Blb8002f Sds SGP Eng WT Act

Download as pdf or txt
Download as pdf or txt
You are on page 1of 7

SAFETY DATA SHEET

BULAB® 8002F

Section 1. Identification
Product identifier : BULAB® 8002F

Relevant identified uses of the substance or mixture and uses advised against
Dispersant

Supplier's details : Buckman Laboratories (Asia) Pte Ltd


33 Tuas South Street 1
Singapore 638038
Telephone: (65) 6891-9200

Emergency telephone : Singapore : (65) 6863-5470


number

Section 2. Hazards identification


Classification of the : SKIN CORROSION/IRRITATION - Category 2
substance or mixture SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2

GHS label elements, including precautionary statements


Hazard pictograms :

Signal word : Warning


Hazard statements : H319 - Causes serious eye irritation.
H315 - Causes skin irritation.
Precautionary statements
Prevention : P280 - Wear protective gloves. Wear eye or face protection.
P264 - Wash hands thoroughly after handling.
Response : P302 + P352 + P362+P364 - IF ON SKIN: Wash with plenty of soap and water.
Take off contaminated clothing and wash it before reuse.
P332 + P313 - If skin irritation occurs: Get medical attention.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 - If eye irritation persists: Get medical attention.
Storage : Not applicable.
Disposal : Not applicable.

Other hazards which do not : None known.


result in classification

Section 3. Composition/information on ingredients


Ingredient name % CAS number
Polyethylene glycol monotridecyl ether phosphate 1 - 2.5 9046-01-9

Any concentration shown as a range is to protect confidentiality or is due to batch variation. All known
hazards are clearly communicated within this document.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.

Date of issue/Date of revision : 7 February 2020 Date of previous issue : 3 August 2017 Version : 1.03 1/7
BULAB® 8002F

Section 4. First aid measures


Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 15
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
If not breathing, if breathing is irregular or if respiratory arrest occurs, provide
artificial respiration or oxygen by trained personnel. It may be dangerous to the
person providing aid to give mouth-to-mouth resuscitation. Get medical attention if
adverse health effects persist or are severe. If unconscious, place in recovery
position and get medical attention immediately. Maintain an open airway. Loosen
tight clothing such as a collar, tie, belt or waistband.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 15 minutes. Get medical attention. Wash
clothing before reuse. Clean shoes thoroughly before reuse.
Ingestion : Wash out mouth with water. Remove dentures if any. Remove victim to fresh air
and keep at rest in a position comfortable for breathing. If material has been
swallowed and the exposed person is conscious, give small quantities of water to
drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If vomiting occurs,
the head should be kept low so that vomit does not enter the lungs. Get medical
attention if adverse health effects persist or are severe. Never give anything by
mouth to an unconscious person. If unconscious, place in recovery position and get
medical attention immediately. Maintain an open airway. Loosen tight clothing such
as a collar, tie, belt or waistband.

Most important symptoms/effects, acute and delayed


Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : No known significant effects or critical hazards.
Skin contact : Causes skin irritation.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : No specific data.

Indication of immediate medical attention and special treatment needed, if necessary


Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Date of issue/Date of revision : 7 February 2020 Date of previous issue : 3 August 2017 Version : 1.03 2/7
BULAB® 8002F

Section 5. Fire-fighting measures


Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media

Specific hazards arising : In a fire or if heated, a pressure increase will occur and the container may burst.
from the chemical
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
Nitrogen oxides.
Sulfur oxides.

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.

Section 6. Accidental release measures


Personal precautions, protective equipment and emergency procedures
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up


Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop
up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry
material and place in an appropriate waste disposal container. Dispose of via a
licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas.
Wash spillages into an effluent treatment plant or proceed as follows. Contain and
collect spillage with non-combustible, absorbent material e.g. sand, earth,
vermiculite or diatomaceous earth and place in container for disposal according to
local regulations (see Section 13). Dispose of via a licensed waste disposal
contractor. Contaminated absorbent material may pose the same hazard as the
spilled product. Note: see Section 1 for emergency contact information and Section
13 for waste disposal.

