INDICATOR FOR TRO CALIBRATION KIT

Wilhelmsen Ships Service AS

Part Number: 779211-b Issue Date: 29/09/2023
Version No: 3.13 Print Date: 12/08/2024
Safety Data Sheet (Conforms to Annex II of REACH (1907/2006) - Regulation 2020/878) L.REACH.NOR.EN

SECTION 1 Identification of the substance / mixture and of the company / undertaking

1.1. Product Identifier

Product name INDICATOR FOR TRO CALIBRATION KIT

Chemical Name Not Applicable

Synonyms 779211
ARYLSULPHONIC ACIDS, LIQUID, WITH 5% OR LESS FREE SULPHURIC ACID (contains toluene-4-sulfonic acid
Proper shipping name
monohydrate)
Chemical formula Not Applicable
Other means of
779211-b | UFI:QR0M-87HX-520X-SKHQ
identification

1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses Use according to manufacturer's directions.
Uses advised against No specific uses advised against are identified.

1.3. Details of the manufacturer or supplier of the safety data sheet

Outback (M)SDS portal:
Wilhelmsen Ships Service AS*
Registered company name Wilhelmsen Ships Service AS https://jr.chemwatch.net/outb/account/autologin?
Central Warehouse
login=wilhelmsen
--------Use our Outback portal to obtain our (M)SDSs
in other languages and/or format.--------- For
Strandveien 20 Lysaker 1366 Willem Barentszstraat 50
Address questions relating to our SDSs please use Email:
Norway Rotterdam Netherlands
WSS.GLOBAL.SDSINFO@wilhelmsen.com ---------
Norway

Telephone +47 67 58 40 00 Not Available +31 10 4877 777

Fax Not Available Not Available Not Available

Website https://www.wilhelmsen.com/ https://www.wilhelmsen.com https://www.wilhelmsen.com

Email wss.norway.cs@wilhelmsen.com wss.global.sdsinfo@wilhelmsen.com wss.rotterdam@wilhelmsen.com

1.4. Emergency telephone number

Association / Organisation Giftinformasjonssentralen - 24 timer 24hrs - Chemwatch Dutch nat. poison centre
Emergency telephone
+47 22591300 +31-10-4877700 + 31 88 7558561
numbers

Other emergency
+31-10-4877700 +31-10-4877700 + 31 10 4877700
telephone numbers

Association / Organisation CHEMWATCH EMERGENCY RESPONSE (24/7)

Emergency telephone
+47 23 25 25 84
numbers
Other emergency
+61 3 9573 3188
telephone numbers

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Once connected and if the message is not in your preferred language then please dial 01

SECTION 2 Hazards identification

2.1. Classification of the substance or mixture

Classification according to
regulation (EC) No H302 - Acute Toxicity (Oral) Category 4, H312 - Acute Toxicity (Dermal) Category 4, H315 - Skin Corrosion/Irritation Category 2,
H319 - Serious Eye Damage/Eye Irritation Category 2, H332 - Acute Toxicity (Inhalation) Category 4, H335 - Specific Target
1272/2008 [CLP] and
Organ Toxicity - Single Exposure (Respiratory Tract Irritation) Category 3, H350i - Carcinogenicity Category 1A
amendments [1]
Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI

2.2. Label elements

Hazard pictogram(s)

Signal word Danger

Hazard statement(s)
H302 Harmful if swallowed.

H312 Harmful in contact with skin.

H315 Causes skin irritation.
H319 Causes serious eye irritation.

H332 Harmful if inhaled.

H335 May cause respiratory irritation.
H350i May cause cancer by inhalation.

Supplementary statement(s)
Not Applicable

Precautionary statement(s) General

P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read carefully and follow all instructions.

Precautionary statement(s) Prevention

P201 Obtain special instructions before use.

P271 Use only outdoors or in a well-ventilated area.

P280 Wear protective gloves, protective clothing, eye protection and face protection.
P261 Avoid breathing mist/vapours/spray.

P264 Wash all exposed external body areas thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.

Precautionary statement(s) Response

P308+P313 IF exposed or concerned: Get medical advice/ attention.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/physician/first aider if you feel unwell.

P302+P352 IF ON SKIN: Wash with plenty of water.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P330 Rinse mouth.

P332+P313 If skin irritation occurs: Get medical advice/attention.

P362+P364 Take off contaminated clothing and wash it before reuse.

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Precautionary statement(s) Storage

P405 Store locked up.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

Precautionary statement(s) Disposal

P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation.

Material contains toluene-4-sulfonic acid monohydrate.

2.3. Other hazards

REACH - Art.57-59: The mixture does not contain Substances of Very High Concern (SVHC) at the SDS print date.

