Cumene

Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
Date of issue: 11/19/2019 Version: 1.0

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Product form : Substance
Substance name : Cumene
Chemical name : cumene
EC Index-No. : 601-024-00-X
EC-No. : 202-704-5
CAS-No. : 98-82-8
Product code : 90026779
Product group : Raw material
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Main use category : Laboratory use,Industrial use,Professional use
Industrial/Professional use spec : For professional use only
Use of the substance/mixture : For analytical purposes
Scientific research and development
Not for human consumption or veterinary purposes.

1.2.2. Uses advised against

No additional information available
1.3. Details of the supplier of the safety data sheet
Supplier
Scafell Organics
Molekula Ltd
Lingfield Way
Darlington - England
T +44 (0) 1949 823777 / +44 (0) 7590 545705
info@molekula.com / kbowen@molekula.com - www.molekula.com
1.4. Emergency telephone number
Emergency number : +44 (0) 7590 545705

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable liquids, Category 3 H226
Aspiration hazard, Category 1 H304
Specific target organ toxicity — Single exposure, Category 3, H335
Respiratory tract irritation
Hazardous to the aquatic environment — Chronic Hazard, Category 2 H411
Full text of H statements : see section 16

Adverse physicochemical, human health and environmental effects

No additional information available
2.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]Extra labelling to displayExtra classification(s) to display
Hazard pictograms (CLP) :

GHS02 GHS08 GHS07 GHS09

Signal word (CLP) : Danger
Hazard statements (CLP) : H226 - Flammable liquid and vapour.
H304 - May be fatal if swallowed and enters airways.
H335 - May cause respiratory irritation.
H411 - Toxic to aquatic life with long lasting effects.

EN (English) 1/8
Cumene
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
Precautionary statements (CLP) : P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources.
No smoking.
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.
P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor.
P331 - Do NOT induce vomiting.
2.3. Other hazards
This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

SECTION 3: Composition/information on ingredients

3.1. Substances
Name Product identifier %
Cumene (CAS-No.) 98-82-8 100
(EC-No.) 202-704-5
(EC Index-No.) 601-024-00-X
Full text of H-statements: see section 16
3.2. Mixtures
Not applicable

SECTION 4: First aid measures

4.1. Description of first aid measures
First-aid measures general : If possible show this sheet, if not available show packaging or label. Never give anything by
mouth to an unconscious person. Do not leave affected person unattended.
First-aid measures after inhalation : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable
for breathing. Give oxygen or artificial respiration if necessary. If breathing difficulties
persist : Get medical advice/attention.
First-aid measures after skin contact : After contact with skin, take off immediately all contaminated clothing, and wash
immediately with plenty of water. Do not remove clothing if it sticks to the skin. If irritation
persists, consult a doctor.
First-aid measures after eye contact : Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth out with water. Do not induce vomiting. Get medical advice/attention.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects after inhalation : Aspiration of the product into the lungs may cause very serious pneumonia. May cause
shortness of breath, tightness of the chest, a sore throat and cough.
Symptoms/effects after skin contact : May cause moderate irritation. Redness, pain.
Symptoms/effects after eye contact : May cause slight irritation. redness, itching, tears.
Symptoms/effects after ingestion : May be fatal if swallowed and enters airways. Symptoms similar to those listed under
inhalation.
4.3. Indication of any immediate medical attention and special treatment needed
Get immediate medical advice/attention.

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : Dry powder. Sand. Water spray. Carbon dioxide. Foam.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapour-air mixture.
Hazardous decomposition products in case of fire : Carbon oxides (CO, CO2).
5.3. Advice for firefighters
Precautionary measures fire : Keep container tightly closed and away from heat, sparks and flame. Keep away from
combustible materials.
Firefighting instructions : Exercise caution when fighting any chemical fire. Use water spray or fog for cooling
exposed containers. Prevent fire fighting water from entering the environment.
Protection during firefighting : Wear recommended personal protective equipment. Use self-contained breathing
apparatus and chemically protective clothing.
Other information : Warn all persons of toxic hazard.

