IUPAC NOMENCLATURE FIITJEE.L.T.

D
Q.1 Compound having open chain is - Q.11 How many secondary carbon atoms does methyl
(A) Pentane (B) Isopentane cyclopropane have ?
(C) Neopentane (D) All the above [D] (A) None (B) One
(C) Two (D) Three [C]

Q.2 No. of heteroatoms (other than C) present in the Q.13 The total number of secondary H-atoms in the
following heterocyclic compound is – structure given below are :
O (CH3)2CHCH2C2H5
(A) 1 (B) 4
N–H
(C) 3 (D) 2 [B]

CH3 CH3
O
(A) 3 (B) 2 Q.14 and
CH3
(C) 1 (D) 0 [C]
Number of secondary carbon atoms present in
Q.4 Alicyclic compound is the above compounds are respectively :
(A) Aromatic compound
(A) 6, 4, 5 (B) 4, 5, 6
(B) Aliphatic compound
(C) 5, 4, 6 (D) 6, 2, 1 [A]
(C) Hetero cyclic compound
(D) Aliphatic cyclic compound [D] Q.15 iso-octane contains
(A) 5 prim. one sec. & two ter. C atoms.
Q.6 Which is an acyclic compound : [A] (B) 4 prim. 2 sec. & one ter. C atoms.
(A) Methane (B) Benzene (C) 5 (10C). one (20C), one (30C) & one (40C)
(C) Pyrrole (D) Cyclobutane atoms.
(D) 4 (10C). two (20C), one (30C) & one (40C)
Q.7 The group of heterocyclic compounds is ; atoms. [C]
(A) Phenol, Furan
(B) Furan, Thiophene Q.17 Which of the following radicals are bivalent ?
(C) Thiophene, Phenol (a) Ethylidene (b) Vinylidene
(c) Benzyl (d) Methylidyne
(D) Furan, Aniline [B]
(A) a , d (B) a , b , d
Q.8 Which of the following compound’s prefix ‘iso’ (C) a , b (D) a, b, c [C]
is not correct – [D]
(A) Iso pentane (B) Iso Hexane OH
(C) Iso butane (D) Iso octane Q.18 (a) and

CH2CH2OH

Q.10 The compound which has one isopropyl group (b)

is :
True statement for the above compounds is :
(A) 2,2,3,3-tetramethyl pentane
(A) (a) is phenol while (b) is alcohol [D]
(B) 2,2-dimethyl pentane
(C) 2,2,3-trimethyl pentane (B) Both (a) and (b) are primary alcohol

(D) 2-methyl pentane [D] (C) (a) is primary and (b) is secondary alcohol
(D) (a) is secondary and (b) is primary alcohol

CRA CLASSIFICATION & NOMENCLATURE 1

 The common name of given ester is -
Q.19 In homologous series : (A) neo butyl iso butyrate
(A) Molecular formula is same (B) t-butyl n- butyrate
(B) Structural formula is same (C) t- butyl iso butyrate
(C) Physical properties are same (D) iso butyl iso butyrate [C]
(D) General formula is same [D]
Q.25 The structure of allyl vinyl thioether is -
(A) CH2 = CH – CH2 – S – CH2 – CH = CH2
Q.20 Which of the following is the first member of (B) CH2 = CH – S – CH2 – CH = CH2
ester homologous series ? [C] (C) CH2 = CH – S – CH = CH2
(A) Ethyl ethanoate (B) Methyl ethanoate (D) None [B]
(C) Methyl methanoate (D)Ethyl methanoate

Q.21 Which of the following is the triad of a Q.26 Ethyl methyl vinyl amine has the structure -
homologous series - [D] (A) CH3CH2–N–CH2CH=CH2 [B](B) CH3CH2–N

(A) CH3NH2, (CH3)2NH, (CH3)3 N CH3 C

(B) C2H5OH, (CH3)2CHOH, (CH3)3COH (C) CH2=CH–N–CH=CH2 (D) CH3–N–CH

(C) Both the above CH3 CH3

(D) CH2 = CH2, CH3 – CH = CH2,
Q.27 Which of the following are correctly matched–
C2H5 – CH = CH2 (a) Trimethyl amine (CH3)3 CNH2 [C](b) Isobutyroni
Q.22 The homologue of phenol is - (c) Secondary butyl alcohol C2H5–CHOH
CH2OH OH CH3
CH3
(d) Acetoisonitrile CH3–N →
=C
(A) (B)
(A) a and b (B) b and c
(C) c and d (D) a and d
OH OH
OH Q.28 The structure of –butylene bromide is
(A) CH3–CH(Br) CH(Br)CH3
(C) (D) [B]
(B) CH2(Br)CH(Br)CH2CH3
(C) (CH3)2C(Br)CH2Br
Q.23 What is not true about homologous series ?
(D) None [A]
(A) All the members have similar chemical
properties Q.29 The structure of Isobutyro-isonitrile is : –
(A) CH3–CH–CH3–CN (B) CH3–CH–C
(B) They have identical physical properties
(C) They can be represented by a general CH3 CH3
formula (C) CH3–CH–CN
(D) Adjacent members differ in molecular mass
CH3
by 14 [B]
(D) CH3–CH–N = C
CH3 CH3
CH3
Q.24 CH3–CH–C–O–C–CH3

O CH3 Q.30 Which of the following is crotonic acid :

CRA CLASSIFICATION & NOMENCLATURE 2
 (A) CH2 = CH-COOH (D) 3-Methyl-2-ethyl pentane
(B) C6H5-CH=CH-COOH
(C) CH3-CH=CH-COOH F Cl
CH–COOH
Q.38 CH3 – C – CH2 – C – CH3
(D) [C]
CH–COOH
CH2CH3 CH2CH3
Q.31 The derived name of (CH3)4C is – The IUPAC name of this compound is :
(A) Tetramethylmethane (A) 2-fluoro-4-chloro-2,4-diethyl pentane
(B) 3-fluoro-5-chloro-3-methyl-5-ethyl hexane
(B) 2,2-Dimethylpropane
(C) 3-chloro-5-fluoro-3,5-dimethyl heptane
(C) Neopentane
(D) 3,5-dimethyl-5-fluoro-3-chloro heptane [C]
(D) None of these [A]
Q.32 The structural formula of isopropyl carbinol is– Q.39 The IUPAC name of the compound
CH3 CHCH2CH3 is:
(A) (CH3)2 CHOH
(B) CH3–CHOH–CH2–CH3 C6H5
(C) (CH3)2 CH.CH2OH (A) 2-cyclohexyl butane
(B) 2-phenyl butane
(D) (CH3)3COH [C]
(C) 3-cyclohexyl butane
Q.33 The derived name of butenyne is – (D) 3-phenyl butane [B]
(A) Vinylacetylene (B) Ethenylacetylene Q.40 What is the correct IUPAC name for the
(C) Ethenyl ethyne (D) Ethynyl ethane[A] following compound ?
CH3
Q.34 The derived name of iso-valeric acid is.
(A) Ethyl methyl acetic acid CH3(CH2)4CH–C–CH2CH2CH3
(B) iso-propyl acetic acid
CH3 CH2CH3
(C) trimethyl acetic acid
(A) 3,4 - Dimethyl -3-n - propyl nonane
(D) all are [B]
(B) 6, 7 - Dimethyl -2- n- propyl nonane
Q.35 Derived name of CH2=CH–CH2CO–CH3 is – (C) 6,7- Dimethyl -7- ethyl decane
(A) 1-Pentene-1-one (B) Allyl methyl ketone (D) 4- Ethyl- 4, 5 - dimethyl decane [D]
(C) 4-Pentene-2-one (D) Vinyl acetone [D] Q.41 The IUPAC name of C6H5–CH–CH2–CCl3 is ;

C6H5
Q.36 I.U.P.A.C. name of (CH3)2CH–CH2–CH2Br is
(A) 1,1,1-trichloro-3,3-diphenyl propane
(A) 1-bromo pentane
(B) 1,1-diphenyl-3,3,3-trichloro propane
(B) 2-methyl-4-bromo pentane (C) both (A) and (B)
(C) 1-bromo-3-methyl butane (D) none of these [A]
(D) 2-methyl-3-bromo propane [C]
Q.42 The IUPAC name of is -
Br
Q.37 Which one of the following I.U.P.A.C. name is
(A) 2-bromo-4-isopropylpentane
correct ? [C] (B) 2, 3-dimethyl-5-bromohexane
(A) 2-Methyl-3-ethyl pentane (C) 2-bromo-4, 5-dimethylhexane
(B) 2-Ethyl-3-methyl pentane (D) 5-bromo-2, 3-dimethylhexane [B]
(C) 3-Ethyl-2-methyl pentane Q.43 Give the IUPAC name of
CRA CLASSIFICATION & NOMENCLATURE 3
 CH3 (B) 2-ethyl- 2-propenoic acid
(C) 2- carboxy-1- butene
H3C–C–CH3
(D) None of the above [B]
CH3–CH2–CH2–CH–CH– CH2–CH2–CH3
Q.49 The correct IUPAC name of :
H3C–CH CH3–CH2–CH–CH2COCl

CH3 CH3
(A) 4-isopropyl-5-ter. butyl octane [B] (A) 3-methyl pentanoyl chloride
(B) 4-ter. butyl-5-isopropyl octane (B) 3-methyl butanoyl chloride
(C) 2-methyl-3-propyl-4-ter. butyl heptane (C) 1-chloro-3-ethyl butanone
(D) 1-chloro-3-methyl pentanone [A]
(D) 2, 2-dimethyl-3-propyl-4-isopropyl heptane
Q.44 The IUPAC name of the compound Br (Cl) Q.50 IUPAC name of the following compound is –
CH.CF3 is : [C] O
(A) haloethane CH3–CH CH–C–CH2Br
(B) 1, 1, 1- trifluoro-2-bromo-2- chloroethane
C
(C) 2-bromo-2-chloro-1, 1, 1- trifluoroethane O
(D) 1-bromo-1-chloro-2, 2, 2- trifloro ethane H3C CH3
(A)1-Bromo-3,5-epoxy-4,4-dimethyl-
2-hexanone [A]
Q.45 The IUPAC name of is - (B) 1-Bromo-3,3-dimethyl-2-oxo-2-hexanone
(C) 1-Bromo-3,3-dimethyl acetone
(A) 4-ethyl -3- methyl hexane
(B) 3-ethyl -4- methyl hexane (D) 1-Bromo-4,4-dimethyl-5-oxo-hexanone
(C) 3-methyl -4- ethyl hexane
Q.51 The correct name of 3,3-dimethyl propanamide
(D) None of these [B]
is
Q.46 The I.U.P.A.C. name of (C2H5)2 CH.CH2 OH is (A) 2-methyl butanamide
(A) 2-ethyl butanol-1 (B) 3-methyl butanamide
(B) 2-methyl pentanol-1 (C) iso-propyl ethanamide
(C) 2-ethyl pentanol-1 (D) iso propyl acetamide [B]
(D) 3-ethyl butanol-1 [A] OH

Q.47 I.U.P.A.C. name of compound is Q.52 IUPAC name of is :

CH3–CH–CH2–CHOH–CH3
OH
CH2CH3 (A) But-2-ene-2,3-diol
(A) 4-methyl-3-hexanol (B) Pent-2-ene-2,3-diol
(B) heptanol (C) 2-methylbut-2-ene-2,3-diol
(C) 4-methyl-2-hexanol (D) Pent-3-ene-3,4-diol [B]
(D) none of these [C] Q.53 The IUPAC name of

Q.48 The correct IUPAC name of BrCH2–CH–CO–CH2–CH2CH3 is :

CH3–CH2–C–COOH CONH2
is :
CH2 (A) 2-bromo methyl-3-oxo hexanamide
(A) 2-methyl butanoic acid (B) 1-bromo-2-amido-3-oxo hexane

