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3M(TM) Scotch-Weld(TM) Epoxy Adhesive DP105 Clear 11/03/22

Safety Data Sheet


Copyright,2022, 3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed
provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither
the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 05-6784-2 Version Number: 13.01


Issue Date: 11/03/22 Supercedes Date: 06/15/20

Product identifier
3M(TM) Scotch-Weld(TM) Epoxy Adhesive DP105 Clear

ID Number(s):

62-3287-1430-8, 62-3287-1431-6, 62-3287-1435-7, 62-3287-1436-5, 62-3287-3530-3, 62-3287-3830-7

7010367387, 7100076770, 7100076786, 7010309884, 7010412196, 7100148733

Recommended use
Two-part adhesive system., Structural adhesive

Supplier's details

MANUFACTURER: 3M
DIVISION: Industrial Adhesives and Tapes Division

ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA


Telephone: 1-888-3M HELPS (1-888-364-3577)

Emergency telephone number


1-800-364-3577 or (651) 737-6501 (24 hours)

This product is a kit or a multipart product which consists of multiple, independently packaged components. A Safety Data
Sheet (SDS), Article Information Sheet (AIS), or Article Information Letter (AIL) for each of these components is included.
Please do not separate the component documents from this cover page. The document numbers for components of this
product are:

05-6783-4, 05-6781-8

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO
WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M.

________________________________________________________________________________________________________
Page 1 of 2
3M(TM) Scotch-Weld(TM) Epoxy Adhesive DP105 Clear 11/03/22

3M USA SDSs are available at www.3M.com

________________________________________________________________________________________________________
Page 2 of 2
3M™ Scotch-Weld™ Epoxy Adhesive DP105 Clear, Part B 06/30/22

Safety Data Sheet


Copyright,2022, 3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 05-6781-8 Version Number: 16.02


Issue Date: 06/30/22 Supercedes Date: 06/15/20

SECTION 1: Identification
1.1. Product identifier
3M™ Scotch-Weld™ Epoxy Adhesive DP105 Clear, Part B

Product Identification Numbers


ID Number UPC ID Number UPC
LA-D100-2964-4

1.2. Recommended use and restrictions on use

Recommended use
Part B of 2-Component Epoxy Adhesive, Structural adhesive

1.3. Supplier’s details


MANUFACTURER: 3M
DIVISION: Industrial Adhesives and Tapes Division
ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA
Telephone: 1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number


1-800-364-3577 or (651) 737-6501 (24 hours)

SECTION 2: Hazard identification


2.1. Hazard classification
Serious Eye Damage/Irritation: Category 2A.
Skin Sensitizer: Category 1.

2.2. Label elements


Signal word
Warning

Symbols
Exclamation mark |

Pictograms

__________________________________________________________________________________________

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3M™ Scotch-Weld™ Epoxy Adhesive DP105 Clear, Part B 06/30/22

Hazard Statements
Causes serious eye irritation.
May cause an allergic skin reaction.

Precautionary Statements

Prevention:
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves and eye/face protection.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.

Response:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF ON SKIN: Wash with plenty of soap and water.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.

Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

SECTION 3: Composition/information on ingredients


Ingredient C.A.S. No. % by Wt
Epoxy Resin 2 30583-72-3 70 - 80 Trade Secret *
Epoxy Resin 1 25068-38-6 20 - 24 Trade Secret *
Organosilane 2530-83-8 0.5 - 1.5 Trade Secret *

*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.

SECTION 4: First aid measures


4.1. Description of first aid measures

Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get
medical attention.

Eye Contact:
Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention.

If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.

__________________________________________________________________________________________

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3M™ Scotch-Weld™ Epoxy Adhesive DP105 Clear, Part B 06/30/22

4.2. Most important symptoms and effects, both acute and delayed

Allergic skin reaction (redness, swelling, blistering, and itching).

4.3. Indication of any immediate medical attention and special treatment required
Not applicable

SECTION 5: Fire-fighting measures


5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.

5.2. Special hazards arising from the substance or mixture


None inherent in this product.

Hazardous Decomposition or By-Products


Substance Condition
Aldehydes During Combustion
Hydrocarbons During Combustion
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Hydrogen Chloride During Combustion
Ketones During Combustion
Toxic Vapor, Gas, Particulate During Combustion

5.3. Special protective actions for fire-fighters


Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus,
bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head.

