Revision date: 17/04/2015 Revision: 25 Supersedes date: 27/02/2014

SAFETY DATA SHEET

KORROBOND 65 COMPONENT A

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name KORROBOND 65 COMPONENT A

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Crusher Backing Compound

1.3. Details of the supplier of the safety data sheet

Supplier ITW Engineered Polymers
Bay 150
Shannon Industrial Estate
Shannon
Co. Clare

+353 (0)61 471 299

+353 (0)61 471 285
mail@itwep.com

1.4. Emergency telephone number

Emergency telephone +44(0)1235 239 670 (24h)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification
Physical hazards Not Classified

Health hazards Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Skin Sens. 1 - H317

Environmental hazards Aquatic Chronic 3 - H412

Classification (67/548/EEC or Xi;R36/38. R43. R52/53.

1999/45/EC)

2.2. Label elements

Pictogram

Signal word Warning

Hazard statements H315 Causes skin irritation.

H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H412 Harmful to aquatic life with long lasting effects.

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KORROBOND 65 COMPONENT A

Precautionary statements P280 Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352 IF ON SKIN: Wash with plenty of water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P501 Dispose of contents/container in accordance with national regulations.

Contains EPOXY RESIN (Number average MW <= 700 ), BUTANEDIOLDIGLYCIDYL ETHER

Supplementary precautionary P261 Avoid breathing vapour/spray.

statements P264 Wash contaminated skin thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P321 Specific treatment (see medical advice on this label).
P332+P313 If skin irritation occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.

2.3. Other hazards

SECTION 3: Composition/information on ingredients

3.2. Mixtures

EPOXY RESIN (Number average MW <= 700 ) 10-30%

CAS number: 25068-38-6 EC number: 500-033-5 REACH registration number: 01-
2119456619-26-0000

Classification Classification (67/548/EEC or 1999/45/EC)

Skin Irrit. 2 - H315 R43 Xi;R36/38 N;R51/53
Eye Irrit. 2 - H319
Skin Sens. 1 - H317
Aquatic Chronic 2 - H411

BUTANEDIOLDIGLYCIDYL ETHER 1-5%

CAS number: 2425-79-8 EC number: 219-371-7

Classification Classification (67/548/EEC or 1999/45/EC)

Acute Tox. 4 - H312 Xn;R20/21 R43 Xi;R36/38
Acute Tox. 4 - H332
Skin Irrit. 2 - H315
Eye Irrit. 2 - H319
Skin Sens. 1 - H317

BENZYL ALCOHOL 1-5%

CAS number: 100-51-6 EC number: 202-859-9

Classification Classification (67/548/EEC or 1999/45/EC)

Acute Tox. 4 - H302 Xn;R20/22
Acute Tox. 4 - H332

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KORROBOND 65 COMPONENT A

2-METHOXY-1-METHYLETHYL ACETATE <1%

CAS number: 108-65-6 EC number: 203-603-9

Classification Classification (67/548/EEC or 1999/45/EC)

Flam. Liq. 3 - H226 R10

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

General information Avoid contact with skin and eyes. In case of accident or if you feel unwell, seek medical
advice immediately (show the label where possible).

Inhalation Move affected person to fresh air at once. When breathing is difficult, properly trained
personnel may assist affected person by administering oxygen. Get medical attention if any
discomfort continues.

Ingestion Rinse mouth thoroughly with water. Do not induce vomiting. Never give anything by mouth to
an unconscious person. Do not induce vomiting. If vomiting occurs, the head should be kept
low so that vomit does not enter the lungs. Get medical attention immediately.

Skin contact Remove affected person from source of contamination. Wash skin thoroughly with soap and
water. Get medical attention if irritation persists after washing.

Eye contact Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 15
minutes. Continue to rinse for at least 15 minutes and get medical attention. Get medical
attention if irritation persists after washing.

4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor No specific recommendations. If in doubt, get medical attention promptly.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media Extinguish with foam, carbon dioxide or dry powder.

5.2. Special hazards arising from the substance or mixture

Specific hazards Irritating gases or vapours.

5.3. Advice for firefighters

Protective actions during Avoid breathing fire gases or vapours. Keep up-wind to avoid fumes. Do not use water jet as
firefighting an extinguisher, as this will spread the fire. Control run-off water by containing and keeping it
out of sewers and watercourses.

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

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KORROBOND 65 COMPONENT A

Personal precautions Warn everybody of potential hazards and evacuate if necessary. Provide adequate ventilation.
Wear protective clothing as described in Section 8 of this safety data sheet. Avoid contact with
skin and eyes.

6.2. Environmental precautions

Environmental precautions Avoid the spillage or runoff entering drains, sewers or watercourses. Spillages or uncontrolled
discharges into watercourses must be reported immediately to the Environmental Agency or
other appropriate regulatory body.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Absorb spillage with non-combustible, absorbent material. Collect and place in suitable waste
disposal containers and seal securely. Containers with collected spillage must be properly
labelled with correct contents and hazard symbol.

