Nitobond EP SDS2

Revision date: 07/09/2020 Revision: 5c Supersedes date: 07/10/2019
SAFETY DATA SHEET

NITOBOND EP BASE
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier

Product name NITOBOND EP BASE
Product number A1711113UK9, A1711115UK9, A1711391UK9
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Base Component of Two-Part Epoxy Bonding System
1.3. Details of the supplier of the safety data sheet

Supplier Fosroc International Limited
Drayton Manor Business Park
Coleshill Road
Tamworth
Staffordshire
B78 3XN
England
Tel: +44 (0) 1827 262222
Fax: +44 (0) 1827 262444
enquiryuk@fosroc.com
1.4. Emergency telephone number

Emergency telephone +44 (0) 1827 265 279 (Monday-Sunday 24 hours a day)
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified
Health hazards Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Skin Sens. 1 - H317
Environmental hazards Aquatic Chronic 2 - H411
Human health May cause skin sensitisation or allergic reactions in sensitive individuals.
Environmental The product contains a substance which is toxic to aquatic organisms and which may cause
long-term adverse effects in the aquatic environment.
2.2. Label elements
Hazard pictograms
Signal word Warning
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NITOBOND EP BASE
Hazard statements H315 Causes skin irritation.

H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statements P273 Avoid release to the environment.

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P302+P352 IF ON SKIN: Wash with plenty of water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P501 Dispose of contents/ container in accordance with national regulations.
Contains bis[4-(2,3-EPOXYPROPOXY)PHENYL]PROPANE, Formaldehyde, oligomeric reaction

products with 1-chloro-2,3-epoxypropane and phenol
Supplementary precautionary P261 Avoid breathing vapour/ spray.

statements P264 Wash contaminated skin thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P321 Specific treatment (see medical advice on this label).
P332+P313 If skin irritation occurs: Get medical advice/ attention.
P333+P313 If skin irritation or rash occurs: Get medical advice/ attention.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage.
2.3. Other hazards

This substance is not classified as PBT or vPvB according to current EU criteria.
SECTION 3: Composition/information on ingredients
3.2. Mixtures
bis[4-(2,3-EPOXYPROPOXY)PHENYL]PROPANE 60-100%
CAS number: 1675-54-3 EC number: 216-823-5
Classification
Skin Irrit. 2 - H315
Eye Irrit. 2 - H319
Skin Sens. 1 - H317
Aquatic Chronic 2 - H411
Formaldehyde, oligomeric reaction products with 1-chloro- 10-30%

2,3-epoxypropane and phenol
Classification
Skin Sens. 1 - H317
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NITOBOND EP BASE
DI-ISO-DECYL PHTHALATE 5-10%

Classification
Not Classified
TITANIUM DIOXIDE 5-10%

CAS number: 13463-67-7 EC number: 236-675-5 REACH registration number: 01-
2119489379-17-XXXX
Classification
Not Classified
CALCIUM CARBONATE (STEARATE COATED) 5-10%

Classification Classification (67/548/EEC or 1999/45/EC)

Not Classified -
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
SECTION 4: First aid measures
4.1. Description of first aid measures

Inhalation Move affected person to fresh air at once. Rinse nose and mouth with water. Get medical
attention if any discomfort continues.
Ingestion Remove affected person from source of contamination. Move affected person to fresh air and
keep warm and at rest in a position comfortable for breathing. Rinse mouth thoroughly with
water. Give plenty of water to drink. Keep affected person under observation. Get medical
attention if any discomfort continues. Show this Safety Data Sheet to the medical personnel.
Skin contact Remove affected person from source of contamination. Remove contaminated clothing. Wash
skin thoroughly with soap and water. Get medical attention if irritation persists after washing.
Eye contact Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do.
Continue rinsing. Continue to rinse for at least 10 minutes. Remove affected person from
source of contamination.
4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.
Inhalation May cause respiratory system irritation.
Ingestion May cause discomfort if swallowed.
Skin contact Skin irritation. May cause sensitisation or allergic reactions in sensitive individuals.
Eye contact Irritation of eyes and mucous membranes.
4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
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NITOBOND EP BASE
Suitable extinguishing media Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog.
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
5.2. Special hazards arising from the substance or mixture