SECTION 3 Composition / information on ingredients

3.1.Substances
See 'Composition on ingredients' in Section 3.2

3.2.Mixtures
1. CAS No
2.EC No % Classification according to regulation (EC) No SCL / M- Nanoform Particle
Name
3.Index No [weight] 1272/2008 [CLP] and amendments Factor Characteristics
4.REACH No

Not Available

1. 6192-52-5 Corrosive to Metals Category 1, Skin Acute M

2.Not Available toluene-4-sulfonic Corrosion/Irritation Category 1B, Serious Eye factor: Not
3.016-029-00-7|016-030-00- 7 Damage/Eye Irritation Category 1, Carcinogenicity Available Not Available
2 acid monohydrate
[1] Chronic M
4.Not Available Category 1A; H290, H314, H318, H350i
factor: Not
Available

Not Available

Acute M
1. 7732-18-5
factor: Not
2.231-791-2
3.Not Available
93 water Not Classified [1] Available Not Available

4.Not Available Chronic M

factor: Not
Available

Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI; 3. Classification drawn from
C&L; * EU IOELVs available; [e] Substance identified as having endocrine disrupting properties

SECTION 4 First aid measures

4.1. Description of first aid measures

If this product comes in contact with the eyes:
Immediately hold eyelids apart and flush the eye continuously with running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally
Eye Contact lifting the upper and lower lids.
Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes.
Transport to hospital or doctor without delay.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
If skin or hair contact occurs:
Immediately flush body and clothes with large amounts of water, using safety shower if available.
Skin Contact Quickly remove all contaminated clothing, including footwear.
Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons Information Centre.
Transport to hospital, or doctor.
Inhalation If fumes or combustion products are inhaled remove from contaminated area.
Lay patient down. Keep warm and rested.
Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid
procedures.
Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket
mask as trained. Perform CPR if necessary.
Transport to hospital, or doctor, without delay.
Inhalation of vapours or aerosols (mists, fumes) may cause lung oedema.
Corrosive substances may cause lung damage (e.g. lung oedema, fluid in the lungs).
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As this reaction may be delayed up to 24 hours after exposure, affected individuals need complete rest (preferably in semi-
recumbent posture) and must be kept under medical observation even if no symptoms are (yet) manifested.
Before any such manifestation, the administration of a spray containing a dexamethasone derivative or beclomethasone
derivative may be considered.
This must definitely be left to a doctor or person authorised by him/her.
(ICSC13719)
For advice, contact a Poisons Information Centre or a doctor at once.
Urgent hospital treatment is likely to be needed.
If swallowed do NOT induce vomiting.
If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and
Ingestion prevent aspiration.
Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
Transport to hospital or doctor without delay.

4.2 Most important symptoms and effects, both acute and delayed
See Section 11

4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
For acute or short term repeated exposures to strong acids:
Airway problems may arise from laryngeal edema and inhalation exposure. Treat with 100% oxygen initially.
Respiratory distress may require cricothyroidotomy if endotracheal intubation is contraindicated by excessive swelling
Intravenous lines should be established immediately in all cases where there is evidence of circulatory compromise.
Strong acids produce a coagulation necrosis characterised by formation of a coagulum (eschar) as a result of the dessicating action of the acid on proteins in
specific tissues.
INGESTION:
Immediate dilution (milk or water) within 30 minutes post ingestion is recommended.
DO NOT attempt to neutralise the acid since exothermic reaction may extend the corrosive injury.
Be careful to avoid further vomit since re-exposure of the mucosa to the acid is harmful. Limit fluids to one or two glasses in an adult.
Charcoal has no place in acid management.
Some authors suggest the use of lavage within 1 hour of ingestion.
SKIN:
Skin lesions require copious saline irrigation. Treat chemical burns as thermal burns with non-adherent gauze and wrapping.
Deep second-degree burns may benefit from topical silver sulfadiazine.
EYE:
Eye injuries require retraction of the eyelids to ensure thorough irrigation of the conjuctival cul-de-sacs. Irrigation should last at least 20-30 minutes. DO NOT
use neutralising agents or any other additives. Several litres of saline are required.
Cycloplegic drops, (1% cyclopentolate for short-term use or 5% homatropine for longer term use) antibiotic drops, vasoconstrictive agents or artificial tears
may be indicated dependent on the severity of the injury.
Steroid eye drops should only be administered with the approval of a consulting ophthalmologist).

[Ellenhorn and Barceloux: Medical Toxicology]

SECTION 5 Firefighting measures

5.1. Extinguishing media

Water spray or fog.
Foam.
Dry chemical powder.
BCF (where regulations permit).
Carbon dioxide.

5.2. Special hazards arising from the substrate or mixture

Fire Incompatibility None known.

5.3. Advice for firefighters

Alert Fire Brigade and tell them location and nature of hazard.
Wear full body protective clothing with breathing apparatus.
Prevent, by any means available, spillage from entering drains or water course.
Fire Fighting Use fire fighting procedures suitable for surrounding area.
Do not approach containers suspected to be hot.
Cool fire exposed containers with water spray from a protected location.
If safe to do so, remove containers from path of fire.
Fire/Explosion Hazard Non combustible.
Not considered to be a significant fire risk.
Acids may react with metals to produce hydrogen, a highly flammable and explosive gas.
Heating may cause expansion or decomposition leading to violent rupture of containers.

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May emit corrosive, poisonous fumes. May emit acrid smoke.

SECTION 6 Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

See section 8

6.2. Environmental precautions

See section 12

6.3. Methods and material for containment and cleaning up

Drains for storage or use areas should have retention basins for pH adjustments and dilution of spills before discharge or
disposal of material.
Check regularly for spills and leaks.
Clean up all spills immediately.
Minor Spills Avoid breathing vapours and contact with skin and eyes.
Control personal contact with the substance, by using protective equipment.
Contain and absorb spill with sand, earth, inert material or vermiculite.
Wipe up.
Place in a suitable, labelled container for waste disposal.
Chemical Class:acidic compounds, inorganic
For release onto land: recommended sorbents listed in order of priority.

