Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)

SAFETY DATA SHEET

EDGE
1. Identification of the substance/preparation and of the company/undertaking
Product name : EDGE
Material Uses : Industrial applications: Aqueous Heavy Duty cleaner for the marine industry

Manufacturer / Supplier :
Drew Marine Drew Marine
Ashland Specialty Chemical Company Ashland Specialty Chemical Company
Malledijk 20 One Drew Plaza
3208 LA Spijkenisse Boonton, NJ 07005
Netherlands United States
Tel. No.: Tel. No.:
+31 181 457 070 +1 (973) 263 7600
Fax: Fax:
+31 181 625 792 +1 (973) 263 4491
Emergency telephone number
(Germany) : +49 621 60-43333
Fax:
(Germany) : +49 621 60-92664

2. Composition/information on ingredients
Substance/Preparation : Preparation

Chemical name* CAS No. % EC Number Classification

Ethoxylated tert-dodecyl mercaptan 9004-83-5 10-20 Xi; R36/38
R52/53
Dodecylbenzenesulphonic acid (Sodium salt) 25155-30-0 1-5 246-680-4 Xn; R22
Sodium metasilicate 6834-92-0 0.5-1 229-912-9 C; R34
Xi; R37
See Section 16 for the full text of the R Phrases declared above

* Occupational Exposure Limit(s), if available, are listed in Section 8

3. Hazards identification
The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification : Irritant
R36/38- Irritating to eyes and skin.
Effects and symptoms
Ingestion : discomfort (gastrointestinal)
Skin contact : Hazardous in case of skin contact (irritant). Skin inflammation is
characterized by itching, scaling, reddening, or, occasionally, blistering.
Eye Contact : Hazardous in case of eye contact (irritant).
Target Organs : Contains material which causes damage to the following organs: skin, eye,
lens or cornea.

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4. First-aid measures
First-Aid measures
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Obtain medical attention.
Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel.
Never give anything by mouth to an unconscious person. If large quantities of
this material are swallowed, call a physician immediately. Loosen tight clothing
such as a collar, tie, belt or waistband.
Skin contact : In case of contact, immediately flush skin with plenty of water. Cover the
irritated skin with an emollient. Remove contaminated clothing and shoes.
Cold water may be used. Wash clothing before reuse. Clean shoes
thoroughly before reuse. Obtain medical attention.
Eye Contact : Check for and remove any contact lenses. In case of contact, immediately
flush eyes with a copious amount of water for at least 15 minutes. Cold water
may be used. Obtain medical attention.

5. Fire-fighting measures
Extinguishing Media
Suitable : Not applicable.
Hazardous thermal (de)composition : These products are carbon oxides (CO, CO2) and water, sulphur oxides (SO2,
products SO3, etc.), phosphates. Some metallic oxides.
Protection of fire-fighters : Fire fighters should wear self-contained positive pressure breathing apparatus
(SCBA) and full turnout gear.

6. Accidental release measures

Personal Precautions : Splash goggles. Full suit. Boots. Gloves.
Environmental precautions and : Absorb with an inert material and put the spilled material in an appropriate
cleanup methods waste disposal. Neutralize the residue with a dilute solution of acetic acid.
Finish cleaning by spreading water on the contaminated surface and allow to
evacuate through the sanitary system.
Note: See section 8 for personal protective equipment and section 13 for waste disposal.

7. Handling and storage

Handling : Do not breathe gas/fumes/vapour/spray. Wear suitable protective clothing. If
ingested, seek medical advice immediately and show the container or the
label.
Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area.
Packaging materials
Recommended use : Use original container.

8. Exposure controls/personal protection

Engineering measures : Provide exhaust ventilation or other engineering controls to keep the airborne
concentrations of vapours below their respective occupational exposure limits.
Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and
before eating, smoking, using lavatory, and at the end of day.

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Respiratory system : Wear appropriate respirator when ventilation is inadequate.

