Msds 3m Resin

Bondo® Fiberglass Resin Kit, P.N.
401, 401C, 402, 402M, 402C, 402ES, 402T, 402Z, 404, 404C, 404Z 01/12/18
Safety Data Sheet

Copyright,2018,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed
provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither
the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group: 24-2437-2 Version Number: 7.01

Issue Date: 01/12/18 Supercedes Date: 09/04/15
Product identifier
Bondo® Fiberglass Resin Kit, P.N. 401, 401C, 402, 402M, 402C, 402ES, 402T, 402Z, 404, 404C, 404Z
ID Number(s):
60-4550-4826-8, 60-4550-5662-6, 60-4550-5663-4, 60-4550-5664-2, 60-4550-5665-9, 60-4550-5666-7, 60-4550-5667-5, 60-4550-

6602-1, 60-4550-6603-9, 60-4550-6605-4, 60-4550-6742-5, 60-4550-7373-8, 60-4550-7374-6, 60-4550-7375-3, 60-4550-7376-1, 60-
4550-7377-9, 60-4550-8100-4, 60-4550-8101-2, 60-4550-8102-0, 60-4550-8287-9, 60-4550-8288-7, 60-4550-8297-8, 60-4550-8298-
6, 60-4550-8299-4, 60-4550-8325-7, 60-4550-8326-5, 60-4550-8327-3, 70-0080-0014-6, 70-0080-0015-3, 70-0080-0016-1, 70-0080-
0148-2, 70-0080-0149-0, 70-0080-0150-8, 70-0080-0151-6, 70-0080-0152-4, 70-0080-0153-2
Recommended use
Automotive, Repairing Auto Body
Supplier's details
MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA

Telephone: 1-888-3M HELPS (1-888-364-3577)
Emergency telephone number

1-800-364-3577 or (651) 737-6501 (24 hours)
This product is a kit or a multipart product which consists of multiple, independently packaged components. A Safety Data
Sheet (SDS), Article Information Sheet (AIS), or Article Information Letter (AIL) for each of these components is included.
Please do not separate the component documents from this cover page. The document numbers for components of this
product are:
24-2429-9, 24-2440-6
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.3MMAKES NO
WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE.User is responsible for determining whether the3Mproduct is fit for a particular purpose and suitable for user's method of use
or application.Given the variety of factors that can affect the use and application of a3Mproduct, some of which are uniquely within
the user's knowledge and control,it is essential that the user evaluate the3Mproduct to determine whether it is fit for a particular
purpose and suitable for user's method of use or application.
________________________________________________________________________________________________________
Page 1 of 2
Bondo® Fiberglass Resin Kit, P.N. 401, 401C, 402, 402M, 402C, 402ES, 402T, 402Z, 404, 404C, 404Z 01/12/18
3Mprovides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information,3Mmakes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the SDS available directly from3M
3M USA SDSs are available at www.3M.com
________________________________________________________________________________________________________
Page 2 of 2
3M™ Bondo® MEKP Liquid Hardener for Fiberglass Resin Kit, P.N. 401, 401C, 402, 402C, 402T, 402Z, 404, 404C, 404Z 05/22/18
Safety Data Sheet

All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

SECTION 1: Identification
1.1. Product identifier
3M™ Bondo® MEKP Liquid Hardener for Fiberglass Resin Kit, P.N. 401, 401C, 402, 402C, 402T, 402Z, 404, 404C, 404Z
Product Identification Numbers

LB-K100-0411-2, LB-K100-0414-8, LB-K100-0414-9
1.2. Recommended use and restrictions on use
Recommended use
Automotive, Curing Agent
1.3. Supplier’s details

MANUFACTURER: 3M
1.4. Emergency telephone number

1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification

The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200.
This information may be different from the actual product label information for labels regulated by other agencies.
2.1. Hazard classification

Organic Peroxide: Type D.
Acute Toxicity (oral): Category 4.
Serious Eye Damage/Irritation: Category 1.
Skin Corrosion/Irritation: Category 1C.
2.2. Label elements

Signal word
Danger
Symbols
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Page 1 of 12
Flame | Corrosion | Exclamation mark |
Pictograms
Hazard Statements
Heating may cause a fire.
Harmful if swallowed.
Causes severe skin burns and eye damage.
Precautionary Statements
General:
Keep out of reach of children.
Prevention:
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Keep away from clothing and other combustible materials.
Keep only in original container.
Do not breathe dust/fume/gas/mist/vapors/spray.
Wear protective gloves, protective clothing, and eye/face protection.
Do not eat, drink or smoke when using this product.
Wash thoroughly after handling.
Response:
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a POISON CENTER or doctor/physician.
Wash contaminated clothing before reuse.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
Storage:
Protect from sunlight.
Store at temperatures not exceeding 25C/77F. Keep cool.
Store locked up.
Store away from other materials.
Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
2.3. Hazards not otherwise classified