SORBENT
RANK APPLICATION COLLECTION LIMITATIONS
TYPE

LAND SPILL - SMALL

foamed glass - pillows 1 throw pitchfork R, P, DGC, RT

expanded mineral - particulate 2 shovel shovel R, I, W, P, DGC
foamed glass - particulate 2 shovel shovel R, W, P, DGC

LAND SPILL - MEDIUM

expanded mineral -particulate 1 blower skiploader R, I, W, P, DGC

foamed glass- particulate 2 blower skiploader R, W, P, DGC

foamed glass - particulate 3 throw skiploader R, W, P, DGC
Major Spills Legend
DGC: Not effective where ground cover is dense
R; Not reusable
I: Not incinerable
P: Effectiveness reduced when rainy
RT:Not effective where terrain is rugged
SS: Not for use within environmentally sensitive sites
W: Effectiveness reduced when windy
Reference: Sorbents for Liquid Hazardous Substance Cleanup and Control;
R.W Melvold et al: Pollution Technology Review No. 150: Noyes Data Corporation 1988
Clear area of personnel and move upwind.
Alert Fire Brigade and tell them location and nature of hazard.
Wear full body protective clothing with breathing apparatus.
Prevent, by any means available, spillage from entering drains or water course.
Consider evacuation (or protect in place).
Stop leak if safe to do so.
Contain spill with sand, earth or vermiculite.

6.4. Reference to other sections

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 Handling and storage

7.1. Precautions for safe handling

Avoid all personal contact, including inhalation.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
Safe handling WARNING: To avoid violent reaction, ALWAYS add material to water and NEVER water to material.
Avoid smoking, naked lights or ignition sources.
Avoid contact with incompatible materials.
When handling, DO NOT eat, drink or smoke.
Fire and explosion
See section 5
protection

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Store in original containers.

Keep containers securely sealed.
Store in a cool, dry, well-ventilated area.
Other information
Store away from incompatible materials and foodstuff containers.
Protect containers against physical damage and check regularly for leaks.
Observe manufacturer's storage and handling recommendations contained within this SDS.

7.2. Conditions for safe storage, including any incompatibilities

DO NOT use aluminium or galvanised containers
Check regularly for spills and leaks
Lined metal can, lined metal pail/ can.
Plastic pail.
Polyliner drum.
Packing as recommended by manufacturer.
Check all containers are clearly labelled and free from leaks.
For low viscosity materials
Drums and jerricans must be of the non-removable head type.
Suitable container Where a can is to be used as an inner package, the can must have a screwed enclosure.
For materials with a viscosity of at least 2680 cSt. (23 deg. C) and solids (between 15 C deg. and 40 deg C.):
Removable head packaging;
Cans with friction closures and
low pressure tubes and cartridges
may be used.
-
Where combination packages are used, and the inner packages are of glass, porcelain or stoneware, there must be sufficient
inert cushioning material in contact with inner and outer packages unless the outer packaging is a close fitting moulded plastic
box and the substances are not incompatible with the plastic.
Inorganic acids are generally soluble in water with the release of hydrogen ions. The resulting solutions have pH's of less
than 7.0.
Inorganic acids neutralise chemical bases (for example: amines and inorganic hydroxides) to form salts - neutralisation can
generate dangerously large amounts of heat in small spaces.
The dissolution of inorganic acids in water or the dilution of their concentrated solutions with additional water may generate
Storage incompatibility significant heat.
The addition of water to inorganic acids often generates sufficient heat in the small region of mixing to cause some of the
water to boil explosively. The resulting "bumping" can spatter the acid.
Inorganic acids react with active metals, including such structural metals as aluminum and iron, to release hydrogen, a
flammable gas.
Reacts with mild steel, galvanised steel / zinc producing hydrogen gas which may form an explosive mixture with air.
Hazard categories in
accordance with
Not Available
Regulation (EC) No
2012/18/EU (Seveso III)
Qualifying quantity
(tonnes) of dangerous
substances as referred to Not Available
in Article 3(10) for the
application of

+ x + o + + +

X — Must not be stored together

0 — May be stored together with specific preventions
+ — May be stored together

Note: Depending on other risk factors, compatibility assessment based on the table above may not be relevant to storage situations, particularly where large volumes
of dangerous goods are stored and handled. Reference should be made to the Safety Data Sheets for each substance or article and risks assessed accordingly.

7.3. Specific end use(s)

See section 1.2

SECTION 8 Exposure controls / personal protection

8.1. Control parameters

DNELs PNECs
Ingredient
Exposure Pattern Worker Compartment
toluene-4-sulfonic acid Dermal 7 mg/kg bw/day (Systemic, Chronic) 0.073 mg/L (Water (Fresh))
monohydrate Inhalation 24.7 mg/m³ (Systemic, Chronic) 0.73 mg/L (Water - Intermittent release)
Dermal 2.5 mg/kg bw/day (Systemic, Chronic) * 0.007 mg/L (Water (Marine))

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DNELs PNECs
Ingredient
Exposure Pattern Worker Compartment
Inhalation 0.00435 mg/m³ (Systemic, Chronic) * 0.35 mg/kg sediment dw (Sediment (Fresh Water))
Oral 2.5 mg/kg bw/day (Systemic, Chronic) * 0.035 mg/kg sediment dw (Sediment (Marine))
0.028 mg/kg soil dw (Soil)
65 mg/L (STP)

* Values for General Population

Occupational Exposure Limits (OEL)

INGREDIENT DATA

Source Ingredient Material name TWA STEL Peak Notes

Not Available Not Available Not Available Not Available Not Available Not Available Not Available

Not Applicable

Emergency Limits

Ingredient TEEL-1 TEEL-2 TEEL-3

toluene-4-sulfonic acid
7.7 mg/m3 85 mg/m3 510 mg/m3
monohydrate

Ingredient Original IDLH Revised IDLH

toluene-4-sulfonic acid
Not Available Not Available
monohydrate
water Not Available Not Available

MATERIAL DATA

Exposed individuals are NOT reasonably expected to be warned, by smell, that the Exposure Standard is being exceeded.

