Air Cooler Cleaner 25 LTR
Air Cooler Cleaner 25 LTR
Air Cooler Cleaner 25 LTR
1.2. Relevant identified uses of the substance or mixture and uses advised against
Product Category
PC35 Washing and cleaning products
Consumer
Sectors of Use SU3 Industrial uses: Uses of substances as such or in preparations* at industrial sites
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Other emergency
+31-10-4877700 +31-10-4877700 + 31 10 4877700
telephone numbers
Association / Organisation Dutch nat. poison centre CHEMWATCH EMERGENCY RESPONSE (24/7)
Emergency telephone
+ 31 30 274 88 88 +47 23 25 25 84
numbers
Other emergency
+ 31-10-4877700 +61 3 9573 3188
telephone numbers
Once connected and if the message is not in your preferred language then please dial 01
Hazard pictogram(s)
Hazard statement(s)
H319 Causes serious eye irritation.
H372 Causes damage to organs through prolonged or repeated exposure.
H304 May be fatal if swallowed and enters airways.
H412 Harmful to aquatic life with long lasting effects.
Supplementary statement(s)
EUH066 Repeated exposure may cause skin dryness or cracking.
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P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314 Get medical advice/attention if you feel unwell.
3.1.Substances
See 'Composition on ingredients' in Section 3.2
3.2.Mixtures
1. CAS No
2.EC No Classification according to regulation (EC) SCL / Nanoform Particle
%[weight] Name
3.Index No No 1272/2008 [CLP] and amendments M-Factor Characteristics
4.REACH No
1. 160875-66-1*
Serious Eye Damage/Eye Irritation Category
2.Not Available Not
2 Fatty alcohol ethoxylates 1, Acute Toxicity (Oral) Category 4; H318, Not Available
3.Not Available Available
H302 [1]
4.Not Available
Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI; 3. Classification drawn from
C&L; * EU IOELVs available; [e] Substance identified as having endocrine disrupting properties
If fumes, aerosols or combustion products are inhaled remove from contaminated area.
Inhalation
Other measures are usually unnecessary.
4.2 Most important symptoms and effects, both acute and delayed
See Section 11
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4.3. Indication of any immediate medical attention and special treatment needed
Any material aspirated during vomiting may produce lung injury. Therefore emesis should not be induced mechanically or pharmacologically. Mechanical means
should be used if it is considered necessary to evacuate the stomach contents; these include gastric lavage after endotracheal intubation. If spontaneous vomiting
has occurred after ingestion, the patient should be monitored for difficult breathing, as adverse effects of aspiration into the lungs may be delayed up to 48 hours.
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Hazard categories in
accordance with
Not Available
Regulation (EC) No
1272/2008
Qualifying quantity
(tonnes) of dangerous
substances as referred to Not Available
in Article 3(10) for the
application of
+ x + o + + +
Note: Depending on other risk factors, compatibility assessment based on the table above may not be relevant to storage situations, particularly where large volumes
of dangerous goods are stored and handled. Reference should be made to the Safety Data Sheets for each substance or article and risks assessed accordingly.
INGREDIENT DATA
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Not Applicable
Emergency Limits
MATERIAL DATA
Sensory irritants are chemicals that produce temporary and undesirable side-effects on the eyes, nose or throat. Historically occupational exposure standards for
these irritants have been based on observation of workers' responses to various airborne concentrations. Present day expectations require that nearly every
individual should be protected against even minor sensory irritation and exposure standards are established using uncertainty factors or safety factors of 5 to 10 or
more. On occasion animal no-observable-effect-levels (NOEL) are used to determine these limits where human results are unavailable. An additional approach,
typically used by the TLV committee (USA) in determining respiratory standards for this group of chemicals, has been to assign ceiling values (TLV C) to rapidly
acting irritants and to assign short-term exposure limits (TLV STELs) when the weight of evidence from irritation, bioaccumulation and other endpoints combine to
warrant such a limit. In contrast the MAK Commission (Germany) uses a five-category system based on intensive odour, local irritation, and elimination half-life.
However this system is being replaced to be consistent with the European Union (EU) Scientific Committee for Occupational Exposure Limits (SCOEL); this is
more closely allied to that of the USA.
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from
manufacturer to manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material
can not be calculated in advance and has therefore to be checked prior to the application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and has to be
Hands/feet protection observed when making a final choice.
Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands
should be washed and dried thoroughly. Application of a non-perfumed moisturiser is recommended.
Wear chemical protective gloves, e.g. PVC.
Wear safety footwear or safety gumboots, e.g. Rubber
Overalls.
Other protection P.V.C apron.
Barrier cream.