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation
to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions


Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or
bodies of water.

6.3. Methods and material for containment and cleaning up


Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible.
Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate
solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions
on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible in accordance with
applicable local/regional/national/international regulations.

SECTION 7: Handling and storage


7.1. Precautions for safe handling
Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke
when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the
workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidizing
__________________________________________________________________________________________

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3M™ Scotch-Weld™ Epoxy Adhesive DP105 Clear, Part B 06/30/22

agents (eg. chlorine, chromic acid etc.)

7.2. Conditions for safe storage including any incompatibilities


Store away from acids. Store away from oxidizing agents.

SECTION 8: Exposure controls/personal protection


8.1. Control parameters

Occupational exposure limits


No occupational exposure limit values exist for any of the components listed in Section 3 of this SDS.

8.2. Exposure controls

8.2.1. Engineering controls


Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles

Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Polymer laminate

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part
of a full respiratory protection program. Based on the results of the exposure assessment, select from the following
respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties
Appearance
Physical state Liquid
Color Colorless

Specific Physical Form: Viscous Liquid


Odor Slight Epoxy
Odor threshold No Data Available
pH Not Applicable
Melting point Not Applicable
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3M™ Scotch-Weld™ Epoxy Adhesive DP105 Clear, Part B 06/30/22

Boiling Point >=240 ºF


Flash Point >=240 ºF [Test Method:Pensky-Martens Closed Cup]
Evaporation rate No Data Available
Flammability (solid, gas) Not Applicable
Flammable Limits(LEL) No Data Available
Flammable Limits(UEL) No Data Available
Vapor Pressure <=27 psia [@ 131 ºF]
Vapor Density No Data Available
Density 1.11 g/ml
Specific Gravity 1.11 [Ref Std:WATER=1]
Solubility in Water Nil
Solubility- non-water No Data Available
Partition coefficient: n-octanol/ water No Data Available
Autoignition temperature No Data Available
Decomposition temperature No Data Available
Viscosity 1,000 - 5,000 centipoise
Hazardous Air Pollutants 0 % weight [Test Method:Calculated]
Molecular weight No Data Available
VOC Less H2O & Exempt Solvents < 20 g/l [Test Method:calculated SCAQMD rule 443.1]
[Details:when used as intended with Part A]
VOC Less H2O & Exempt Solvents 1.5 % [Test Method:calculated per CARB title 2] [Details:when
used as intended with Part A]
VOC Less H2O & Exempt Solvents 11 g/l [Test Method:calculated SCAQMD rule 443.1] [Details:as
supplied]

SECTION 10: Stability and reactivity


10.1. Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.

10.2. Chemical stability


Stable.

10.3. Possibility of hazardous reactions


Hazardous polymerization will not occur.

10.4. Conditions to avoid


Heat is generated during cure. Do not cure a mass larger than 50 grams in a confined space to prevent a premature exothermic
reaction with production of intense heat and smoke.

10.5. Incompatible materials


Strong acids
Strong oxidizing agents

10.6. Hazardous decomposition products


Substance Condition
None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information


The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be

__________________________________________________________________________________________

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3M™ Scotch-Weld™ Epoxy Adhesive DP105 Clear, Part B 06/30/22

reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.

Skin Contact:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction
(non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.

Eye Contact:
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.

Ingestion:
May be harmful if swallowed.
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity
Name Route Species Value
Overall product Dermal No data available; calculated ATE >5,000 mg/kg
Overall product Ingestion No data available; calculated ATE >2,000 - =5,000
mg/kg
Epoxy Resin 2 Dermal Rat LD50 > 2,000 mg/kg
Epoxy Resin 2 Ingestion Rat LD50 > 2,000 mg/kg
Epoxy Resin 1 Dermal Rat LD50 > 1,600 mg/kg
Epoxy Resin 1 Ingestion Rat LD50 > 1,000 mg/kg
Organosilane Dermal Rabbit LD50 4,000 mg/kg
Organosilane Inhalation- Rat LC50 > 5.3 mg/l
Dust/Mist
(4 hours)
Organosilane Ingestion Rat LD50 7,010 mg/kg
ATE = acute toxicity estimate