Odour Safety Factor (OSF) is determined to fall into either Class C, D or E.

The Odour Safety Factor (OSF) is defined as:

OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm

Classification into classes follows:

ClassOSF Description
Over 90% of exposed individuals are aware by smell that the Exposure Standard (TLV-TWA for example) is being reached, even when distracted by
A 550
working activities
26-
B As "A" for 50-90% of persons being distracted
550
1-26 As "A" for less than 50% of persons being distracted
D 0.18-1 10-50% of persons aware of being tested perceive by smell that the Exposure Standard is being reached
E <0.18 As "D" for less than 10% of persons aware of being tested
NOTE: Detector tubes for sulfuric acid, measuring in excess of 1 mg/m3, are commercially available.
Based on controlled inhalation studies the TLV-TWA is thought to be protective against the significant risk of pulmonary irritation and incorporates a margin of
safety so as to prevent injury to the skin and teeth seen in battery workers acclimatised to workplace concentrations of 16 mg/m3. Experimental evidence in
normal unacclimated humans indicates the recognition, by all subjects, of odour, taste or irritation at 3 mg/m3 or 5 mg/m3. All subjects reported these levels to be
objectionable but to varying degrees.

8.2. Exposure controls

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed
engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to
provide this high level of protection.
The basic types of engineering controls are:
8.2.1. Appropriate
Process controls which involve changing the way a job activity or process is done to reduce the risk.
engineering controls
Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation
that strategically "adds" and "removes" air in the work environment. Ventilation can remove or dilute an air contaminant if
designed properly. The design of a ventilation system must match the particular process and chemical or contaminant in use.
Employers may need to use multiple types of controls to prevent employee overexposure.

8.2.2. Individual protection

measures, such as
personal protective
equipment

Eye and face protection Safety glasses with unperforated side shields may be used where continuous eye protection is desirable, as in laboratories;
spectacles are not sufficient where complete eye protection is needed such as when handling bulk-quantities, where there is

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a danger of splashing, or if the material may be under pressure.

Chemical goggles. Whenever there is a danger of the material coming in contact with the eyes; goggles must be properly
fitted. [AS/NZS 1337.1, EN166 or national equivalent]
Full face shield (20 cm, 8 in minimum) may be required for supplementary but never for primary protection of eyes; these
afford face protection.
Alternatively a gas mask may replace splash goggles and face shields.
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy
document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task.
Skin protection See Hand protection below
Elbow length PVC gloves
Hands/feet protection
When handling corrosive liquids, wear trousers or overalls outside of boots, to avoid spills entering boots.
Body protection See Other protection below
Overalls.
PVC Apron.
Other protection PVC protective suit may be required if exposure severe.
Eyewash unit.
Ensure there is ready access to a safety shower.

Recommended material(s) Respiratory protection

GLOVE SELECTION INDEX Type -P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 &
Glove selection is based on a modified presentation of the: 149:2001, ANSI Z88 or national equivalent)
"Forsberg Clothing Performance Index". Selection of the Class and Type of respirator will depend upon the level of
The effect(s) of the following substance(s) are taken into account in the breathing zone contaminant and the chemical nature of the contaminant.
computer-generated selection: Protection Factors (defined as the ratio of contaminant outside and inside the
INDICATOR FOR TRO CALIBRATION KIT mask) may also be important.

Material CPI Required

Maximum gas/vapour
BUTYL A minimum Half-face Full-Face
concentration present in
protection Respirator Respirator
NEOPRENE A air p.p.m. (by volume)
factor
VITON A
-AUS /
up to 10 1000 -
NATURAL RUBBER C Class1 P2
PVA C -AUS / Class
up to 50 1000 -
1 P2
* CPI - Chemwatch Performance Index
up to 50 5000 Airline * -
A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion up to 100 5000 - -2 P2
C: Poor to Dangerous Choice for other than short term immersion up to 100 10000 - -3 P2
NOTE: As a series of factors will influence the actual performance of the glove,
100+ Airline**
a final selection must be based on detailed observation. -
* Where the glove is to be used on a short term, casual or infrequent basis,
* - Continuous Flow ** - Continuous-flow or positive pressure demand
factors such as "feel" or convenience (e.g. disposability), may dictate a choice
A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or
of gloves which might otherwise be unsuitable following long-term or frequent
hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur
use. A qualified practitioner should be consulted. dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury,
NO = Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organic
Ansell Glove Selection compounds(below 65 degC)

Glove — In order of recommendation

AlphaTec 02-100
AlphaTec® Solvex® 37-185
AlphaTec® 38-612
AlphaTec® 58-530B
AlphaTec® 58-735
AlphaTec® 79-700
AlphaTec® Solvex® 37-675
MICROFLEX® 73-847
MICROFLEX® 93-244
MICROFLEX® 93-252

The suggested gloves for use should be confirmed with the glove supplier.