CRA CLASSIFICATION & NOMENCLATURE 4

 (C) 1-bromo-2-amido-n-propyl ketone (C) -one, carboxy, chloro, methyl, hydroxy,
(D) 3-bromo-2-proponyl propanamide [A] 4-heptene
(D) -one, carboxy, chloro, methyl, hydroxy,
Q.54 The IUPAC name of 4-heptene [B]

CH3–CH2–CH–COOC2H5 is Q.59 The IUPAC name of compound

COOH–CH–COOH
CH3
(A) 2-ethyl-ethyl acetate COOH
(B) ethyl 3-methyl butanoate (A) Tricarboxy methane
(B) Propane trioic acid
(C) ethyl 2-methyl butanoate
(C) Tributanoic acid
(D) 2-methyl butanoic acid ethylester [C]
(D) 2- carboxy propanedioic acid [D]
O OH
Q.55 The IUPAC name of N  C–CH2–CH2–OH is;
(A) 1-hydroxy ethanenitrile Q.60 The IUPAC name of is -
(B) 3-hydroxy propanenitrile (A) 4-oxo-2-pentanol
(C) 2-hydroxy ethyl cyanide (B) 4-hydroxy-2-pentanone
(D) 1-hydroxy-2-cyanoethane [B] (C) pentane-4-ol-2-one
CHO (D) pentane-2-one-4-ol [B]

Q.56 CH3–CH2–CH–CH–CH3 Q.61 The I.U.P.A.C name of the compound having

structure C2H5 – C –– CH – CH3 is :
CH3
The IUPAC name of this compound is CH2 CH3
(A) 2-isopropyl butanal (A) 3-methyl-2-ethyl butene-1
(B) 2-ethyl-3-methyl butanal (B) 2-ethyl-3-methyl butene-1
(C) 3-ethyl-2-methyl butanal (C) 3-ethyl-3-methyl butene-1
(D) 2-methyl pentane-3-aldehyde [B] (D) ethyl isopropyl ethane [B]

Q.57 The IUPAC name of Q.62 The IUPAC name of CH2 = CH – C  CH is –

CH2CHO (A) 1–Butenyne–3 (B) 1–Butynene–3
OHC–CH2–CH2–CH–CH2–CHO is : (C) Vinyl acetylene (D) all of them [A]

(A) 4, 4-di(formylmethyl) butanal

(B) 2-(formylmethyl) butane-1, Q.63 I.U.P.A.C. name of, is
4-dicarbaldehyde
(C) hexane-3-acetal-1, 6-dial (A) 4, 5-dimethyl oct-4-ene
(D) 3-(formylmethyl) hexane-1, 6-dial [D] (B) 3, 4-dimethyl oct-5-ene
Q.58 The suffix of the principal group, the prefixes (C) 4, 5-dimethyl oct-5-ene
for the other groups and the name of the parent (D) None [A]
in the structure
Q.64 The correct IUPAC name of 2-ethyl-3-pentyne
HO–CH2–CH–CH=C–CH2–C–C–OH
is :
CH3 Cl O O (A) 3-methyl hexyne-4
are given by the set : (B) 4-ethyl pentyne-2
(A) -oic acid, chloro, hydroxy, oxo, methyl, (C) 4-methyl hexyne-2
4-heptene (D) None of these [C]
(B) -oic acid, chloro, hydroxy, methyl, oxo,
4-heptene
CRA CLASSIFICATION & NOMENCLATURE 5
Q.65 The I.U.P.A.C. name of following structure
(CH3) C.C.C. (CH3) CH (CH3) is - Q.71 The IUPAC name of is -
OH
(A) 3-methyl-4-hexynene-2
(A) 3-hydroxycyclohexene
(B) 3-methyl-2-hexenyne-4 (B) cyclohexen-3-ol
(C) 4-methyl-4-hexenyne-4 (C) 2-cyclohexenol
(D) all are correct [B] (D) 2-ene-cyclohexan-1-ol [C]

Q.72 The IUPAC name of the given compound

Q.66 The IUPAC name of is -
(A) 2-ethyl-3-methyl-1-penten-4-yne is -
(B) 2-ethyl-3-methyl-4-pentyn-1-ene
(C) 4-ethyl-3-methyl-1-pentyn-4-ene (A) Octylcyclopentane
(D) 4-ethyl-3-ethyl-4-penten-1-yne [A] (B) 3-cyclopentyloctane
(C) cyclopentaneoctane
Q.67 The IUPAC name of the given compound is :
(D) 6-cyclopentyloctane [B]
CH3 Q.73 The IUPAC name of the compound is :
HO CH3 H
(A) 1, 1-dimethyl-3- hydroxy cyclohexane CH3
C–CH
(B) 3,3-dimethyl-1-hydroxy cyclohexane
CH3
(C) 3, 3-dimethyl-1-cyclohexanol NH2
(D) 1,1-dimethyl-3-cyclohexanol [C] (A) 1-amino-1-phenyl-2-methyl propane
(B) 1-amino-2-methyl-1-phenyl propane
(C) 2-methyl-1-amino-1-phenyl propane
Q.68 The IUPAC name of the compound
Cl (D) 1-isopropyl-1-phenyl methyl amine [B]
Br
is -(A) 1-chloro-2-bromocylohexane Q.74 The IUPAC name of O2N CHO is:
(B) 1, 2-bromochlorocyclohexane
(C) 4-bromo-3-chlorocyclohexane OCH3
(D) 1-bromo-2-chlorocyclohexane [D] (A) 2-methoxy-4-nitro benzaldehyde
(B) 4-nitro anisaldehyde
(C) 3-methoxy-4-formyl nitro benzene
(D) 2-formyl-4-nitro anisole [B]
OH
Q.69 The IUPAC name of is O
CH3
(A) 3-Methyl cyclo-1-buten-2-ol Q.75 The IUPAC name of C–CH3 is :
(B) 4-Methyl cyclo-2-buten-1-ol
(A) phenyl ethanone
(C) 4-Methyl cyclo-1-buten-3-ol
B) methyl phenyl ketone
(D) 2-Methyl cyclo-3-buten-1-ol. [B]
(C) acetophenone
Q.70 The IUPAC name for the compound : (D) phenyl methyl ketone [A]
O COOC2H5
H2C CH–CH3 Q.76 The IUPAC name of is :
(A) Propylene Oxide COCl
(B) 1, 2-Oxo propane (A) 2-chlorocarbonyl ethylbenzoate
(C) 1, 2-Epoxy propane (B) 2-carboxyethyl benzoyl chloride
(D) 1, 2-Propoxide. [C] (C) ethyl-2-(chlorocarbonyl) benzoate
(D) ethyl-1-(chlorocarbonyl) benzoate [C]

CRA CLASSIFICATION & NOMENCLATURE 6

 NH2 OH
COOH
Q.82 The IUPAC name of is –
Q.77 The IUPAC name of is -
(A) bicyclo [3.2.0] hexan-2-ol
(A) 1-amino-2-carboxybenzene
(B) spiro [3.2] hexan-1-ol
(B) 2-amino-1-carboxybenzene
(C) spiro [3.2] hexan-4-ol
(C) 1-amino-2-benzenecaroxylic acid
(D) spiro [2.3] hexan-4-ol [D]
(D) 2-aminobenzenecarboxylic acid [D]

CH2OH Q.83 The IUPAC name of camphor is - [B]

Q.78 The systematic name for OH is :

(A) ortho hydroxy methyl phenol O

(B) 2-hydroxy benzyl alcohol
(C) salicyl alcohol
(A) 6-oxo-1,2,2- trimethyl bicyclo [2,2,1]
(D) 2-hydroxy methyl phenol [B]
heptane
(B) 1,7,7-trimethyl bicyclo [2,2,1] heptan-2-one
Q.79 The IUPAC name of (C) 1,5,5-trimethyl bicyclo [2,1,1] hexan-2-one
CH3 O (D) 1,7,7-trimethyl bicyclo [2,1,2] heptan-2-one
CH–O–C–CH3
is -
(A) 1-phenyl-1-acetyloxyethane
(B) 1-acetoxyethylbenzene Q.84 The IUPAC name of compound is -
(C) 1-phenylethyl ethanoate
(D) 1-methylbenzyl acetate [C]

(A) Bicyclo [2.2.1] hept-2-ene

(B) Bicyclo [2.2.1] hept-5-ene
Q.80 The name of the compound is - (C) Bicyclo [2.1.2] hept-2-ene
(A) bicyclo [2.2.1] octane (D) Bicyclo [1.2.2] hept-2-ene [A]
(B) bicyclo [1.1.1] octane Q.85 The IUPAC name of compound is -
(C) 1, 4-bismethylenecyclohexane
(D) bicyclo [2.2.2] octane [D] (A) Spiro [5.3] nonane
(B) Spiro [3.5] nonane
Q.81 Which of the following structures represents (C) Spiro [5.4] nonane
bicyclo [3.2.0] heptane - [C] (D) Spiro [4.5] nonane [B]
Q.86 The molecular formula of the first member of
the family of alkenynes and its name is given by
the set:
(A) (B)
(A) C3H2 , allene
(B) C5H6 , 1-penten-3-yne
(C) C6H8 , 1-hexen-5-yne
(C) (D) (D) C4H4 , butenyne [D]

Q.87 Formula of vinyl methanoate is:

(A) CH3 – C – O – CH = CH2
O

CRA CLASSIFICATION & NOMENCLATURE 7

 (B) CH3 – CH2 – C – O – CH3 (A) Acetonitrile CH2 = CHCN
CH2
O (B) Allyl chloride CH2 = CH – C
(C) CH 2 = CH – O –C–H
CH2 (C) s-Butyl group CH3–CH–C2H
O
(D) Ethylene chloride
(D) H – C – O – CH2 – CH = CH2 [C]
CH2Cl –CH2Cl [A]
O
Q.94 Choose the correctly matched pair from the
Q.88 The general molecular formula of nitroalkanes is :
(A) CnH2nNO2 codes given below :
(B) Cn + 1 H2n + 3 NO2 (1) 2-Octanone (A) CH3(CH2)5COCH3
(C) Cn + 1 H2n NO2
(D) Cn + 1 H2n + 2 NO2 [B] (2) Trimethyl amine (B) (CH3)3C–NH2

Q.89 Write the correct IUPAC name of the following (3) Acrolein (C) CH2 = CH – CN
bond line formula :
(4) Vinyl acetylene (D) CH2 = CH – C 
N
CH
(A) N-Methyl N-Ethyl propanamine
` Code is :
(B) N-Ethyl N-methyl propane 1-amine
(A) 1 and 4 (B) 2 and 3
(C) N-Methyl N-propyl ethan 1-amine
(C) 2 and 4 (D) 1 and 3 [A]
(D) N-Ethyl N-propyl N-methyl amine [B]
Q.95 Number of heteroatoms present in the following
CH3 heterocyclic compound :
O
Q.90 The derived name of (CH3)3 C – C – OH is –
O
C2H5
O
(A) t-Butyl ethyl methyl carbinol
(A) 3 (B) 2
(B) t-Butyl ethylethanol (C) 1 (D) zero [C]
(C) t-Butyl ethyl methyl methanol
(D) None of these [A] Q.96 Number of 3° carbon and 1° hydrogen
respectively in the following structure are :
Q.91 CH3–CH(CH3)CH2–C  C–CH=CH2 its derived Me Me Me H
name is H – C – C – C – C – Me
(A) 6-methyl-1-heptenyne-3 Me H Me Me
(B) iso-butyl vinyl acetylene (A) 3, 21 (B) 3, 23
(C) 2, 18 (D) 3,18 [A]
(C) iso hexynyl ethylene
(D) None [B] Q.97 Which of the following compound is wrongly
named ? [B]
Q.92 IUPAC name of isobutyraldehyde is : (A) CH 3CH 2CH 2CHCOOH ;
(A) 2-methyl propanal Cl
(B) 2, 2-dimethylethanal 2-Chloro pentanoic acid
(B) CH3CCCHCOOH ;
(C) 2,2-dimethyl acetaldehyde
(D) Isopropyl aldehyde [A] Cl
2-Methyl hex-3-enoic acid
Q.93 Which of the following is not correctly (C) CH3CH2CH = CHCOCH3 ;
matched: Hex -3- en-2- one