Skin Corrosion/Irritation
Name Species Value

Epoxy Resin 2 Rabbit Minimal irritation


Epoxy Resin 1 Rabbit Mild irritant
Organosilane Rabbit Mild irritant

Serious Eye Damage/Irritation


Name Species Value

Epoxy Resin 2 Rabbit Mild irritant


Epoxy Resin 1 Rabbit Moderate irritant
__________________________________________________________________________________________

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3M™ Scotch-Weld™ Epoxy Adhesive DP105 Clear, Part B 06/30/22

Organosilane Rabbit Corrosive

Skin Sensitization
Name Species Value
Epoxy Resin 2 Mouse Sensitizing
Epoxy Resin 1 Human Sensitizing
and
animal
Organosilane Guinea Not classified
pig

Respiratory Sensitization
Name Species Value

Epoxy Resin 1 Human Not classified

Germ Cell Mutagenicity


Name Route Value

Epoxy Resin 2 In vivo Not mutagenic


Epoxy Resin 2 In Vitro Some positive data exist, but the data are not
sufficient for classification
Epoxy Resin 1 In vivo Not mutagenic
Epoxy Resin 1 In Vitro Some positive data exist, but the data are not
sufficient for classification
Organosilane In vivo Not mutagenic
Organosilane In Vitro Some positive data exist, but the data are not
sufficient for classification

Carcinogenicity
Name Route Species Value
Epoxy Resin 1 Dermal Mouse Some positive data exist, but the data are not
sufficient for classification
Organosilane Dermal Mouse Not carcinogenic

Reproductive Toxicity

Reproductive and/or Developmental Effects


Name Route Value Species Test Result Exposure
Duration
Epoxy Resin 2 Ingestion Not classified for development Rat NOAEL 300 during
mg/kg/day gestation
Epoxy Resin 1 Ingestion Not classified for female reproduction Rat NOAEL 750 2 generation
mg/kg/day
Epoxy Resin 1 Ingestion Not classified for male reproduction Rat NOAEL 750 2 generation
mg/kg/day
Epoxy Resin 1 Dermal Not classified for development Rabbit NOAEL 300 during
mg/kg/day organogenesi
s
Epoxy Resin 1 Ingestion Not classified for development Rat NOAEL 750 2 generation
mg/kg/day
Organosilane Ingestion Not classified for female reproduction Rat NOAEL 1,000 1 generation
mg/kg/day
Organosilane Ingestion Not classified for male reproduction Rat NOAEL 1,000 1 generation
mg/kg/day
Organosilane Ingestion Not classified for development Rat NOAEL 3,000 during
mg/kg/day organogenesi
s

Target Organ(s)

Specific Target Organ Toxicity - single exposure


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3M™ Scotch-Weld™ Epoxy Adhesive DP105 Clear, Part B 06/30/22

For the component/components, either no data are currently available or the data are not sufficient for classification.

Specific Target Organ Toxicity - repeated exposure


Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Epoxy Resin 2 Ingestion kidney and/or Some positive data exist, but the Rat NOAEL 100 90 days
bladder data are not sufficient for mg/kg/day
classification
Epoxy Resin 2 Ingestion heart | endocrine Not classified Rat NOAEL 600 90 days
system | mg/kg/day
gastrointestinal tract
| bone, teeth, nails,
and/or hair |
hematopoietic
system | liver |
immune system |
nervous system |
vascular system |
skin | muscles | eyes
| respiratory system
Epoxy Resin 1 Dermal liver Not classified Rat NOAEL 2 years
1,000
mg/kg/day
Epoxy Resin 1 Dermal nervous system Not classified Rat NOAEL 13 weeks
1,000
mg/kg/day
Epoxy Resin 1 Ingestion auditory system | Not classified Rat NOAEL 28 days
heart | endocrine 1,000
system | mg/kg/day
hematopoietic
system | liver | eyes |
kidney and/or
bladder
Organosilane Ingestion heart | endocrine Not classified Rat NOAEL 28 days
system | bone, teeth, 1,000
nails, and/or hair | mg/kg/day
hematopoietic
system | liver |
immune system |
nervous system |
kidney and/or
bladder | respiratory
system

Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification.