8.2.3. Environmental exposure controls

See section 12

SECTION 9 Physical and chemical properties

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9.1. Information on basic physical and chemical properties

Appearance Colourless

Relative density (Water =

Physical state Liquid 1.1
1)
Partition coefficient n-
Odour Not Available Not Available
octanol / water

Auto-ignition temperature
Odour threshold Not Available Not Available
(°C)
Decomposition
pH (as supplied) 1-2 Not Available
temperature (°C)
Melting point / freezing
Not Available Viscosity (cSt) Not Available
point (°C)
Initial boiling point and
100 Molecular weight (g/mol) Not Available
boiling range (°C)
Flash point (°C) Not Available Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Not Available Oxidising properties Not Available
Surface Tension (dyn/cm
Upper Explosive Limit (%) Not Available Not Available
or mN/m)
Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water Miscible pH as a solution (1%) 1-2
Vapour density (Air = 1) Not Available VOC g/L Not Available
Nanoform Particle
Nanoform Solubility Not Available Not Available
Characteristics
Particle Size Not Available

9.2. Other information

Not Available

SECTION 10 Stability and reactivity

10.1.Reactivity See section 7.2

Contact with alkaline material liberates heat
Unstable in the presence of incompatible materials.
10.2. Chemical stability
Product is considered stable.
Hazardous polymerisation will not occur.
10.3. Possibility of
See section 7.2
hazardous reactions
10.4. Conditions to avoid See section 7.2
10.5. Incompatible
See section 7.2
materials
10.6. Hazardous
See section 5.3
decomposition products

SECTION 11 Toxicological information

11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008

Inhalation of vapours or aerosols (mists, fumes), generated by the material during the course of normal handling, may be
harmful.
Evidence shows, or practical experience predicts, that the material produces irritation of the respiratory system, in a substantial
number of individuals, following inhalation. In contrast to most organs, the lung is able to respond to a chemical insult by first
removing or neutralising the irritant and then repairing the damage. The repair process, which initially evolved to protect
mammalian lungs from foreign matter and antigens, may however, produce further lung damage resulting in the impairment of
gas exchange, the primary function of the lungs. Respiratory tract irritation often results in an inflammatory response involving
Inhaled
the recruitment and activation of many cell types, mainly derived from the vascular system.

Acidic corrosives produce respiratory tract irritation with coughing, choking and mucous membrane damage. Symptoms of
exposure may include dizziness, headache, nausea and weakness. In more severe exposures, pulmonary oedema may be
evident either immediately or after a latent period of 5-72 hours. Symptoms of pulmonary oedema include a tightness in the
chest, dyspnoea, frothy sputum and cyanosis. Examination may reveal hypotension, a weak and rapid pulse and moist rates.
Death, due to anoxia, may occur several hours after onset of the pulmonary oedema.

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Accidental ingestion of the material may be harmful; animal experiments indicate that ingestion of less than 150 gram may be
fatal or may produce serious damage to the health of the individual.

Ingestion of acidic corrosives may produce circumoral burns with a distinct discolouration of the mucous membranes of the
Ingestion mouth, throat and oesophagus. Immediate pain and difficulties in swallowing and speaking may also be evident. Oedema of the
epiglottis may produce respiratory distress and possibly, asphyxia. Nausea, vomiting, diarrhoea and a pronounced thirst may
occur. More severe exposures may produce a vomitus containing fresh or dark blood and large shreds of mucosa. Shock, with
marked hypotension, weak and rapid pulse, shallow respiration and clammy skin may be symptomatic of the exposure.
Circulatory collapse may, if left untreated, result in renal failure.
Skin contact with the material may be harmful; systemic effects may result following absorption.
Skin contact with acidic corrosives may result in pain and burns; these may be deep with distinct edges and may heal slowly with
the formation of scar tissue.
Skin Contact
Open cuts, abraded or irritated skin should not be exposed to this material
Entry into the blood-stream through, for example, cuts, abrasions, puncture wounds or lesions, may produce systemic injury with
harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.

Direct eye contact with acid corrosives may produce pain, lachrymation, photophobia and burns. Mild burns of the epithelia
generally recover rapidly and completely. Severe burns produce long-lasting and possible irreversible damage. The appearance
of the burn may not be apparent for several weeks after the initial contact. The cornea may ultimately become deeply
Eye vascularised and opaque resulting in blindness.
When applied to the eye(s) of animals, the material produces severe ocular lesions which are present twenty-four hours or more
after instillation.
Irritation of the eyes may produce a heavy secretion of tears (lachrymation).
Repeated or prolonged exposure to acids may result in the erosion of teeth, inflammatory and ulcerative changes in the mouth
and necrosis (rarely) of the jaw. Bronchial irritation, with cough, and frequent attacks of bronchial pneumonia may ensue.
Gastrointestinal disturbances may also occur. Chronic exposures may result in dermatitis and/or conjunctivitis.
The impact of inhaled acidic agents on the respiratory tract depends upon a number of interrelated factors. These include
physicochemical characteristics, e.g., gas versus aerosol; particle size (small particles can penetrate deeper into the lung); water
solubility (more soluble agents are more likely to be removed in the nose and mouth). Given the general lack of information on
the particle size of aerosols involved in occupational exposures to acids, it is difficult to identify their principal deposition site
Chronic
within the respiratory tract.
On the basis of epidemiological data, it has been concluded that prolonged inhalation of the material, in an occupational setting,
may produce cancer in humans.
Long-term exposure to respiratory irritants may result in disease of the airways involving difficult breathing and related systemic
problems.
Limited evidence suggests that repeated or long-term occupational exposure may produce cumulative health effects involving
organs or biochemical systems.