Section 7. Handling and storage


Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not ingest.
Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Keep in
the original container or an approved alternative made from a compatible material,
kept tightly closed when not in use. Empty containers retain product residue and
can be hazardous. Do not reuse container.
Compatible materials of : Not Tested.
construction NOTE: With respect to all other materials not listed above, user should be aware
that use of such materials with this product may be hazardous and result in
damages to such materials and other property and personal injuries. No data
concerning such materials not listed above should be implied by the user.

Date of issue/Date of revision : 7 February 2020 Date of previous issue : 3 August 2017 Version : 1.03 3/7
BULAB® 8002F

Section 7. Handling and storage


Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.

Conditions for safe storage, : Do not store below the following temperature: 5°C (41°F). Store in accordance with
including any local regulations. Store in original container protected from direct sunlight in a dry,
incompatibilities cool and well-ventilated area, away from incompatible materials (see Section 10)
and food and drink. Keep container tightly closed and sealed until ready for use.
Containers that have been opened must be carefully resealed and kept upright to
prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination.

Section 8. Exposure controls/personal protection


Control parameters
Occupational exposure limits
None.

Appropriate engineering : Good general ventilation should be sufficient to control worker exposure to airborne
controls contaminants.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures


Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: chemical splash
goggles.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Considering the parameters specified by the glove manufacturer,
check during use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material may be
different for different glove manufacturers. In the case of mixtures, consisting of
several substances, the protection time of the gloves cannot be accurately
estimated.
Body protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.

Date of issue/Date of revision : 7 February 2020 Date of previous issue : 3 August 2017 Version : 1.03 4/7
BULAB® 8002F

Section 9. Physical and chemical properties


Appearance
Physical state : Liquid.
Color : Yellow to brown
Odor : Not available.
Odor threshold : Not available.
pH : 3 to 5
Melting point : Not available.
Boiling point : Not available.
Flash point : Closed cup: >100°C (>212°F) [Pensky-Martens.]
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive : Not available.
(flammable) limits
Vapor pressure : Not available.
Vapor density : Not available.
Relative density : Not available.
Density : 1.09 to 1.15 g/cm³
Solubility : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Not available.

Section 10. Stability and reactivity


Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Do not heat and/or store above 50°C as decomposition may increase packaging
pressure.

Incompatible materials : strong alkalis Strong oxidizer Strong reducer

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products
products should not be produced.

Section 11. Toxicological information


Information on toxicological effects
Acute toxicity
Not available.
Irritation/Corrosion
Not available.
Sensitization
Not available.
Mutagenicity
Date of issue/Date of revision : 7 February 2020 Date of previous issue : 3 August 2017 Version : 1.03 5/7
BULAB® 8002F

Section 11. Toxicological information


Not available.
Carcinogenicity
Not available.

Section 12. Ecological information


Toxicity
Not available.

Section 13. Disposal considerations


Disposal methods : The generation of waste should be avoided or minimized wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Waste should not be
disposed of untreated to the sewer unless fully compliant with the requirements of
all authorities with jurisdiction. Waste packaging should be recycled. Incineration or
landfill should only be considered when recycling is not feasible. This material and
its container must be disposed of in a safe way. Care should be taken when
handling emptied containers that have not been cleaned or rinsed out. Empty
containers or liners may retain some product residues. Avoid dispersal of spilled
material and runoff and contact with soil, waterways, drains and sewers.

Section 14. Transport information


Road & Rail IMDG IATA
Class - - -
UN number Not regulated. Not regulated. Not regulated.

Packing group - - -

Section 15. Regulatory information


International regulations
FDA : This product is allowed under the following FDA (21 CFR) sections :Refer product
data sheet, if applicable.
International lists
National inventory
Japan : Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
HMIS
Health Flammability Reactivity Special
1 1 0

Section 16. Other information


History
Date of issue/Date of : 7 February 2020
revision
Version : 1.03

Date of issue/Date of revision : 7 February 2020 Date of previous issue : 3 August 2017 Version : 1.03 6/7
BULAB® 8002F

Section 16. Other information


Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Procedure used to derive the classification
Classification Justification
Skin Irrit. 2, H315 Expert judgment
Eye Irrit. 2, H319 Expert judgment
References : Not available.
Indicates information that has changed from previously issued version.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-
named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described herein,
we cannot guarantee that these are the only hazards that exist.

Date of issue/Date of revision : 7 February 2020 Date of previous issue : 3 August 2017 Version : 1.03 7/7

You might also like