Specific hazards No unusual fire or explosion hazards noted.
Hazardous combustion Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or
products vapours.
5.3. Advice for firefighters

Protective actions during No specific firefighting precautions known. Control run-off water by containing and keeping it
firefighting out of sewers and watercourses.
Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet.
6.2. Environmental precautions

Environmental precautions Avoid discharge into drains or watercourses or onto the ground. Spillages or uncontrolled
discharges into watercourses must be reported immediately to the Environmental Agency or
other appropriate regulatory body.
6.3. Methods and material for containment and cleaning up

Methods for cleaning up Absorb in vermiculite, dry sand or earth and place into containers. Flush contaminated area
with plenty of water. Avoid the spillage or runoff entering drains, sewers or watercourses.
6.4. Reference to other sections

Reference to other sections For waste disposal, see section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling

Usage precautions For professional users only. Provide adequate ventilation. Avoid the formation of mists. Avoid
inhalation of vapours/spray and contact with skin and eyes.
7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place. Keep only in
the original container.
Storage class Chemical storage.
7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.
SECTION 8: Exposure controls/Personal protection
8.1. Control parameters

Occupational exposure limits
DI-ISO-DECYL PHTHALATE
Long-term exposure limit (8-hour TWA): WEL 5 mg/m³
TITANIUM DIOXIDE
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NITOBOND EP BASE
Long-term exposure limit (8-hour TWA): WEL 10 mg/m³ inhalable dust

Long-term exposure limit (8-hour TWA): WEL 4 mg/m³ respirable dust
CALCIUM CARBONATE (STEARATE COATED)
Long-term exposure limit (8-hour TWA): WEL 10 mg/m3 Inhal. Dust 4 mg/m3 Resp. Dust
WEL = Workplace Exposure Limit
Ingredient comments WEL = Workplace Exposure Limits
Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol (CAS: 9003-36-5)
DNEL Workers - Inhalation; Long term systemic effects: 29.39 mg/m³

Workers - Dermal; Long term systemic effects: 104.15 mg/kg/day
Workers - Dermal; Short term local effects: 8.3 µg/cm2
PNEC - Fresh water; 0.003 mg/l

- marine water; 0.0003 mg/l
- STP; 10 mg/l
TITANIUM DIOXIDE (CAS: 13463-67-7)
DNEL Industry - Inhalation; Long term local effects: 10 mg/m³

Consumer - Oral; Long term systemic effects: 700 mg/kg/day
PNEC - Fresh water; 0.127 mg/l

- Sediment (Freshwater); >=1000 mg/kg
- marine water; 1 mg/l
- Sediment (Marinewater); >= 100 mg/kg
- Soil; 100 mg/kg
- STP; 100 mg/l
8.2. Exposure controls
Protective equipment
Appropriate engineering Provide adequate ventilation. Avoid inhalation of vapours. Observe any occupational
controls exposure limits for the product or ingredients.
Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicates
eye contact is possible. The following protection should be worn: Chemical splash goggles or
face shield.
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn if
a risk assessment indicates skin contact is possible. The most suitable glove should be
chosen in consultation with the glove supplier/manufacturer, who can provide information
about the breakthrough time of the glove material. Wear protective gloves made of the
following material: Butyl rubber. Nitrile rubber. Polyvinyl chloride (PVC).
Other skin and body Wear appropriate clothing to prevent any possibility of skin contact. Wear apron or protective
protection clothing in case of contact.
Hygiene measures Wash at the end of each work shift and before eating, smoking and using the toilet. Wash
promptly if skin becomes contaminated. Promptly remove any clothing that becomes
contaminated. Do not eat, drink or smoke when using this product. Do not smoke in work
area.
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NITOBOND EP BASE
Respiratory protection No specific recommendations. Respiratory protection may be required if excessive airborne
contamination occurs.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties

Appearance Viscous liquid.
Colour White.
Odour Mild.
Odour threshold Not determined.
pH Not determined.
Melting point Not determined.
Initial boiling point and range Not determined.
Flash point >150°C Closed cup.
Evaporation rate Not determined.
Evaporation factor Not determined.
Flammability (solid, gas) Not applicable.
Upper/lower flammability or Not determined.

explosive limits
Other flammability Not applicable.
Vapour pressure <0.1 kPa @ 20°C
Vapour density Not determined.
Relative density 1.12 @ at 20°C
Bulk density Not applicable.
Solubility(ies) Insoluble in water.
Partition coefficient Not applicable.
Auto-ignition temperature Not determined.
Decomposition Temperature Not determined.
Viscosity Not determined.
Explosive properties Not considered to be explosive.
Explosive under the influence Not considered to be explosive.

of a flame
Oxidising properties Does not meet the criteria for classification as oxidising.
9.2. Other information

Other information No data available.
SECTION 10: Stability and reactivity
10.1. Reactivity
Reactivity The reactivity data for this product will be typical of those for the following class of materials:
Epoxides.
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NITOBOND EP BASE
10.2. Chemical stability

Stability Stable at normal ambient temperatures.
10.3. Possibility of hazardous reactions

Possibility of hazardous Reacts with substances which contain active hydrogen.
reactions
10.4. Conditions to avoid

Conditions to avoid Avoid excessive heat for prolonged periods of time.
10.5. Incompatible materials

Materials to avoid Strong acids. Strong alkalis. Strong oxidising agents.
10.6. Hazardous decomposition products

Hazardous decomposition When heated, vapours/gases hazardous to health may be formed. Oxides of carbon.
products
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Inhalation Gas or vapour may irritate the respiratory system.
Ingestion May cause discomfort if swallowed.
Skin contact Irritating to skin. May cause sensitisation by skin contact.
Eye contact Irritating to eyes.
Route of exposure Skin and/or eye contact
SECTION 12: Ecological information
Ecotoxicity Dangerous for the environment. May cause long-term adverse effects in the aquatic
environment.
12.1. Toxicity
Toxicity Ecotoxic to fish / daphnia / algae
12.2. Persistence and degradability

Persistence and degradability The product is not expected to be biodegradable.
12.3. Bioaccumulative potential

Bioaccumulative potential The product contains potentially bioaccumulating substances.
Partition coefficient Not applicable.
12.4. Mobility in soil

Mobility The product is immiscible with water and will sediment in water systems.
12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment
12.6. Other adverse effects

Other adverse effects None known.
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NITOBOND EP BASE
SECTION 13: Disposal considerations
13.1. Waste treatment methods

General information Waste is classified as hazardous waste.
Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.
SECTION 14: Transport information
14.1. UN number
UN No. (ADR/RID) 3082
UN No. (IMDG) 3082
UN No. (ICAO) 3082
UN No. (ADN) 3082
14.2. UN proper shipping name

Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS bis[4-(2,3-
(ADR/RID) EPOXYPROPOXY)PHENYL]PROPANE, EPOXY RESIN (Type F) (Number average MW <=
700 ))
Proper shipping name (IMDG) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS bis[4-(2,3-
EPOXYPROPOXY)PHENYL]PROPANE, EPOXY RESIN (Type F) (Number average MW <=
700 ))
Proper shipping name (ICAO) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS bis[4-(2,3-
700 ))
Proper shipping name (ADN) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS bis[4-(2,3-
700 ))
14.3. Transport hazard class(es)

ADR/RID class 9
ADR/RID classification code M6
ADR/RID label 9
IMDG class 9
ICAO class/division 9
ADN class 9
Transport labels
14.4. Packing group

ADR/RID packing group III
IMDG packing group III
ICAO packing group III
ADN packing group III
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NITOBOND EP BASE
14.5. Environmental hazards
Environmentally hazardous substance/marine pollutant
14.6. Special precautions for user

EmS F-A, S-F
ADR transport category 3
Emergency Action Code •3Z
Hazard Identification Number 90

(ADR/RID)
Tunnel restriction code (-)
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations The Control of Substances Hazardous to Health Regulations 2002 (SI 2002 No. 2677) (as
amended).
EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).
Commission Regulation (EU) No 2015/830 of 28 May 2015.
Guidance Workplace Exposure Limits EH40.