INDICATOR FOR TRO TOXICITY IRRITATION

CALIBRATION KIT Not Available Not Available

TOXICITY IRRITATION
toluene-4-sulfonic acid
Oral (Rat) LD50: 2480 mg/kg[2] Eye: adverse effect observed (irreversible damage)[1]
monohydrate
Skin: adverse effect observed (corrosive)[1]

TOXICITY IRRITATION
water
Oral (Rat) LD50: >90000 mg/kg[2] Not Available

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2. Value obtained from manufacturer's SDS.
Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances

for acid mists, aerosols, vapours

Data from assays for genotoxic activity in vitro suggest that eukaryotic cells are susceptible to genetic damage when the pH falls
to about 6.5. Cells from the respiratory tract have not been examined in this respect. Mucous secretion may protect the cells of
the airways from direct exposure to inhaled acidic mists, just as mucous plays an important role in protecting the gastric
INDICATOR FOR TRO epithelium from its auto-secreted hydrochloric acid. ln considering whether pH itself induces genotoxic events in vivo in the
CALIBRATION KIT respiratory system, comparison should be made with the human stomach, in which gastric juice may be at pH 1-2 under fasting
or nocturnal conditions, and with the human urinary bladder, in which the pH of urine can range from <5 to > 7 and normally
averages 6.2. Furthermore, exposures to low pH in vivo differ from exposures in vitro in that, in vivo, only a portion of the cell
surface is subjected to the adverse conditions, so that perturbation of intracellular homeostasis may be maintained more readily
than in vitro.
TOLUENE-4-SULFONIC
ACID MONOHYDRATE The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to
irritants may produce conjunctivitis.
The material may produce respiratory tract irritation. Symptoms of pulmonary irritation may include coughing, wheezing,
laryngitis, shortness of breath, headache, nausea, and a burning sensation.
Unlike most organs, the lung can respond to a chemical insult or a chemical agent, by first removing or neutralising the irritant
and then repairing the damage (inflammation of the lungs may be a consequence).

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INDICATOR FOR TRO CALIBRATION KIT

The repair process (which initially developed to protect mammalian lungs from foreign matter and antigens) may, however, cause
further damage to the lungs (fibrosis for example) when activated by hazardous chemicals. Often, this results in an impairment of
gas exchange, the primary function of the lungs. Therefore prolonged exposure to respiratory irritants may cause sustained
breathing difficulties.

The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic).
This form of dermatitis is often characterised by skin redness (erythema) and swelling the epidermis. Histologically there may be
intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of the epidermis.
WATER No significant acute toxicological data identified in literature search.
Asthma-like symptoms may continue for months or even years after exposure to the material ends. This may be due to a non-
allergic condition known as reactive airways dysfunction syndrome (RADS) which can occur after exposure to high levels of
highly irritating compound. Main criteria for diagnosing RADS include the absence of previous airways disease in a non-atopic
INDICATOR FOR TRO individual, with sudden onset of persistent asthma-like symptoms within minutes to hours of a documented exposure to the
CALIBRATION KIT & irritant. Other criteria for diagnosis of RADS include a reversible airflow pattern on lung function tests, moderate to severe
TOLUENE-4-SULFONIC bronchial hyperreactivity on methacholine challenge testing, and the lack of minimal lymphocytic inflammation, without
ACID MONOHYDRATE eosinophilia. RADS (or asthma) following an irritating inhalation is an infrequent disorder with rates related to the concentration of
and duration of exposure to the irritating substance. On the other hand, industrial bronchitis is a disorder that occurs as a result
of exposure due to high concentrations of irritating substance (often particles) and is completely reversible after exposure
ceases. The disorder is characterized by difficulty breathing, cough and mucus production.

Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity
Serious Eye
STOT - Single Exposure
Damage/Irritation
Respiratory or Skin
STOT - Repeated Exposure
sensitisation

Mutagenicity Aspiration Hazard

Legend: – Data either not available or does not fill the criteria for classification
– Data available to make classification

11.2 Information on other hazards

11.2.1. Endocrine disrupting properties

No evidence of endocrine disrupting properties were found in the current literature.

11.2.2. Other information

See Section 11.1

SECTION 12 Ecological information

12.1. Toxicity

Endpoint Test Duration (hr) Species Value Source

INDICATOR FOR TRO
CALIBRATION KIT Not Not Not
Not Available Not Available
Available Available Available

Endpoint Test Duration (hr) Species Value Source

EC50 72h Algae or other aquatic plants 70mg/l 2

toluene-4-sulfonic acid NOEC(ECx) 72h Algae or other aquatic plants 40mg/l 2

monohydrate EC50 48h Crustacea >=40.3mg/l 2

LC50 96h Fish >=128mg/l 2

EC50 96h Algae or other aquatic plants >=230mg/l 2

Endpoint Test Duration (hr) Species Value Source

water Not Not Not
Not Available Not Available
Available Available Available

Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity
4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) -
Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data

Ecotoxicity:
The tolerance of water organisms towards pH margin and variation is diverse. Recommended pH values for test species listed in OECD guidelines are between
6.0 and almost 9. Acute testing with fish showed 96h-LC50 at about pH 3.5
Prevent, by any means available, spillage from entering drains or water courses.
DO NOT discharge into sewer or waterways.