May cause chemical gastrointestinal burns.
1% of the mixture consists of ingredients of unknown acute inhalation toxicity.
SECTION 3: Composition/information on ingredients

Ingredient C.A.S. No. % by Wt
Dimethyl Phthalate 131-11-3 30 - 60 Trade Secret *
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Methyl Ethyl Ketone Peroxide 1338-23-4 15 - 40 Trade Secret *

Phlegmatizer Trade Secret* 10 - 30 Trade Secret *
Methyl Ethyl Ketone 78-93-3 < 3 Trade Secret *
Hydrogen Peroxide 7722-84-1 < 3 Trade Secret *
Water 7732-18-5 < 3 Trade Secret *
*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
SECTION 4: First aid measures

4.1. Description of first aid measures
Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Immediately flush with large amounts of water for at least 15 minutes. Remove contaminated clothing. Get immediate
medical attention. Wash clothing before reuse.
Eye Contact:
Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue
rinsing. Immediately get medical attention.
If Swallowed:
Rinse mouth. Do not induce vomiting. Get immediate medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures

5.1. Suitable extinguishing media
In case of fire: Use a carbon dioxide or dry chemical extinguisher to extinguish.
5.2. Special hazards arising from the substance or mixture

Closed containers exposed to heat from fire may build pressure and explode.
Hazardous Decomposition or By-Products

Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Irritant Vapors or Gases During Combustion
5.3. Special protective actions for fire-fighters

Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and
prevent explosive rupture. Wear full protective clothing, including helmet, self-contained, positive pressure or pressure
demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering
for exposed areas of the head.
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SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools.
Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or
exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and
could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions

Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or
bodies of water.
6.3. Methods and material for containment and cleaning up

Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible
using non-sparking tools. Place in a closed container approved for transportation by appropriate authorities. Clean up
residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and
follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as
possible in accordance with applicable local/regional/national/international regulations.
SECTION 7: Handling and storage

7.1. Precautions for safe handling
Keep out of reach of children. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe
dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this
product. Wash thoroughly after handling. Avoid release to the environment. Wash contaminated clothing before reuse.
Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.)
7.2. Conditions for safe storage including any incompatibilities

Protect from sunlight. Store at temperatures not exceeding 25C/77F. Keep cool. Keep only in original container. Store
away from acids. Store away from oxidizing agents. Store away from other materials. Keep/store away from clothing
and other combustible materials.
SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Occupational exposure limits

If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient C.A.S. No. Agency Limit type Additional Comments
Dimethyl Phthalate 131-11-3 ACGIH TWA:5 mg/m3
Dimethyl Phthalate 131-11-3 OSHA TWA:5 mg/m3
Methyl Ethyl Ketone Peroxide 1338-23-4 ACGIH CEIL:0.2 ppm
Hydrogen Peroxide 7722-84-1 ACGIH TWA:1 ppm A3: Confirmed animal
carcin.
Hydrogen Peroxide 7722-84-1 OSHA TWA:1.4 mg/m3(1 ppm)
Methyl Ethyl Ketone 78-93-3 ACGIH TWA:200 ppm;STEL:300 ppm
Methyl Ethyl Ketone 78-93-3 OSHA TWA:590 mg/m3(200 ppm)
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
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OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls

Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Full Face Shield
Indirect Vented Goggles
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing.
Gloves made from the following material(s) are recommended: Butyl Rubber
If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then
use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an
exposure assessment. The following protective clothing material(s) are recommended: Apron – Butyl rubber
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part
of a full respiratory protection program. Based on the results of the exposure assessment, select from the following
respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
General Physical Form: Liquid
Odor, Color, Grade: Slight odor. Clear.
Odor threshold No Data Available
pH No Data Available
Melting point No Data Available
Boiling Point 244 ºF
Flash Point > 200 ºF [Test Method:Closed Cup] [Details:No flash to boiling
point.]
Evaporation rate No Data Available
Flammability (solid, gas) Not Applicable
Flammable Limits(LEL) No Data Available
Flammable Limits(UEL) No Data Available
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Vapor Pressure No Data Available