CRA CLASSIFICATION & NOMENCLATURE 8

 (D) CH3–CHCH2CH2CHO ; (D) none of these [A]
CH3 Q.103 IUPAC name of,
4-Methyl pentanal OHC–CH=CH–CH–CH=CH2
Q.98 The I.U.P.A.C. name of following structure is OCH2CH3
CH2CH2CH2CH3 is :
[CH3CH(CH3)]2 C(CH2 CH3) C(CH3) C (CH2
CH3)2 (A) 4-butyl-2,5-hexadien-1-al
(A) 3,5-diethyl-5-[1-methylethyl]-4,6-dimethyl- (B) 5-vinyloct-3-en-1-al
3- heptene (C) 5-vinyloct-5-en-8-al
(B) 3,5-diethyl-5-isopropyl-4,6-dimethyl-2- (D) 3-butyl-1,4-hexadien-6-al [A]
heptene
(C) 3,5-diethyl-5-propyl-4,6-dimethyl-3- Q.104 The IUPAC name of
heptene CH–CH–CH2–C–(CH3)2
(D) None of these [A] OCH2CH3
OH OH is :
Q.99 The IUPAC name of the compound is :
CH.COOH (A) 2-methyl-2,4-dihydroxy propane
(B) 2,2-dimethyl-4-hydroxy butanol
(C2H5)2NCH2Cl (C) 2-methyl-2,4-pentane diol
(A) 2- chloro-4- N-ethylpentanoic acid
(D) 2-hydroxy-4,4-dimethyl butanol-4 [C]
(B) 2- chloro-3- (N, N-diethyl amino)-propanoic
acid
(C) 2- chloro-2- oxo diethylamine
(D) 2- chloro-2-carboxy-N-ethyl ethane [B]
Q.105 The correct IUPAC name of :
Q.100 The IUPAC name of the compound is :
CH3 – CH = CH – CH3
O CN
C2H5 C2H5
CH3–C–CH2–C–CH3
(A) 1, 2-diethyl butane
CH3 (B) 2-ethyl 3-methylpentane
(A) 4- cyano-4-methyl -2- oxo pentane (C) 3, 4-dimethyl-3-hexene
(B) 2-cyano-2-methyl-4-oxo pentane (D) none is correct [C]

(C) 2, 2-dimethyl -4- oxo pentanenitrile

(D) 4- cyano-4-methyl-2-pentanone [C] Q.106 IUPAC name of OH is :
CH3
OH
(A) 5-methyl hexanol
Q.101 Correct IUPAC name of is – (B) 2-methyl hexanol
CH3 (C) 2-methyl hex-3-enol
(A) 3-Methylcyclopentanol (D) 4-methyl pent-2-en-1-ol [D]
(B) 4-Methylcyclopentanol
Q.107 IUPAC name of the compound,
(C) 1-Hydroxy-3-Methylcyclopentanol
(D) None [A] OH is :
(A) But-2-en-l-ol
O
(B) 1-hydroxy but-1-ene
Q.102 CH3–CH–C–CH–OCH2CH3 (C) 4-hydroxy butene-3
OCH3 CH3 (D) But-1-en-1-ol [D]
The IUPAC name of this compound is
Q.108 The IUPAC name of
(A) 2-ethoxy-4-methoxy pentan-3-one
CH3CH2 – N – CH2CH3
(B) 2-methoxy-4-ethoxy-pentan-3-one
CH3 is:
(C) 2-ethoxy-4-methoxy pentan-3-one
CRA CLASSIFICATION & NOMENCLATURE 9
 (A) N-methyl-N-ethylethyl amine (C) 3-Hydroxy-3-Carboxy-1, 5-pentane dioic
(B) diethyl methyl amine acid
(D) None [B]
(C) N-ethyl-N-methyl ethan amine
(D) methyl diethyl amine [C] Q.115 One among the following is the correct IUPAC
name for the compound
Q.109 The IUPAC name of C6H5CH = CH – COOH H
is :
CH3CH2 – N – CHO
(A) cinnamic acid (A) N-Formyl aminoethane
(B) 1-phenyl-2-carboxy ethene (B) N-Ethyl formyl amine
(C) 3-phenyl prop-2-enoic acid (C) N-Ethyl methanamide
(D) Ethylamino methanal. [C]
(D) dihydroxy-3-phenyl propionic acid [C]
Q.116 The systematic name for
Q.110 The IUPAC name of
HO – C – C = C –– CH – CH3 is [C]
CH=CH–CHCH2CH3 is
O CH3 NH2 Cl
CH3 (A) 2-methyl-3-amino-4-chloro-2-pentenoic
(A) 1-cyclohexyl-3-methyl-1-pentene acid
(B) 1-hydroxy-1-oxo-2-methyl-3-amino-4-
(B) 3-methyl-5-cyclohexyl-pent-ene chloro-
(C) 1-cyclohexyl-3-ethyl-but-1-ene 2pentene
(D) 1-cyclohexyl-3,4-dimethyl-but-1-ene [A] (C) 3-amino-4-chloro-2-methyl-2-pentenoic acid
(D) 3-amino-2, 4-dimethyl-4-chloro-2-butenoic
Q.111 The systematic name of acid
CH3–C–O – CH2 – C – OH Q.117 The IUPAC name of C6H5CH2CH2NH2 is :
O O is : (A) -phenyl ethylamine
(A) 1-acetoxy acetic acid (B) 2-phenyl aminoethane
(B) 2-acetoxy ethanoic acid (C) 2-phenyl ethanamine
(C) 2-ethanoyl oxyacetic acid
(D) benzyl methyl amine [C]
(D) 2-ethanoyl oxyethanoic acid [D]
Q.112 The IUPAC name of (CH3)2 CH-CO-O-CH2-
Q.118 The IUPAC name of
CH3 is :
CH3 – NH – CH – CH2 – CH – CH3
(A) Ethyl butyrate
(B) Isopropyl propionate CH3 CH3 is :
(C) Ethyl-2-methyl propanoate (A) 2- (N-methyl amino) -4-methyl pentane
(D) Isobutyl ethanoate [C]
(B) N, 4-dimethyl pentan-2-amine
Q.113 The IUPAC name of
CH–CH3 (C) 2-(N-methyl amino)-3-isopropyl propane
(D) 2-(N-methyl amino)-1, 4, 4-trimethyl
HC  C – C  C – C – CH2 – CH3 is : butane [B]
(A) 5-ethyl- 5-heptene-1, 3- diyne
(B) 3-ethyl- 2-heptene-4, 6- diyne
Q.119 CH3 – O – C – CH2 – COOH
(C) 5-ethenyl-1, 3- heptatriyne
(D) 3-ethenyl-4, 6-heptatriyne [A] O
Q.114 The IUPAC name of compound The correct systematic name of the above
O compound is :
CH2 – C – OH (A) 2-acetoxy ethanoic acid
OH (B) 2-methoxy carbonyl ethanoic acid
C
COOH (C) 3-methoxy formyl ethanoic acid
CH2–COOH (D) 2-methoxy formyl acetic acid [B]
(A) 1,2,3-tricarboxy -2,1- propane
(B) 3-Carboxy-3-hydroxy-1,5 -pentane dioic Q.120 The IUPAC name of
acid

CRA CLASSIFICATION & NOMENCLATURE 10

 CH2 = CH H CH3 is -
Q.126 The IUPAC name of
HC  C – CH2 – CH2 – C = CH – C = O is : (A) 3-cyclobutylcyclopropane
(A) 3-(1-butynyl)-3-vinyl-2-pentadienal (B) 1-cyclopropyl-3-methylcyclobutane
(B) 5-ethynyl-3-vinyl-2-pentenal (C) 1, 3-cyclopropylmethylcyclobutane
(C) 3-vinyl-2-heptene-6-ynal (D) 2-methylbicyclo [4.3.0] heptane [B]
(D) 5-acetylenyl-3-ethenyl-2-pentenal [C]
O
Q.121 The IUPAC name of
Q.127 The IUPAC name of Cl
CH3
O
CH3CHOHCH2 – C – OH is - is -
CH3 (A)(2-chloro-1-methyl)ethyl-2-
(A) 1, 1-dimethyl-1, 3-butanediol methylpropanoate
(B) 4-methyl-2, 4-pentanediol (B) 2-chloropropyl 2-methylpropanoate
(C) 1, 3, 3-trimethyl-1, 3-propanediol (C) chloroisopropyl isobutyrate
(D) 2-methyl-2, 4-pentanediol [D] (D) 1, 2-dimethyl-2-chloroethylpropanoate [A]

Q.122 The IUPAC name of Q.128 The IUPAC name of

O O
Ph Ph
(CH3)2 CH(CH2)2 – C – N(CH3)2 is - O is -
(A) N, N, 4-trimethylpentanamide (A) benzyl benzoate
(B) dimethylamino-4-methylpentanone (B) 2-phenylethyl phenylacetate
(C) N, N-dimethylamino-4-methylpentanamide (C) 2, 2-diphenyl ethylethanoate
(D) 2-methyl-5-oxodimethylpentanamine [A] (D) 2-phenylethyl phenylethanoate [B]

HO C  CH
Q.123 The IUPAC name of C = CH – CH3 is - Q.129 The IUPAC name of is -
H5C2
(A) 3-cyclopropyl-3-ethyl-2-propene (A) 1-ethynyl-1-hydroxycyclohexane
(B) 1-cyclopropyl-1-ethylpropene (B) 1-(hydroxycyclohexyl) ethyne
(C) 3-cyclopropyl-2-pentene
(C) 1-ethynylcyclohexanol
(D) (1-ethyl-1-propenyl) cyclopropane [C]
(D) 1-acetylenyl-1-hydroxycyclohexane [C]
CN
COOH
Q.124 The IUPAC name of is -
Q.130 The IUPAC name of is
COOH
(A) 2-cycano-3-ethyl-4-methylpentane (A) 6-carboxy-2, 3-dimethyl-4-heptenoic acid
(B) 3-isopropyl-2-methylpentanenitrile (B) 2, 3, 6-trimethyl-1-heptene-1, 7-dioic acid
(C) 3-ethyl-2, 4-dimethylpentanenitrile (C) 2, 5, 6-trimethyl-3-heptenedioic acid [C]
(D) 3-isopropyl-2-pentylcyanide [C] (D) 6-carboxy-2, 5-dimethyl-3-heptenoic acid
O
Q.131 The IUPAC name of
Q.125 The IUPAC name of is - CH2–CH3
O OH HOCH2 – CH – CH – OH is -
(A) 5-hydroxy-3, 4-hxanedione
(B) 3, 4-dioxo-2-hexanol CH3–CH–OH
(C) 2-hydroxy-3, 4-hexanedione (A) 3-hydroxymethyl-2, 4-hexanediol
(D) 2-hydroxy-3, 4-diketohexane [C] (B) 4-hydroxymethyl-3, 5-hexanediol
(C) 4-hydroxyethyl-3, 5-pentanediol
CRA CLASSIFICATION & NOMENCLATURE 11
 (D) 2-(1-hydroxyethyl)-1, 3-pentanediol [A] CH2–CH3

