSAL CONSIDERATIONS

Waste disposal methods - : Do not contaminate water, food or feed by disposal. Wastes resulting from the
Product use of this product must be disposed of on site or at an approved waste
disposal facility.

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Safety Data Sheet

DuPont™ Canopy® Herbicide

Version 3.0

Issue Date : 03/18/2019 Ref. 130000028928

Revision Date : 02/11/2019

Waste disposal methods - : Container Refilling and Disposal:

Container Refer to the product label for instructions.

In the event of a major spill, fire or other emergency, call 1-800-441-3637 day
or night.

Contaminated packaging : No applicable data available.

SECTION 14. TRANSPORT INFORMATION

IATA_C UN number : 3077

Proper shipping name : Environmentally hazardous substance, solid, n.o.s.
(Chlorimuron ethyl)
Class : 9
Packing group : III
Labelling No. : 9
IMDG UN number : 3077
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
SOLID, N.O.S. (Chlorimuron ethyl)
Class : 9
Packing group : III
Labelling No. : 9

Marine pollutant : yes (Chlorimuron ethyl)

Not regulated as a hazardous material by DOT.

SECTION 15. REGULATORY INFORMATION

Other regulations : This Safety Data Sheet is for a pesticide product registered by the US
Environmental Protection Agency (USEPA) and various state regulatory
agencies, and is therefore also subject to certain requirements under US and
state pesticide laws, including the Federal Insecticide Fungicide and
Rodenticide Act (FIFRA). These requirements differ from the classification
criteria and hazard information required by OSHA for safety data sheets, and
for workplace labels of non-pesticide chemicals. The following is information
determined by USEPA, and various states.

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Safety Data Sheet

DuPont™ Canopy® Herbicide

Version 3.0

Issue Date : 03/18/2019 Ref. 130000028928

Revision Date : 02/11/2019

CAUTION!

Harmful if swallowed, inhaled or absorbed through skin. Causes moderate

eye irritation. Avoid breathing dust. Avoid breathing vapours or mist. Avoid
contact with skin, eyes and clothing.

SARA 311/312 Hazard : Acute toxicity (any route of exposure)

classification Skin corrosion or irritation
Serious eye damage or eye irritation
Specific target organ toxicity (single or repeated exposure)

SARA 313 Regulated : The following components are subject to reporting levels established by
Chemical(s) SARA Title III, Section 313: Metribuzin, Chlorimuron ethyl

PA Right to Know : Substances on the Pennsylvania Hazardous Substances List present at a

Regulated Chemical(s) concentration of 1% or more (0.01% for Special Hazardous Substances):
Metribuzin, Kaolin

CERCLA Reportable : This material does not contain any components with a CERCLA RQ.
Quantity

SARA Reportable Quantity : This material does not contain any components with a SARA 302 RQ.

EPA Reg. No. : 352-444

In the United States this product is regulated by the US Environmental
Protection Agency (EPA) under the Federal Insecticide, Fungicide and
Rodenticide Act (FIFRA). It is a violation of Federal law to use this product in
a manner inconsistent with its labeling. Read and follow all label directions.
This product is excluded from listing requirements under EPA/TSCA.

California Prop. 65 : This product can expose you to substances including Titanium dioxide, which
is/are known to the State of California to cause cancer. For more information
go to www.P65Warnings.ca.gov.

SECTION 16. OTHER INFORMATION

NFPA
Health : 1
Flammability : 1
Reactivity/Physical hazard : 0
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Safety Data Sheet

DuPont™ Canopy® Herbicide

Version 3.0

Issue Date : 03/18/2019 Ref. 130000028928

Revision Date : 02/11/2019

™ Trademark of E.I. du Pont de Nemours and Company.

® Registered trademark of E.I. du Pont de Nemours and Company

Issue Date : 03/18/2019

Revision Date : 02/11/2019

Contact person : DuPont Crop Protection, Wilmington, DE, 19805, Phone: 1-888-638-7668

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any
other materials or in any process, unless specified in the text.

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