MSDS-080039-1 MGG NKPL-2 HP9

Section 1 - Chemical Product and Company Identification
Product/Chemical Name :Seatbelt Assy/Micro Gas Generator Type NKPL-2

Chemical Formula :N/A
CAS Number :N/A
Other Designations :Belt pretensioner
General Use :Gas Generant for Automotive Safety Systems
Manufacturer :Ashimori Industry Co ., Ltd,
Automotive Safety Systems Company
Address :7-11-61 Senrioka Settsu-City Osaka, Japan 566-0001
Phone : +81-6-6380-7651, Fax: +81-6-6387-3561
Section 2 - Hazards Identification

EXLOSIVE :
Electrically and flame sensitive article. Sensitive to, including but not limited, AC, DC and ESD. Upon ignition the articles emit a sharp crack
and release high temperature gases and fragments.
Section 3 - Composition / Information on Ingredients

*1)
1.Squib Charge CAS NO. CAS NO.
Primary Charge Type 1 Primary Charge Type 2 7440-67-7

Zirconium 7440-67-7 Zirconium 12158-75-7
Lead Styphnate 15245-44-0 Basic Copper(Ⅱ) Nitrate 7778-74-7
Potassium Perchlorate 7778-74-7 Potassium Perchlorate 7429-90-5
Total Weight 21 mg or less Aluminum
Total Weight 21 mg or less
*1)
Either Type 1 or Type 2 is used as both Primary charge Secondary charge
Secondary Charge Type 1 Secondary Charge Type 2

Potassium Perchlorate 7778-74-7 Titanium Hydride
Sodium Picramate 831-52-7 Potassium Perchlorate
Antimony Trisulfide 1345-04-6 Total Weight 85 mg or less 7704-98-5
Total Weight 85 mg or less 7778-74-7
*1)Either Type 1 or Type 2 is used as both Primary charge Secondary charge
2.Gas Generant (Smokeless Powder)*2)

Type 1 Type 2
Nitrocellulose 9004-70-0 Nitrocellulose 9004-70-0
Diphenylamine 122-39-4 Diphenylamine 122-39-4
Potassium Sulfate 7778-80-5 Potassium Sulfate 7778-80-5
Total Weight 1300 mg or less Methyl Diphenylurea (Akardite Ⅱ) 13114-72-2
Total Weight 1300 mg or less
*2)Either Type 1 or Type 2 is used as Gas Generant
Section 4 - First Aid Measures

In case of accidental ignition treat for burns and shock. In case of burns, immediately cool the affected area for as long as necessary
with cold water. Seek immediate medical help.
INHALATION :
Remove to fresh air and see a medical doctor. Give oxygen or artificial respiration if needed.
SKIN CONTACT :
Wash with soap and water. Contact a medical doctor.
EYE CONTACT :
Flush immediately with running water for at least 15 minutes. And see a medical doctor.
INGESTION :
See immediately a medical doctor.
Page 1of 4
Micro Gas Generator Type NKPL-2
Section 5 - Fire-Fighting Measures

Burning Rate :The article burns up in milliseconds
Autoignition Temperature : 200 °C (DSC), 170 °C (Krupp method)
Fire-Fighting Instructions :
In the event of fire evacuate the immediate area. Burning of large quantities may accelerate to explosion! Inform the emergency
services of the nature of the product.
Section 6 - Accidental Release Measures

Spill /Leak Procedures :
In the event of spillage, the area should be immediately cordoned off to prevent damage to the gas generants. They may be
recovered by hand and should be inspected for signs of damage prior to re-packing. Suspect or damaged Micro Gas Generator
should be labeled and consigned for appropriate destruction.
Section 7 - Handling and Storage

Operation conditions :
Handle with care and avoid any accidental initiation by stray electric currents, electrostatic discharge, flame or other severe
treatment (see Conditions to Avoid). Keep safety requirements.
Storage Requirements :
Store in approved magazines only. Storage and handling must conform to appropriate statutory and legislation laws and
requirements. Store in dry conditions, at common temperatures.
Section 8 - Exposure Controls / Personal Protection

Respiratory Protection :N/A
Protective Clothing/Equipment :
Conductive floor. Wear clothes made of cotton fabrics, safety glasses (goggles), conductive shoes and grounded wristband.
Comments :
Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material, especially before eating,
drinking, smoking, using the toilet, or applying cosmetics.
Section 9 - Physical and Chemical Properties

Appearance :specific sealed unit Odour :no odour at normal conditions
Autoignition temperature :200 °C (DSC), 170 °C (Krupp method) Burn time :milliseconds
Solubility in water :
Not applicable, because this is a sealed unit. The solubility in water of the chemical materials inside the sealed unit is as follows:
(a) Smokeless powder Insoluble
(b) Primary charge Insoluble
(c)Secondarycharge Soluble
Boilingpoint :N/A
Density :N/A
Section 10 - Stability and Reactivity

Stability :
Micro Gas Generator Type NKPL-2 is stable at room temperature in closed containers under normal storage and handling
conditions.
Polymerization :
Hazardous polymerization cannot occur.
Chemical Incompatibilities :
Avoid strong acids, bases, oxidizers, high heat, any electrical currents, and impact. Do not mix with any other igniter material
before determining the hazards and taking the proper safety precautions.
Conditions to Avoid :
Shock, impact, friction, electrostatic discharge, high temperature, open flame, contamination.
Hazardous Decomposition Products :

