Graphene batteries: introduction and market status

Battery basics

Batteries serve as a mobile source of power, allowing electricity-operated devices to work without
being directly plugged into an outlet. While many types of batteries exist, the basic concept by which
they function remains similar: one or more electrochemical cells convert stored chemical energy into
electrical energy. A battery is usually made of a metal or plastic casing, containing a positive terminal
(an anode), a negative terminal (a cathode) and electrolytes that allow ions to move between them. A
separator (a permeable polymeric membrane) creates a barrier between the anode and cathode to
prevent electrical short circuits while also allowing the transport of ionic charge carriers that are
needed to close the circuit during the passage of current. Finally, a collector is used to conduct the
charge outside the battery, through the connected device.

When the circuit between the two terminals is

completed, the battery produces electricity through a
series of reactions. The anode experiences an
oxidation reaction in which two or more ions from
the electrolyte combine with the anode to produce a
compound, releasing electrons. At the same time, the
cathode goes through a reduction reaction in which
the cathode substance, ions and free electrons
combine into compounds. Simply put, the anode
reaction produces electrons while the reaction in the
cathode absorbs them and from that process
electricity is produced. The battery will continue to
produce electricity until electrodes run out of
necessary substance for creation of reactions.

Battery types and characteristics

Batteries are divided into two main types: primary and secondary. Primary batteries (disposable), are
used once and rendered useless as the electrode materials in them irreversibly change during
charging. Common examples are the zinc-carbon battery as well as the alkaline battery used in toys,
flashlights and a multitude of portable devices. Secondary batteries (rechargeable), can be discharged
and recharged multiple times as the original composition of the electrodes is able to regain
functionality. Examples include lead-acid batteries used in vehicles and lithium-ion batteries used for
portable electronics.

Batteries come in various shapes and sizes for countless different purposes. Different kinds of
batteries display varied advantages and disadvantages. Nickel-Cadmium (NiCd) batteries are
relatively low in energy density and are used where long life, high discharge rate and economical
price are key. They can be found in video cameras and power tools, among other uses. NiCd batteries
contain toxic metals and are environmentally unfriendly. Nickel-Metal hydride batteries have a
higher energy density than NiCd ones, but also a shorter cycle-life. Applications include mobile
phones and laptops. Lead-Acid batteries are heavy and play an important role in large power
applications, where weight is not of the essence but economic price is. They are prevalent in uses like
hospital equipment and emergency lighting.

Lithium-Ion (Li-ion) batteries are used where high-energy and minimal weight are important, but the
technology is fragile and a protection circuit is required to assure safety. Applications include cell
phones and various kinds of computers. Lithium Ion Polymer (Li-ion polymer) batteries are mostly
found in mobile phones. They are lightweight and enjoy a slimmer form than that of Li-ion batteries.
They are also usually safer and have longer lives. However, they seem to be less prevalent since Li-
ion batteries are cheaper to manufacture and have higher energy density.

Graphene and batteries

Graphene, a sheet of carbon atoms bound together in a honeycomb lattice pattern, is hugely
recognized as a “wonder material” due to the myriad of astonishing attributes it holds. It is a potent
conductor of electrical and thermal energy, extremely lightweight chemically inert, and flexible with
a large surface area. It is also considered eco-friendly and sustainable, with unlimited possibilities for
numerous applications.

In the field of batteries, conventional battery electrode materials (and prospective ones) are
significantly improved when enhanced with graphene. Graphene can make batteries that are light,
durable and suitable for high capacity energy storage, as well as shorten charging times. It will extend
the battery’s life-time, which is negatively linked to the amount of carbon that is coated on the
material or added to electrodes to achieve conductivity, and graphene adds conductivity without
requiring the amounts of carbon that are used in conventional batteries.

Graphene can improve such battery attributes as energy density and form in various ways. Li-ion
batteries can be enhanced by introducing graphene to the battery’s anode and capitalizing on the
material’s conductivity and large surface area traits to achieve morphological optimization and
performance.

It has also been discovered that creating hybrid materials can also be useful for achieving battery
enhancement. A hybrid of Vanadium Oxide (VO2) and graphene, for example, can be used on Li-ion
cathodes and grant quick charge and discharge as well as large charge cycle durability. In this case,
VO2 offers high energy capacity but poor electrical conductivity, which can be solved by using
graphene as a sort of a structural “backbone” on which to attach VO2 - creating a hybrid material that
has both heightened capacity and excellent conductivity.

Another example is LFP ( Lithium Iron Phosphate) batteries, that is a kind of rechargeable Li-ion
battery. It has a lower energy density than other Li-ion batteries but a higher power density (an
indicator of of the rate at which energy can be supplied by the battery). Enhancing LFP cathodes with
graphene allowed the batteries to be lightweight, charge much faster than Li-ion batteries and have a
greater capacity than conventional LFP batteries.