CH3–CH–CH2–C–OH
Q.132 The IUPAC name of
O OH CH2–CH3 is :
(A) 2, 4 - Hexanediol
CH3 – C – OCH2CH = CH CH3 is -
(B) 4-Ethyl-2,4-hexanediol
(A) 1-acetyloxy-2-butene (C) 2,4-Hexanediol-2-ethyl
(B) 4-acetoxy-2-butene (D) 3, 3 -Diethyl-1, 3-butanediol [B]
(C) 2-butenyl ehtanoate Q.139 The IUPAC name of the given compound
(D) methyl-2-butanoate [C] Br

Cl–C–CHO is :
Q.133 The IUPAC name of BrCH2CH2OCH = CH2 is -
(A) Bromoethyl ethenyl ether F
(B) 1-bromo-2-ethenyloxyethane (A) 2-Bromo-2-chloro-2-fluoroethanal
(B) 1-Bromo-1-chloro-2-fluoroethanal
(C) (2-bromoethoxy) ethene
(C) 2-Fluoro-2-chloro-2-bromoethanal
(D) 1-bromo-2-ethoxyethene [C]
(D) 1-Fluoro-1-chloro-1-bromoethanal [A]
Me
HO
Q.134 The IUPAC name of is - Me Me
O Q.140
Me Me
(A) 2-acetyl-2-buten-1-ol
(B) 3-hydroxymethyl-3-penten-2-one The IUPAC name of the above structure is :
(C) 3-ethylidene-4-hydroxy-2-butanone (A) 2, 4, 5 - Triethyl-3-nonene
(D) 3-acetyl-2-buten-4-ol [B] (B) 5, 6 - Diethyl -3- methyl -4-decene
(C) 2, 4, 5 - Triethyl -3- octene
Q.135 The IUPAC name of the given structure is - (D) 3 - Heptyl - 5- methyl-3- heptene [B]

Cl Q.141 x-Ethyl-y, z- dimethyl-p-heptanol is the IUPAC

Br name of the compound -
(A) 5-Bromo-6-chloro-1-cyclohexen-3-yne (CH3)2C(C2H5)–CH(C2H5)–CH–CH2–CH3
(B) 6-Bromo-5-chlorocyclohexen-3-yne
(C) 6-Bromo-5-chloro-3-cyclohexen-1-yne OH
(D) 4-Bromo-3-chloro-1-cylohexen-5-yne [A] x, y, z, p are -
(A) 4, 5, 5, 3 (B) 1,2, 2, 4
Q.136 The IUPAC name of (C) 4, 3, 3, 5 (D) None [A]
CH3–CH2–CH–CH2–CH2–NH–CH3

CH3 Q.142 The IUPAC name of following polyfunctional

is -
(A) 1-(Methyl amino)-3-methylpentane compound is -
(B) 3-(Methyl amino) hexane OHC O
COOH
(C) 3-Methyl hexane amine
(D) 3-Methyl-N-Methyl pentane [A] H H
(A) 2,4-dioxo cyclohexanoic acid [C]
Q.137 The IUPAC name of [(CH3)3C]4C is - (B) 2,4-dioxo cycloheptanoic acid
(A) tetra-t-butyl methane (C) 4-formyl-2-oxocyclohexane-1carboxylic
(B) 3, 3-bis(1, 1-dimethyl ethyl) -2, 2, 4, 4- acid
tetramethyl pentane (D) 2,4-dioxo cyclohexane-1-carboxylic acid
(C) tetra kis (1, 1-diemthyl ethyl) methane
(D) tetraneobutyl methane [B] Q.143 IUPAC name of the compound

Q.138 The IUPAC name of the given compound

CRA CLASSIFICATION & NOMENCLATURE 12

 CH3 (C) 1-(1-methylethyl) cyclobutene
CH3–C–COOC2H5 is - [C] (D) 3-(1-methylethyl) cyclobutene [D]

O OH

NO2 OH
Q.148 The IUPAC name of is -
(A) ethyl-2-methyl-2-(m-nitro) phenyl propanoate O
(B) ethyl-2-methyl-2-(o-nitro) phenyl propanoate (A) 4-carboxy-5-methylheptanoic acid
(C) ethyl-2-methyl-2-(3-nitro) phenyl propanoate (B) 1, 3-dicarboxy-4methylhexane [D]
(C) 4-(1-methylpropyl)-1, 5-pentanedioic acid
(D) ethyl-2-methyl-2-(3-nitro) phenyl propanoic
(D) 2-(1-methylpropyl)-1, 5-pentanedioic acid
acid

Q.144 The IUPAC name of the given compound

CHO CONH2 Q.149 The IUPAC name of N is -
CH3–CH–CH––CH–CH–COOH
(A) N-ethyl-N, 2-dimethyl-4-hexanamine
Br COCl is - (B) N, 4-diethyl-N, 2-dimethyl-4-butanamine
(A) 2-Bromo-4-carbamoyl-5-chloroformyl-3- (C) N-ethyl-N, 5-dimethyl-3-hexanamine
formylhexanoic acid (D) 3-(ethylmethylamino)-5-methylhexane [C]
(B) 5-Bromo-3-carbamoyl-2-chloroformyl-4- O
O
formylhexanoic acid
Q.150 The IUPAC name of OH is -
(C) 4-Formyl-2-chloroformyl-5-carbamoyl-5-
bromohexanoic acid (A) 2-carboxyethylcyclohexanone
(D) 2-Chloroformyl-3-carbamoyl-4-formyl-5- (B) 3-(2-oxocyclohexyl) propanoic acid
bromohexanoic acid [B] (C) cyclohexanone-2-propanoic acid
(D) 2-propanoic cyclohexanone [B]

Q.145 The IUPAC name of CH=CHCH3

CH3–C=C––CH–CH2–C  CH is - [A] Cl
Q.151 The IUPAC name of is -
Cl CH3 C2H5
Cl
(A) 6-Chloro-4-ethyl-5-methyl-5-hepten-1-yne
(A) 1-(2, 4-dichlorophenyl) propene
(B) 5-methyl-4-ethyl-6-chloro-5-hepten-1-yne
(C) 6-Chloro-4-ethyl-5-methyl-1-hepten-5-yne (B) 2, 4-dichloro-1-(1-propenyl) benzene
(D) 2-Chloro-4-ethyl-methyl-6-hepten-2-ene] (C) 1, 3-dichloro-4-propenylbenzene
(D) 3-(2, 4-dichlorophenyl) propene [A]
O
OH
Q.146 The IUPAC name of C–O–CH2CH3 is -
(A) ethyl cyclohexanoate Q.152 The IUPAC name of is -
(B) cyclohexyl propanoate O H
(C) ethoxycyclohexyl ketone (A) 2-formyl-3-hydroxy-4-methylenepentane
(D) ethyl cyclohexanecarboxylate [D] (B) 4-formyl-2-methyl-1-penten-3-ol
CH3 (C)3-hydroxy-2-methyl-4-methylenepentanal
(D) 3-hydroxy-2, 4-dimethyl-4-pentenal [D]
Q.147 The IUPAC name of CH–CH3 is -
Q.153 Give systematic name of the following :
(A) 2-cyclobutenylpropane
(B) 2-(2-cyclobutenyl) propane

CRA CLASSIFICATION & NOMENCLATURE 13

 CH3–CH–CHO (A) 7,7-Dimethyl bicyclo [3.1.1] hept-3-ene-2-one
(B) 6,6-Di-methyl bicyclo [3.1.1] hept-3-ene-2one
(C) 2,2-Dimethyl bicyclo [3.1.1] hept-5-ene-4-one
(A) 2-cyclobutyl propanal
(D) 5,5-Dimethyl bicyclo [3.1.1] hept-2-ene-1-one
(B) 2-cyclobutyl 2-methyl ethanal
(C) 2-cyclobutyl propane-3-al Q.158 Write the correct IUPAC name of the following
(D) cyclobutane propane-1-al [A] spiro compound :

Q.154 Give IUPAC name of the following structure :

(A) Spiro [4.5] deca-1,7-di-ene
(B) Spiro [4.5] deca-2,7-di-ene
(C) Spiro [4.5] deca-1,6-di-ene
(A) 4-ethyl 5-ethenyle 2,7-dimethyl octane (D) Spiro [4.5] nona-1,6-di-ene [C]
(B) 4-ethyl-3-(2’-methyl propyl)hept-1-ene
(C) 3(1’-ethyl 3’-methyl butyl) 5-methyl
hex-1-ene Q.159 Give IUPAC name of the following :
(D) None of these [B] O OC2H5
C

Q.155 Give IUPAC name of the following structure :

COOH

Br
Cl (A) Ethyl-1-bromo 4-benzoate
(A) 3-chloro-2-(1-propenyl)-2,4-hexa-di-enoic (B) Ethyl-4-bromobenzoate
acid (C) Bromo benzoate
(B) 4-chloro-5-(1-propenyl) 2,4-hexa-di-enoic acid (D) Bromo benzene ester [B]
(C) 3-chloro 2,3-di(1-propenyl) propanoic acid
(D) 4-carboxy 5-chloro octa-2, 4,6-tri-ene [A]
Q.160 Give IUPAC name of the following :
Q.156 Write the correct IUPAC name of the following CH2CHO
bond line formula : Br

CHO
(A) 2(-2-Bromophenyl)ethanal
(B) 2-Bromo phenyl ethanal
(A) 3-(1’-methyl propyl)-4-methyl pent-3-enal
(C) 2-Bromo benzene ethanal
(B) 3-Iso propenyl-4-methyl hexanal
(D) Bromo benzene carbaldehyde [A]
(C) 3,5-di-methyl hex-4-en-al
(D) None of these [A] Q.161 Of the following compounds which has a wrong
IUPAC name -
Q.157 Write the correct IUPAC name of the following
–C–
bicyclic compound : [B]
O  CH3 – CH2 – CH2 O O – CH2 – CH3
ethyl butanoate

CRA CLASSIFICATION & NOMENCLATURE 14

 CH3–CH––C–CH–CH3 (A) 1, 1-diethyl-2-dimethylpentane

 CH3 O CH3 (B) 4, 4-dimethyl-5, 5-diethylpentane

2,4 dimethyl -3- pentanone
(C) 5, 5-diethyl-4, 4-dimethylpentane
CH3
H3C–CH–CH–CH3 (D) 3-ethyl-4, 4 dimethylheptane

 OH Q.166 The correct decreasing order of priority for the

2-methyl -3- butanol
functional groups of organic compounds in the
IV CH3 – CH2 – CH2 – CHO
IUPAC system of nomenclature is
butanal
(A)  (B)  (A) –SO3H, –COOH, –CONH2, –CHO
(C)  (D) IV [C]
(B) –CHO, –COOH, –SO3H, –CONH2
Q.162 The IUPAC name of CH3COCH(CH3)2 is – (C) –CONH2, –CHO, –SO3H, –COOH
(A) 4-methylisopropyl ketone
(D) –COOH, –SO3H, –CONH2, –CHO [D]
(B) 3-methyl-2-butanone
(C) Isopropylmethyl ketone
(D) 2-methyl-3-butanone [B]
Q.167 The correct IUPAC name of the compound is-

Q.163 The IUPAC name of the compound

CH3
is – CH3–CH2C=CH–CHCH2CH3
HO
CH3CH2–CH–CH2CH2CH2CH3
(A) 3,3 -dimethyl-1-hydroxy cyclohexane
(B) 1, 1 – dimethyl–3– hydroxy cyclohexane (A) 5,6-diethyl-8-methyl dec-6-ene
(C) 3,3-dimethyl-1-cyclohexanol (B) 5,6-diethyl -3-methyl dec -4-ene
(D) 1,1 - dimethyl - 3- cyclohexanol [C] (C) 6-butyl-5-ethyl-3-methyl-oct-4-ene
(D) 2,4,5-triethyl-3-ene [B]
Q.168 IUPAC name of the compound is
Q.164 The IUPAC name of the compound shown
CH3
below is - [B]
CH3–N–––C–CH2CH3
Cl
CH3 CH2CH3