Hot gases, fragments and extreme heat will be emitted by large quantities of igniters during their combustion, deflagration,
detonation or chemical reaction.
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Section 11 - Toxicological Information
Toxicity Data :
Toxicity of electric belt pretensioner is negligible at normal conditions. On initiation small amount of toxic fumes will be released.
Effect of overexposure to the chemical material is not completely determined:
(a)Smokeless Powder Type 1
(i) Nitrocellulose LD50 5000 mg/kg (rat, Oral)
(ii) Diphenylamine LD50 2000 mg/kg (rat, Oral)
LD50 1750 mg/kg (mouse, Oral)
(ⅲ) Potassium Sulfate LD50 6600 mg/kg (rat, Oral)
Smokeless Powder Type 2
(i) Nitrocellulose LD50 5000 mg/kg (rat, Oral)
(ii) Diphenylamine LD50 2000 mg/kg (rat, Oral)
LD50 1750 mg/kg (mouse, Oral)
(ⅲ) Potassium Sulfate LD50 6600 mg/kg (rat, Oral)
(ⅳ) Methyl Diphenylurea (AkarditeⅡ) LD50 2000 mg/kg (mouse, Oral)
(b)Primary chargeType 1
(i) Lead Styphnate N/A
(ii) Potassium Perchlorate LD50 2100mg/kg(rat,Oral)
LD50 551 mg/kg (mouse, in-vivo)
(ⅲ)Zirconium N/A
Primary charge Type 2
(i) Basic Copper(Ⅱ) Nitrate LD50 300 mg/kg (rat, Oral)
(ii) Potassium Perchlorate LD50 2100 mg/kg (rat, Oral)
(ⅲ)Zirconium N/A
(ⅳ) Aluminum N/A
(c)Secondary charge Type 1
LD50 2100 mg/kg (rat, Oral)
(i) Potassium Perchlorate
(ii) Sodium Picramate LD50 378 mg/kg (rat, Oral)
(ⅲ)Antimony Trisulfide LD50 2500 mg/kg (rat, Oral)
Secondary charge Type 2
(i) Titanium Hydride N/A
(ii) Potassium Perchlorate LD50 2100 mg/kg (rat, Oral)
Section 12 - Ecological Information
Hazard of damaging of environment is during common handling negligible.
Section 13 - Disposal Considerations

Disposal :
Generants should be destroyed by open burning/open detonation in an approved incinerator, or by other approved method such
as chemical treatment/destruction. This material should be disposed of by a competent body familiar with explosive materials.
Contact your supplier or a licensed contractor for detailed recommendations.
Section 14 - Transport Information

DOT Transportation Data :
(a)Shipping Name :Seatbelt Assy
(b)Shipping Number :UN 3268
(c)UN Classification Code :9
Page 3 of 4
Section 15 - Regulatory Information
Risk Phrases :
R3: Extreme risk of explosion by shock, friction, fire or other sources of ignition.
Safety Phrases :
S33: Take precautionary measures against static discharge.
S35: This material and its container must be disposed of in a safe way.
S39: Wear eye / face protection.
S47: Keep at temperatures not exceeding 70 ℃
Hazard symbol :
E : Explosive
Section 16 - Other Information
Disclaimer :
The technical information provided in this MSDS should only be used for the purposes of assessing hazards, with respect to
safety or the environment. It should not be used as a technical specification or for engineering calculations.
The information contained herein is accurate to the best knowledge and belief of Ashimori Industry Co., Ltd.
and is intended to describe the product for health, safety and environmental requirements only. It is not intended and should not
be construed as a warranty. Consult Ashimori Industry Co., Ltd.for further information.
This product contains “Potassium Perchlorate”.

According to “California Code of regulations” , it is required to be labeled, marked clearly with the following note on the
package or enclosed this MSDS with the package when this product is delivered to California.
“Perchlorate Material− special handling may apply, See www.dtsc.ca.gov/hazardouswaste/perchlorate.”
Page 4 of 4

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Section 1 - Chemical Product and Company Identification

Product/Chemical Name :Seatbelt Assy/Micro Gas Generator Type NKPL-2

Section 2 - Hazards Identification

Section 3 - Composition / Information on Ingredients

1.Squib Charge CAS NO. CAS NO.

Primary Charge Type 1 Primary Charge Type 2 7440-67-7

Secondary Charge Type 1 Secondary Charge Type 2

*1)Either Type 1 or Type 2 is used as both Primary charge Secondary charge

2.Gas Generant (Smokeless Powder)*2)

*2)Either Type 1 or Type 2 is used as Gas Generant

Section 4 - First Aid Measures

Section 5 - Fire-Fighting Measures

Section 6 - Accidental Release Measures

Section 7 - Handling and Storage

Section 8 - Exposure Controls / Personal Protection

Section 9 - Physical and Chemical Properties

Section 10 - Stability and Reactivity

Hazardous Decomposition Products :

Section 12 - Ecological Information

Hazard of damaging of environment is during common handling negligible.

Section 13 - Disposal Considerations

Section 14 - Transport Information

Section 16 - Other Information

This product contains “Potassium Perchlorate”.

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