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Partition coefficient
Odour Not Available Not Available
n-octanol / water
Auto-ignition temperature
Odour threshold Not Available >200
(°C)
Decomposition
pH (as supplied) Not Available Not Available
temperature (°C)
Melting point / freezing
Not Available Viscosity (cSt) Not Available
point (°C)
Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water Miscible pH as a solution (1%) Not Available
10.5. Incompatible
See section 7.2
materials
10.6. Hazardous
See section 5.3
decomposition products
Inhaled The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified by EC Directives
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using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable control
measures be used in an occupational setting.
Swallowing of the liquid may cause aspiration of vomit into the lungs with the risk of haemorrhaging, pulmonary oedema,
progressing to chemical pneumonitis; serious consequences may result.
Signs and symptoms of chemical (aspiration) pneumonitis may include coughing, gasping, choking, burning of the mouth, difficult
breathing, and bluish coloured skin (cyanosis).
The material has NOT been classified by EC Directives or other classification systems as "harmful by ingestion". This is because
Ingestion
of the lack of corroborating animal or human evidence. The material may still be damaging to the health of the individual,
following ingestion, especially where pre-existing organ (e.g liver, kidney) damage is evident. Present definitions of harmful or
toxic substances are generally based on doses producing mortality rather than those producing morbidity (disease, ill-health).
Gastrointestinal tract discomfort may produce nausea and vomiting. In an occupational setting however, ingestion of insignificant
quantities is not thought to be cause for concern.
The material is not thought to produce adverse health effects or skin irritation following contact (as classified by EC Directives
using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable gloves
be used in an occupational setting.
Skin Contact Repeated exposure may cause skin cracking, flaking or drying following normal handling and use.
Open cuts, abraded or irritated skin should not be exposed to this material
Entry into the blood-stream through, for example, cuts, abrasions, puncture wounds or lesions, may produce systemic injury with
harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.
Eye Direct contact with the eye may produce transient discomfort characterised by tearing or conjunctival redness (as with windburn).
Long-term exposure to the product is not thought to produce chronic effects adverse to health (as classified by EC Directives
using animal models); nevertheless exposure by all routes should be minimised as a matter of course.
Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed.
Serious damage (clear functional disturbance or morphological change which may have toxicological significance) is likely to be
Chronic
caused by repeated or prolonged exposure. As a rule the material produces, or contains a substance which produces severe
lesions. Such damage may become apparent following direct application in subchronic (90 day) toxicity studies or following
sub-acute (28 day) or chronic (two-year) toxicity tests.
Prolonged or repeated skin contact may cause drying with cracking, irritation and possible dermatitis following.
TOXICITY IRRITATION
AIR COOLER CLEANER
Not Available Not Available
TOXICITY IRRITATION
Fatty alcohol ethoxylates
Not Available Not Available
TOXICITY IRRITATION
Hydrocarbons, C10-C13, Dermal (Other) LD50: >3400 mg/kg[2] Not Available
n-alkanes, isoalkanes,
cyclics, aromatics (2-25%)- Inhalation(Rat) LC50: 13,1 mg/kg[2]
Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2. Value obtained from manufacturer's SDS.
Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances
Human beings have regular contact with alcohol ethoxylates through a variety of industrial and consumer products such as
soaps, detergents, and other cleaning products . Exposure to these chemicals can occur through ingestion, inhalation, or contact
with the skin or eyes. Studies of acute toxicity show that volumes well above a reasonable intake level would have to occur to
produce any toxic response. Moreover, no fatal case of poisoning with alcohol ethoxylates has ever been reported. Multiple
studies investigating the acute toxicity of alcohol ethoxylates have shown that the use of these compounds is of low concern in
terms of oral and dermal toxicity .
Clinical animal studies indicate these chemicals may produce gastrointestinal irritation such as ulcerations of the stomach,
pilo-erection, diarrhea, and lethargy. Similarly, slight to severe irritation of the skin or eye was generated when undiluted alcohol
ethoxylates were applied to the skin and eyes of rabbits and rats.
Alcohol ethoxylates are according to CESIO (2000) classified as Irritant or Harmful depending on the number of EO-units:
EO < 5 gives Irritant (Xi) with R38 (Irritating to skin) and R41 (Risk of serious damage to eyes)
Fatty alcohol ethoxylates EO > 5-15 gives Harmful (Xn) with R22 (Harmful if swallowed) - R38/41
EO > 15-20 gives Harmful (Xn) with R22-41
>20 EO is not classified (CESIO 2000)
Oxo-AE, C13 EO10 and C13 EO15, are Irritating (Xi) with R36/38 (Irritating to eyes and skin) .
