Class 12 Revision Paper On Chapter 2

ANAND CLASSES
Revision 1 CHAPTER 3 TOTAL MARKS 35
All questions are compulsory.

a) Section A: Q. no. 1 to 15carry 1 mark each.
b) Section B: Q. No. 16 to 19 carries 2 mark each
c) Section C: Q. No. 20 to 23 carries 3 marks each
Section A
1. Toluene reacts with a halogen in the presence of iron (III) chloride giving ortho and para halo
compounds. The reaction is
A. Electrophilic elimination reaction
B. Electrophilic substitution reaction
C. Free radical addition reaction
D. Nucleophilic substitution reaction
2. Which of the following is an example of vic-dihalide?
A. Dichloromethane
B. 1,2-dicholoroethane
C. Ethylidene Chloride
D. Allyl chloride
3. The position of -Br in the compound in CH3CH = CHC(Br)(CH3)2 can be classified as
A. Allyl
B. Aryl
C. Vinyl
D. Secondary
4. Chlorobenzene is formed by reaction of chlorine with benzene in the presence of AlcL3.
Which of the following species attacks the benzene ring in this reaction ?
A. Cl-
B. Cl+
C. AlCl2
D. ][AlCl4]-
5. What should be the correct IUPAC name for diethylbromomethane?
A. 1-Bromo-1, 1-diethylmethane
B. 3-Bromopentane
C. 1-Bromo-1-ethypropane
D. 1-Bromopentane
6. Molecules whose mirror image is non superimposable over them are known as chiral. Which
of the following molecules is chiral in nature?
A. 2-Bromobutane
B. 1-Bromobutane
C. 2-Brompropane
D. 2-Bromopropan-2-o1-
7. Reaction of C6H5CH2Br with aqueous sodium hydroxide follows_______.
A. SN1 mechanism
B. SN2 mechanism
C. Any of the above two depending upon the temperature of reaction
D. Saytzeff rule
8. Which is the correct increasing order of boiling points of the following compounds?
1-Iodobutane, 1-Bromobutane, 1-Chlorobutane, Butane
A. Butane < 1-Chlorobutane < 1-Bromobutane < 1-Iodobutane
B. 1-Iodobutane < 1- Bromobutane < 1-Chlorobutane < Butane
C. Butane < 1-Iodobutane < 1-Bromobutane < 1-Chlorobutane
D. Butane < 1-Chlorobutane < 1-Iodobutane < 1-Bromobutane
9. Haloalkanes contains halogen atom(s) attached to the sp3 hybridised carbon atom of an alkyl
group. Identify haloalkane from the following compounds.
A. 2-Bromopentane
B. Vinyl Chloride (chloroethene)
C. 2-chloroacetophenone
D. Trichloromethane
10. Ethylene chloride and ethylidene chloride are isomers, identify the correct statements
A. Both the compounds form same product on treatment with alcoholic KOH
B. Both the compounds form same product on treatment with aq.NaOH
C. Both the compounds form same product on reduction
D. Both the compounds are optically active.
11. Which of the following compounds ar gem-dihalides?
A. Ethylidene chloride
B. Ethylene dichloride
C. Methylene chloride
D. Benzyl chloride.
12. Alkyl fluorides are synthesised by heating an alkyl chloride/bromide in presence of
______________ or _________________
A. CaF2
B. CoF2
C. Hg2F2
D. .NaF
In the following questions a statement of assertion followed by a statement of reason is given.
Choose the correct answer out of the following choices
(i) Assertion and reason both are correct and reason is correct explanation of assertion
(ii) Assertion and reason both are wrong statements
(iii) Assertion is correct but reason is wrong statement
(iv) Assertion is wrong but reason is correct statement
(v) Assertion and reason both are correct statements but reason is not correct explanation of
assertion.
13. Assertion :The boiling points of alkyl halides decrease in the order
RI > RBr >RCl > RF
Reason :The boiling points of alkyl chlorides, bromides and iodides are considerably
higher than that of the hydrocarbon of comparable molecular mass
14. Assertion :KCN reacts with methyl chloride to give methyl isocyanide
Reason :CN- is an ambident nucleophile.
15. Assertion :Presence of a nitro group at ortho or para position increases the reactivity of
haloarenes towards nucleophilic substitution
Reason :Nitro group, being an electron withdrawing group decreases the electron density
over the benzene ring
Section B
16. (a) Aryl chlorides and bromides can be easily prepared by electrophilic substitution of
arenes with chlorine and bromine respectively in the presence of Lewis acid catalysts. But
why does preparation of aryl iodides requires presence of an oxidising agent.
(b) Out of o- and p-dibromobenzene which one has higher melting point and why?
17. (a) Why iodoform has appreciable antiseptic property?
(b) Haloarenes are less reactive than haloalkanes and haloalkenes Explain.
18. (a) Discuss the role of Lewis acids in the preparation of aryl bromides and chlorides in the
dark
(b) Why is solubility of haloalkanes in water very low?
19. (a) Classify the following compounds as primary, secondary and tertiary halides
(I)1-Bromobut-2-ene (II) 4-Brompent-2-ene (III) 2-Bromo-2-methylpropane
(b) Write down the structure and IUPAC name of neo-pentylbromide
Section C
20. Compound ‘A’ with molecular formula C4H9Br is treated with aq.KOH solution. The rate of
this reaction depends upon the concentration of the compound ‘A’ only. When another
optically active isomer ‘B’ of this compound was treated with aq.KOH solution, the rate of
reaction was found to be dependent on concentration of compound and KOH both
(i) Write down the structural formula of both compounds ‘A’ ad ‘B’
(ii) Out of these two compounds which one will be converted to the product with inverted
configuration.
21. (a) Allyl chloride is hydrolysed more readily than n-propyl chloride why?
(b) Why is it necessary to avoid even traces of moisture during the use of a Grignard reagent
(c) How do polar solvents help in the first step in SN1 mechanism?
22. Carry out the following conversions
a) Chloroethane to propanoic acid
b) Chloroethane to butane
c) 2iodopropane to 1iodopropane
23. (a) Diphenyls are potential threat to the environment. How are these produced from
arylhalides?
(b)How will you obtain monobromobenzene from aniline?
( c) Predict the major product formed when HCl is added to isobutylene. Explain the
mechanism involved.

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ANAND CLASSES

Revision 1 CHAPTER 3 TOTAL MARKS 35

All questions are compulsory.

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