Respiratory protective equipment at work (HSG53).
15.2. Chemical safety assessment

No chemical safety assessment has been carried out.
SECTION 16: Other information
General information The user must be instructed in the proper work procedure and be familiar with the contents of
these instructions.
Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision.
Revision date 07/09/2020
Revision 5c
Supersedes date 07/10/2019
SDS number 12436
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NITOBOND EP BASE
Hazard statements in full H315 Causes skin irritation.

The information on this data sheet represents our current data and is reliable provided that the product is used under the
prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance
literature. Any other use of the product which involves using the product in combination with any other product or any other
process is the responsibility of the user.
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Revision date: 14/12/2022 Revision: 6 Supersedes date: 07/10/2019
SAFETY DATA SHEET

NITOBOND EP HARDENER
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier

Product name NITOBOND EP HARDENER
Product number A1711114UK9, A1711116UK9, A1711392UK9
UFI UFI: 5G50-Q0UW-F00K-DY8H
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Hardener Component of Two-Part Epoxy Bonding System
1.3. Details of the supplier of the safety data sheet

Supplier Fosroc International Limited
Drayton Manor Business Park
Coleshill Road
Tamworth
Staffordshire
B78 3XN
England
Tel: +44 (0) 1827 262222
Fax: +44 (0) 1827 262444
enquiryuk@fosroc.com
1.4. Emergency telephone number

Emergency telephone +44 (0) 1827 265 279 (Monday-Sunday 24 hours a day)
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture

Classification (SI 2019 No. 720)
Physical hazards Not Classified
Health hazards Skin Corr. 1B - H314 Eye Dam. 1 - H318 Skin Sens. 1 - H317
Environmental hazards Aquatic Chronic 2 - H411
Environmental The product contains a substance which is harmful to aquatic organisms and which may
cause long-term adverse effects in the aquatic environment.
2.2. Label elements
Hazard pictograms
Signal word Danger
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Hazard statements H314 Causes severe skin burns and eye damage.
Precautionary statements P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water or shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P501 Dispose of contents/ container in accordance with national regulations.
Contains POLYMER OF C-18 UNSATURATED FATTY ACID DIMER WITH

TRIETHYLENETETRAMINE & TALL OIL FATTY ACIDS, N'-(3AMINOPROPYL)-N,N-
DIMETHYLPROPANE-1,3-DIAMINE, 3-AMINOPROPYLTRIETHOXYSILANE
Supplementary precautionary P260 Do not breathe vapour/ spray.

statements P261 Avoid breathing vapour/ spray.
P264 Wash contaminated skin thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P302+P352 IF ON SKIN: Wash with plenty of water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P310 Immediately call a POISON CENTER/ doctor.
P321 Specific treatment (see medical advice on this label).
P333+P313 If skin irritation or rash occurs: Get medical advice/ attention.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P363 Wash contaminated clothing before reuse.
P405 Store locked up.
2.3. Other hazards

This substance is not classified as PBT or vPvB according to current UK criteria.
SECTION 3: Composition/information on ingredients
3.2. Mixtures
POLYMER OF C-18 UNSATURATED FATTY ACID DIMER 50-100%

WITH TRIETHYLENETETRAMINE & TALL OIL FATTY
ACIDS
Classification
Eye Irrit. 2 - H319
Skin Sens. 1 - H317
BENZYL ALCOHOL 10-30%

Classification
Acute Tox. 4 - H302
Acute Tox. 4 - H332
Eye Irrit. 2 - H319
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N'-(3AMINOPROPYL)-N,N-DIMETHYLPROPANE-1,3- 5-10%
DIAMINE
Classification
Acute Tox. 4 - H302
Acute Tox. 4 - H312
Skin Corr. 1B - H314
Eye Dam. 1 - H318
Skin Sens. 1 - H317
3-AMINOPROPYLTRIETHOXYSILANE 1-5%
Classification
Acute Tox. 4 - H302
Skin Corr. 1B - H314
Eye Dam. 1 - H318
Skin Sens. 1 - H317
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
SECTION 4: First aid measures
4.1. Description of first aid measures