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

SECTION 12: Ecological information


Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.

SECTION 13: Disposal considerations


__________________________________________________________________________________________

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3M™ Scotch-Weld™ Epoxy Adhesive DP105 Clear, Part B 06/30/22

13.1. Disposal methods


Dispose of contents/ container in accordance with the local/regional/national/international regulations.

Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative,
incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel
during incineration processes. Combustion products will include halogen acid (HCl/HF/HBr). Facility must be capable of
handling halogenated materials. Empty drums/barrels/containers used for transporting and handling hazardous chemicals
(chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered,
stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the
respective regulating authorities to determine the available treatment and disposal facilities.

SECTION 14: Transport Information


For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.

SECTION 15: Regulatory information

15.1. US Federal Regulations


Contact 3M for more information.

EPCRA 311/312 Hazard Classifications:


Physical Hazards
Not applicable

Health Hazards
Respiratory or Skin Sensitization
Serious eye damage or eye irritation

15.2. State Regulations


Contact 3M for more information.

15.3. Chemical Inventories


The components of this product are in compliance with the chemical notification requirements of TSCA. All required
components of this product are listed on the active portion of the TSCA Inventory.

Contact 3M for more information.

15.4. International Regulations


Contact 3M for more information.

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: Other information


NFPA Hazard Classification
Health: 2 Flammability: 1 Instability: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
__________________________________________________________________________________________

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3M™ Scotch-Weld™ Epoxy Adhesive DP105 Clear, Part B 06/30/22

Document Group: 05-6781-8 Version Number: 16.02


Issue Date: 06/30/22 Supercedes Date: 06/15/20

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M.

3M USA SDSs are available at www.3M.com

__________________________________________________________________________________________

Page 10 of 10
3M™ Scotch-Weld™ Epoxy Adhesive DP105 Clear, Part A 11/03/22

Safety Data Sheet


Copyright,2022, 3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 05-6783-4 Version Number: 21.01


Issue Date: 11/03/22 Supercedes Date: 06/15/20

SECTION 1: Identification
1.1. Product identifier
3M™ Scotch-Weld™ Epoxy Adhesive DP105 Clear, Part A

1.2. Recommended use and restrictions on use

Recommended use
Part A of 2-Component Epoxy Adhesive, Structural adhesive

1.3. Supplier’s details


MANUFACTURER: 3M
DIVISION: Industrial Adhesives and Tapes Division
ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA
Telephone: 1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number


1-800-364-3577 or (651) 737-6501 (24 hours)

SECTION 2: Hazard identification


2.1. Hazard classification
Acute Toxicity (oral): Category 4.
Skin Sensitizer: Category 1A.

2.2. Label elements


Signal word
Warning

Symbols
Exclamation mark |

Pictograms

Hazard Statements

__________________________________________________________________________________________

Page 1 of 11
3M™ Scotch-Weld™ Epoxy Adhesive DP105 Clear, Part A 11/03/22

Harmful if swallowed.
May cause an allergic skin reaction.

Precautionary Statements

Prevention:
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves.
Do not eat, drink or smoke when using this product.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.

Response:
IF ON SKIN: Wash with plenty of soap and water.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
Rinse mouth.

Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

Supplemental Information:
Persons previously sensitized to amines may develop a cross-sensitization reaction to certain other amines.

10% of the mixture consists of ingredients of unknown acute inhalation toxicity.

SECTION 3: Composition/information on ingredients


Ingredient C.A.S. No. % by Wt
Mercaptan Polymer 72244-98-5 85 - 100 Trade Secret *
Triethylenetetramine, propoxylated 26950-63-0 1 - 10 Trade Secret *
bis(dimethylaminoethyl) ether 3033-62-3 < 5 Trade Secret *
1,8-Diazabicyclo[5.4.0]undec-7-ene 6674-22-2 < 3 Trade Secret *
Triethylenetetramine 112-24-3 < 3 Trade Secret *

*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.

SECTION 4: First aid measures


4.1. Description of first aid measures

Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get
medical attention.

Eye Contact:
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical
attention.