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12.2. Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air

toluene-4-sulfonic acid
HIGH HIGH
monohydrate
water LOW LOW

12.3. Bioaccumulative potential

Ingredient Bioaccumulation

toluene-4-sulfonic acid
LOW (LogKOW = -0.6177)
monohydrate

12.4. Mobility in soil

Ingredient Mobility
toluene-4-sulfonic acid
LOW (Log KOC = 19.12)
monohydrate

12.5. Results of PBT and vPvB assessment

P B T
Relevant available data Not Available Not Available Not Available

PBT
vPvB

PBT Criteria fulfilled? No

vPvB No

12.6. Endocrine disrupting properties

No evidence of endocrine disrupting properties were found in the current literature.

12.7. Other adverse effects

No evidence of ozone depleting properties were found in the current literature.

SECTION 13 Disposal considerations

13.1. Waste treatment methods

Containers may still present a chemical hazard/ danger when empty.
Return to supplier for reuse/ recycling if possible.
Otherwise:
If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to
store the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill.
Where possible retain label warnings and SDS and observe all notices pertaining to the product.
DO NOT allow wash water from cleaning or process equipment to enter drains.
It may be necessary to collect all wash water for treatment before disposal.
Product / Packaging In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.
disposal Where in doubt contact the responsible authority.
Recycle wherever possible.
Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable
treatment or disposal facility can be identified.
Treat and neutralise at an approved treatment plant. Treatment should involve: Neutralisation with soda-ash or soda-lime
followed by: burial in a land-fill specifically licensed to accept chemical and / or pharmaceutical wastes or Incineration in a
licensed apparatus (after admixture with suitable combustible material).
Decontaminate empty containers with 5% aqueous sodium hydroxide or soda ash, followed by water. Observe all label
safeguards until containers are cleaned and destroyed.
Waste treatment options Not Available

Sewage disposal options Not Available

SECTION 14 Transport information

Labels Required

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INDICATOR FOR TRO CALIBRATION KIT

Marine Pollutant NO

Land transport (ADR-RID)

14.1. UN number or ID
2586
number
14.2. UN proper shipping ARYLSULPHONIC ACIDS, LIQUID,WITH 5% OR LESS FREE SULPHURIC ACID (contains toluene-4-sulfonic acid
name monohydrate)

14.3. Transport hazard Class 8

class(es) Subsidiary Hazard Not Applicable

14.4. Packing group III

14.5. Environmental
Not Applicable
hazard

Hazard identification (Kemler) 80

Classification code C3

14.6. Special precautions Hazard Label 8

for user Special provisions Not Applicable

Limited quantity 5L

Tunnel Restriction Code E

Air transport (ICAO-IATA / DGR)

14.1. UN number 2586
14.2. UN proper shipping ARYLSULPHONIC ACIDS, LIQUID,WITH 5% OR LESS FREE SULPHURIC ACID (contains toluene-4-sulfonic acid
name monohydrate)

ICAO/IATA Class 8
14.3. Transport hazard
ICAO / IATA Subsidiary Hazard Not Applicable
class(es)
ERG Code 8L

14.4. Packing group III

14.5. Environmental
Not Applicable
hazard

Special provisions A803

Cargo Only Packing Instructions 856

Cargo Only Maximum Qty / Pack 60 L

14.6. Special precautions
Passenger and Cargo Packing Instructions 852
for user
Passenger and Cargo Maximum Qty / Pack 5L
Passenger and Cargo Limited Quantity Packing Instructions Y841

Passenger and Cargo Limited Maximum Qty / Pack 1L

Sea transport (IMDG-Code / GGVSee)

14.1. UN number 2586

14.2. UN proper shipping ARYLSULPHONIC ACIDS, LIQUID,WITH 5% OR LESS FREE SULPHURIC ACID (contains toluene-4-sulfonic acid
name monohydrate)

14.3. Transport hazard IMDG Class 8

class(es) IMDG Subsidiary Hazard Not Applicable

14.4. Packing group III

14.5 Environmental hazard Not Applicable

14.6. Special precautions
EMS Number F-A , S-B
for user
Special provisions Not Applicable

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INDICATOR FOR TRO CALIBRATION KIT

Limited Quantities 5L

Inland waterways transport (ADN)

14.1. UN number 2586

14.2. UN proper shipping ARYLSULPHONIC ACIDS, LIQUID,WITH 5% OR LESS FREE SULPHURIC ACID (contains toluene-4-sulfonic acid
name monohydrate)
14.3. Transport hazard
8 Not Applicable
class(es)

14.4. Packing group III

14.5. Environmental
Not Applicable
hazard

Classification code C3
Special provisions Not Applicable
14.6. Special precautions
Limited quantity 5L
for user
Equipment required PP, EP