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Cumene
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
General measures : Do not handle until all safety precautions have been read and understood. Ventilate the
area thoroughly, especially low lying areas (basements, workpits etc). Keep away from
combustible materials.

6.1.1. For non-emergency personnel

Protective equipment : Wear recommended personal protective equipment.
Emergency procedures : Evacuate unnecessary personnel. Mark out the contaminated area with signs and prevent
access to unauthorized personnel. Do not touch or walk on the spilled product. Avoid
contact with skin, eyes and clothing.
Measures in case of dust release : Shelter from vapours by keeping upwind. Ventilate the area thoroughly, especially low lying
areas (basements, workpits etc). Special attention should be given to low areas/pits where
flammable vapours can accumulate.

6.1.2. For emergency responders

Protective equipment : Do not attempt to take action without suitable protective equipment. Use self-contained
breathing apparatus and chemically protective clothing.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Collect spillage. Contain the spilled material by bunding.
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible.
Try to stop release if without risk.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling : Avoid formation of vapours. Avoid contact with skin, eyes and clothing. Do not handle until
all safety precautions have been read and understood. Ensure that there is a suitable
ventilation system. Do not handle in a confined space.
Hygiene measures : Take off immediately all contaminated clothing and wash it before reuse. Contaminated
work clothing should not be allowed out of the workplace. Wash hands and other exposed
areas with mild soap and water before eating, drinking or smoking and when leaving work.
Do not eat, drink or smoke when using this product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Ensure adequate ventilation, especially in confined areas. Proper grounding procedures to
avoid static electricity should be followed.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Heat
sources, Direct sunlight. Keep container closed when not in use. Air sensitive. Store
contents under inert gas.
Incompatible products : Strong oxidizing agents.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources. open flames. sparks. Air contact.
Heat and ignition sources : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
Storage area : Keep away from combustible materials. Store below 20 °C. Store in a dry place. Store in a
closed container.
7.3. Specific end use(s)
For analytical purposes. Scientific research and development. Not for human consumption or veterinary purposes.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Cumene (98-82-8)
United Kingdom Local name Cumene
United Kingdom WEL TWA (mg/m³) 125 mg/m³
United Kingdom WEL TWA (ppm) 25 ppm
United Kingdom WEL STEL (mg/m³) 250 mg/m³
United Kingdom WEL STEL (ppm) 50 ppm
United Kingdom Remark (WEL) Sk (Can be absorbed through the skin. The assigned
substances are those for which there are concerns that
dermal absorption will lead to systemic toxicity)

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Cumene
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

Cumene (98-82-8)
United Kingdom Regulatory reference EH40/2005 (Third edition, 2018). HSE
8.2. Exposure controls
Appropriate engineering controls:
Handle in accordance with good industrial hygiene and safety procedures. Floors should be impervious, resistant to liquids and easy to clean.
Personal protective equipment:
Avoid all unnecessary exposure.

Materials for protective clothing:

Wear suitable protective clothing, gloves and eye/face protection

Hand protection:
The protective gloves to be used must comply with the specifications of the regulation 2016/425 and the resultant standard EN 374

Type Material Permeation Thickness (mm) Penetration Standard

Disposable gloves Fluoroelastomer 6 (> 480 minutes) 0.7 EN 374
(FKM)

Eye protection:
Emergency eye wash fountains should be available in the immediate vicinity of any potential exposure. Use eye protection according to EN 166,
designed to protect against liquid splashes.

Type Use Characteristics Standard

Safety goggles, Face shield Droplet, vapours tightly fitting safety goggles, With EN 166
side shields

Skin and body protection:

Emergency safety showers should be available in the immediate vicinity of any potential exposure. Keep suitable chemically resistant protective
clothing readily available for emergency use

Type Standard
Total impervious protective suits, gloves, and boots must be worn to EN 14605
prevent any contact with the product, Flame retardant antistatic
protective clothing

Respiratory protection:
Keep self contained breathing apparatus readily available for emergency use. Where exposure through inhalation may occur from use, respiratory
protection equipment is recommended