If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
__________________________________________________________________________________________

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3M™ Scotch-Weld™ Epoxy Adhesive DP105 Clear, Part A 11/03/22

4.2. Most important symptoms and effects, both acute and delayed

Allergic skin reaction (redness, swelling, blistering, and itching).

4.3. Indication of any immediate medical attention and special treatment required
Not applicable

SECTION 5: Fire-fighting measures


5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.

5.2. Special hazards arising from the substance or mixture


Closed containers exposed to heat from fire may build pressure and explode.

Hazardous Decomposition or By-Products


Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Oxides of Sulfur During Combustion
Toxic Vapor, Gas, Particulate During Combustion

5.3. Special protective actions for fire-fighters


Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and
prevent explosive rupture. Wear full protective clothing, including helmet, self-contained, positive pressure or pressure
demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering
for exposed areas of the head.

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation
to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions


Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or
bodies of water.

6.3. Methods and material for containment and cleaning up


Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible.
Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate
solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions
on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible in accordance with
applicable local/regional/national/international regulations.

SECTION 7: Handling and storage


7.1. Precautions for safe handling
Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke
when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the
workplace. Avoid release to the environment. Wash contaminated clothing before reuse.
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7.2. Conditions for safe storage including any incompatibilities


No special storage requirements.

SECTION 8: Exposure controls/personal protection


8.1. Control parameters

Occupational exposure limits


If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient C.A.S. No. Agency Limit type Additional Comments
Triethylenetetramine 112-24-3 AIHA TWA:6 mg/m3(1 ppm) SKIN
bis(dimethylaminoethyl) ether 3033-62-3 ACGIH TWA:0.05 ppm;STEL:0.15 Danger of cutaneous
ppm absorption
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling

8.2. Exposure controls

8.2.1. Engineering controls


Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection
None required.

Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Polymer laminate

If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then
use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an
exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part
of a full respiratory protection program. Based on the results of the exposure assessment, select from the following
respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

SECTION 9: Physical and chemical properties


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9.1. Information on basic physical and chemical properties


Appearance
Physical state Liquid
Color Colorless

Odor Mercaptan
Odor threshold No Data Available
pH Not Applicable
Melting point Not Applicable
Boiling Point >=200 ºF
Flash Point >=200 ºF [Test Method:Closed Cup]
Evaporation rate No Data Available
Flammability (solid, gas) Not Applicable
Flammable Limits(LEL) No Data Available
Flammable Limits(UEL) No Data Available
Vapor Pressure <=.1 mmHg
Vapor Density No Data Available
Density 1.15 g/ml
Specific Gravity 1.15 [Ref Std:WATER=1]
Solubility in Water Nil
Solubility- non-water No Data Available
Partition coefficient: n-octanol/ water No Data Available
Autoignition temperature No Data Available
Decomposition temperature No Data Available
Viscosity 8,000 - 16,000 centipoise [@ 73 ºF ]
Hazardous Air Pollutants 0 % weight [Test Method:Calculated]
Molecular weight No Data Available
VOC Less H2O & Exempt Solvents < 20 g/l [Test Method:calculated SCAQMD rule 443.1]
[Details:when used as intended with Part B]
VOC Less H2O & Exempt Solvents 1.5 % [Test Method:calculated SCAQMD rule 443.1]
[Details:when used as intended with Part B]
VOC Less H2O & Exempt Solvents <= 35 g/l [Test Method:calculated SCAQMD rule 443.1]
[Details:as supplied]

SECTION 10: Stability and reactivity


10.1. Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.

10.2. Chemical stability


Stable.

10.3. Possibility of hazardous reactions


Hazardous polymerization will not occur.

10.4. Conditions to avoid


Heat is generated during cure. Do not cure a mass larger than 50 grams in a confined space to prevent a premature exothermic
reaction with production of intense heat and smoke.

10.5. Incompatible materials


None known.

10.6. Hazardous decomposition products


Substance Condition

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None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information


The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.

Skin Contact:
May be harmful in contact with skin.
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin
Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.

Eye Contact:
Contact with the eyes during product use is not expected to result in significant irritation.

Ingestion:
Harmful if swallowed. Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea,
vomiting and diarrhea.

Additional Information:
Persons previously sensitized to amines may develop a cross-sensitization reaction to certain other amines.

Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity
Name Route Species Value
Overall product Dermal No data available; calculated ATE >2,000 - =5,000
mg/kg
Overall product Inhalation- No data available; calculated ATE >50 mg/l
Vapor(4 hr)
Overall product Ingestion No data available; calculated ATE >300 - =2,000
mg/kg
Mercaptan Polymer Dermal Rabbit LD50 > 10,200 mg/kg
Mercaptan Polymer Ingestion Rat LD50 2,600 mg/kg
Triethylenetetramine, propoxylated Dermal LD50 estimated to be 2,000 - 5,000 mg/kg
Triethylenetetramine, propoxylated Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg
bis(dimethylaminoethyl) ether Dermal Rabbit LD50 311 mg/kg
bis(dimethylaminoethyl) ether Inhalation- Rat LC50 > 3.4 mg/l
Dust/Mist
(4 hours)

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bis(dimethylaminoethyl) ether Inhalation- Rat LC50 > 2.2 mg/l


Vapor (4
hours)
bis(dimethylaminoethyl) ether Ingestion Rat LD50 571 mg/kg
Triethylenetetramine Dermal Rabbit LD50 550 mg/kg
Triethylenetetramine Ingestion Rat LD50 2,500 mg/kg
1,8-Diazabicyclo[5.4.0]undec-7-ene Dermal Rabbit LD50 1,233 mg/kg
1,8-Diazabicyclo[5.4.0]undec-7-ene Ingestion Rat LD50 > 300, < 681 mg/kg
ATE = acute toxicity estimate

Skin Corrosion/Irritation
Name Species Value

Overall product Rabbit Mild irritant


Mercaptan Polymer Rabbit No significant irritation
bis(dimethylaminoethyl) ether Rabbit Corrosive
Triethylenetetramine Rabbit Corrosive
1,8-Diazabicyclo[5.4.0]undec-7-ene In vitro Corrosive
data

Serious Eye Damage/Irritation


Name Species Value

Overall product Rabbit Mild irritant


Mercaptan Polymer Rabbit Mild irritant
Triethylenetetramine, propoxylated Rabbit Severe irritant
bis(dimethylaminoethyl) ether Rabbit Corrosive
Triethylenetetramine Rabbit Corrosive
1,8-Diazabicyclo[5.4.0]undec-7-ene similar Corrosive
health
hazards

Skin Sensitization
Name Species Value
Mercaptan Polymer Mouse Sensitizing
Triethylenetetramine, propoxylated Mouse Sensitizing
bis(dimethylaminoethyl) ether Multiple Not classified
animal
species
Triethylenetetramine Guinea Sensitizing
pig

Respiratory Sensitization
For the component/components, either no data are currently available or the data are not sufficient for classification.

Germ Cell Mutagenicity


Name Route Value

Mercaptan Polymer In Vitro Not mutagenic


Triethylenetetramine, propoxylated In Vitro Some positive data exist, but the data are not
sufficient for classification
bis(dimethylaminoethyl) ether In Vitro Not mutagenic
bis(dimethylaminoethyl) ether In vivo Not mutagenic
1,8-Diazabicyclo[5.4.0]undec-7-ene In Vitro Not mutagenic

Carcinogenicity
For the component/components, either no data are currently available or the data are not sufficient for classification.

Reproductive Toxicity

Reproductive and/or Developmental Effects


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Name Route Value Species Test Result Exposure


Duration
Triethylenetetramine, propoxylated Ingestion Not classified for female reproduction Rat NOAEL 750 premating
mg/kg/day into lactation
Triethylenetetramine, propoxylated Ingestion Not classified for male reproduction Rat NOAEL 750 43 days
mg/kg/day
Triethylenetetramine, propoxylated Ingestion Not classified for development Rat NOAEL 750 premating
mg/kg/day into lactation
bis(dimethylaminoethyl) ether Dermal Not classified for development Rabbit NOAEL 12 during
mg/kg/day organogenesi
s
1,8-Diazabicyclo[5.4.0]undec-7-ene Ingestion Not classified for female reproduction Rat NOAEL 150 premating
mg/kg/day into lactation
1,8-Diazabicyclo[5.4.0]undec-7-ene Ingestion Not classified for male reproduction Rat NOAEL 150 29 days
mg/kg/day
1,8-Diazabicyclo[5.4.0]undec-7-ene Ingestion Not classified for development Rat NOAEL 150 during
mg/kg/day gestation

