Conforms to US OSHA Hazard Communication 29CFR1910.

1200

SAFETY DATA SHEET

Antifoam agent, Antifoam 1520, Part Number 5190-2235

Section 1. Identification
1.1 Product identifier
Product name : Antifoam agent, Antifoam 1520, Part Number 5190-2235
Part no. : 5190-2235
Validation date : 5/20/2020
1.2 Relevant identified uses of the substance or mixture and uses advised against
Material uses : Reagents and Standards for Analytical Chemistry Laboratory Use
10 ml

1.3 Details of the supplier of the safety data sheet

Supplier/Manufacturer : Agilent Technologies, Inc.
5301 Stevens Creek Blvd
Santa Clara, CA 95051, USA
800-227-9770

1.4 Emergency telephone number

In case of emergency : CHEMTREC®: 1-800-424-9300

Section 2. Hazards identification

2.1 Classification of the substance or mixture
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the substance or mixture
H319 EYE IRRITATION - Category 2A
Percentage of the mixture consisting of ingredient(s) of unknown hazards to the aquatic
environment: 20%

2.2 GHS label elements

Hazard pictograms :

Signal word : Warning

Hazard statements : H319 - Causes serious eye irritation.
Precautionary statements
Prevention : P280 - Wear eye or face protection.
Response : P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 - If eye irritation persists: Get medical advice or attention.
Storage : Not applicable.
Disposal : Not applicable.
2.3 Other hazards
Hazards not otherwise : None known.
classified

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Antifoam agent, Antifoam 1520, Part Number 5190-2235

Section 3. Composition/information on ingredients

Substance/mixture : Mixture

Ingredient name % CAS number

Siloxanes and Silicones, di-Me ≥10 - <25 63148-62-9
benzoic acid <1 65-85-0
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

4.1 Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects
persist or are severe. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Ingestion : Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention if adverse health
effects persist or are severe. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

4.2 Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.

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Section 4. First aid measures

4.3 Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

5.2 Special hazards arising from the substance or mixture

Specific hazards arising : In a fire or if heated, a pressure increase will occur and the container may burst.
from the chemical
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
metal oxide/oxides
Formaldehyde.

5.3 Advice for firefighters

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

6.2 Environmental : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
precautions and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

6.3 Methods and materials for containment and cleaning up

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Section 6. Accidental release measures

Methods for cleaning up : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.

Section 7. Handling and storage

7.1 Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid
contact with eyes, skin and clothing. Avoid breathing vapor or mist. Keep in the original
container or an approved alternative made from a compatible material, kept tightly
closed when not in use. Empty containers retain product residue and can be hazardous.
Do not reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

7.2 Conditions for safe : Store in accordance with local regulations. Store in original container protected from
storage, including any direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
incompatibilities (see Section 10) and food and drink. Keep container tightly closed and sealed until
ready for use. Containers that have been opened must be carefully resealed and kept
upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination. See Section 10 for incompatible
materials before handling or use.

7.3 Specific end use(s)

Recommendations : Industrial applications, Professional applications.
Industrial sector specific : Not applicable.
solutions

Section 8. Exposure controls/personal protection

8.1 Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Siloxanes and Silicones, di-Me None.
benzoic acid None.

8.2 Exposure controls

Appropriate engineering : Good general ventilation should be sufficient to control worker exposure to airborne
controls contaminants.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.

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Antifoam agent, Antifoam 1520, Part Number 5190-2235

Section 8. Exposure controls/personal protection

Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.

Section 9. Physical and chemical properties

9.1 Information on basic physical and chemical properties
Appearance
Physical state : Liquid. [Emulsion.]
Color : Milky white
Odor : Characteristic.
Odor threshold : Not available.
pH : 3.5
Melting point : Not available.
Boiling point : 65°C (149°F)
Flash point : Closed cup: >101.1°C (>214°F)
Evaporation rate : Not available.
Flammability (solid, gas) : Not applicable.
Lower and upper explosive : Not available.
(flammable) limits
Vapor pressure : Not available.
Vapor density : Not available.
Relative density : 1
Density : 1 g/cm³ [25°C (77°F)]
Solubility : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Kinematic (room temperature): 50 cm2/s (5000 cSt)

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Antifoam agent, Antifoam 1520, Part Number 5190-2235

Section 10. Stability and reactivity

10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.

10.2 Chemical stability : The product is stable.

10.3 Possibility of : Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions

10.4 Conditions to avoid : No specific data.

10.5 Incompatible materials : May react or be incompatible with oxidizing materials.

10.6 Hazardous : Under normal conditions of storage and use, hazardous decomposition products should
decomposition products not be produced.

Section 11. Toxicological information

11.1 Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
benzoic acid LD50 Oral Rat 1700 mg/kg -
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
Siloxanes and Silicones, di- Eyes - Mild irritant Rabbit - 1 hours 100 -
Me mg
Eyes - Mild irritant Rabbit - 24 hours 100 -
Ul
Eyes - Moderate irritant Rabbit - 24 hours 100 -
Ul
Skin - Mild irritant Rabbit - 24 hours 500 -
Ul
benzoic acid Skin - Mild irritant Human - 40 minutes -
0.76 %
Skin - Moderate irritant Human - 72 hours 22 -
mg I
Sensitization
Not available.
Mutagenicity
Conclusion/Summary : Not available.
Carcinogenicity
Conclusion/Summary : Not available.
Reproductive toxicity
Conclusion/Summary : Not available.
Teratogenicity
Conclusion/Summary : Not available.
Specific target organ toxicity (single exposure)

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Antifoam agent, Antifoam 1520, Part Number 5190-2235

Section 11. Toxicological information

Name Category Route of Target organs
exposure
benzoic acid Category 3 - Respiratory tract
irritation
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
benzoic acid Category 1 inhalation lungs

Aspiration hazard
Not available.

