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Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)

SAFETY DATA SHEET


AMERGY 1000
1. Identification of the substance/preparation and of the company/undertaking
Product name : AMERGY 1000
Material Uses : Industrial applications: Fuel additive. Combustion Improver

Manufacturer / Supplier :
Drew Marine Drew Marine
Ashland Specialty Chemical Company Ashland Specialty Chemical Company
Malledijk 20 One Drew Plaza
3208 LA Spijkenisse Boonton, NJ 07005
Netherlands United States
Tel. No.: Tel. No.:
+31 181 457 070 +1 (973) 263 7600
Fax: Fax:
+31 181 625 792 +1 (973) 263 4491
Emergency telephone number
(Germany) : +49 621 60-43333
Fax:
(Germany) : +49 621 60-92664

2. Composition/information on ingredients
Substance/Preparation : Preparation

Chemical name* CAS No. % EC Number Classification


Distillates (petroleum) 68476-30-2 70-80 265-044-7 Carc. Cat. 3; R40
Xn; R65
R66
R52/53
Dipentene (derivative) 68956-56-9 10-20 273-309-3 R10
Xi; R36/38
See Section 16 for the full text of the R Phrases declared above

* Occupational Exposure Limit(s), if available, are listed in Section 8

3. Hazards identification
The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification : Harmful
R10- Flammable.
R36/38- Irritating to eyes and skin.
R40- Limited evidence of a carcinogenic effect.
R52/53- Harmful to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
R65- Harmful: may cause lung damage if swallowed.
Effects and symptoms
Inhalation : Slightly hazardous in case of inhalation.
Skin contact : Hazardous in case of skin contact (irritant). Skin inflammation is
characterized by itching, scaling, reddening, or, occasionally, blistering.
Eye Contact : Hazardous in case of eye contact (irritant).

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AMERGY 1000

Target Organs : Contains material which causes damage to the following organs: central
nervous system (CNS).
Contains material which may cause damage to the following organs: the
nervous system.

4. First-aid measures
First-Aid measures
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Obtain medical attention.
Ingestion : If swallowed, do NOT induce vomiting. Do NOT induce vomiting unless
directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. Aspiration hazard if swallowed- can enter lungs and
cause damage. Loosen tight clothing such as a collar, tie, belt or waistband.
Obtain medical attention. Get medical attention if symptoms appear.
Skin contact : In case of contact, immediately flush skin with plenty of water. Cover the
irritated skin with an emollient. Remove contaminated clothing and shoes.
Wash clothing before reuse. Clean shoes thoroughly before reuse. Obtain
medical attention.
Eye Contact : Check for and remove any contact lenses. In case of contact, immediately
flush eyes with a copious amount of water for at least 15 minutes. Obtain
medical attention.

5. Fire-fighting measures
Extinguishing Media
Suitable : SMALL FIRE: Use dry chemical powder or CO2.
LARGE FIRE: Use water spray or fog. Cool containing vessels with water jet
in order to prevent pressure build-up, autoignition or explosion.
Hazardous thermal (de)composition : These products are carbon oxides (CO, CO2) and water.
products
Protection of fire-fighters : Fire fighters should wear self-contained positive pressure breathing apparatus
(SCBA) and full turnout gear.

6. Accidental release measures


Personal Precautions : Splash goggles. Full suit. Vapour respirator. Boots. Gloves. A self-contained
breathing apparatus should be used to avoid inhalation of the product.
Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.
Environmental precautions and : Keep away from heat. Keep away from sources of ignition. Stop leak if
cleanup methods without risk. Absorb with dry earth, sand or other noncombustible materia
Prevent entry into sewers, basements or confined areas; dike if needed. Call
for assistance on disposal.
Note: See section 8 for personal protective equipment and section 13 for waste disposal.

7. Handling and storage


Handling : Keep locked up. Keep away from heat. Keep away from sources of ignition.
Ground all equipment containing material. Do not breathe
gas/fumes/vapour/spray. Wear suitable protective clothing. If ingested, seek
medical advice immediately and show the container or the label. Keep away
from incompatibles such as oxidizing agents.
Storage : Store in a segregated and approved area. Keep container in a cool,
well-ventilated area. Keep container tightly closed and sealed until ready f
use. Avoid all possible sources of ignition (spark or flame).
Packaging materials
Recommended use : Use original container.

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AMERGY 1000

8. Exposure controls/personal protection


Engineering measures : Provide exhaust ventilation or other engineering controls to keep the airborne
concentrations of vapours below their respective occupational exposure limits.
Ensure that eyewash stations and safety showers are close to the workstation
location.
Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and
before eating, smoking, using lavatory, and at the end of day.
Occupational Exposure Limits

Ingredient Name Occupational Exposure Limits


Distillates (petroleum) EH40 (United Kingdom (UK)). Notes: Supplier's
information
TWA: 500 mg/m3

Respiratory system : Wear appropriate respirator when ventilation is inadequate. Vapour respirator.