Vapor Density >1
Density 1.1 g/ml
Specific Gravity 1.1 [Ref Std:WATER=1]
Solubility in Water Negligible
Solubility- non-water No Data Available
Partition coefficient: n-octanol/ water No Data Available
Autoignition temperature No Data Available
Decomposition temperature No Data Available
Viscosity No Data Available
Hazardous Air Pollutants 43.1 % weight
Volatile Organic Compounds 39 g/l [Test Method:calculated SCAQMD rule 443.1]
Volatile Organic Compounds 3.5 % weight [Test Method:Tested per ASTM protocol]
Percent volatile 45.0 % weight
VOC Less H2O & Exempt Solvents 39 g/l [Test Method:calculated SCAQMD rule 443.1]
SECTION 10: Stability and reactivity

10.1. Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.
10.2. Chemical stability

Stable.
10.3. Possibility of hazardous reactions

Hazardous polymerization will not occur.
10.4. Conditions to avoid

Light
Sparks and/or flames
Temperatures above the boiling point
10.5. Incompatible materials

Strong oxidizing agents
Alkali and alkaline earth metals
Strong acids
10.6. Hazardous decomposition products

Substance Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
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Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
May be harmful if inhaled.
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and
nose and throat pain.
Skin Contact:
Corrosive (Skin Burns): Signs/symptoms may include localized redness, swelling, itching, intense pain, blistering, ulceration,
and tissue destruction.
Eye Contact:
Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing,
ulcerations, significantly impaired vision or complete loss of vision.
Ingestion:
Harmful if swallowed. Gastrointestinal Corrosion: Signs/symptoms may include severe mouth, throat and abdominal pain;
nausea; vomiting; and diarrhea; blood in the feces and/or vomitus may also be seen.
Additional Health Effects:
Single exposure may cause target organ effects:

Dermal Effects: Signs/symptoms may include changes in skin pigmentation and/or coloration.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Dermal No data available; calculated ATE >5,000 mg/kg
Overall product Inhalation- No data available; calculated ATE20 - 50 mg/l
Vapor(4 hr)
Overall product Ingestion No data available; calculated ATE300 - 2,000 mg/kg
Dimethyl Phthalate Inhalation- Other LC50 > 15.1 mg/l
Dust/Mist
(4 hours)
Dimethyl Phthalate Dermal Rabbit LD50 > 11,940 mg/kg
Dimethyl Phthalate Ingestion Rat LD50 6,800 mg/kg
Methyl Ethyl Ketone Peroxide Dermal Rabbit LD50 4,000 mg/kg
Methyl Ethyl Ketone Peroxide Inhalation- Rat LC50 15.4 mg/l
Vapor (4
hours)
Methyl Ethyl Ketone Peroxide Ingestion Rat LD50 484 mg/kg
Phlegmatizer Dermal Guinea LD50 > 18,800 mg/kg
pig
Phlegmatizer Inhalation- Rat LC50 > 8 mg/l
Dust/Mist
(4 hours)
Phlegmatizer Ingestion Rat LD50 > 3,200 mg/kg
Methyl Ethyl Ketone Dermal Rabbit LD50 > 8,050 mg/kg
Methyl Ethyl Ketone Inhalation- Rat LC50 34.5 mg/l
Vapor (4
hours)
Methyl Ethyl Ketone Ingestion Rat LD50 2,737 mg/kg
Hydrogen Peroxide Dermal Rabbit LD50 > 2,000 mg/kg
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Hydrogen Peroxide Inhalation- Rat LC50 2 mg/l

Dust/Mist
(4 hours)
Hydrogen Peroxide Ingestion Rat LD50 1,193 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Methyl Ethyl Ketone Peroxide Rabbit Corrosive

Methyl Ethyl Ketone Rabbit Minimal irritation
Hydrogen Peroxide Rabbit Corrosive
Serious Eye Damage/Irritation

Name Species Value
Methyl Ethyl Ketone Peroxide Human Corrosive

Methyl Ethyl Ketone Rabbit Severe irritant
Hydrogen Peroxide Rabbit Corrosive
Skin Sensitization
Name Species Value
Methyl Ethyl Ketone Peroxide Human Not classified
Hydrogen Peroxide Guinea Not classified
pig
Respiratory Sensitization
For the component/components, either no data are currently available or the data are not sufficient for classification.
Germ Cell Mutagenicity

Name Route Value
Methyl Ethyl Ketone Peroxide In vivo Not mutagenic

Methyl Ethyl Ketone Peroxide In Vitro Some positive data exist, but the data are not
sufficient for classification
Methyl Ethyl Ketone In Vitro Not mutagenic
Hydrogen Peroxide In vivo Not mutagenic
Hydrogen Peroxide In Vitro Some positive data exist, but the data are not
Carcinogenicity
Methyl Ethyl Ketone Peroxide Not Mouse Some positive data exist, but the data are not
Specified sufficient for classification
Methyl Ethyl Ketone Inhalation Human Not carcinogenic
Hydrogen Peroxide Dermal Multiple Some positive data exist, but the data are not
animal sufficient for classification
species
Hydrogen Peroxide Ingestion Mouse Some positive data exist, but the data are not
Reproductive Toxicity
Reproductive and/or Developmental Effects