Inhalation Move affected person to fresh air at once. Rinse nose and mouth with water. Get medical
attention if any discomfort continues.
Ingestion Do not induce vomiting. Never give anything by mouth to an unconscious person. Do not
induce vomiting. Rinse mouth thoroughly with water. Give plenty of water to drink. Move
affected person to fresh air and keep warm and at rest in a position comfortable for breathing.
Get medical attention immediately.
Skin contact Remove affected person from source of contamination. Remove contaminated clothing
immediately and wash skin with soap and water. Get medical attention promptly if symptoms
occur after washing.
Eye contact Remove affected person from source of contamination. Remove any contact lenses and open
eyelids wide apart. Continue to rinse for at least 15 minutes and get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.
Inhalation Upper respiratory irritation. Coughing, chest tightness, feeling of chest pressure.
Ingestion May cause chemical burns in mouth and throat. May cause stomach pain or vomiting.
Skin contact Chemical burns.
Eye contact Irritation, burning, lachrymation, blurred vision after liquid splash.
4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.
SECTION 5: Firefighting measures
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5.1. Extinguishing media

Suitable extinguishing media Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog.
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
5.2. Special hazards arising from the substance or mixture

Specific hazards No unusual fire or explosion hazards noted.
Hazardous combustion Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or
products vapours. Oxides of nitrogen.
5.3. Advice for firefighters

Protective actions during Containers close to fire should be removed or cooled with water.
firefighting
Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Wear suitable protective equipment, including gloves, goggles/face shield, respirator, boots,
clothing or apron, as appropriate. Do not breathe vapour.
6.2. Environmental precautions

Environmental precautions Do not discharge into drains or watercourses or onto the ground. Contain spillage with sand,
earth or other suitable non-combustible material.
6.3. Methods and material for containment and cleaning up

Methods for cleaning up Wear suitable protective equipment, including gloves, goggles/face shield, respirator, boots,
clothing or apron, as appropriate. Stop leak if possible without risk. Absorb in vermiculite, dry
sand or earth and place into containers. Avoid contamination of ponds or watercourses with
washing down water.
6.4. Reference to other sections

Reference to other sections For personal protection, see Section 8. For waste disposal, see section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling

Usage precautions Provide adequate ventilation. Avoid contact with skin and eyes. Avoid the formation of mists.
Do not use in confined spaces without adequate ventilation and/or respirator.
7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place. Keep only in
the original container.
Storage class Corrosive storage.
7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.
SECTION 8: Exposure controls/Personal protection
8.1. Control parameters
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BENZYL ALCOHOL (CAS: 100-51-6)
DNEL Workers - Inhalation; Short term systemic effects: 110 mg/m³

Workers - Inhalation; Long term systemic effects: 22 mg/m³
Workers - Dermal; Short term systemic effects: 40 mg/kg bw/day
Workers - Dermal; Long term systemic effects: 8 mg/kg bw/day
PNEC - Fresh water; 1 mg/l

- marine water; 0.1 mg/l
- STP; 39 mg/l
N'-(3AMINOPROPYL)-N,N-DIMETHYLPROPANE-1,3-DIAMINE (CAS: 10563-29-8)
DNEL Workers - Inhalation; Long term local effects, systemic effects: 3.7 mg/m³
Workers - Inhalation; Long term local effects, systemic effects: 7.5 mg/m³
Workers - Dermal; Long term systemic effects: 0.67 mg/kg/day
PNEC - Fresh water; 9.2 µg/l

- marine water; 0.92 µg/l
- STP; 18.1 mg/l
8.2. Exposure controls
Protective equipment
Appropriate engineering Provide adequate general and local exhaust ventilation.