Skin and body : Lab coat.


Hands : Impervious gloves.
Eyes : Splash goggles.

9. Physical and chemical properties


Physical state : Liquid.
Colour : Yellow.
Odour : Hydrocarbon.
Boiling point : >148°C (298°F)
Melting point : May start to solidify at <0°C (32°F) based on data for: Distillates (petroleum).
Density : 0.84 g/cm3
Vapour density : >1 (Air = 1)
Vapour pressure : <0.13 kPa (<1 mmHg) (at 20°C)
Evaporation Rate : <1 compared to Ether (anhydrous).

Solubility : Insoluble in cold water.


pH : Not applicable.
Flash point : CLOSED CUP: 55°C (131°F).
Autoignition temperature : The lowest known value is >220°C (428°F) (Distillates (petroleum)).
Lower explosion limit : The greatest known range is LOWER: 0.6% UPPER: 6.5% (Distillates
(petroleum))

10. Stability and reactivity


Stability : The product is stable.
Materials to avoid : Reactive with oxidizing agents.
Hazardous decomposition products : These products are carbon oxides (CO, CO2) and water.

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AMERGY 1000

11. Toxicological information


Acute toxicity
Ingredient Name Test Result Route Species
Distillates (petroleum) LD50 >5000 Oral Rat
mg/kg
LD50 >2000 Dermal Rabbit
mg/kg
LC50 2500 mg/m3 Inhalation Rat
(4 hours)

Chronic toxicity : Repeated exposure to an highly toxic material may produce general
deterioration of health by an accumulation in one or many human organs.
Local effects
Skin irritation : Hazardous in case of skin contact (irritant).
Eye irritation : Hazardous in case of eye contact (irritant).
Specific effects
Carcinogenic effects : Classified 3 (Possible for humans.) by European Union [Distillates
(petroleum)].

Mutagenic Effects : Not available.


Reproduction toxicity : Not available.

12. Ecological information

Persistence/degradability : Not available.

13. Disposal considerations


Methods of disposal ; Waste of : Waste must be disposed of in accordance with federal, state and local
residues ; Contaminated packaging environmental control regulations.

European Waste Catalogue (EWC) : 14 02 02


Hazardous Waste : The classification of the product may meet the criteria for a hazardous waste.
Additional Information : 14 02 02 solvent mixes or organic liquids free of halogenated solvents

14. Transport information


International transport regulations
Land - Road/Railway
UN number : 1268
Proper shipping name : PETROLEUM PRODUCTS, N.O.S.
ADR/RID Class : 3
Packing group : III
ADR/RID label :

Other information : Hazard identification number


30
Sea
UN number : 1268

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AMERGY 1000

Proper shipping name : PETROLEUM PRODUCTS, N.O.S.


IMDG Class : 3
Packing group : III
IMDG label :

Other information : Emergency Schedules (EmS)


3-07

15. Regulatory information


EU Regulations
Hazard symbol(s) :

Harmful
Risk Phrases : R10- Flammable.
R36/38- Irritating to eyes and skin.
R40- Limited evidence of a carcinogenic effect.
R52/53- Harmful to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
R65- Harmful: may cause lung damage if swallowed.
Safety Phrases : S16- Keep away from sources of ignition - No smoking.
S23- Do not breathe vapour.
S37/39- Wear suitable gloves and eye/face protection.
S56- Dispose of this material and its container at hazardous or special waste
collection point.
Contains : Distillates (petroleum) 265-044-7
Product Use : Classification and labelling have been performed according to EU directives
67/548/EEC, 88/379/EEC, including amendments and the intended use.
- Industrial applications.

16. Other information


Full text of R-Phrases with no. : R10- Flammable.
appearing in Section 2 - United R36/38- Irritating to eyes and skin.
Kingdom (UK) R40- Limited evidence of a carcinogenic effect.
R52/53- Harmful to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
R65- Harmful: may cause lung damage if swallowed.
R66- Repeated exposure may cause skin dryness or cracking.
Text of classifications appearing in : Carc. Cat.3 - Carcinogen Category 3
Section 2 - United Kingdom (UK) Xn - Harmful
Xi - Irritant
HISTORY
Date of printing : 10/17/2002.
Date of issue : 10/16/2002.
Version : 3
AMERGY® is a registered trademark of Ashland Inc.
Notice to Reader

Date of issue : 10/16/2002. Page: 5/6


AMERGY 1000

To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor
any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these
are the only hazards that exist.
Date of issue Version
10/16/2002. 3 Page: 6/6

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