Name Route Value Species Test Result Exposure
Duration
Methyl Ethyl Ketone Peroxide Dermal Not classified for female reproduction Rat NOAEL 70 13 weeks
mg/kg/day
Methyl Ethyl Ketone Peroxide Ingestion Not classified for female reproduction Rat NOAEL 75 premating &
mg/kg/day during
gestation
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Methyl Ethyl Ketone Peroxide Ingestion Not classified for male reproduction Rat NOAEL 75 28 days
mg/kg/day
Methyl Ethyl Ketone Peroxide Dermal Not classified for male reproduction Rat NOAEL 70 13 weeks
mg/kg/day
Methyl Ethyl Ketone Peroxide Ingestion Not classified for development Rat NOAEL 50 premating &
mg/kg/day during
gestation
Methyl Ethyl Ketone Inhalation Not classified for development Rat LOAEL 8.8 during
mg/l gestation
Hydrogen Peroxide Ingestion Not classified for female reproduction Rat LOAEL 5 6 months
mg/kg/day
Hydrogen Peroxide Ingestion Not classified for male reproduction Rat LOAEL 5 6 months
mg/kg/day
Hydrogen Peroxide Ingestion Not classified for development Rat LOAEL 5 during
mg/kg/day gestation
Target Organ(s)
Specific Target Organ Toxicity - single exposure

Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Methyl Ethyl Ketone Inhalation respiratory irritation Some positive data exist, but the NOAEL Not
Peroxide data are not sufficient for available
classification
Methyl Ethyl Ketone Inhalation central nervous May cause drowsiness or official NOAEL Not
system depression dizziness classifica available
tion
Methyl Ethyl Ketone Inhalation respiratory irritation Some positive data exist, but the Human NOAEL Not
data are not sufficient for available
classification
Methyl Ethyl Ketone Ingestion central nervous May cause drowsiness or Professio NOAEL Not
system depression dizziness nal available
judgeme
nt
Methyl Ethyl Ketone Ingestion liver Not classified Rat NOAEL Not not applicable
available
Methyl Ethyl Ketone Ingestion kidney and/or Not classified Rat LOAEL not applicable
bladder 1,080 mg/kg
Hydrogen Peroxide Inhalation respiratory irritation May cause respiratory irritation Human NOAEL Not
available
Hydrogen Peroxide Ingestion nervous system Some positive data exist, but the Human LOAEL Not poisoning
data are not sufficient for available and/or abuse
classification
Specific Target Organ Toxicity - repeated exposure

Duration
Methyl Ethyl Ketone Dermal heart | Not classified Rat NOAEL 70 13 weeks
Peroxide hematopoietic mg/kg/day
system | liver |
immune system |
nervous system |
kidney and/or
bladder | respiratory
system
Methyl Ethyl Ketone Ingestion liver | kidney and/or Not classified Rat LOAEL 97 7 weeks
Peroxide bladder mg/kg/day
Methyl Ethyl Ketone Dermal nervous system Not classified Guinea NOAEL Not 31 weeks
pig available
Methyl Ethyl Ketone Inhalation liver | kidney and/or Not classified Rat NOAEL 14.7 90 days
bladder | heart | mg/l
endocrine system |
gastrointestinal tract
| bone, teeth, nails,
and/or hair |
hematopoietic
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system | immune
system | muscles
Methyl Ethyl Ketone Ingestion liver Not classified Rat NOAEL Not 7 days
available
Methyl Ethyl Ketone Ingestion nervous system Not classified Rat NOAEL 173 90 days
mg/kg/day
Hydrogen Peroxide Ingestion hematopoietic Not classified Rat NOEL 0.005 6 months
system mg/kg/day
Hydrogen Peroxide Ingestion liver | kidney and/or Not classified Mouse NOAEL Not 35 weeks
bladder available
Aspiration Hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecological information

Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
SECTION 13: Disposal considerations

13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during
incineration processes. As a disposal alternative, Dispose of completely cured (or polymerized) material in a permitted
industrial waste facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical
substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated
& disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective
regulating authorities to determine the available treatment and disposal facilities.
SECTION 14: Transport Information
For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.
SECTION 15: Regulatory information

15.1. US Federal Regulations
Contact 3M for more information.
EPCRA 311/312 Hazard Classifications:

Physical Hazards
Organic peroxide
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Page 10 of 12
Health Hazards
Acute toxicity
Hazard Not Otherwise Classified (HNOC)
Serious eye damage or eye irritation
Skin Corrosion or Irritation
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
Dimethyl Phthalate 131-11-3 Trade Secret 30 - 60
15.2. State Regulations