Target Organ(s)

Specific Target Organ Toxicity - single exposure


Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Triethylenetetramine, Inhalation respiratory irritation Some positive data exist, but the similar NOAEL not
propoxylated data are not sufficient for health available
classification hazards
bis(dimethylaminoethyl) Inhalation respiratory irritation May cause respiratory irritation similar NOAEL Not
ether health available
hazards
1,8- Inhalation respiratory irritation Some positive data exist, but the similar NOAEL Not
Diazabicyclo[5.4.0]undec- data are not sufficient for health available
7-ene classification hazards

Specific Target Organ Toxicity - repeated exposure


Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Mercaptan Polymer Ingestion hematopoietic Some positive data exist, but the Rat NOAEL 75 90 days
system data are not sufficient for mg/kg/day
classification
Mercaptan Polymer Ingestion liver Some positive data exist, but the Rat NOAEL 250 90 days
data are not sufficient for mg/kg/day
classification
Mercaptan Polymer Ingestion endocrine system | Not classified Rat NOAEL 90 days
heart | skin | 1,000
immune system | mg/kg/day
nervous system |
eyes | kidney and/or
bladder | respiratory
system | vascular
system
Triethylenetetramine, Ingestion kidney and/or Some positive data exist, but the Rat NOAEL 300 43 days
propoxylated bladder data are not sufficient for mg/kg/day
classification
bis(dimethylaminoethyl) Dermal skin | heart | Not classified Rabbit NOAEL 8 90 days
ether endocrine system | mg/kg/day
gastrointestinal tract
| hematopoietic
system | liver |
immune system |
muscles | nervous
system | kidney
and/or bladder |
respiratory system |
vascular system
bis(dimethylaminoethyl) Inhalation skin | endocrine Not classified Rat NOAEL 14 weeks
ether system | eyes | 0.038 mg/l
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respiratory system |
heart |
hematopoietic
system | liver |
immune system |
nervous system |
kidney and/or
bladder
bis(dimethylaminoethyl) Ingestion gastrointestinal tract Not classified Rat NOAEL 150 7 days
ether | liver | kidney mg/kg/day
and/or bladder |
respiratory system
bis(dimethylaminoethyl) Ingestion heart | endocrine Not classified Rat NOAEL 220 7 days
ether system | mg/kg/day
hematopoietic
system | nervous
system
1,8- Ingestion heart | skin | Not classified Rat NOAEL 120 90 days
Diazabicyclo[5.4.0]undec- endocrine system | mg/kg/day
7-ene gastrointestinal tract
| bone, teeth, nails,
and/or hair |
hematopoietic
system | liver |
immune system |
muscles | nervous
system | eyes |
kidney and/or
bladder | respiratory
system | vascular
system

Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification.

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

SECTION 12: Ecological information


Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.

SECTION 13: Disposal considerations


13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.

Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative,
incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel
during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals
(chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered,
stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the
respective regulating authorities to determine the available treatment and disposal facilities.

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EPA Hazardous Waste Number (RCRA): Not regulated

SECTION 14: Transport Information


For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.

SECTION 15: Regulatory information

15.1. US Federal Regulations


Contact 3M for more information.

EPCRA 311/312 Hazard Classifications:


Physical Hazards
Not applicable

Health Hazards
Acute toxicity
Respiratory or Skin Sensitization

15.2. State Regulations


Contact 3M for more information.

15.3. Chemical Inventories


The components of this product are in compliance with the chemical notification requirements of TSCA. All required
components of this product are listed on the active portion of the TSCA Inventory.

Contact 3M for more information.

15.4. International Regulations


Contact 3M for more information.

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: Other information


NFPA Hazard Classification
Health: 2 Flammability: 1 Instability: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

Document Group: 05-6783-4 Version Number: 21.01


Issue Date: 11/03/22 Supercedes Date: 06/15/20

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to
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determine whether it is fit for a particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M.

3M USA SDSs are available at www.3M.com

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