AE are not included in Annex 1 of the list of dangerous substances of the Council Directive 67/548/EEC
In general, alcohol ethoxylates (AE) are readily absorbed through the skin of guinea pigs and rats and through the
gastrointestinal mucosa of rats. AE are quickly eliminated from the body through the urine, faeces, and expired air (CO2).Orally
dosed AE was absorbed rapidly and extensively in rats, and more than 75% of the dose was absorbed. When applied to the skin
of humans, the doses were absorbed slowly and incompletely (50% absorbed in 72 hours). Half of the absorbed surfactant was
excreted promptly in the urine and smaller amounts of AE appeared in the faeces and expired air (CO2) ). The metabolism of
C12 AE yields PEG, carboxylic acids, and CO2 as metabolites. The LD50 values after oral administration to rats range from
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about 1-15 g/kg body weight indicating a low to moderate acute toxicity.
The ability of nonionic surfactants to cause a swelling of the stratum corneum of guinea pig skin has been studied. The swelling
mechanism of the skin involves a combination of ionic binding of the hydrophilic group as well as hydrophobic interactions of the
alkyl chain with the substrate. No significant acute toxicological data identified in literature search.
Serious Eye
STOT - Single Exposure
Damage/Irritation
Respiratory or Skin
STOT - Repeated Exposure
sensitisation
Mutagenicity Aspiration Hazard
Legend: – Data either not available or does not fill the criteria for classification
– Data available to make classification
12.1. Toxicity
Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity
4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) -
Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Do not contaminate water when cleaning
equipment or disposing of equipment wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste sites.
DO NOT discharge into sewer or waterways.
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Ingredient Mobility
No Data available for all ingredients
PBT
vPvB
vPvB No
Labels Required
Marine Pollutant NO
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14.5. Environmental
Not Applicable
hazard
Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
14.1. UN number Not Applicable
14.2. UN proper shipping
Not Applicable
name
14.5. Environmental
Not Applicable
hazard
Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
14.1. UN number Not Applicable
14.2. UN proper shipping
Not Applicable
name
14.5. Environmental
Not Applicable
hazard
Inland waterways transport (ADN): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
14.1. UN number Not Applicable
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14.7.1. Transport in bulk according to Annex II of MARPOL and the IBC code
Not Applicable
14.7.2. Transport in bulk in accordance with MARPOL Annex V and the IMSBC Code
Product name Group
Fatty alcohol ethoxylates Not Available
Hydrocarbons, C10-C13,
n-alkanes, isoalkanes, Not Available
cyclics, aromatics (2-25%)-
Hydrocarbons, C10-C13,
n-alkanes, isoalkanes, Not Available
cyclics, aromatics (2-25%)-
15.1. Safety, health and environmental regulations / legislation specific for the substance or mixture
Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, aromatics (2-25%)- is found on the following regulatory lists
Not Applicable
This safety data sheet is in compliance with the following EU legislation and its adaptations - as far as applicable - : Directives 98/24/EC, - 92/85/EEC, - 94/33/EC,
- 2008/98/EC, - 2010/75/EU; Commission Regulation (EU) 2020/878; Regulation (EC) No 1272/2008 as updated through ATPs.
ECHA SUMMARY
Ingredient CAS number Index No ECHA Dossier
Acute Tox. 4; Eye Dam. 1; Skin Irrit. 2; STOT SE 3; H302; H318; H315; H202; H335;
2 GHS05; Dgr; GHS09
Aquatic Chronic 2 H411
Harmonisation Code 1 = The most prevalent classification. Harmonisation Code 2 = The most severe classification.
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CONTACT POINT
- For quotations contact your local Customer Services - http://wssdirectory.wilhelmsen.com/#/customerservices - - Responsible for safety data sheet Wilhelmsen
Ships Service AS - Prepared by: Compliance Manager, - Email: Email: wss.global.sdsinfo@wilhelmsen.com - Telephone: Tel.: +47 67584000
Toxicological information - Acute Health (eye), Toxicological information - Acute Health (skin), Toxicological
information - Chronic Health, Hazards identification - Classification, Exposure controls / personal protection -
Engineering Control, Ecological Information - Environmental, First Aid measures - First Aid (eye), First Aid
10.16 30/11/2022
measures - First Aid (skin), Handling and storage - Handling Procedure, Exposure controls / personal protection -
Personal Protection (hands/feet), Accidental release measures - Spills (major), Accidental release measures -
Spills (minor), Identification of the substance / mixture and of the company / undertaking - Use
Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch
Classification committee using available literature references.
The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks
in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available
engineering controls must be considered.
For detailed advice on Personal Protective Equipment, refer to the following EU CEN Standards:
EN 166 Personal eye-protection
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end of SDS