6.4. Reference to other sections

Reference to other sections Wear protective clothing as described in Section 8 of this safety data sheet.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Use only in well-ventilated areas. Keep away from heat, sparks and open flame. Open drum
carefully as content may be under pressure. Avoid contact with skin and eyes. Do not use in
confined spaces without adequate ventilation and/or respirator. Do not eat, drink or smoke
when using the product. Good personal hygiene procedures should be implemented.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure Controls/personal protection

8.1. Control parameters

Occupational exposure limits
2-METHOXY-1-METHYLETHYL ACETATE
Long-term exposure limit (8-hour TWA): WEL 50 ppm(Sk) 274 mg/m3(Sk)
Short-term exposure limit (15-minute): WEL 100 ppm(Sk) 548 mg/m3(Sk)
WEL = Workplace Exposure Limit

8.2. Exposure controls

Protective equipment

Appropriate engineering Provide adequate general and local exhaust ventilation.

controls

Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicates
eye contact is possible. The following protection should be worn: Chemical splash goggles.

Hand protection Wear protective gloves made of the following material: Rubber or plastic.

Other skin and body Wear apron or protective clothing in case of contact.
protection

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KORROBOND 65 COMPONENT A

Hygiene measures Provide eyewash station and safety shower. Keep away from food, drink and animal feeding
stuffs. Good personal hygiene procedures should be implemented. Wash hands and any
other contaminated areas of the body with soap and water before leaving the work site. Do
not eat, drink or smoke when using the product. Change work clothing daily before leaving
workplace.

Respiratory protection If ventilation is inadequate, suitable respiratory protection must be worn. Wear a respirator
fitted with the following cartridge: Gas filter, type A2.

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties

Appearance Viscous liquid.

Colour Light (or pale). Grey.

Melting point n/d°C

Initial boiling point and range >200°C @

Flash point > 200°C

Vapour pressure <0.01 mmHg @ °C

Relative density 1.81 @ 20 ºC°C

Solubility(ies) Insoluble in water.

Auto-ignition temperature >400°C

9.2. Other information

Other information Not available.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity Acids. Strong oxidising agents.

10.2. Chemical stability

Stability Stable at normal ambient temperatures and when used as recommended.

10.3. Possibility of hazardous reactions

Possibility of hazardous Not determined.
reactions

10.4. Conditions to avoid

Conditions to avoid Avoid heat, flames and other sources of ignition. Avoid excessive heat for prolonged periods
of time. Avoid exposure to high temperatures or direct sunlight.

10.5. Incompatible materials

Materials to avoid Avoid contact with the following materials: Acids. Oxidising agents.

10.6. Hazardous decomposition products

Hazardous decomposition Oxides of carbon. Thermal decomposition or combustion may liberate carbon oxides and
products other toxic gases or vapours. Vapours/gases/fumes of: Acids - organic. Aldehydes.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity - oral

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KORROBOND 65 COMPONENT A

ATE oral (mg/kg) 13,368.98

Acute toxicity - dermal

ATE dermal (mg/kg) 19,153.29

Acute toxicity - inhalation

ATE inhalation (gases ppm) 47,452.65

ATE inhalation (vapours mg/l) 116.0

ATE inhalation (dusts/mists 15.82

mg/l)

General information The product contains an epoxy resin. May cause sensitisation or allergic reactions in sensitive
individuals.

Skin contact Irritating to skin. Prolonged and frequent contact may cause redness and irritation. May cause
sensitisation by skin contact.

Eye contact Irritating to eyes. A single exposure may cause the following adverse effects: Corneal
damage.

Acute and chronic health Prolonged or repeated exposure may cause severe irritation.
hazards

Route of entry Inhalation Ingestion. Skin absorption

SECTION 12: Ecological Information

Ecotoxicity Avoid release to the environment. The product contains a substance which is harmful to
aquatic organisms and which may cause long-term adverse effects in the aquatic
environment.

12.1. Toxicity
Toxicity Not considered toxic to fish.

12.2. Persistence and degradability

Persistence and degradability There are no data on the degradability of this product.

12.3. Bioaccumulative potential

Bioaccumulative potential No data available on bioaccumulation.

12.4. Mobility in soil

Mobility Do not discharge into drains or watercourses or onto the ground.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects

Other adverse effects Not available.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information When handling waste, the safety precautions applying to handling of the product should be
considered.

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KORROBOND 65 COMPONENT A

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.

Waste class 08 04 99

SECTION 14: Transport information

General The product is not covered by international regulations on the transport of dangerous goods
(IMDG, IATA, ADR/RID).

14.1. UN number
UN No. (IMDG)

UN No. (ICAO)

14.2. UN proper shipping name

No information required.

14.3. Transport hazard class(es)

ADR/RID class

ADR/RID subsidiary risk

ADR/RID label

IMDG class

IMDG subsidiary risk

ICAO class/division

ICAO subsidiary risk

Transport labels

14.4. Packing group

No information required.

ADR/RID packing group

IMDG packing group

ICAO packing group

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

No.

14.6. Special precautions for user

No information required.

EmS

Emergency Action Code

Hazard Identification Number

(ADR/RID)

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

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KORROBOND 65 COMPONENT A

Transport in bulk according to No information required.

Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).

Water hazard classification WGK 2

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

Revision date 17/04/2015

Revision 25

Supersedes date 27/02/2014

Risk phrases in full NC Not classified.

R10 Flammable.
R20/22 Harmful by inhalation and if swallowed.
R36/38 Irritating to eyes and skin.
R43 May cause sensitisation by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R65 Harmful: may cause lung damage if swallowed.

Hazard statements in full H226 Flammable liquid and vapour.

H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.

This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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