(A) 3-dimethyl amino-3-methyl pentane

Br
(B) 3(N,N-trimethyl) 3 - amino pentane
(A) 6-bromo-2-chlorocyclohexene
(B) 3-bromo-1-chlorocyclohexene (C) 3, N, N -trimethyl pentane
(C) 1-bromo-3-chlorocylohexene (D) 3, N, N-(dimethyl amino)-3-methyl
(D) 2-bromo-6-chlorocycohex-1-ene
pentane [B]

Q.165 The IUPAC name of

Q.169 The IUPAC name of

is – [D] OHCCH = CH–CH–CH =CH 2

CH2CH2CH2CH3 is
CRA CLASSIFICATION & NOMENCLATURE 15
 (A) 5-Vinyloct-3-en-1- al (A) Neononane (B) Tetra ethyl methane
(C) 3-Ethylpentane (D) 3, 3-Diethyl pentane
(B) 4-Butylhexa-2, 5-dien-1-al

(C) 5-Vinyloct-5-en-8-al Q.177 The IUPAC name of the compound is

(D) 3-Butylhexa-1, 4-dien-8-al. [B]

Q.170 Choose the correct IUPAC name for

(A) Bicyclo [2.1.0] pentane
CH3–CH–CHO (B) 1,2-cyclopropylcy clobutane
CH2–CH3 is- (C) 1, 2-Cyclobutyl cyclopropane
(D) 1, 2-Methyl ene cyclobutane
(A) Butan-2-aldehyde

(B) 2-Methylbutanal O
Q.178 The IUPAC name of the compound is-
(C) 3-Methylisobutyraldehyde
O
(D) 2-Ethylpropanal [B]

O (A) Dioxane
(B) Diethylene-1, 4-dioxide
Q.171 IUPAC name of C6H5–C–Cl (C) 1, 4-Dioxocyclohexane
(D) 1, 4-Dioxacyclohexane
(A) Benzoylchloride

(B) Benzenecarbonylchloride Q.179 The diels-Alder reaction between 1,3-

Cyclohexadiene and acrylonitrile gives the
(C ) Chlorophenyl ketone
adduct,
(D) phenylchloroketone [B]

Q.172 An example of alicyclic compound is-

(A) Benzene (B) Hexane (C) Cyclohexane(D) Furan CN
Q.173 Two members of a homologous series have-
Its IUPAC name is-
(A) Different general formula(B) Different molecular weights
(A) Bicyclo [2.2.2] oct-2-en-5-nitrile
(C) Different methods of preparation(D) Different chemical properties
(B) Bicyclo [2.2.2] oct-5-en-2-carbonitrile
(C) 3-Cyanobicyclo [2.2.2] oct-5-ene
Q.174 The lowest molecular weight alkane which has
(D) 2-Cyanobicyclo [2.2.2]oct-5-ene
ethyl group as the substituent has the IUPAC
name as-
Q.180 The IUPAC name of the compound is,
(A) 2-ethyl propane (B) 2-ethyl butane
(C) 2-ethylpentane (D) 3-ethyl pentane CH3

Q.175 The IUPAC name of an alkane containing only

one methyl, one ethyl and one n-propyl group
(A) 2-Methyl spiro [5.4] deca-1, 6-diene
is-
(B) 2-Methylspiro [4.5] deca-1, 6-diene
(A) 2, 3-Dimethyl pentane(B) 3-Methyl hexane
(C) 8-Methylspiro [4.5] deca-1, 7-diene
(C) 2, 3-Dimethyl butane(D) 3-Ethyl-4-methyl
(D) 3-Methylspiro [5.4] deca-3, 7-diene
pentane

Q.176 The correct IUPAC name for is- SUN, P – PATH FINDER, M # 2, DATE 19/10/08
Q.181 The IUPAC name of following compound is :

CRA CLASSIFICATION & NOMENCLATURE 16

 C2H5O Q.188 The IUPAC name of the compound is
C=O
CH3–CH
|
CH3 (A) Bicyclo [2.1.0] pentane
(B) 1,2-cyclopropylcy clobutane
(A) Ethyl-2-methyl propanoate
(C) 1, 2-Cyclobutyl cyclopropane
(B) 1-Ethoxy-2-methyl propanone (D) 1, 2-Methyl ene cyclobutane [A]
(C) Ethoxy propanone
O
(D) Ethoxy methanone Q.189 The IUPAC name of the compound is-
O
(A) Dioxane
Q.182 What is the IUPAC name of ?
(B) Diethylene-1, 4-dioxide
(C) 1, 4-Dioxocyclohexane
(A) Bicyclo (2, 2, 1) heptane
(D) 1, 4-Dioxacyclohexane [D]
(B) Bicyclo (5,5) heptane
Q.190 The diels-Alder reaction between 1,3-
(C) Bicyclo (2, 2, 1) hexane
Cyclohexadiene and acrylonitrile gives the
(D) 1, 4-Methylene cyclohexane adduct,

Q.183 An example of alicyclic compound is - [C]

(A) Benzene (B)Hexane
(C) Cyclohexane (D) Furan
CN
Q.184 Two members of a homologous series have -
Its IUPAC name is-
(A) Different general formula [B]
(A) Bicyclo [2.2.2] oct-2-en-5-nitrile
(B) Different molecular weights
(B) Bicyclo [2.2.2] oct-5-en-2-carbonitrile
(C) Different methods of preparation
(C) 3-Cyanobicyclo [2.2.2] oct-5-ene
(D) Different chemical properties
(D) 2-Cyanobicyclo [2.2.2]oct-5-ene
Q.185 The lowest molecular weight alkane which has
Q.191 The IUPAC name of the compound is, [B]
ethyl group as the substituent has the IUPAC
name as - [D] CH3
(A) 2-ethyl propane (B) 2-ethyl butane
(C) 2-ethylpentane (D) 3-ethyl pentane (A) 2-Methyl spiro [5.4] deca-1, 6-diene
Q.186 The IUPAC name of an alkane containing only (B) 2-Methylspiro [4.5] deca-1, 6-diene
one methyl, one ethyl and one n-propyl group (C) 8-Methylspiro [4.5] deca-1, 7-diene
is- (D) 3-Methylspiro [5.4] deca-3, 7-diene
(A) 2, 3-Dimethyl pentane [B]
(B) 3-Methyl hexane CH3
Q.192 The correct IUPAC name of is
(C) 2, 3-Dimethyl butane
(D) 3-Ethyl-4-methyl pentane OH
(A) 4-Methyl cyclohex-1-en-3-ol
(B) 2-Methylcyclohex-4-en-1-ol
Q.187 The correct IUPAC name for is- (C) 6-Methyl cyclohex-3-en-1-ol
(A) Neononane (D) 5-Methyl cyclohex-1-en-4-ol. [C]
(B) Tetra ethyl methane Q.193 The IUPAC name of the compound
(C) 3-Ethylpentane CH3
(D) 3, 3-Diethyl pentane [D]

CRA CLASSIFICATION & NOMENCLATURE 17

 (A) 2-methyl spiro [4. 5] dec-1-ene O O
(B) 2-Methyl spiro [5.4] dec-1-ene
(C) 3-Methyl spiro [4. 5] dec-2-ene —CH2CH2C—CH3 is-
(D) 3-Methyl spiro [5. 4] dec-2-ene. [A]
Q.194 IUPAC nomenclature of the given organic (A) 6-(3-oxobutyl) cyclohexan-1-one
(B) 6-(2-oxobutyl) cyclohexan-1-one
compound will be; (C) 2-(3-oxobutyl) cyclohexan-1-one
(D) 2-(2-oxobutyl) cyclohexan-1-one
(A) 2, 3,6-Trimethylbicyclo [3. 1.1] hept-2-ene
(B) 2, 5-Dimethyl bicyclo [3. 1. 1] hept-4-ene Q.199 The IUPAC name of,
(C) 2,6,6-Trimethylbicyclo [3.2.2] hept-4-ene CN
(D) 2,6,6-Trimethylbicyclo [3.1.1] hept-2-ene [D] NC—CH2—CH—CH2—CN is:
(A) propane 1,2,3-tricarbonitrile
Q.195 An organic compound X having molecular formula
(B) 3-cyanopropane-1,5-dinitrile
C6H7O2N has 6 carbons in a ring system, two
(C) 1,2,3-propane tricarbonitrile
double bonds and also a nitro group as substituent.
(D) none of these [A]
The X is:
(A) Homocyclic but not aromatic Q.200 The IUPAC name of is:
(B) Aromatic but not homocyclic
(C) Homocyclic and aromatic (A) 2,2,4,4-tetramethyl pentane
(D) Heterocyclic [A] (B) 2,2-dimethyl propane
(C) 3-ethyl-4-methyl, hex-3-ene
Q.196 The IUPAC name of : [B] (D) ethyl isopropyl ethene [A]
NO2 COOH
Q.201 The number of carbon atoms arranged linearly in
the molecule, CH3—C  C — C = CH2 is - [B]
is: H
COOH NO2
(A) 6, 6' dinitrodiphenic acid (A) 5 (B) 4
(B) 6, 6'-dinitro-1,1'-biphenyl-2-2'-dicarboxylic (C) 3 (D) 2
acid Q.202 Which of the following groups is always
(C) 2, 2'-dinitro-1,1'-biphenyl-6,6'-dicarboxylic represented by prefixes in the nomenclature ?
acid (A) –NH2 (B) –CN [D]
(D) 2,2'-dinitrophenic acid (C) —CHO (D) —NO2

Q.203 Which of the following represents the benzal

Q.197 IUPAC name of compound, [C]
group ?
CH3
(A) C (B) CH2 [D]
CH3—C—COOC2H5

(C) (D) CH
is -
NO2
(A) ethyl-2-methyl-2-(m-nitro) phenyl propanoate
Q.204 The compound is named in
(B) ethyl-2-methyl-2-(o-nitro) phenyl propanoate
IUPAC as -
(C) ethyl-2-methyl-2-(3-nitro) phenyl propanoate
(A) 6-Octene-2-yne
(D) ethyl-2-methyl-2-(3-nitro) phenyl propanoic
(B) 1, 6-Dimethyl hex-1-en-4-yne
acid
(C) 7-methyl 2-octene-6-yne
(D) oct-2-en-6-yne [D]
Q.198 The IUPAC name of the compound [C]

CRA CLASSIFICATION & NOMENCLATURE 18

Q.205 The correct IUPAC name of the following (D) 1-ethoxy-3-methoxy propane [C]
compound is :
HO Sunday Paper 26–07–09, Phase – 3
O Q.210 The IUPAC name of the compound
O2N OH
CH3
CH3
O
(A) 7-nitro-4 (carboxymethyl) heptanoic acid is :
(B) 6-nitro-3-(carboxy ethyl) hexanoic acid (A) (2E,4E,6Z)-octa-2, 4, 6- triene
(C) 4-(3-nitro propyl) hexane-1, 6-dioic acid (B) (2E, 4E, 6E)- octa-2,4,6-triene
(D) 3-(3-nitro propyl) hexane-1, 6-dioic acid [C] (C) (2Z, 4E, 6Z)- octa-2,4,6-triene
(D) (2Z, 4Z, 6Z)- octa-2,4,6-triene [C]
Sol. Z
Q.206 The IUPAC name of the compound : E CH3
H3C Z
O is –

