Scribd Logo
Upload

Welcome to Scribd!

  • 9 views

    Chapter 12 Gas Real AP Question With Answers

    Uploaded by

    lolitsjoemalone
    The reactant remaining is O2. The number of moles of O2 remaining is 7.55x10-3 moles. The total pressure at 90°C is 868 mmHg. The number of moles of water vapor present at 90°C is 0.0116 moles. The molecular weight of compound X is 88.1 g/mol. The masses of element Q in 1 mole of each compound are: 57.1 g for compound X, 75.9 g for compound Y, and 38.0 g for compound Z. The most probable atomic weight of element Q is 19. The molecular formula of compound Z is C2H2Q2.

    Copyright:

    © All Rights Reserved
    Download as DOC, PDF, TXT or read online from Scribd

    Chapter 12 Gas Real AP Question With Answers

    Uploaded by

    lolitsjoemalone
    9 views4 pages
    The reactant remaining is O2. The number of moles of O2 remaining is 7.55x10-3 moles. The total pressure at 90°C is 868 mmHg. The number of moles of water vapor present at 90°C is 0.0116 moles. The molecular weight of compound X is 88.1 g/mol. The masses of element Q in 1 mole of each compound are: 57.1 g for compound X, 75.9 g for compound Y, and 38.0 g for compound Z. The most probable atomic weight of element Q is 19. The molecular formula of compound Z is C2H2Q2.

    Original Title

    Chapter-12-Gas-Real-AP-Question-with-Answers

    Copyright

    © © All Rights Reserved

    Available Formats

    DOC, PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    The reactant remaining is O2. The number of moles of O2 remaining is 7.55x10-3 moles. The total pressure at 90°C is 868 mmHg. The number of moles of water vapor present at 90°C is 0.0116 moles. The molecular weight of compound X is 88.1 g/mol. The masses of element Q in 1 mole of each compound are: 57.1 g for compound X, 75.9 g for compound Y, and 38.0 g for compound Z. The most probable atomic weight of element Q is 19. The molecular formula of compound Z is C2H2Q2.

    Copyright:

    © All Rights Reserved
    Download as DOC, PDF, TXT or read online from Scribd
    Download as doc, pdf, or txt
    9 views4 pages

    Chapter 12 Gas Real AP Question With Answers

    Uploaded by

    lolitsjoemalone
    The reactant remaining is O2. The number of moles of O2 remaining is 7.55x10-3 moles. The total pressure at 90°C is 868 mmHg. The number of moles of water vapor present at 90°C is 0.0116 moles. The molecular weight of compound X is 88.1 g/mol. The masses of element Q in 1 mole of each compound are: 57.1 g for compound X, 75.9 g for compound Y, and 38.0 g for compound Z. The most probable atomic weight of element Q is 19. The molecular formula of compound Z is C2H2Q2.

    Copyright:

    © All Rights Reserved
    Download as DOC, PDF, TXT or read online from Scribd
    Download as doc, pdf, or txt
    You are on page 1of 4

    Chapter 13

    Real AP CRQ

    1. A mixture of H2(g), O2(g), and 2 milliliters of H2O(l) is present in a 0.500 litre rigid
    container at 25C. The number of moles of H2 and the number of moles of O2 are equal.
    The total pressure is 1,146 millimeters mercury. (The equilibrium vapor pressure of pure water at
    25C is 24 millimeters mercury.)
    The mixture is sparked, and H2 and O2 react until one reactant is completely consumed.

    (a) Identify the reactant remaining and calculate the number of moles of the reactant
    remaining.

    (b) Calculate the total pressure in the container at the conclusion of the reaction if the
    final temperature is 90C. (The equilibrium vapor pressure of water at 90C is 526
    millimeters mercury.)

    (c) Calculate the number of moles of water present as vapor in the container at 90C.
    2. Three volatile compounds X, Y, and Z each contain element Q. The percent by weight
    of element Q in each compound was determined. Some of the data obtained are given
    below.
    Compound Percent by Weight Molecular
    of Element Q Weight
    X 64.8% ?
    Y 73.0% 104.
    Z 59.3% 64.0
    (a) The vapor density of compound X at 27 degrees Celsius and 750. mm Hg was
    determined to be 3.53 grams per liter. Calculate the molecular weight of compound
    X.

    (b) Determine the mass of element Q contained in 1.00 mole of each of the three
    compounds.

    (c) Calculate the most probable value of the atomic weight of element Q.

    (d) Compound Z contains carbon, hydrogen, and element Q. When 1.00 gram of
    compound Z is oxidized and all of the carbon and hydrogen are converted to oxides,
    1.37 grams of CO2 and 0.281 gram of water are produced. Determine the most
    probable molecular formula.
    Answers:

    1.
    (a) 2 H2 + O2  2 H2O
    mol H2 = mol O2 initially, but 2 mole H2 react for every 1 mol of O2, therefore, O2 is left.
    PT = PH2 + PO2 + PH2O
    1146 mm Hg = PH2 + PO2 + 24 mm Hg
    PH2 + PO2 = 1122 mm Hg
    1122 mm Hg / 4 = PO2 left (1/2 of initial PO2 which is 1/2 total)
    PO2 = 280.5 mm Hg
    PV ( 280
    760
    .5 atm )( 0.500L)
    n = = = 7.55× 10−3 m olO2
    R T (0.0821 L_atm _ )( 298K)
    m ol K
    280.5mmHg PO 2
    = ; P = 342mmHg
    (b) 298K 363K O 2
    PT = PO2 + PH2O = (342 + 526)mm Hg = 868 mm Hg
    526
    PV ( atm)(0.500L)
    n= = 760 L_atm = 0.0116 m ol
    RT (0.0821 mol_K )( 363K)
    (c)

    2.
    Answer:
    L_atm
    gRT ( 3.53g )( 0.0821 mol_K )(300K)
    mol.wt. = =
    PV ( 750
    760 atm)(1.00L)
    (a)
    = 88.1 g/mol
    (b) X Y Z
    88.1 g/mol104 64.0
    %Q 64.8 73.0 59.3
    g Q 57.1 75.9 38.0
    (c) ratio 1.5 2 1
    masses must be integral multiples of atomic weight
    therefore, 3 4 2
    which gives an atomic weight of Q = 19
    1 mol CO2 1 mol C
    (d) 1.37 g CO2 × 44.0 g CO × 1 mol CO =
    2 2
    = 0.0311 mol C
    1 mol H2 O 2 mol H
    0.281 g H2O × 18.0 g H O × 1 mol H O =
    2 2
    0.0312 mol H
    1.00 g Z is 59.3% Q = 0.593 g Q
    1 m ol
    0.593 g Q × = 0.0312 m olQ
    19g
    therefore, the empirical formula = CHQ, the smallest whole number ratio of moles.
    formula wt. of CHQ = 32.0, if mol. wt. Z = 64 then the formula of Z = (CHQ)2 or C2H2Q2

    You might also like