15.3. Chemical Inventories

The components of this product are in compliance with the chemical notification requirements of TSCA. All required
components of this product are listed on the active portion of the TSCA Inventory.
15.4. International Regulations

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: Other information

NFPA Hazard Classification
Health: 3 Flammability: 1 Instability: 1 Special Hazards: Oxidizer
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
HMIS Hazard Classification

Health: 3 Flammability: 1 Physical Hazard: 1 Personal Protection: X - See PPE section.
Hazardous Material Identification System (HMIS® IV) hazard ratings are designed to inform employees of chemical hazards
in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use
and are not intended for use in emergency situations. HMIS® IV ratings are to be used with a fully implemented HMIS® IV
program. HMIS® is a registered mark of the American Coatings Association (ACA).

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.3MMAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE.User is responsible for determining whether the3Mproduct is fit for a particular purpose and suitable for
user's method of use or application.Given the variety of factors that can affect the use and application of a3Mproduct, some of
which are uniquely within the user's knowledge and control,it is essential that the user evaluate the3Mproduct to determine
__________________________________________________________________________________________
Page 11 of 12
whether it is fit for a particular purpose and suitable for user's method of use or application.
3Mprovides information in electronic form as a service to its customers. Due to the remote possibility that electronic
transfer may have resulted in errors, omissions or alterations in this information,3Mmakes no representations as to its
completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the
SDS available directly from3M
__________________________________________________________________________________________
Page 12 of 12
3M™ Bondo® Fiberglass Resin, P.N. 401, 401C, 402, 402C, 402ES, 402T, 402Z, 404, 404C, 404Z 06/04/19
Safety Data Sheet

All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

SECTION 1: Identification
1.1. Product identifier
3M™ Bondo® Fiberglass Resin, P.N. 401, 401C, 402, 402C, 402ES, 402T, 402Z, 404, 404C, 404Z
Product Identification Numbers

LB-K100-1567-8, LB-K100-1567-9, LB-K100-1568-0, LB-K100-0410-9, LB-K100-0411-0, LB-K100-0411-1, LB-K100-
0537-7, LB-K100-0537-8, LB-K100-0537-9, LB-K100-0538-0, LB-K100-0538-1, LB-K100-0538-2, 41-0003-6688-4
1.2. Recommended use and restrictions on use
Recommended use
Automotive, Fiberglass Repair Resin
1.3. Supplier’s details

MANUFACTURER: 3M
1.4. Emergency telephone number

1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification

The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200.
This information may be different from the actual product label information for labels regulated by other agencies.
2.1. Hazard classification

Flammable Liquid: Category 3.
Acute Toxicity (inhalation): Category 3.
Serious Eye Damage/Irritation: Category 2B.
Carcinogenicity: Category 2.
Specific Target Organ Toxicity (single exposure): Category 1.
Specific Target Organ Toxicity (single exposure): Category 3.
Specific Target Organ Toxicity (repeated exposure): Category 1.
2.2. Label elements
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Page 1 of 12
Signal word
Danger
Symbols
Flame | Skull and crossbones | Exclamation mark | Health Hazard |
Pictograms
Hazard Statements
Flammable liquid and vapor.
Toxic if inhaled.
Causes eye irritation.
May cause drowsiness or dizziness.
Suspected of causing cancer.
Causes damage to organs:

liver |
sensory organs |
Causes damage to organs through prolonged or repeated exposure:

sensory organs |
May cause damage to organs through prolonged or repeated exposure:

liver |
Precautionary Statements
General:
Keep out of reach of children.
Prevention:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Ground/bond container and receiving equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Keep container tightly closed.
Use explosion-proof electrical/ventilating/lighting equipment.
Do not breathe dust/fume/gas/mist/vapors/spray.
Use only outdoors or in a well-ventilated area.
Wear protective gloves and eye/face protection.
Do not eat, drink or smoke when using this product.
Wash thoroughly after handling.
Response:
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
__________________________________________________________________________________________
Page 2 of 12
If eye irritation persists: Get medical advice/attention.

