Elapol V.355-100
Elapol V.355-100
Elapol V.355-100
9
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1.2. Relevant identified uses of the substance or mixture and uses advised against.
Intended use. polyether-based resin for polyurethane systems
The product is classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent amendments and
supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulation 1907/2006 and subsequent amendments.
Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet.
Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements.
Hazard pictograms: --
Signal words: --
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Hazard statements:
Precautionary statements:
On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%.
3.1. Substances.
3.2. Mixtures.
Contains:
The full wording of hazard (H) phrases is given in section 16 of the sheet.
Identification. Classification 1272/2008
(CLP).
Ethylene glycol
CAS. 107-21-1 5≤x< 7 Acute Tox. 4 H302, STOT RE
2 H373
EC. 203-473-3
INDEX. 603-027-00-1
ETHANEDIOL
CAS. 107-21-1 0,6 ≤ x < 0,7 Acute Tox. 4 H302
EC. 203-473-3
INDEX. 603-027-00-1
etossilato di isononilfenolo
CAS. 37205-87-1 0,5 ≤ x < 0,6 Acute Tox. 4 H302, Acute
Tox. 4 H312, STOT RE 2
H373, Skin Corr. 1B H314,
Aquatic Acute 1 H400 M=1,
Aquatic Chronic 1 H410 M=1
EC. -
INDEX. -
EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 15 minutes, opening the eyelids fully. If problem persists,
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4.2. Most important symptoms and effects, both acute and delayed.
Specific information on symptoms and effects caused by the product are unknown.
For symptoms and effects caused by the contained substances, see chap. 11.
4.3. Indication of any immediate medical attention and special treatment needed.
GENERAL INFORMATION
Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health. Always
wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated water used for
extinction and the remains of the fire according to applicable regulations.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS
Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with self-contained
open circuit positive pressure compressed air breathing apparatus (BS EN 137).
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The product must not penetrate into the sewer system or come into contact with surface water or ground water.
Collect the leaked product into a suitable container. If the product is flammable, use explosion-proof equipment. Evaluate the compatibility of the
container to be used, by checking section 10. Absorb the remainder with inert absorbent material.
Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13.
Any information on personal protection and disposal is given in sections 8 and 13.
Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the environment. Do not
eat, drink or smoke during use.
Keep the product in clearly labelled containers. Keep containers away from any incompatible materials, see section 10 for details.
Regulatory References:
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ETHANEDIOL
Threshold Limit Value.
Type Country TWA/8h STEL/15min
mg/m3 ppm mg/m3 ppm
AGW DEU 26 10 52 20 SKIN.
MAK DEU 26 10 52 20 SKIN.
VLA ESP 52 20 104 40 SKIN.
VLEP FRA 52 20 104 40 SKIN.
WEL GBR 52 20 104 40
VLEP ITA 52 20 104 40 SKIN.
NDS POL 15 20
ESD TUR 52 20 104 40 SKIN.
OEL EU 52 20 104 40 SKIN.
TLV-ACGIH 10
Legend:
(C) = CEILING ; INHAL = Inhalable Fraction ; RESP = Respirable Fraction ; THORA = Thoracic Fraction.
As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is well aired
through effective local aspiration.
HAND PROTECTION
Protect hands with category III work gloves (see standard EN 374).
The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability.
The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on the duration
and type of use.
SKIN PROTECTION
Wear category I professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body with soap
and water after removing protective clothing.
EYE PROTECTION
Wear airtight protective goggles (see standard EN 166).
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RESPIRATORY PROTECTION
If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type B filter
whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases or vapours of
various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required.
Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the threshold
values considered. The protection provided by masks is in any case limited.
If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an emergency, wear
open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing apparatus (in compliance with
standard EN 138). For a correct choice of respiratory protection device, see standard EN 529.
The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure compliance with
environmental standards.
Product residues must not be indiscriminately disposed of with waste water or by dumping in waterways.
Appearance liquid
Colour biancastro
Odour characteristic
Odour threshold. Not available.
pH. Not available.
Melting point / freezing point. Not available.
Initial boiling point. Not available.
Boiling range. Not available.
Flash point. > 60 °C.
Evaporation Rate Not available.
Flammability of solids and gases Not available.
Lower inflammability limit. Not available.
Upper inflammability limit. Not available.
Lower explosive limit. Not available.
Upper explosive limit. Not available.
Vapour pressure. Not available.
Vapour density Not available.
Relative density. 1,030
Solubility Not available.
Partition coefficient: n-octanol/water Not available.
Auto-ignition temperature. Not available.
Decomposition temperature. Not available.
Viscosity Not available.
Explosive properties Not available.
Oxidising properties Not available.
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10.1. Reactivity.