Information on the likely : Routes of entry anticipated: Oral, Dermal, Inhalation.

routes of exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
General : No known significant effects or critical hazards.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity

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Section 11. Toxicological information

Acute toxicity estimates
Product/ingredient name Oral (mg/ Dermal Inhalation Inhalation Inhalation
kg) (mg/kg) (gases) (vapors) (dusts and
(ppm) (mg/l) mists) (mg/
l)
benzoic acid 1700 N/A N/A N/A N/A

Section 12. Ecological information

12.1 Toxicity
Product/ingredient name Result Species Exposure
Siloxanes and Silicones, di- Acute LC50 44.5 ppm Fresh water Daphnia - Daphnia magna - Instar 48 hours
Me
benzoic acid Acute EC50 140 µg/l Algae - Chlorella vulgaris - 72 hours
Exponential growth phase
Acute EC50 860 mg/l Fresh water Daphnia - Daphnia magna - 48 hours
Neonate
Acute LC50 180 ppm Fresh water Fish - Gambusia affinis - Adult 96 hours

12.2 Persistence and degradability

Product/ingredient name Aquatic half-life Photolysis Biodegradability
benzoic acid - - Readily

12.3 Bioaccumulative potential

Product/ingredient name LogPow BCF Potential
benzoic acid 1.88 - low

12.4 Mobility in soil

Soil/water partition : Not available.
coefficient (KOC)

12.5 Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

13.1 Waste treatment methods
Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.

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Antifoam agent, Antifoam 1520, Part Number 5190-2235

Section 13. Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations. Local
regulations may be more stringent than regional or national requirements.

The information presented below only applies to the material as supplied. The identification based on
characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the
responsibility of the waste generator to determine the toxicity and physical properties of the material generated to
determine the proper waste identification and disposal methods in compliance with applicable regulations.

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees.

Section 14. Transport information

DOT / TDG / Mexico / IMDG / : Not regulated.
IATA

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.

Transport in bulk according : Not available.

to IMO instruments

Section 15. Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
U.S. Federal regulations : TSCA 8(a) PAIR: Siloxanes and Silicones, di-Me; Siloxanes and Silicones, di-Me,
reaction products with silica
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
Clean Water Act (CWA) 311: benzoic acid; Sulphuric acid

Clean Air Act Section 112 : Not listed

(b) Hazardous Air
Pollutants (HAPs)
Clean Air Act Section 602 : Not listed
Class I Substances
Clean Air Act Section 602 : Not listed
Class II Substances
DEA List I Chemicals : Not listed
(Precursor Chemicals)
DEA List II Chemicals : Not listed
(Essential Chemicals)
SARA 302/304
Composition/information on ingredients
SARA 302 TPQ SARA 304 RQ
Name % EHS (lbs) (gallons) (lbs) (gallons)
Sulphuric acid <0.1 Yes. 1000 66.3 1000 66.3
SARA 304 RQ : 1111111.1 lbs / 504444.4 kg [133260.1 gal / 504444.4 L]
SARA 311/312
Classification : EYE IRRITATION - Category 2A

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Antifoam agent, Antifoam 1520, Part Number 5190-2235

Section 15. Regulatory information

Composition/information on ingredients
Name % Classification
Siloxanes and Silicones, di-Me ≥10 - <25 EYE IRRITATION - Category 2A

State regulations
Massachusetts : None of the components are listed.
New York : None of the components are listed.
New Jersey : None of the components are listed.
Pennsylvania : None of the components are listed.
California Prop. 65
WARNING: This product can expose you to Strong inorganic acid mists containing sulfuric acid, which is known to
the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov.

Ingredient name No significant risk Maximum

level acceptable dosage
level
Strong inorganic acid mists containing sulfuric acid - -

International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
Inventory list
Australia : All components are listed or exempted.
Canada : All components are listed or exempted.
China : All components are listed or exempted.
Europe : Not determined.
Japan : Japan inventory (ENCS): All components are listed or exempted.
Japan inventory (ISHL): All components are listed or exempted.
New Zealand : All components are listed or exempted.
Philippines : All components are listed or exempted.
Republic of Korea : All components are listed or exempted.
Taiwan : All components are listed or exempted.
Thailand : Not determined.
Turkey : Not determined.
United States : All components are active or exempted.
Viet Nam : All components are listed or exempted.

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Section 16. Other information

History
Date of issue : 05/20/2020
Date of previous issue : 04/30/2018
Version : 5
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
UN = United Nations
Procedure used to derive the classification
Classification Justification
EYE IRRITATION - Category 2A Calculation method
Indicates information that has changed from previously issued version.

Notice to reader
Disclaimer: The information contained in this document is based on Agilent’s state of knowledge at the time of
preparation. No warranty as to its accurateness, completeness or suitability for a particular purpose is expressed
or implied.

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