Skin and body : Lab coat.

Hands : Impervious gloves.
Eyes : Splash goggles.

9. Physical and chemical properties

Physical state : Liquid.
Colour : Yellowish.
Odour : Slight.
Boiling point : 100°C (212°F)
Melting point : 0°C (32°F)
Density : 1.07 g/cm3
Vapour pressure : The highest known value is 2.33 kPa (17.5 mmHg) (at 20°C) (Water).
Evaporation Rate : <1 compared to n-Butyl acetate

Solubility : Soluble in cold water.

pH : 12 to 13 [Basic.]
Flash point : Not applicable.

10. Stability and reactivity

Stability : The product is stable.
Materials to avoid : Slightly reactive to reactive with acids.
Hazardous decomposition products : These products are carbon oxides (CO, CO2) and water, sulphur oxides (SO2,
SO3, etc.), phosphates. Some metallic oxides.

11. Toxicological information

Acute toxicity
Ingredient Name Test Result Route Species
Ethoxylated tert-dodecyl mercaptan LD50 >2000 Oral Rat
mg/kg
Dodecylbenzenesulphonic acid (Sodium LD50 438 mg/kg Oral Rat
salt) LD50 1330 mg/kg Oral Mouse
Sodium metasilicate LD50 1153 mg/kg Oral Rat
LD50 770 mg/kg Oral Mouse
LDLo 250 mg/kg Oral Dog
LDLo 250 mg/kg Oral pig

Chronic toxicity : Repeated or prolonged exposure is not known to aggravate medical condition.
Skin irritation : Hazardous in case of skin contact (irritant).
Eye irritation : Hazardous in case of eye contact (irritant).
Carcinogenic effects : Not available.

Mutagenic Effects : Not available.

Reproduction toxicity : Not available.

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12. Ecological information

Persistence/degradability : Ecological testing has not been conducted on this product.

Additional Information : This material contains phosphorus, which is a controlled element for disposal
in effluents in most parts of North America. Phosphorus is known to greatly
enhance the formation of algae in water streams. In turn, algae will absorb
oxygen from

13. Disposal considerations

Methods of disposal ; Waste of : Waste must be disposed of in accordance with federal, state and local
residues ; Contaminated packaging environmental control regulations.

European Waste Catalogue (EWC) : 20 01 16

Hazardous Waste : The classification of the product may meet the criteria for a hazardous waste.
Additional Information : 20 01 16 detergents

14. Transport information

International transport regulations
Land - Road/Railway
UN number : Not regulated.
Proper shipping name : -
ADR/RID Class : -
Other information : Remarks
Not controlled under ADR (Europe).
Sea
UN number : Not regulated.
Proper shipping name : -
IMDG Class : -
Other information : Remarks
Not controlled under IMDG.

15. Regulatory information

EU Regulations
Hazard symbol(s) :

Irritant
Risk Phrases : R36/38- Irritating to eyes and skin.
Safety Phrases : S23- Do not breathe vapour/spray.
S37/39- Wear suitable gloves and eye/face protection.
S38- In case of insufficient ventilation, wear suitable respiratory equipment.
Product Use : Classification and labelling have been performed according to EU directives
67/548/EEC, 88/379/EEC, including amendments and the intended use.
- Industrial applications, Used by Spraying.

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16. Other information

Full text of R-Phrases with no. : R22- Harmful if swallowed.
appearing in Section 2 - United R34- Causes burns.
Kingdom (UK) R36/38- Irritating to eyes and skin.
R37- Irritating to respiratory system.
R52/53- Harmful to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
Text of classifications appearing in : C - Corrosive
Section 2 - United Kingdom (UK) Xn - Harmful
Xi - Irritant
HISTORY
Date of printing : 10/17/2002.
Date of issue : 10/16/2002.
Version : 3
EDGE® is a registered trademark of Ashland Inc.
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor
any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these
are the only hazards that exist.
Date of issue Version
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