Call a POISON CENTER or doctor/physician if you feel unwell.
In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to
extinguish.
Storage:
Store in a well-ventilated place. Keep container tightly closed.
Keep cool.
Store locked up.
Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
64% of the mixture consists of ingredients of unknown acute oral toxicity.
SECTION 3: Composition/information on ingredients

Ingredient C.A.S. No. % by Wt
POLYMER 2 Trade Secret* 30 - 60 Trade Secret *
Styrene Monomer 100-42-5 15 - 40 Trade Secret *
POLYMER 1 Trade Secret* 7 - 13 Trade Secret *
*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
SECTION 4: First aid measures

4.1. Description of first aid measures
Inhalation:
Remove person to fresh air. Get medical attention.
Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms
develop, get medical attention.
Eye Contact:
Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue
rinsing. Immediately get medical attention.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures

5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish.
__________________________________________________________________________________________
Page 3 of 12
5.2. Special hazards arising from the substance or mixture

Closed containers exposed to heat from fire may build pressure and explode.
5.3. Special protective actions for fire-fighters

Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and
prevent explosive rupture. Wear full protective clothing, including helmet, self-contained, positive pressure or pressure
demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering
for exposed areas of the head.
SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools.
Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or
exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and
could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions

Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or
bodies of water.
6.3. Methods and material for containment and cleaning up

Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is recommended.
Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic
absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not
remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking
tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an
appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety
precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible in
accordance with applicable local/regional/national/international regulations.
SECTION 7: Handling and storage

7.1. Precautions for safe handling
Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from
heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Take precautionary measures against
static discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat,
drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid
contact with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. Use personal
protective equipment (gloves, respirators, etc.) as required. To minimize the risk of ignition, determine applicable electrical
classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable
vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation
during transfer.
7.2. Conditions for safe storage including any incompatibilities

Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store away from heat. Store away from
acids. Store away from strong bases. Store away from oxidizing agents.
SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Occupational exposure limits
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Page 4 of 12
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient C.A.S. No. Agency Limit type Additional Comments
Styrene Monomer 100-42-5 ACGIH TWA:20 ppm;STEL:40 ppm A4: Not class. as human
carcin
Styrene Monomer 100-42-5 OSHA TWA:100 ppm;CEIL:200 ppm
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls

Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.
Use explosion-proof ventilation equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Fluoroelastomer
Polyvinyl Alcohol (PVA)
Polymer laminate
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part
of a full respiratory protection program. Based on the results of the exposure assessment, select from the following
respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
General Physical Form: Liquid
Specific Physical Form: Paste
Odor, Color, Grade: Pungent organic odor. Light straw color.
Odor threshold No Data Available
pH No Data Available
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Page 5 of 12
Melting point No Data Available

Boiling Point 180 ºF - 415 ºF
Flash Point 88 ºF [Test Method:Closed Cup]
Evaporation rate No Data Available
Flammability (solid, gas) Not Applicable
Flammable Limits(LEL) 1.1 %
Flammable Limits(UEL) No Data Available
Vapor Pressure 3.45 mmHg
Vapor Pressure No Data Available
Vapor Density No Data Available
Density 1.14 g/ml
Specific Gravity 1.14 [Ref Std:WATER=1]
Solubility in Water Negligible
Solubility- non-water No Data Available
Partition coefficient: n-octanol/ water No Data Available
Autoignition temperature No Data Available
Decomposition temperature No Data Available
Viscosity No Data Available
Hazardous Air Pollutants 33.8 lb HAPS/lb solids [Test Method:Calculated]
Volatile Organic Compounds 386 g/l [Test Method:calculated SCAQMD rule 443.1]
Volatile Organic Compounds 33.8 % weight [Test Method:calculated per CARB title 2]
Percent volatile 33.8 % weight
VOC Less H2O & Exempt Solvents 386 g/l [Test Method:calculated SCAQMD rule 443.1]
SECTION 10: Stability and reactivity

10.1. Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.
10.2. Chemical stability

Stable.
10.3. Possibility of hazardous reactions

Hazardous polymerization will not occur.
10.4. Conditions to avoid

Heat
Sparks and/or flames
10.5. Incompatible materials

Strong acids
Strong bases
Strong oxidizing agents
10.6. Hazardous decomposition products

Substance Condition
Hydrocarbons Not Specified
Carbon monoxide Not Specified
Carbon dioxide Not Specified
SECTION 11: Toxicological information
__________________________________________________________________________________________
Page 6 of 12
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
Toxic if inhaled.
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and
nose and throat pain.
May cause additional health effects (see below).
Skin Contact:
May be harmful in contact with skin.
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Ingestion:
May be harmful if swallowed.
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May cause additional health effects (see below).
Additional Health Effects:
Single exposure may cause target organ effects:

Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears.
Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and
jaundice.
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination,
nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.
Prolonged or repeated exposure may cause target organ effects:

Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision.
Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears.
Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and
jaundice.
Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.
Ingredient CAS No. Class Description Regulation
__________________________________________________________________________________________
Page 7 of 12
Styrene Monomer 100-42-5 Grp. 2A: Probable human carc. International Agency for Research on Cancer
Styrene Monomer 100-42-5 Anticipated human carcinogen National Toxicology Program Carcinogens
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
Overall product Dermal No data available; calculated ATE2,000 - 5,000 mg/kg
Overall product Inhalation- No data available; calculated ATE2 - 10 mg/l
Vapor(4 hr)
Overall product Ingestion No data available; calculated ATE2,000 - 5,000 mg/kg
Styrene Monomer Dermal Rat LD50 > 2,000 mg/kg
Styrene Monomer Inhalation- Rat LC50 8.3 mg/l
Vapor (4
hours)
Styrene Monomer Ingestion Rat LD50 5,000 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Styrene Monomer official Mild irritant

classifica
tion
Serious Eye Damage/Irritation

Name Species Value
Styrene Monomer official Moderate irritant

classifica
tion
Skin Sensitization
Name Species Value
Styrene Monomer Guinea Not classified
pig
Respiratory Sensitization
Germ Cell Mutagenicity

Name Route Value
Styrene Monomer In Vitro Some positive data exist, but the data are not
Styrene Monomer In vivo Some positive data exist, but the data are not
Carcinogenicity
Styrene Monomer Ingestion Mouse Carcinogenic
Styrene Monomer Inhalation Human Carcinogenic
and
animal
Reproductive Toxicity
Reproductive and/or Developmental Effects

__________________________________________________________________________________________
Page 8 of 12
Name Route Value Species Test Result Exposure

Duration
Styrene Monomer Ingestion Not classified for female reproduction Rat NOAEL 21 3 generation
mg/kg/day
Styrene Monomer Inhalation Not classified for female reproduction Rat NOAEL 2.1 2 generation
mg/l
Styrene Monomer Inhalation Not classified for male reproduction Rat NOAEL 2.1 2 generation
mg/l
Styrene Monomer Ingestion Not classified for male reproduction Rat NOAEL 400 60 days
mg/kg/day
Styrene Monomer Ingestion Not classified for development Rat NOAEL 400 during
mg/kg/day gestation
Styrene Monomer Inhalation Not classified for development Multiple NOAEL 2.1 during
animal mg/l gestation
species
Target Organ(s)
Specific Target Organ Toxicity - single exposure

Duration
Styrene Monomer Inhalation auditory system Causes damage to organs Multiple LOAEL 4.3 not available
animal mg/l
species
Styrene Monomer Inhalation liver Causes damage to organs Mouse LOAEL 2.1 not available
mg/l
Styrene Monomer Inhalation central nervous May cause drowsiness or Human NOAEL Not occupational
system depression dizziness available exposure
Styrene Monomer Inhalation respiratory irritation Some positive data exist, but the Human NOAEL Not
data are not sufficient for and available
classification animal
Styrene Monomer Inhalation endocrine system Not classified Rat NOAEL Not not available
available
Styrene Monomer Inhalation kidney and/or Not classified Multiple NOAEL 2.1 not available
bladder animal mg/l
species
Specific Target Organ Toxicity - repeated exposure

Duration
Styrene Monomer Inhalation eyes Causes damage to organs through Human NOAEL Not occupational
prolonged or repeated exposure available exposure
Styrene Monomer Inhalation auditory system May cause damage to organs Multiple NOAEL 1.3 not available
though prolonged or repeated animal mg/l
exposure species
Styrene Monomer Inhalation liver May cause damage to organs Mouse LOAEL 0.85 13 weeks
though prolonged or repeated mg/l
exposure
Styrene Monomer Inhalation nervous system Some positive data exist, but the Multiple LOAEL 1.1 not available
data are not sufficient for animal mg/l
classification species
Styrene Monomer Inhalation hematopoietic Not classified Rat NOAEL 0.85 7 days
system mg/l
Styrene Monomer Inhalation endocrine system Not classified Rat NOAEL 0.6 10 days
mg/l
Styrene Monomer Inhalation respiratory system Not classified Multiple LOAEL 0.09 not available
animal mg/l
species
Styrene Monomer Inhalation heart | Not classified Multiple NOAEL 4.3 2 years
gastrointestinal tract animal mg/l
| bone, teeth, nails, species
and/or hair |
muscles | kidney
and/or bladder
Styrene Monomer Ingestion nervous system Some positive data exist, but the Rat LOAEL 500 8 weeks
data are not sufficient for mg/kg/day
__________________________________________________________________________________________
Page 9 of 12
classification
Styrene Monomer Ingestion immune system Some positive data exist, but the Multiple NOAEL Not not available
data are not sufficient for animal available
classification species
Styrene Monomer Ingestion liver | kidney and/or Not classified Rat NOAEL 677 6 months
bladder mg/kg/day
Styrene Monomer Ingestion hematopoietic Not classified Dog NOAEL 600 470 days
system mg/kg/day
Styrene Monomer Ingestion heart | respiratory Not classified Rat NOAEL 35 105 weeks
system mg/kg/day
Aspiration Hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecological information

Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
SECTION 13: Disposal considerations

13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Incinerate uncured product in a permitted waste incineration facility. As a disposal alternative, utilize an acceptable permitted
waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical
substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated
& disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective
regulating authorities to determine the available treatment and disposal facilities.
SECTION 14: Transport Information
For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.
SECTION 15: Regulatory information
15.1. US Federal Regulations

EPCRA 311/312 Hazard Classifications:

Physical Hazards
Flammable (gases, aerosols, liquids, or solids)
Health Hazards
__________________________________________________________________________________________
Page 10 of 12
Acute toxicity
Carcinogenicity
Serious eye damage or eye irritation
Specific target organ toxicity (single or repeated exposure)
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
Styrene Monomer 100-42-5 Trade Secret 15 - 40
15.2. State Regulations

California Proposition 65
Ingredient C.A.S. No. Listing

STYRENE 100-42-5 Carcinogen
15.3. Chemical Inventories

The components of this product are in compliance with the chemical notification requirements of TSCA. All required
components of this product are listed on the active portion of the TSCA Inventory.
15.4. International Regulations

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: Other information

NFPA Hazard Classification
Health: 3 Flammability: 3 Instability: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.3MMAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE.User is responsible for determining whether the3Mproduct is fit for a particular purpose and suitable for
user's method of use or application.Given the variety of factors that can affect the use and application of a3Mproduct, some of
which are uniquely within the user's knowledge and control,it is essential that the user evaluate the3Mproduct to determine
whether it is fit for a particular purpose and suitable for user's method of use or application.
3Mprovides information in electronic form as a service to its customers. Due to the remote possibility that electronic
__________________________________________________________________________________________
Page 11 of 12
transfer may have resulted in errors, omissions or alterations in this information,3Mmakes no representations as to its
completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the
SDS available directly from3M
__________________________________________________________________________________________
Page 12 of 12

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Bondo® Fiberglass Resin Kit, P.N.

Safety Data Sheet

Document Group: 24-2437-2 Version Number: 7.01

60-4550-4826-8, 60-4550-5662-6, 60-4550-5663-4, 60-4550-5664-2, 60-4550-5665-9, 60-4550-5666-7, 60-4550-5667-5, 60-4550-

ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA

Emergency telephone number

3M USA SDSs are available at www.3M.com

Safety Data Sheet

Document Group: 24-2440-6 Version Number: 12.00

Product Identification Numbers

1.2. Recommended use and restrictions on use

1.3. Supplier’s details

1.4. Emergency telephone number

SECTION 2: Hazard identification

2.1. Hazard classification

2.2. Label elements

Flame | Corrosion | Exclamation mark |

2.3. Hazards not otherwise classified

1% of the mixture consists of ingredients of unknown acute inhalation toxicity.

SECTION 3: Composition/information on ingredients

Methyl Ethyl Ketone Peroxide 1338-23-4 15 - 40 Trade Secret *

SECTION 4: First aid measures

SECTION 5: Fire-fighting measures

5.2. Special hazards arising from the substance or mixture

Hazardous Decomposition or By-Products

5.3. Special protective actions for fire-fighters

SECTION 6: Accidental release measures

6.2. Environmental precautions

6.3. Methods and material for containment and cleaning up

SECTION 7: Handling and storage

7.2. Conditions for safe storage including any incompatibilities

SECTION 8: Exposure controls/personal protection

Occupational exposure limits

8.2. Exposure controls

8.2.1. Engineering controls

8.2.2. Personal protective equipment (PPE)

SECTION 9: Physical and chemical properties

Vapor Pressure No Data Available

SECTION 10: Stability and reactivity

10.2. Chemical stability

10.3. Possibility of hazardous reactions

10.4. Conditions to avoid

10.5. Incompatible materials

10.6. Hazardous decomposition products

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Additional Health Effects:

Single exposure may cause target organ effects:

Hydrogen Peroxide Inhalation- Rat LC50 2 mg/l

Methyl Ethyl Ketone Peroxide Rabbit Corrosive

Serious Eye Damage/Irritation

Methyl Ethyl Ketone Peroxide Human Corrosive

Germ Cell Mutagenicity

Methyl Ethyl Ketone Peroxide In vivo Not mutagenic

Reproductive and/or Developmental Effects

Specific Target Organ Toxicity - single exposure

Specific Target Organ Toxicity - repeated exposure