In addition to revolutionizing the battery market, combined use of graphene batteries and
supercapacitors could yield amazing results, like the noted concept of improving the electric car’s
driving range and efficiency.
Batteries and supercapacitors
While there are certain types of batteries that are able to store a large amount of energy, they are very
large, heavy and release energy slowly. Capacitors, on the other hand, are able to charge and
discharge quickly but hold much less energy than a battery. The use of graphene in this area, though,
presents exciting new possibilities for energy storage, with high charge and discharge rates and even
economical affordability. Graphene-improved performance thereby blurs the conventional line of
distinction between supercapacitors and batteries.

Commercial Graphene-enhanced battery products

In June 2014, US based Vorbeck Materials announced the Vor-Power strap, a lightweight flexible
power source that can be attached to any existing bag strap to enable a mobile charging station (via 2
USB and one micro USB ports). the product weighs 450 grams, provides 7,200 mAh and is probably
the world’s first graphene-enhanced battery.

In May 2014, American company Angstron Materials rolled out several new graphene products. The
products, said to become available roughly around the end of 2014, include a line of graphene-
enhanced anode materials for Lithium-ion batteries. The battery materials were named “NANO
GCA” and are supposed to result in a high capacity anode, capable of supporting hundreds of
charge/discharge cycles by combining high capacity silicon with mechanically reinforcing and
conductive graphene.

Developments are also made in the field of graphene batteries for electric vehicles, such as Graphene
Nanochem and Sync R&D’s October 2014 plan to co-develop graphene-enhanced Li-ion batteries for
electric buses, under the Electric Bus 1 Malaysia program. In August 2014, Tesla suggested the
development of a "new battery technology" that will almost double the capacity for their Model S
electric car. It is unofficial but reasonable to assume graphene involvement in this battery. UK based
Perpetuus Carbon Group and OXIS Energy agreed in June 2014 to co-develop graphene-based
electrodes for Lithium-Sulphur batteries, which will offer improved energy density and possibly
enable electric cars to drive a much longer distance on a single battery charge.

Another interesting venture, announced in September 2014 by US based Graphene 3D Labs, regards
plans to print 3D graphene batteries. These graphene-based batteries can potentially outperform
current commercial batteries as well as be tailored to various shapes and sizes.

Other prominent companies which declared intentions to develop and commercialize graphene-
enhanced battery products are: Grafoid, SiNode together with AZ Electronic Materials, XG Sciences,
Graphene Batteries together with CVD Equipment and CalBattery.

Exciting research in the field of graphene batteries

The field of graphene-enhanced batteries is brimming with activity and research, striving to develop
and improve materials. One example of such research is the development of a new battery technology
based on graphene and aluminum by Stanford scientists in April 2015. The stanford team claims that
their aluminum battery has a number of advantages over lithium: it's flexible, can be charged in
a minute instead of hours and is very durable. it's also cheaper and non-reactive (meaning
compromising it will not result in sparks like lithium batteries).

In February 2015, researchers from the Korean Sungkyunkwan University announced the
development of a sponge-like electrode material using graphene and a polymer that enables the
assembly of a light and efficient graphene battery. The electrode was made from porous graphene
aerogel that was a result of combining alcohol and graphene. The graphene aerogel electrode material
is easily compressed and highly durable, with about 90-99.9 percent of it filled with air and pores
smaller than 100 nanometers that form a 3D web. The researchers state that they have achieved a
battery that is 10 times smaller than existing graphene batteries, but have similar performance
capabilities. Moreover, it was able to maintain the same product performance even after going
through the compression and restoration process for more than 10 million times.

The Korean KAIST institute developed in August 2014 a new method of fabricating defect-free
graphene. This enabled them to develop a promising high-performance anode for Li-ion batteries.
Also in August 2014, researchers from Rice University developed a new chemical process that can be
used to create a tough, ultra-light foam (called GO-0.5BN) that is made from two 2D ,materials:
graphene oxide and hexagonal boron nitride (hBN) platelets. This foam can serve as a structural
component in applications such as electrodes for batteries, supercapacitors and gas absorption
material.

In April 2014, researchers from the University of Southern California designed better performing and
cheaper Li-Ion batteries. The anode was made from silicon and the cathode was made of sulfur
powder coated with graphene oxide. Another example is Wuhan University of Technology’s
development of a new graphene-based high-energy electrode for Li-ion batteries in August 2014,
using a 3D-crumpled graphene that encapsulates Nickel-Sulfide.

Also in April 2014, researchers from the University of Southern California developed better
performing and cheaper Li-ion batteries. The anode in these batteries is made from Silicon (and is
said to be three times more powerful and longer lasting compared to conventional graphite anodes).
The cathode is made of sulfur powder coated with graphene oxide. the GO coating seems to solve
sulfur’s poor conductivity and cyclability issues, resulting in newly developed cathodes that offer 5
times the capacity of commercial ones.