OH Sunday Paper 29–11–09, Phase – 3 & 4

(A) Cinnamic acid
(B) 2-methyl-prop-2-enoic acid Q.211 The amyl group is -
(C) 2-phenyl-prop-2-enoic acid (A) CH3–CH2–
(D) 3-phenyl-prop-2-enoic acid [D] (B) CH3–CH2–CH2–
(C) CH3–CH2–CH2–CH2–
Q.207 The IUPAC name including the stereo chemical (D) CH3– CH –CH2–CH2– [D]
|
notation (for the chiral C) of CH 3
O
Q.212 The number of alkyl group possible in C3H8 -
Br : (A) 1 (B) 2 (C) 3 (D) 4 [A]
H H

(A) (S)-2 Bromo-(Z)-hex-3-en-4-one

(B) (R)-2 Bromo-(E)-hex-3-en-4-one Q.213 The Root word of the compound
(C) (R)-5-Bromo-(Z)-hex-3-en-2-one
(D) (S)-5-Bromo-(E)-hex-3-en-4-one [D]
is-
O
||
Q.208 The correct IUPAC name of is (A) pent (B) hept
(C) ene (D) propyl [A]
||
O Q.214 The correct formula of organic compound is -
- (A) prefix + rootword + suffix first + suffix second
(B) Rootword+suffix first + suffix second + prefix
(A) 3-Acetohex-5-ene-2-one (C) Rootword + suffix second + prefix + suffix first
(B) Acetylhex-l-ene-5-one (D) none of these [A]
(C) 3-(Prop-2-enyl)-2, 4-pentanedione
Q.215 The I.U.P.A.C Name of compound
(D) none of these [C]
CH3
Q.209 CH3OCH2CH2CH2OCH2CH3 is : CH3–C–CH2–CH–CH3 is -
(A) ethylmethylpropyl diether CH3 CH3
(B) ethylmethoxypropyl ether (A) 2, 2, 4-trimethyl pentane
(C) 3-ethoxy-1-methoxy propane (B) 2, 4, 4-trimethyl pentane
(C) isooctane
CRA CLASSIFICATION & NOMENCLATURE 19
 (D) neooctane [A]
Q.221 The IUPAC name of the compound

Q.216 The structure of isobutane is - CH2 = C – CH2 – C  CH is -

(A) CH3–CH–CH3 (B) CH3–CH2–CH2 CH3
CH3 CH3 (A) 4-Methyl-2-penten-1-yne
CH3
(B) 4-Methyl-4-penten-1-yne
(C) CH3–CH2–CH–CH3 (D) CH3–C–CH3
(C) 2-Methyl-2-penten-4-yne
CH3 CH3 [A] (D) 2-Methyl-1-penten-4-yne

Q.217 Which of the following order is incorrect Sol.[D] correct numbering

according to periorty table : 1 2 3 4 5
O O H2C = C – CH2 – C  CH
(A) –C–OH>–C–NH CH3
2
O O
(B) –C–Cl>–C–NH Q.222 IUPAC name of the given compound
2
O O
CH3
(C) –C–H> C
CH3 – (CH2)4 – CH – C – CH2 – CH2 – CH3 is -
(D) –C C– > C=C
[D]
CH3 CH2 – CH3

Q.218 The I.U.P.A.C Name of compound

CH=C–––C=CH2 is - (A) 4-Ethyl-4, 5-dimethyldecane
(B) 3, 4-Dimethyl-3-n-propylnonane
Et Pr
(C) 6, 7-Dimethyl-7-n-propylnonane
(A) 2-methyl-3-propyl buta-1,3-diene
(B) 2-Ethyl-3-propyl buta-1,3-diene (D) 6, 7-Dimethyl-7-ethyldecane
(C) 2-propyl-3-ethyl buta-1,3-diene Sol.[A] Alphabetical arrangement of prefixes. di, tri,
(D) 2-propyl-3-ethyl butane [B] tetra etc never included.

Q.223 The IUPAC name of

Q.219 The I.U.P.A.C. Name of compound
CH3–CH–CH–CH3 CH3
is - CH – CH2 – Cl is -
Et CH3
CH3
(A) 2,3-dimethyl pentane
(B)2-ethyl-3-methyl pentane (A) 2-Chloro-2-methylpropane
(C) 3,4-dimethyl pentane (B) 2-Chloro-1-methylpropane
(D) 2-methyl-3-ethyl pentane [A]
(C) 1-Chloro-2-methylpropane

Q.220 The I.U.P.A.C Name of compound (D) 2-Chloro-2-methyl butane

O
|| Sol.[C] correct numbering
3
CH3– CH –CH2– C –OH is - CH3 2 1
| CH – CH2 – Cl
CH 3
H3C
(A) 3-methyl butanoic acid Q.224 IUPAC name of the given compound
(B) 2-methyl butanoic acid
(C) pentanoic acid
(D) none of these [A]
CRA CLASSIFICATION & NOMENCLATURE 20
 CH3 – C  C – CH – C = CH2 is -
is
CH3 CH2 – CH3
(A) 3-Ethylbutane (B) 1-Ethylbutane
(A) 3-Methylene-4-methyl-5-heptene
(C) 2-Ethylbutane (D) 3-Methylpentane
(B) 2-Ethyl-3-methyl-1-hexen-4-yne
Sol.[D] 2 1
(C) 5-Methylene-5-ethyl-4-methyl-2-heptyne C C

(D) 5-Ethyl-4-methyl-2-hexyn-5-ene 3C C

Sol. [B] C C
correct numbering 4 5
6 5 4 3 2 1
CH3 – C  C – CH – C = CH2 Q.229 IUPAC name of the compound
CH3 – CH – CH2 – CHOH – CH3 is -
CH3 CH2 – CH3
CH2 – CH3
Q.225 The IUPAC name of the (A) 4-Methyl-3-hexanol
CH3 – CH = CH – C  CH is - (B) Heptanol
(A) 3-Penten-1-yne (B) 2-Penten-4-yne (C) 4-Methyl-2-hexanol
(D) 4-Ethyl-2-pentanol
(C) 3-Pentyn-1-ene (D) 2-Pentyn-1-ene
Sol.[C] OH
Sol.[A] correct numbering 4 3 2 1
CH3 – CH – CH2 – CH – CH3
5 4 3 2 1
CH3 – CH = CH – C  CH CH2 – CH3
5 6

Q.230 The IUPAC name of the given compound -

Q.226 The IUPAC name of the given compound CCl4 Br
is - Cl – C – CHO is -
(A) Pyrene F
(B) Carbon tetrachloride (A) 2-Bromo-2-chloro-2-fluoroethanal
(C) Tetrachlorocarbon (B) 1-Bromo-1-chloro-2-fluoroethanal
(D) Tetrachloromethane (C) 2-Fluoro-2-chloro-2-bromoethanal
Sol.[D] Cl (D) 1-Fluoro-1-chloro-1-bromoethanal
Sol.[A] Br O
Cl – C – Cl
Cl – C – C – H
Cl 2 1
Q.227 The IUPAC name of the given structure F

is Q.231 The IUPAC name of the given compound

CH2 – CH3
(A) 3, 3-Dimethylpentane
(B) 3, 3-Diethylpentane CH3 – CH – CH2 – C – OH is -
(C) 3-Ethyl-3-methylpentane OH CH2 – CH3
(D) 3-Ethyl-3-ethylpentane (A) 2, 4-Hexanediol
Sol.[B] 2 1 (B) 4-Ethyl-2, 4-hexanediol
C C C
(C) 2, 4-Hexanediol-2-ethyl
3
C C C (D) 3, 3-Diethyl-1, 3-butanediol
C C C
5 4

Q.228 The IUPAC name of the given structure

CRA CLASSIFICATION & NOMENCLATURE 21

Sol.[B] correct numbering
CH2 – CH3 OH
1 2 3 4
CH3 – CH – CH2 – C – OH
OH CH2 – CH3 Q.236 In the nomenclature of priority order
5 6

Q.232 The name of the given structure CH3

O is-
CH3
(A) –CH3 < –OH < C = C (first)
CH3 – CH – CH2 – C – CH2 – CH is - (B) –OH<–CH3 < C = C (first)
CH3 (C) C=C<–CH3 <–OH (first)
CH3
(D) –CH3 < C=C < –OH (first) [D]
(A) 2, 4-Dimethyl-3-hexanone
(B) 2, 6-Dimethyl-5-heptanone
(C) 2, 6-Dimethyl-4-hexanone Q.237 The hetero atoms present in the following
compound is/are –
(D) 2, 6-Dimethyl-4-heptanone NH2
Sol.[D]
N
Q.233 The IUPAC name of the given compound
N
is -
(A) 2 (B) 3 (C) 1 (D) 4
(A) 4, 5-Dimethyl-4-octene [A]

(B) 4, 5-Dimethyl-5-octene Q.238 The IUPAC name of the

(C) 3, 4-Dimethyl-5-octene Me
(D) 2, 3-Dipropyl-2-butene
Me Me
Sol.[A] 1 3
C
structure is-
C 2 4 C
C C Me Me
C
C 7
C
C (A) 2,4,5-Triethyl-3-nonene
C 5
8 6 (B) 5,6-Diethyl-3-methyl-4-decene
(C) 2,4,5-Triethyl-3-octene
(D) 3-Ethyl-5-methyl-3-hepetene [B]

Q.239 The IUPAC name of the given compound is –

Q.234 IUPAC name of the hydrocarbon (A) is –
O
CH3
C–NH2
A: (A) Cyclohexanamide
C2H5 (B) 1-Cyclohexyl formamide
(A) 2-ethyl-5methylhexane (C) Cyclohexanecarboxamide
(B) 5-ehtyl-2methylhexane (D) 1-Amino-1- cyclohexylketone [C]
(C) 2, 5-dimethylheptane
(D) 5-ethyl-2, 5-dimethylpentane [C] Q.240 IUPAC name of the compound
CH3
Q.235 IUPAC name of neopentyl group is -
(A) 2, 2-dimethylbutyl
(B) 2, 2-dimethylpropyl CH2–CH3
(C) 1, 1-dimethylbutyl is-
(D) 1, 1-dimethylpropyl [B] (A) 4-Ethyl-3-methylcyclopent-1-ene
CRA CLASSIFICATION & NOMENCLATURE 22
 (B) 3-Ethyl-4-methylcyclopent-1-ene CH3
(C) 1-Ethyl-2-methylcyclopent-4-ene
(D) 2-Ethyl-1-methylcyclopent-3-ene [B] (A) CH3 CH2 NH (B) CH3 C O

CH3
Q.241 IUPAC name of compound
(C) CH3 CH2 (D) CH2 CH [B]

Q.245 Which of the following has minimum base

is- strength?
(A) 1,2-Dimethyl-4-(3-methylbuta-1,3-dienyl)
(A) CH3 CH2 (B) HC C
Cyclobut-1-ene
(B) 1-(2,3-Dimethylcyclobut-2-enyl)-3-methyl (C) NH2 (D) CH2 CH [B]
buta-1,3-diene
(C) 1-(1,2-Dimethylcyclobut-1-enyl)-3-methyl
Q.246 What is the order of base strength ?
buta-1,3-diene
R C N R CH NH R NH2
(D) 4-(2,3-Dimethylcyclobut-2-enyl)-2-methyl
buta-1,3-diene [A] I II III
(A) I > II > III (B) III > I > II
Q.242 The correct structure of the compound
4-Methylcyclobut-2-en-1-ol is- (C) III > II > I (D) None of these

OH OH [C]

(A) (B)
Q.247 Give the correct order of acidic strength-
CH3 CH3
OH OH

I
(C) (D)
OH CH3 CH3 NH2 C CH
[A]
II III
(A) II > I > III (B) III > I > II
(C) I > III > II (D) None of these

Q.243 The correct order of IUPAC numbering is- [C]