There are no particular risks of reaction with other substances in normal conditions of use.
ETHANEDIOL
In the air absorbs moisture.Decomposes at temperatures above 200°C/392°F.
ETHANEDIOL
Risk of explosion on contact with: perchloric acid.May react dangerously with: chlorosulphuric acid,sodium hydroxide,sulphuric acid,phosphorus
pentasulphide,chromium (III) oxide,chromyl chloride,potassium perchlorate,potassium dichromate,sodium peroxide,aluminium.Forms explosive mixtures
with: air.
None in particular. However the usual precautions used for chemical products should be respected.
ETHANEDIOL
Avoid exposure to: sources of heat,naked flames.
ETHANEDIOL
May develop: hydroxyacetaldehyde,glyoxal,acetaldehyde,methane,carbon monoxide,hydrogen.
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ETHANEDIOLFollowing ingestion it initially stimulates the CNS; later on depression results. Renal damage with anuria and uremia may occur. Symptoms
of over exposure are: vomiting, somnolence, difficulty in breathing, convulsions. The lethal dose in man is approximately 1,4 l/kg. The way of entry is
inhalation and ingestion.
ACUTE TOXICITY.
ETHANEDIOL
LD50 (Oral).> 2000 mg/kg Rat
LD50 (Dermal).9530 mg/kg Rabbit
This product is dangerous for the environment and the aquatic organisms. In the long term, it have negative effects on aquatic environment.
12.1. Toxicity.
Information not available.
ETHANEDIOL
Solubility in water. 1000 - 10000 mg/l
Rapidly biodegradable.
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ETHANEDIOL
Partition coefficient: n- -1,36
octanol/water.
On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%.
Reuse, when possible. Neat product residues should be considered special non-hazardous waste.
Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations.
CONTAMINATED PACKAGING
Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.
The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail (RID), of
the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations.
14.1. UN number.
Not applicable.
Not applicable.
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Not applicable.
Not applicable.
Not applicable.
Not applicable.
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code.
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture.
Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006.
Product.
Point. 3
On the basis of available data, the product does not contain any SVHC in percentage greater than 0,1%.
None.
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- (NONYLPHENOL ETHOXYLATES)
None.
None.
Healthcare controls.
No chemical safety assessment has been processed for the mixture and the substances it contains.
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LEGEND:
- ADR: European Agreement concerning the carriage of Dangerous goods by Road
- CAS NUMBER: Chemical Abstract Service Number
- CE50: Effective concentration (required to induce a 50% effect)
- CE NUMBER: Identifier in ESIS (European archive of existing substances)
- CLP: EC Regulation 1272/2008
- DNEL: Derived No Effect Level
- EmS: Emergency Schedule
- GHS: Globally Harmonized System of classification and labeling of chemicals
- IATA DGR: International Air Transport Association Dangerous Goods Regulation
- IC50: Immobilization Concentration 50%
- IMDG: International Maritime Code for dangerous goods
- IMO: International Maritime Organization
- INDEX NUMBER: Identifier in Annex VI of CLP
- LC50: Lethal Concentration 50%
- LD50: Lethal dose 50%
- OEL: Occupational Exposure Level
- PBT: Persistent bioaccumulative and toxic as REACH Regulation
- PEC: Predicted environmental Concentration
- PEL: Predicted exposure level
- PNEC: Predicted no effect concentration
- REACH: EC Regulation 1907/2006
- RID: Regulation concerning the international transport of dangerous goods by train
- TLV: Threshold Limit Value
- TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure.
- TWA STEL: Short-term exposure limit
- TWA: Time-weighted average exposure limit
- VOC: Volatile organic Compounds
- vPvB: Very Persistent and very Bioaccumulative as for REACH Regulation
- WGK: Water hazard classes (German).
GENERAL BIBLIOGRAPHY
1. Regulation (EU) 1907/2006 (REACH) of the European Parliament
2. Regulation (EU) 1272/2008 (CLP) of the European Parliament
3. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament
4. Regulation (EU) 2015/830 of the European Parliament
5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament
6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament
7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament
8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament
9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament
- The Merck Index. - 10th Edition
- Handling Chemical Safety
- INRS - Fiche Toxicologique (toxicological sheet)
- Patty - Industrial Hygiene and Toxicology
- N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition
- ECHA website
Note for users:
The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the suitability and
thoroughness of provided information according to each specific use of the product.
This document must not be regarded as a guarantee on any specific product property.
The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health and safety
laws and regulations. The producer is relieved from any liability arising from improper uses.
Provide appointed staff with adequate training on how to use chemical products.
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01 / 02 / 03 / 04 / 06 / 08 / 09 / 10 / 11 / 14 / 15 / 16.