Device Filter type Condition Standard

Air-Purifying Respirator (APR), ABEK Moist condition, Mist formation, EN 14387
reusable Protection for Liquid particles,
Vapour protection
Other information:
Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Clear.
Molecular mass : 120.19 g/mol
Colour : Colourless.
Odour : No data available.
Odour threshold : No data available
pH : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : -96 °C lit.
Freezing point : No data available
Boiling point : 152 - 154 °C lit.
Flash point : 31 °C closed cup.
Auto-ignition temperature : No data available

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Cumene
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
Decomposition temperature : No data available
Flammability (solid, gas) : Flammable
Vapour pressure : 10.7 hPa at 20°C
Relative vapour density at 20 °C : No data available
Relative density : 0.864 g/mL
Solubility : No data available
Log Pow : 3.55
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits :
Lower explosive limit (LEL) : 0.9 vol %
Upper explosive limit (UEL) : 6.5 vol %
9.2. Other information
No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity
Flammable liquid and vapour.
10.2. Chemical stability
Flammable liquid and vapour. May form flammable/explosive vapour-air mixture.
10.3. Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.
10.4. Conditions to avoid
Protect from sunlight. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Air contact.
10.5. Incompatible materials
Strong oxidizers.
10.6. Hazardous decomposition products
No hazardous decomposition products known at room temperature. Thermal decomposition generates : Carbon oxides (CO, CO2).

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified

Cumene (98-82-8)
LD50 oral rat 2260 mg/kg
Skin corrosion/irritation : Not classified
Additional information : Based on available data, the classification criteria are not met
Serious eye damage/irritation : Not classified
Additional information : Based on available data, the classification criteria are not met
Respiratory or skin sensitisation : Not classified
Additional information : Based on available data, the classification criteria are not met
Germ cell mutagenicity : Not classified
Additional information : Based on available data, the classification criteria are not met
Carcinogenicity : Not classified
Additional information : Based on available data, the classification criteria are not met

Reproductive toxicity : Not classified

Additional information : Based on available data, the classification criteria are not met
STOT-single exposure : May cause respiratory irritation.
Additional information : Based on available data, the classification criteria are not met
STOT-repeated exposure : Not classified
Additional information : Based on available data, the classification criteria are not met
Aspiration hazard : May be fatal if swallowed and enters airways.
Additional information : Based on available data, the classification criteria are not met
Potential adverse human health effects and : Based on available data, the classification criteria are not met.
symptoms

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Cumene
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

SECTION 12: Ecological information

12.1. Toxicity
Hazardous to the aquatic environment, short-term : Not classified
(acute)
Hazardous to the aquatic environment, long-term : Toxic to aquatic life with long lasting effects.
(chronic)

Cumene (98-82-8)
LC50 fish 1 4.8 mg/l Oncorhynchus mykiss (rainbow trout) 96hr
EC50 Daphnia 1 2.14 mg/l Daphnia (water flea) 48hr
EC50 72h algae (1) 2.6 mg/l Pseudokirchneriella subcapitata (green algae) 72hr
12.2. Persistence and degradability
Cumene (98-82-8)
Persistence and degradability No data available.
12.3. Bioaccumulative potential
Cumene (98-82-8)
Log Pow 3.55
Bioaccumulative potential No data available.
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
Cumene (98-82-8)
This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII
12.6. Other adverse effects
Additional information : Avoid release to the environment.

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations.
Additional information : Handle empty containers with care because residual vapours are flammable.
Ecology - waste materials : Avoid release to the environment.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
ADR IMDG IATA ADN RID

14.1. UN number
1918 1918 1918 1918 1918

14.2. UN proper shipping name

ISOPROPYLBENZENE ISOPROPYLBENZENE Isopropylbenzene ISOPROPYLBENZENE ISOPROPYLBENZENE
Transport document description
UN 1918 UN 1918 UN 1918 Isopropylbenzene UN 1918 UN 1918
ISOPROPYLBENZENE ISOPROPYLBENZENE (Cumene), 3, III, ISOPROPYLBENZENE ISOPROPYLBENZENE
(Cumene), 3, III, (D/E), (Cumene), 3, III, MARINE ENVIRONMENTALLY (Cumene), 3, III, (Cumene), 3, III,
ENVIRONMENTALLY POLLUTANT/ENVIRONME HAZARDOUS ENVIRONMENTALLY ENVIRONMENTALLY
HAZARDOUS NTALLY HAZARDOUS HAZARDOUS HAZARDOUS
(31°C c.c.)