controls
Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicates
eye contact is possible. The following protection should be worn: Chemical splash goggles.
Hand protection The most suitable glove should be chosen in consultation with the glove
supplier/manufacturer, who can provide information about the breakthrough time of the glove
material. Wear protective gloves made of the following material: Nitrile rubber. Viton rubber
(fluoro rubber). Polyvinylidene chloride/polyethylene (PVDC/PE).
Other skin and body Wear apron or protective clothing in case of contact.
protection
Hygiene measures Provide eyewash station and safety shower. Wash at the end of each work shift and before
eating, smoking and using the toilet. Wash promptly with soap and water if skin becomes
contaminated. Promptly remove any clothing that becomes wet or contaminated.
Respiratory protection If ventilation is inadequate, suitable respiratory protection must be worn. In confined or poorly-
ventilated spaces, a supplied-air respirator must be worn. Gas filter, type A2.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties

Appearance Liquid.
Colour Green.
Odour Amine.
Odour threshold Not determined.
pH Not determined.
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Melting point Not determined.
Initial boiling point and range > 200°C @ 1 atm
Flash point 130°C
Evaporation factor Not determined.
Flammability (solid, gas) Not applicable.
Upper/lower flammability or Upper flammable/explosive limit: 13% Lower flammable/explosive limit: 1.3%
explosive limits
Other flammability Not determined.
Vapour pressure 0.01 kPa @ 20°C
Vapour density Not determined.
Relative density 1.15 @ 20°C
Bulk density Not applicable.
Solubility(ies) Insoluble in water.
Partition coefficient Not determined.
Auto-ignition temperature 335°C
Decomposition Temperature Not determined.
Viscosity Not determined.
Explosive properties Not considered to be explosive.
Explosive under the influence Not considered to be explosive.

of a flame
Oxidising properties Does not meet the criteria for classification as oxidising.
9.2. Other information

Other information No data available.
SECTION 10: Stability and reactivity
10.1. Reactivity
Reactivity There are no known reactivity hazards associated with this product.
10.2. Chemical stability

Stability Stable at normal ambient temperatures.
10.3. Possibility of hazardous reactions

Possibility of hazardous Not determined. Will not polymerise.
reactions
10.4. Conditions to avoid

Conditions to avoid Avoid heat.
10.5. Incompatible materials

Materials to avoid Strong acids. Strong oxidising agents.
10.6. Hazardous decomposition products
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Hazardous decomposition Ammonia or amines. Thermal decomposition or combustion may liberate carbon oxides and
products other toxic gases or vapours. Oxides of nitrogen.
SECTION 11: Toxicological information
11.1. Information on toxicological effects

Acute toxicity - oral
ATE oral (mg/kg) 3,037.05
Acute toxicity - dermal

ATE dermal (mg/kg) 11,275.11
Acute toxicity - inhalation

ATE inhalation (vapours mg/l) 56.38
Inhalation May cause respiratory system irritation.
Ingestion Causes burns. May cause chemical burns in mouth and throat. May cause stomach pain or
vomiting.
Skin contact Product has a defatting effect on skin. May cause allergic contact eczema. May cause
sensitisation by skin contact. Causes burns. Harmful in contact with skin.
Eye contact Irritating to eyes. Symptoms following overexposure may include the following: Redness.
Pain. Risk of serious damage to eyes.
Acute and chronic health May cause sensitisation by skin contact.

hazards
Route of exposure Inhalation Ingestion. Skin and/or eye contact
Toxicological information on ingredients.
BENZYL ALCOHOL
Acute toxicity oral (LD₅₀ 1,620.0

mg/kg)
Species Rat
ATE oral (mg/kg) 1,620.0
Acute toxicity dermal (LD₅₀ 2,000.0

mg/kg)
Species Rabbit
ATE dermal (mg/kg) 2,001.0
Acute toxicity - inhalation
Acute toxicity inhalation 11.0