(A) Principal functional group > substitutents

Q. 248 The IUPAC name of the following structure –
> triple bond > double bond
(B) Principal functional group > triple bond CH3 — C == C — CH — CH— CH2 —C  CH
> double bond > substitutents
Cl H CH3 C2H5
(C) Principal functional group > double bond
> substitutents > triple bond (A) 7 chloro- 4 ethyl-5 methyl-6 octen -1-yne
(D) Principal functional group > double bond (B) 5 methyl - 4 ethyl-6 chloro -5 hepten -1-yne
> triple bond > substitutents [D] (C) 6 chloro- 4 ethyl-5 methyl-1 hepten -5-yne
(D) 2 chloro- 4 ethyl- methyl-6 hepten -2-ene
Q.244 Which of the following has maximum stability ? [A]
Q.249 The structure of spiro [3,3] heptane is -

CRA CLASSIFICATION & NOMENCLATURE 23

 O
(A) (B)
C –– O –– CH2 –– CH2 –– CH3
(C) (D)
[D]

Q.250 Vinylcarbinol is -
OH
(A) HO — CH2 — CH == CH2
(A) Propyl – 4 – hydroxybenzoate
(B) CH3 — CH (OH) == CH2 (B) 4 – hydroxy propyl benzoate
(C) CH3 — CH == CH — OH (C) Propyl – 4 – Hydroxy benzene carboxylate
(D) CH3 — C (CH2OH) == CH2 [A] (D) Propoxy Benzophenone [C]
Q.255 Given IUPAC name for the compound –
Q.251 Which of the following cannot be written in the
5 4
isomeric form ? 6
(A) CH3 — CH(OH) — CH2 — CH3 8 Br 3
(B) CH3 — CHO
7
(C) CH2 == CH — Cl 1 2
(D) Cl — CH2 — CH2 — Cl [C] CH3
(A) 8–Bromo–2–methylbicyclo [3, 2, 1] octane
Q.252 Give the IUPAC name – (B) 2–Bromo–6–methylbicyclo [3, 2, 1] octane
(C) 2–Methyl–6–Bromobicyclo [3, 2, 1] octane
O
|| (D) 3–Bromo–6–methylbicyclo [3, 2, 0] octane
C— O —CH2— CH2 — CH3 [A]

Q.256 Give IUPAC name for the compound –

OH O

(A) 4-hydroxy propyl benzoate

NH
(B) Propyl – 4- hydrobenzoate
(C) Propyl-4-hydroxy Benzene Carboxylate
(D) Propoxy Benzo Phenone [C] (A) 5 – aminopentanoic acid lactam
(B) 5 – aminopentanoic acid lactaone
(C) 2 – Azacyclohexanone
(D) None of these [A]
Q.253 Give the IUPAC name of compound –
CONH2
Q.257 Give IUPAC name for the compound –
NH2CO –– CH2 –– CH2 –– CH –– CH2 OH
CH3 –– CH2 –– CH2
(A) 1,3 – Dicarbonoylheptane
O COOH
(B) 4 – Carbonoyloctane
(C) 2 – n – Butylpentanediamide
(D) 2–n– Butylpentanediaminoketone [C] (A) 4 – hydroxy–7 formyl–5 heptenoic acid
(B) 3 – hydroxy – 4 – oxocylhexanecarboxylic
Q.254 Give IUPAC name for the compound – acid
(C) Cyclopropanecarboxylic acid
CRA CLASSIFICATION & NOMENCLATURE 24
 (D) 3–hydroxy–4–oxocycloheptanecarboxylic CN
acid [B]
Q.263 The IUPAC name of is –

Q.258 Choose correct IUPAC name of the following

given compounds – (A) 2-cyano-3-ethyl-4-methylpentane
(B) 3-isopropyl-2-methylpentanenitrile
(C) 3-ethyl-2,4-dimethylpentanenitrile
(D) 3-isopropyl-2-pentylcyanide [C]

Q.264 The IUPAC name of

CH2 CH — CH CH — CH — C CH
(A) 5-(2-methyl propyl)-5-(1, 1-dimethyl propyl) |
nonane CH CH2
is –
(B) 5, 5-dibutyl-3, 3, 6-trimethyl heptane
(A) 3-ethenyl-4, 6-heptadien-1-yne
(C) 5-(1, 1-dimethyl butyl)-5-(2-methyl propyl)
(B) 5-ethenyl-1,3-heptadien-6-yne
nonane
(C) 2-ethynyl-1, 4, 6-heptatriene
(D) All of these [C]
(D) 5-ethynyl-1,3,6-heptatriene [D]

Q.259 The no. of -electrons in isoprene is - Q.265 The IUPAC name of

(A) 2 (B) 1 (C) 3 (D) 4
O O
[D]
C – O – C – CH2 CH3 is –
Q.260 The IUPAC name of crotyl chloride is -
(A) 1-chlorobut-1-ene (B) 1-chlorobut-2-ene (A) cyclohexanoic propanoic anhydride
(C) 2-chlorobut-2-ene (D) 3-chlorobut-1-ene (B) cyclohexanecarboxylic propanoic anhydride
[D] (C) cyclohexyl ethyl anhydride
(D) benzoic propanoic anhydride [B]
Q.261 Give correct IUPAC name of the following –
CH = CHCH3

H Cl
Q.266 The IUPAC name of is
(A) 1-methyl-1-cyclopropyl propane
(B) 2-cyclopropyl butane Cl
(C) 2-propyl butane
(A) 1- (2,4 - dichlorophenyl) propene
(D) 1-(1-methyl propyl) cyclopropane [B]
(B) 2, 4 - dichloro -1- (1-propenyl) benzene
Q.262 The IUPAC name of (C) 1, 3 - dichloro - 4 – propenylbenzene
O
(D) 3 - (2, 4 - dichlorophenyl) propene [A]
C – O – CH2CH3 is –
(A) Ethyl cyclohexanoate
(B) cyclohexyl propanoate Q.267 The IUPAC name of
(C) ethoxycyclohexyl ketone
CH2 – CH3
(D) ethyl cyclohexanecarboxylate [D]
HOCH2 – CH – CH – OH is –
CH3 – CH – OH
(A) 3-hydroxymethyl-2, 4-hexanediol
(B) 4-hydroxymethyl-3,5-hexanediol
CRA CLASSIFICATION & NOMENCLATURE 25
 (C) 4-hydroxyethyl-3,5-pentanediol (C) CH3–CH–CH–CH3
(D) 2-(1-hydroxyethyl)- 1, 3-pentanediol [A] OH CH3
2-Methyl-3-butanol

(D) CH3–CH–C–CH2–CH3 [C]

NH2
COOH CH3 O
Q. 268 The IUPAC name of is 2-Methyl-3-pentanone

Sol. 3-methyl-2-butanol
(A) 1- amino-2-carboxybenzene
(B) 2-amino-1-carboxybenzene
Q.272 The IUPAC name of the given structure
(C) 1-amino-2-benzenecarboxylic acid
(D) 2-aminobenzenecarboxylic acid [D]
is
Q. 269 Which one of the following is correct IUPAC
name for mesityl oxide - (A) 1, 2- Dimethylcyclopropane
(A) 4-methylpent-3-en-2-one
(B) Cyclopropane- 1, 2-demethyl
(B) 1, 3, 5-trimethylbenzene
(C) 2-hydroxybutane-1, 4-dioic acid (C) 1-Methyl-1-methylcyclopropane
(D) 1, 5-dioxacyclohexane [A] (D) Cyclopentane [A]

Q.270 In the following reaction

Q.273 IUPAC name of the hydrocarbon (A) is –
CH3 EtO C O
CH3
+ COOEt
NO2 A:
  C2H5
⎯⎯ ⎯ ⎯
⎯→
EtO Na
− EtOH
(A) 2-ethyl-5methylhexane
CH2 C O
(B) 5-ehtyl-2methylhexane
COOEt
(C) 2, 5-dimethylheptane
NO2
(D) 5-ethyl-2, 5-dimethylpentane [C]
The correct IUPAC name of product will be-
(A) 1(3-ethoxy, 2,3 dioxo-propane)2-nitrobenzene
Q.274 IUPAC name of neopentyl group is -
(B) Ethyl 3-(2-nitro phenyl) 2-oxo propanoate
(C) Ethyl-2-(2-nitro phenyl methyl)-2-oxo (A) 2, 2-dimethylbutyl (B) 2, 2-dimethylpropyl

ethanoate (C) 1, 1-dimethylbutyl (D) 1, 1-dimethylpropyl

(D) 1-ethoxy-2(2-nitro phenyl) propan-1,2-di [B]
one [B] OH
Q.271 Which of the following compound has wrong
IUPAC name ? Q.275 In the nomenclature of priority order
(A) CH 3 – CH 2 – CH 2 – COOCH 2 CH 3
Ethyl bu tanoate
CH3
(B) CH3–CH–CH2–CHO is-
(A) –CH3 < –OH < C = C (first)
CH3 (B) –OH<–CH3 < C = C (first)
3-Methylbutanal
(C) C=C<–CH3 <–OH (first)
CRA CLASSIFICATION & NOMENCLATURE 26
 (D) –CH3 < C=C < –OH (first) [D] (A) 2, 4, 5, 6-tetramethyl-4-propylheptane
(B) 2,2,4,6-tetramethyl-4-propylheptane
Q.276 The hetero atoms present in the following
(C) 2,4-Dimethyl-4-neopentylheptane
compound is/are –
NH2 (D) 2,4,5,6-tetramethyl-4-pentylheptane [B]
19 Jun 09 ______________________________
N Q.281 The IUPAC name of the given compound is

N
(A) 2 (B) 3 (C) 1 (D) 4
[A] (A) 5-ethynylcyclopenta-1,3-diene
(B) 1-(cyclopenta-2,4-dienyl)-ethyne
Q.277 The IUPAC name of the (C) 1-ethynyl-2,4-cyclopentadiene
Me
(D) 1-ethynylcyclopent-2,4-diene [A]
Me Me
Q.282 Choose correct IUPAC name of the following
Me Me
given compounds –
structure is -

(A) 2,4,5-Triethyl-3-nonene
(B) 5,6-Diethyl-3-methyl-4-decene
(C) 2,4,5-Triethyl-3-octene
(D) 3-Ethyl-5-methyl-3-hepetene [B]
(A) 5-(2-methyl propyl)-5-(1, 1-dimethyl propyl)
Q.278 In the compound,
nonane
CH2 = CH–CH2–CH2–C  CH, the
C2—C3 bond is of the type. (B) 5, 5-dibutyl-3, 3, 6-trimethyl heptane
(A) sp – sp2 (B) sp3 – sp3 (C) 5-(1, 1-dimethyl butyl)-5-(2-methyl propyl)
(C) sp – sp 3
(D) sp2 – sp3 [D] nonane
(D) All of these [C]
Q.279 The IUPAC name of the given compound
OH
CH3 Q.283 The no. of -electrons in isoprene is -
is : (A) 2 (B) 1 (C) 3 (D) 4
Cl Br [D]
(A)3-Bromo-5-chloro-1-methylcyclohexanol
(B)5-Bromo-3-chloro-1-methylcyclohexanol Q.284 The IUPAC name of crotyl chloride is -
(C)5-Bromo-1-chloro-3-methyl-3-cyclohexanol (A) 1-chlorobut-1-ene (B) 1-chlorobut-2-ene
(D)1-Bromo-5-chloro-3-methyl-3-cyclohexanol. (C) 2-chlorobut-2-ene (D) 3-chlorobut-1-ene
[A]
[B]
Q.280 Give the correct IUPAC name of the following Q.285 Give correct IUPAC name of the following –
compound:
CH2–CH2–CH3 H
CH3
(A) 1-methyl-1-cyclopropyl propane
CH3—C—CH2—C—CH3
(B) 2-cyclopropyl butane
CH3
CH2–CH–CH3 (C) 2-propyl butane
CH3 (D) 1-(1-methyl propyl) cyclopropane [B]