Fire cones number 0

14.7. Maritime transport in bulk according to IMO instruments

14.7.1. Transport in bulk according to Annex II of MARPOL and the IBC code
Not Applicable

14.7.2. Transport in bulk in accordance with MARPOL Annex V and the IMSBC Code
Product name Group
toluene-4-sulfonic acid
Not Available
monohydrate

water Not Available

14.7.3. Transport in bulk in accordance with the IGC Code

Product name Ship Type

toluene-4-sulfonic acid
Not Available
monohydrate
water Not Available

SECTION 15 Regulatory information

15.1. Safety, health and environmental regulations / legislation specific for the substance or mixture

toluene-4-sulfonic acid monohydrate is found on the following regulatory lists

Europe EC Inventory
European Union - European Inventory of Existing Commercial Chemical Substances (EINECS)
European Union (EU) Regulation (EC) No 1272/2008 on Classification, Labelling and Packaging of Substances and Mixtures - Annex VI

water is found on the following regulatory lists

Europe EC Inventory
European Union - European Inventory of Existing Commercial Chemical Substances (EINECS)

Additional Regulatory Information

Not Applicable

This safety data sheet is in compliance with the following EU legislation and its adaptations - as far as applicable - : Directives 98/24/EC, - 92/85/EEC, - 94/33/EC,
- 2008/98/EC, - 2010/75/EU; Commission Regulation (EU) 2020/878; Regulation (EC) No 1272/2008 as updated through ATPs.

Information according to 2012/18/EU (Seveso III):

Seveso Category Not Available

15.2. Chemical safety assessment

No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

Continued...
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National Inventory Status

National Inventory Status

Australia - AIIC / Australia

Yes
Non-Industrial Use

Canada - DSL Yes

Canada - NDSL No (toluene-4-sulfonic acid monohydrate; water)

China - IECSC Yes

Europe - EINEC / ELINCS /

Yes
NLP

Japan - ENCS Yes

Korea - KECI Yes

New Zealand - NZIoC Yes

Philippines - PICCS Yes

USA - TSCA Yes

Taiwan - TCSI Yes

Mexico - INSQ Yes

Vietnam - NCI Yes

Russia - FBEPH Yes

Yes = All CAS declared ingredients are on the inventory

Legend: No = One or more of the CAS listed ingredients are not on the inventory. These ingredients may be exempt or will require
registration.

SECTION 16 Other information

Revision Date 29/09/2023

Initial Date 10/03/2021

CONTACT POINT
- For quotations contact your local Customer Services - https://wssdirectory.wilhelmsen.com/#/customerservices - - Responsible for safety data sheet Wilhelmsen
Ships Service AS - Prepared by: Compliance Manager, - Email: Email: wss.global.sdsinfo@wilhelmsen.com - Telephone: Tel.: +47 67584000

Full text Risk and Hazard codes

H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.

H318 Causes serious eye damage.

SDS Version Summary

Version Date of Update Sections Updated

2.13 29/09/2023 Hazards identification - Classification

Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch
Classification committee using available literature references.

The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks
in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available
engineering controls must be considered.

For detailed advice on Personal Protective Equipment, refer to the following EU CEN Standards:
EN 166 Personal eye-protection
EN 340 Protective clothing
EN 374 Protective gloves against chemicals and micro-organisms
EN 13832 Footwear protecting against chemicals
EN 133 Respiratory protective devices

Definitions and abbreviations

PC TWA: Permissible Concentration-Time Weighted Average
PC STEL: Permissible Concentration-Short Term Exposure Limit
IARC: International Agency for Research on Cancer
ACGIH: American Conference of Governmental Industrial Hygienists
STEL: Short Term Exposure Limit
TEEL: Temporary Emergency Exposure Limit

Continued...
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IDLH: Immediately Dangerous to Life or Health Concentrations

ES: Exposure Standard
OSF: Odour Safety Factor
NOAEL: No Observed Adverse Effect Level
LOAEL: Lowest Observed Adverse Effect Level
TLV: Threshold Limit Value
LOD: Limit Of Detection
OTV: Odour Threshold Value
BCF: BioConcentration Factors
BEI: Biological Exposure Index
DNEL: Derived No-Effect Level
PNEC: Predicted no-effect concentration

AIIC: Australian Inventory of Industrial Chemicals

DSL: Domestic Substances List
NDSL: Non-Domestic Substances List
IECSC: Inventory of Existing Chemical Substance in China
EINECS: European INventory of Existing Commercial chemical Substances
ELINCS: European List of Notified Chemical Substances
NLP: No-Longer Polymers
ENCS: Existing and New Chemical Substances Inventory
KECI: Korea Existing Chemicals Inventory
NZIoC: New Zealand Inventory of Chemicals
PICCS: Philippine Inventory of Chemicals and Chemical Substances
TSCA: Toxic Substances Control Act
TCSI: Taiwan Chemical Substance Inventory
INSQ: Inventario Nacional de Sustancias Químicas
NCI: National Chemical Inventory
FBEPH: Russian Register of Potentially Hazardous Chemical and Biological Substances

Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP]
Classification according to
regulation (EC) No
Classification Procedure
1272/2008 [CLP] and
amendments

Acute Toxicity (Oral)

Expert judgement
Category 4, H302

Acute Toxicity (Dermal)

Expert judgement
Category 4, H312
Skin Corrosion/Irritation
Expert judgement
Category 2, H315

Serious Eye Damage/Eye

Expert judgement
Irritation Category 2, H319

Acute Toxicity (Inhalation)

Expert judgement
Category 4, H332
Specific Target Organ
Toxicity - Single Exposure
Expert judgement
(Respiratory Tract Irritation)
Category 3 , H335

Carcinogenicity Category 1A,

Calculation method
H350i

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end of SDS