(LC₅₀ vapours mg/l)
Species Rat
ATE inhalation (vapours 11.0

mg/l)
Skin sensitisation
7/11
Skin sensitisation Not sensitising.
Carcinogenicity
Carcinogenicity NOAEL 200 mg/kg/day, Oral, Mouse There is no evidence that the product can
cause cancer.
Specific target organ toxicity - repeated exposure
STOT - repeated exposure NOAEL 400 mg/kg, Oral, Rat
Inhalation May cause coughing and difficulties in breathing.
Ingestion May cause burns in mucous membranes, throat, oesophagus and stomach.
Skin contact Prolonged and frequent contact may cause redness and irritation.
Eye contact Severe irritation, burning and tearing.
N'-(3AMINOPROPYL)-N,N-DIMETHYLPROPANE-1,3-DIAMINE
Notes (oral LD₅₀) LD₅₀ 1545 mg/kg, Oral, Rat
Notes (dermal LD₅₀) LD₅₀ 1310 mg/kg, Dermal, Rat
SECTION 12: Ecological information
Ecotoxicity The product contains a substance which is harmful to aquatic organisms and which may
cause long-term adverse effects in the aquatic environment.
12.1. Toxicity
Toxicity Ecotoxic to fish / daphnia / algae
Ecological information on ingredients.
BENZYL ALCOHOL
Acute aquatic toxicity
Acute toxicity - fish LC₅₀, 96 hours: 460 mg/l, Pimephales promelas (Fat-head Minnow)
LC₅₀, 96 hours: 10 mg/l, Lepomis macrochirus (Bluegill)
Acute toxicity - aquatic EC₈₀, 48 hours: 230 mg/l, Daphnia magna

invertebrates
Acute toxicity - aquatic EC₅₀, 72 hours: 770 mg/l, Pseudokirchneriella subcapitata

plants NOEC, 72 hours: 310 mg/l, Pseudokirchneriella subcapitata
Acute toxicity - LC₅₀, 49 hours: 2100 mg/l, Activated sludge

microorganisms
Acute aquatic toxicity
Acute toxicity - fish LC₈₀, 96 hours: >100 mg/l, Brachydanio rerio (Zebra Fish)
12.2. Persistence and degradability
8/11
Persistence and degradability There are no data on the degradability of this product. The product is not expected to be
biodegradable.
12.3. Bioaccumulative potential

Bioaccumulative potential No data available on bioaccumulation. Not expected to be bioaccumulative.
Partition coefficient Not determined.
12.4. Mobility in soil

Mobility The product is immiscible with water and will sediment in water systems.
12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment
Ecological information on ingredients.
Results of PBT and vPvB This substance is not classified as PBT or vPvB according to current UK criteria.
assessment
12.6. Other adverse effects

Other adverse effects None known.
SECTION 13: Disposal considerations
13.1. Waste treatment methods

General information Waste is classified as hazardous waste. Dispose of waste to licensed waste disposal site in
accordance with the requirements of the local Waste Disposal Authority.
Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority. Waste material and any included combustible absorbent and
containers should be suitable for incineration at an approved facility. Note that fully cured
material is not considered as hazardous waste.
SECTION 14: Transport information
14.1. UN number
UN No. (ADR/RID) 2735
UN No. (IMDG) 2735
UN No. (ICAO) 2735
UN No. (ADN) 2735
14.2. UN proper shipping name

Proper shipping name AMINES, LIQUID, CORROSIVE, N.O.S. (CONTAINS N'-(3AMINOPROPYL)-N,N-
(ADR/RID) DIMETHYLPROPANE-1,3-DIAMINE, POLYMER OF C-18 UNSATURATED FATTY ACID
DIMER WITH TRIETHYLENETETRAMINE & TALL OIL FATTY ACIDS)
Proper shipping name (IMDG) AMINES, LIQUID, CORROSIVE, N.O.S. (CONTAINS N'-(3AMINOPROPYL)-N,N-
DIMETHYLPROPANE-1,3-DIAMINE, POLYMER OF C-18 UNSATURATED FATTY ACID
Proper shipping name (ICAO) AMINES, LIQUID, CORROSIVE, N.O.S. (CONTAINS N'-(3AMINOPROPYL)-N,N-
9/11
Proper shipping name (ADN) AMINES, LIQUID, CORROSIVE, N.O.S. (CONTAINS N'-(3AMINOPROPYL)-N,N-
14.3. Transport hazard class(es)

ADR/RID class 8
ADR/RID classification code C7
ADR/RID label 8
IMDG class 8
ICAO class/division 8
ADN class 8
Transport labels
14.4. Packing group