CRA CLASSIFICATION & NOMENCLATURE 27

Q.286 Give the IUPAC name of compound – (C) 2–Methyl–6–Bromobicyclo [3, 2, 1] octane
CONH2 (D) 3–Bromo–6–methylbicyclo [3, 2, 0] octane
[A]
NH2CO –– CH2 –– CH2 –– CH –– CH2
Q.290 Give IUPAC name for the compound –
CH3 –– CH2 –– CH2 O
(A) 1,3 – Dicarbonoylheptane
(B) 4 – Carbonoyloctane
(C) 2 – n – Butylpentanediamide NH
(D) 2–n– Butylpentanediaminoketone [C]

Q.287 The IUPAC name of the given compound – (A) 5 – aminopentanoic acid lactam
CH3 –– CH2 –– CH –– CH2 –– CH –– CH2CH2CH3 (B) 5 – aminopentanoic acid lactaone
(C) 2 – Azacyclohexanone
CH3 CH –– CH3 (D) None of these [A]

CH3 Q.291 Give IUPAC name for the compound –

(A) 4 – Isopropyl – 6 – methyloctane OH
(B) 3 – Methyl – 5 – (1' – methyethyl) octane
(C) 3 – Methyl – 5 – isopropyloctane
(D) 6 – Methyl – 4 – (1' Methylethyl) Octane O COOH
[B]
(A) 4 – hydroxy–7 formyl–5 heptenoic acid
Q.288 Give IUPAC name for the compound – (B) 3 – hydroxy – 4 – oxocylhexanecarboxylic
O acid
(C) Cyclopropanecarboxylic acid
C –– O –– CH2 –– CH2 –– CH3
(D) 3–hydroxy–4–oxocycloheptanecarboxylic
acid [B]

Q.292 The IUPAC name of the following structure –

CH3 — C == C — CH — CH— CH2 —C  CH
OH
(A) Propyl – 4 – hydroxybenzoate Cl H CH3 C2H5
(B) 4 – hydroxy propyl benzoate
(A) 7 chloro- 4 ethyl-5 methyl-6 octen -1-yne
(C) Propyl – 4 – Hydroxy benzene carboxylate
(B) 5 methyl - 4 ethyl-6 chloro -5 hepten -1-yne
(D) Propoxy Benzophenone [C]
(C) 6 chloro- 4 ethyl-5 methyl-1 hepten -5-yne
(D) 2 chloro- 4 ethyl- methyl-6 hepten -2-ene
[A]
Q.289 Given IUPAC name for the compound – Q.293 The structure of spiro [3,3] heptane is –
5 4
6 (A) (B)
8 Br 3
7 (C) (D) [D]
1 2
CH3
Q.294 Vinylcarbinol is -
(A) 8–Bromo–2–methylbicyclo [3, 2, 1] octane
(A) HO — CH2 — CH == CH2
(B) 2–Bromo–6–methylbicyclo [3, 2, 1] octane
(B) CH3 — CH (OH) == CH2
CRA CLASSIFICATION & NOMENCLATURE 28
 (C) CH3 — CH == CH — OH (B) 8-Carboxy-2-methyl spiro [3.4] octane-6-
(D) CH3 — C (CH2OH) == CH2 [A] carbonyl chloride
(C) 7-Chloro carbonyl-2-methyl spiro [3.4]
Q.295 Give the IUPAC name – octane-5-carboxylic acid
O (D) None of above [C]
||
C— O —CH2— CH2 — CH3
Q.298 The correct IUPAC name of the compound
Me
Br
OH HO
(A) 4-hydroxy propyl benzoate H OCOCHCH3
(B) Propyl – 4- hydrobenzoate
(C) Propyl-4-hydroxy Benzene Carboxylate (A) (E)-2-Bromopropyl-3-hydroxy-1-methyl
(D) Propoxy Benzo Phenone [C] cyclopentane carboxylate
3 July 09______________________________________ (B) (E)-3-Hydroxy-1-methylcyclopentyl-2-
Q.296 IUPAC name of the following is - bromopropanoate
(C) (Z)-3-Hydroxy-1- methylcyclopentyl-2-
CH3
Cl
C2H5 bromopropanoate
(D) None of above [B]

HO C Q.299 Which of the following show inductive,

mesomerism and hyperconjugation effect at the
O
same time?
(A) 3-chloro-3-methyl-4-chloro cyclopent -4-en -
(A) OMe
carbaldehyde
(B) 4-ethyl-3-chloro-3-methyl cyclopent -5-en OH
carboxylic acid (B)

(C) 3-Formyl-5-chloro-5-methyl,-1-ethyl cyclo

D D
pentene
(D) 4-chloro -3- ethyl-4-methyl cyclo pent- 2 ene
(C)
N
carboxylic acid [D]
H
Sol. Main function group is carboxylic acid (–COOH).
(D) (CD3)3CCH = CHOCH3 [C]
Q.300 The correct order of heat of hydrogenation in
--------- 09_____________________________________
following is
Q.297 The correct name of the spiro compound
(A) <
ClOC Me CH3 CH2

CH3
is
(B) H3C
>
COOH
(A) 4-Chlorocarbonyl-6-methyl spiro [3.4]
octane-2-carboxylic acid
CRA CLASSIFICATION & NOMENCLATURE 29
 (C)    
> HO = CH – CH – CH HO = CH = CH – C – H
(D) All of above [B] O O
(I) (II)
Q.301 The correct order of heat of hydrogenation per 
bond in the following compounds is:  
HO = CH – CH = CH HO – CH = CH – CH
CH2 = CH – CH2 – CH = CH2 CH2 = C = CHCH2CH3
– –
(I) (II) O O
CH2 = C = C = CHCH3 CH2 = CH – CH (III) (IV)
= CHCH3
The correct order of stability is:
(III) (IV)
(A) I > II > III > IV (B) III > I > II > IV (A) III > I > II > IV (B) I > III > II > IV
(C) II > III > IV > I (D) III > II > I > IV (C) III > I > IV > II (D) I > III > IV > II
[D] [C]
Q.305 The correct stereochemical name of
Q.302 The correct order of resonance energy of
following compounds is: CH3 H
C C H
H CH2 C
C CH3
N N COOCH3

(I) (II) (III) (IV) (A) Methyl 2-methylhepta (2E, 5E) dienoate
(A) IV > I > I > III (B) IV > II > I > III (B) Methyl 2-methylhepta (2Z, 5Z) dienoate
(C) II > IV > III > I (D) IV > I > II > III
(C) Methyl 2-methylhepta (2E, 5Z) dienoate
[B]
(D) Methyl 2-methylhepta (2Z, 5E) dienoate
Q.303 For the species [D]
 Q.306 Tautomerism is not shown by -
 NH3

H3N COOH H3N H (A) O O
H
& H (B) CH NOH
,
H H H COOH COOH
O
I II III
(C) O

The correct order of pH of their aqueous O

solutions having equal concentrations of these (D) O
species is: [A]
(A) I > II > III (B) II > I > III Q.307 What, if anything can be said about the
(C) III > I > II (D) III > II > I [B] magnitude of the equilibrium constant K for the
following equilibrium
H H
Q.304 For the following structures of 3-Hydroxy prop-
H CH(CH3)2 H3C
2-enal H
CH3 CH(CH3)2
(A) K =1
(B) K < 1
(C) K > 1
(D) No estimate of K can be made [B]
---------------2010------------------
Q.308 The IUPAC name of the following compound is -

CRA CLASSIFICATION & NOMENCLATURE 30

 CH2=C–CH2–CCH 3
| H3C 2 1
CH3 Sol.[C] CH – CH2 – Cl
H3C
(A) 4-Methyl-2-penten-1-yne
(B) 4-Methyl-4-Penten-1-yne
Q.312 IUPAC name of the given compound
(C) 2-Methyl-2-penten-4-yne
CH3–CC–CH–C=CH2 is -
(D) 2-Methyl-1-penten-4-yne | |
CH3 CH2–CH3
1 2 3 4 5
Sol.[D] H2C = C – CH2 – C  CH (A) 3-Methylene-4-methyl-5-heptene
|
CH3 (B) 2-Ethyl-3-methyl-1-hexen-4-yne
(C) 5-Methylene-5-ethyl-4-methyl-2-heptyne
Q.309 IUPAC name of the given compound
(D) 5-Ethyl-4-methyl-2-hexyn-5-ene
CH3 6 5 4 3 2 1
| Sol.[B] H3C–CC–CH–C=CH2
CH3–(CH2)4–CH–C–CH2–CH2–CH3 is - | |
| | CH3 CH2–CH3
CH3 CH2 – CH3

(A) 4-Ethyl-4,5-dimethyldecane Q.313 The IUPAC name of the given structure

(B) 3,4-Dimethyl-3-n-propylnonane is -
(C) 6, 7-Dimethyl-7-n-propylnonane
(A) 3, 3-Dimethylpentane
(D) 6, 7-Dimethyl-7-ethyldecane
(B) 3, 3-Diethylpentane
Sol.[A] (C) 3-Ethyl-3-methylpentane
Q.310 The IUPAC name of (D) 3-Ethyl-3-Ethylpentane
C 4C C 5
CH3
| Sol.[B] C 3C
C
CH3 – C – CH = CH2 is- 2
| 1C C C
CH3 c

(A) 2, 2-Dimethyl-3-butene Q.314 The IUPAC name of the given compound

(B) 2, 2-Dimethyl-4-pentene CH2=CH–CH–CH3is -
|
(C) 3, 3-Dimethyl-1-butene CH3
(A) 1, 1- Dimethyl-2-propene
(D) 1-Hexene
(B) 3-Methyl-1-butene
CH3
|3 2 (C) 2-Vinylpropane
4 1
Sol.[C] H3C – C – CH = CH2 (D) 1-Isopropylethylene
| 1 2 3 4
CH3 Sol.[B] H2C=CH–CH–CH3
|
Q.311 The IUPAC name of CH3

CH3
CH – CH2 – Cl is - Q.315 The IUPAC name of the given compound
CH3
is -
(A) 2-Chloro-2-methylpropane
(B) 2-Chloro-1-methylpropane (A) 4, 5-Dimethyl-4-octene
(C) 1-Chloro-2-methylpropane (B) 4, 5-Dimethyl-5-octene
(D) 2-Chloro-2-methylbutane
(C) 3, 4-Dimethyl-5-octene
(D) 2, 3-Dipropyl-2-butene

CRA CLASSIFICATION & NOMENCLATURE 31

 1 3
2 4
Sol.[A]
7 5
8 6

Q.316 The IUPAC name of the

CH3–CH=CH–CCH is -
(A) 3-Penten-1-yne (B) 2-Penten-4-yne
(C) 3-Pentyn-1-ene (D) 2-Pentyn-1-ene
Sol.[A] 5 4 3 2 1

H3C – CH = CH – C  CH

Q.316 The IUPAC name of the structure

E is -
(A) 3-Ethylbutane (B) 1-Ethylbutane
(C) 2-Ethylbutane (D) 3-Methylpentane
1
2C C
3C C
Sol.[D]
4C C
5

Q.317 The IUPAC name of the given compound

(A) 5,6-Diethyl-3-methyl-4-decene
(B) 7-Methyl-2, 4, 6-triene octanal
(C) 6-Methyl heptene
(D) 3,3-Diethyl-5-ethyl-4-decene
4 C 2
5
C C C C 1
C C C
Sol.[A] C
C C
C C C 8 C 10 6 7 9

:: -------Continuous Next File (Q. 318 to …)-------- ::

CRA CLASSIFICATION & NOMENCLATURE 32