14.3. Transport hazard class(es)

3 3 3 3 3

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Cumene
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

14.4. Packing group

III III III III III

14.5. Environmental hazards

Dangerous for the Dangerous for the Dangerous for the Dangerous for the Dangerous for the
environment : Yes environment : Yes environment : Yes environment : Yes environment : Yes
Marine pollutant : Yes
No supplementary information available
14.6. Special precautions for user
Overland transport
Classification code (ADR) : F1
Limited quantities (ADR) : 5l
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P001, IBC03, LP01, R001
Mixed packing provisions (ADR) : MP19
Portable tank and bulk container instructions : T2
(ADR)
Portable tank and bulk container special provisions : TP1
(ADR)
Tank code (ADR) : LGBF
Vehicle for tank carriage : FL
Transport category (ADR) :3
Special provisions for carriage - Packages (ADR) : V12
Special provisions for carriage - Operation (ADR) : S2
Hazard identification number (Kemler No.) : 30
Orange plates :

Tunnel restriction code (ADR) : D/E

EAC code : 3Y
Transport by sea
Packing instructions (IMDG) : P001, LP01
IBC packing instructions (IMDG) : IBC03
Tank instructions (IMDG) : T2
Tank special provisions (IMDG) : TP1
EmS-No. (Fire) : F-E
EmS-No. (Spillage) : S-E
Stowage category (IMDG) :A
Flash point (IMDG) : 31°C c.c.
Properties and observations (IMDG) : Colourless liquid with a chloroform-like odour. Flashpoint: 31°C c.c. Explosive limits: 0.9%
to 6.5% Immiscible with water.
Air transport
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y344
PCA limited quantity max net quantity (IATA) : 10L
PCA packing instructions (IATA) : 355
PCA max net quantity (IATA) : 60L
CAO packing instructions (IATA) : 366
CAO max net quantity (IATA) : 220L
ERG code (IATA) : 3L
Inland waterway transport
Classification code (ADN) : F1
Limited quantities (ADN) :5L
Excepted quantities (ADN) : E1
Carriage permitted (ADN) :T
Equipment required (ADN) : PP, EX, A
Ventilation (ADN) : VE01

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Cumene
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
Number of blue cones/lights (ADN) :0
Rail transport
Classification code (RID) : F1
Excepted quantities (RID) : E1
Packing instructions (RID) : P001, IBC03, LP01, R001
Mixed packing provisions (RID) : MP19
Portable tank and bulk container instructions (RID) : T2
Portable tank and bulk container special provisions : TP1
(RID)
Tank codes for RID tanks (RID) : LGBF
Transport category (RID) :3
Special provisions for carriage – Packages (RID) : W12
Colis express (express parcels) (RID) : CE4
Hazard identification number (RID) : 30
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations

No REACH Annex XVII restrictions

Cumene is not on the REACH Candidate List
Directive 2012/18/EU (SEVESO III)

15.1.2. National regulations

No additional information available
15.2. Chemical safety assessment
No chemical safety assessment has been carried out for the substance or the mixture by the supplier

SECTION 16: Other information

Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16
December 2008 on classification, labelling and packaging of substances and mixtures, amending and
repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
Other information : None.

Full text of H- and EUH-statements:

Aquatic Chronic 2 Hazardous to the aquatic environment — Chronic Hazard, Category 2
Asp. Tox. 1 Aspiration hazard, Category 1
Flam. Liq. 3 Flammable liquids, Category 3
STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation
H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H335 May cause respiratory irritation.
H411 Toxic to aquatic life with long lasting effects.

SDS EU (REACH Annex II)

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental
requirements only. It should not therefore be construed as guaranteeing any specific property of the product.

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