ADR/RID packing group II
IMDG packing group II
ICAO packing group II
ADN packing group II
14.5. Environmental hazards
Environmentally hazardous substance/marine pollutant
14.6. Special precautions for user

IMDG Code segregation 18. Alkalis
group
EmS F-A, S-B
ADR transport category 2
Emergency Action Code 2X
Hazard Identification Number 80

(ADR/RID)
Tunnel restriction code (E)
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
10/11
National regulations Control of Substances Hazardous to Health Regulations 2002 (as amended).
Guidance Workplace Exposure Limits EH40.
15.2. Chemical safety assessment

No chemical safety assessment has been carried out.
SECTION 16: Other information
Abbreviations and acronyms DMEL: Derived Minimal Effect Level.

used in the safety data sheet DNEL: Derived No Effect Level.
EC₅₀: 50% of maximal Effective Concentration.
LC50: Lethal Concentration to 50 % of a test population.
LD50: Lethal Dose to 50% of a test population (Median Lethal Dose).
NOEC: No Observed Effect Concentration.
PBT: Persistent, Bioaccumulative and Toxic substance.
PNEC: Predicted No Effect Concentration.
SVHC: Substances of Very High Concern.
vPvB: Very Persistent and Very Bioaccumulative.
General information Only trained personnel should use this material. For professional users only.
Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision.
Revision date 14/12/2022
Revision 6
Supersedes date 07/10/2019
SDS number 12021
Hazard statements in full H302 Harmful if swallowed.

H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H332 Harmful if inhaled.
The information on this data sheet represents our current data and is reliable, provided that the product is used under the
prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance
literature. Any other use of the product which involves using the product in combination with any other product or any other
process is the responsibility of the user.
11/11

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Revision date: 07/09/2020 Revision: 5c Supersedes date: 07/10/2019

SAFETY DATA SHEET

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product number A1711113UK9, A1711115UK9, A1711391UK9

1.3. Details of the supplier of the safety data sheet

1.4. Emergency telephone number

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Environmental hazards Aquatic Chronic 2 - H411

2.2. Label elements

Signal word Warning

Hazard statements H315 Causes skin irritation.

Precautionary statements P273 Avoid release to the environment.

Contains bis[4-(2,3-EPOXYPROPOXY)PHENYL]PROPANE, Formaldehyde, oligomeric reaction

Supplementary precautionary P261 Avoid breathing vapour/ spray.

2.3. Other hazards

SECTION 3: Composition/information on ingredients

Formaldehyde, oligomeric reaction products with 1-chloro- 10-30%

DI-ISO-DECYL PHTHALATE 5-10%

TITANIUM DIOXIDE 5-10%

CALCIUM CARBONATE (STEARATE COATED) 5-10%

Classification Classification (67/548/EEC or 1999/45/EC)

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation May cause respiratory system irritation.

Ingestion May cause discomfort if swallowed.

Eye contact Irritation of eyes and mucous membranes.

SECTION 5: Firefighting measures

5.1. Extinguishing media

5.2. Special hazards arising from the substance or mixture

5.3. Advice for firefighters

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.2. Environmental precautions

6.3. Methods and material for containment and cleaning up

6.4. Reference to other sections

SECTION 7: Handling and storage

7.1. Precautions for safe handling

7.2. Conditions for safe storage, including any incompatibilities

Storage class Chemical storage.

7.3. Specific end use(s)

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

Long-term exposure limit (8-hour TWA): WEL 10 mg/m³ inhalable dust

Ingredient comments WEL = Workplace Exposure Limits

DNEL Workers - Inhalation; Long term systemic effects: 29.39 mg/m³

PNEC - Fresh water; 0.003 mg/l

TITANIUM DIOXIDE (CAS: 13463-67-7)

DNEL Industry - Inhalation; Long term local effects: 10 mg/m³

PNEC - Fresh water; 0.127 mg/l

8.2. Exposure controls

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Odour threshold Not determined.

Melting point Not determined.

Initial boiling point and range Not determined.

Flash point >150°C Closed cup.