Class Test SRG - DT Sir - 02-06-2023 - SC

IOC_Class Test_SRG_DT sir_02-6-2023
SECTION I: (Maximum Marks: 06)

• This section contains TEN (10) Questions.
• Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct
answer.
• For each question, choose the option corresponding to the correct answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases.
1. Change in size is maximum in which process :

(A) O(g) → O+(g) (B) O(g) → O–(g) (C) O+(g) → O–(g) (D) All have same change
1
2. If 13th electron of Phosphorous have n = 3,  =1,m = −1, s =+ . Which set of quantum number is
2
possible for 15th electron of Phosphorous in ground state :
n l m s n l m s
1 1
(A) 3 1 − 1 + (B) 3 1 − 1 −
2 2
1 1
(C) 3 1 + 1 − (D) 3 1 0 +
2 2
3. Atomic number of Ag is 47. In the same group, the atomic numbers of elements placed above and
below Ag in Long form of periodic table will be :
(A) 29, 65 (B) 39, 79 (C) 29, 79 (D) 39, 65
4. Among following species which of them have maximum Zeff.

(A) Sn (B) Sn4+ (C) In (D) In+
5. Which of the following relation is correct with respect to first (I) and second (II) ionization enthalpies
of potassium and calcium ?
(A) ICa > IIK (B) IK > ICa (C) IICa > IIK (D) IIK > IICa
6. Among halogens, the correct order of amount of energy released in electron gain (electron gain
enthalpy) is:
(A) F > Cl > Br > I (B) F < Cl < Br < I (C) F < Cl > Br > I (D) Cl > Br > F > I
7. Correct order of electronegativity of N, P, C and Si on Pauling scale is :

(A) N > P > C > Si (B) C > Si > N > P (C) N < P < C < Si (D) N > C > P > Si
8. Hydrations energies for Li+, Na+ and K+ ions are respectively (in KJ/ mole) :
(A) 590, 402, 314 (B) 314, 402, 590 (C) 402, 590, 314 (D) 314, 590, 402
9. Screening effect is not observed in :

(A) He+ (B) Li2+ (C) Be3+ (D) All these
10. When the following five anions are arranged in order of decreasing ionic radius, the correct sequence
is:
(A) Se2– > I– > Br– > O2– > F– (B) I– > Se2– > Br– > F– > O2–
(C) Se > I > Br > F > O
2– – – – 2–
(D) I– > Se2– > Br– > O2– > F–
1
SECTION II: (Maximum Marks: 24)
• This section contains FOUR (04) Questions.
• Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four options
is/are the correct answer(s).
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and
both of which are correct.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is
a correct option.
Zero Marks : 0 If none of the options is chosen (i.e., the question is unanswered).
Negative Marks : –2 In all other cases.
For Example : If first, third and fourth are the ONLY three correct options for a question
with second option being an incorrect option; selecting only all the three correct options will result
in +4 marks. Selecting only two of the three correct options (e.g., the first and fourth options),
without selecting any incorrect option (second option in this case), will result in +2 marks. Selecting
only one of the three correct options (either first or third or fourth option), without selecting any
incorrect option (second option in this case), will result in +1 marks. Selecting any incorrect option(s)
(second option in this case), with or without selection of any correct option(s) will result in –2
marks.
1. "M" is the second member of the 4 d transition series and has two 4 d electrons. Select correct
statement about "M"
(A) It is Zr
(B) Electronic configuration of M = 1s2 ,2 s2 ,2p6 , 3 s2 , 3p6 , 4 s2 , 3 d10 , 4p6 ,5 s2 , 4 d2
(C) Electronic configuration of M2+ = [Kr]4 d2
(D) Electronic configuration of M4+ = [Ar]4 s2 4p6
2. Two elements M and X (both from same period) form oxide M2O and X2O. If X2O is acidic and M2O is
basic then select correct option(s) about M and X :
(A) M > X (size) (B) (IE) X > M (C) (EN) M > X (D) (Acidic strength) MOH > XOH
3. The ionic radii depends upon in the following factors : The ionic radii depends upon in the following
factors :
(A) Charge on cation
(B) Charge on anion
(C) Shell number of valence shell electron(s) of the ion.
(D) Effective nuclear charge
4. Which is/are the correct order/s of atomic radius ?

(A) Li < B < Be (C) Be < B < Li
(C) Li > Be > B (D) N > O > F
2
SECTION-III: (Maximum Marks: 12)
• This section contains THREE (03) questions.
• The answer to each question is a NUMERICAL VALUE.
• Numerical Grid Type (Single digit Ranging from 0 to 9)
Full Marks : +3 If ONLY the correct numerical value is entered at the designated place;
Zero Marks : 0 In all other cases.
1. An element belonging to 3d series of modern periodic table has spin magnetic moment = 5.92 B.M.
in +3 oxidation state. Determine the atomic number of element.
2.
Where a, b, c, d, e, f, g, h are 3rd period elements. If difference between atomic number of elements
b and e is x and difference between atomic number of elements c and f is y. What is the value of
x – y.
3. A– (g) → A2+(g) ∆H = 1100 KJ/mol

A (g) → A2+(g) ∆H = 1200 KJ/mol
Electron gain enthalphy of A is P × 101 KJ/mol. What is the value of P ?
SECTION-IV: (Maximum Marks: 4)

• This section contains TWO (02) Matching List Sets.
• Each set has ONE Multiple Choice Question.
• Each set has TWO lists: List-I and List-II.
• List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and (T).
• List-I has one or more correct matches in List-II
Full Marks : +4 ONLY if the option corresponding to the correct combination is chosen;
1. Match the correct atomic radius with the element :
(A) (i) – r, (ii) – q, (iii) – t, (iv) – s, (v) – p

(B) (i) – t, (ii) – s, (iii) – r, (iv) – p, (v) – q
(C) (i) – r, (ii) – s, (iii) – t, (iv) – q, (v) – p
(D) (i) – t, (ii) – p, (iii) – r, (iv) – s, (v) –q
3
2. Match the column.
(i)
(ii)
(iii)
(iv)
(A) (i - q,r) ; (ii - p,s) ; (iii - s) ; (iv - q,r)
(B) (i - r) ; (ii - p) ; (iii - s) ; (iv - q,r)
(C) (i - q,r) ; (ii - s) ; (iii - p) ; (iv - q,r)
(D) (i - q) ; (ii - p,s) ; (iii - s) ; (iv - r)
SECTION III: (Maximum Marks: 12)

• This section contains ONE (01) paragraphs. Based on each paragraph, there are TWO (02) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct
answer.
Full Marks : +3 If ONLY the correct option is chosen;
Negative Marks : −1 In all other cases.
Paragraph for Questions 1 and 2
Generally metals belongs to left hand side, while non-metals belonging to right hand site of the
modern periodic table. As we move across the period from left to right then I.E., E.A. / E.N.
increases with increasing Zeff , while decreases down the group. But atomic radii follow reverse
order.
1. Which of the following order is correct with their indicated properties -

(A) O > S : Electron affinity
(B) Na > Mg : 2nd ionization enthalpy
(C) Li2O > Na2O : Basic oxide
(D) Cl Θ > S2Θ : Ionic radius
2. Which has highest ionization enthalpy :

(A) P (B) Si (C) S (D) Cl

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IOC_Class Test_SRG_DT sir_02-6-2023

SECTION I: (Maximum Marks: 06)

1. Change in size is maximum in which process :

4. Among following species which of them have maximum Zeff.

7. Correct order of electronegativity of N, P, C and Si on Pauling scale is :

9. Screening effect is not observed in :

4. Which is/are the correct order/s of atomic radius ?

3. A– (g) → A2+(g) ∆H = 1100 KJ/mol

SECTION-IV: (Maximum Marks: 4)

1. Match the correct atomic radius with the element :

(A) (i) – r, (ii) – q, (iii) – t, (iv) – s, (v) – p

SECTION III: (Maximum Marks: 12)

1. Which of the following order is correct with their indicated properties -

2. Which has highest ionization enthalpy :

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